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In studying H2S emissions, it is desirable to have an analytical technique which is rapid, continuous, accurate and easy to use in a laboratory or vehicle exhaust environment. Typically, H2S has been measured using the EPA impinger method with collection times on the order of 1 to 2 minutes. Other techniques have been developed with significantly shorter response times. However, it has been shown that the major release of H2S occurs in less than 20 seconds after a vehicle changes from rich to lean operation. Therefore, it is highly desirable to have an H2S analytical technique with a response time of less than 10 seconds. In this paper, the benefits of use of a chemical ionization mass spectrometer (CIMS) to continuously monitor H2S and SO2, emissions are reported. Using the CIMS technique, the effects of several operating parameters on the release of H2S and SO2 from automotive catalysts were studied.

For the BMW V8 engine, a new LEV/EU3 emission concept has been developed by improvements to the previous engine management and secondary air supply and a complete new exhaust system. Beside the emission limits, also high engine output targets and high operating reliability were targeted. In addition the new exhaust system had to meet low cost targets. Based on these requirements an exhaust concept with separate pre catalyst and main catalyst was chosen. To reduce the heat mass and to optimize the pressure drop, 4.3mil/400cpsi thin wall ceramic substrates were used for the pre and main catalyst.

To meet LEV and EU Stage III emission requirements, it is necessary for new catalytic converters to be designed which exceed light-off temperature as quickly as possible. The technical solutions are secondary air injection, active heating systems such as the electrically heated catalytic converter, and the close coupled catalytic converter. Engine control functions are extensively used to heat the converter and will to play a significant role in the future. The concept of relocating the converter to a position close to the engine in an existing vehicle involves new conflicts. Examples include the space requirements, the thermal resistance of the catalytic coating and high temperature loads in the engine compartment.

For the measurement of exhaust emissions, Constant Volume Sampling (CVS) technology is recommended by legislation and has proven its practical capability in the past. However, the introduction of new low emission standards has raised questions regarding the accuracy and variability of the CVS system when measuring very low emission levels. This paper will show that CVS has the potential to achieve sufficient precision for certification of SULEV concepts. Thus, there is no need for the introduction of new test methods involving high cost. An analysis of the CVS basic equations indicates the importance of the Dilution Factor (DF) for calculating true mass emissions. A test series will demonstrate that, by adjusting the dilution and using state of the art analyzers, the consistency of exhaust results is comparable with those of LEV concepts, measured with conventional CVS systems and former standard analyzers.

Sensing and acting elements to guarantee the locking functions of seat belt retractors can emit noise when the retractor is subjected to externally applied vibrations. For these elements to function correctly, stiffness, inertia and friction needs to be in tune, leading to a complex motion resistance behavior, which makes it delicate to test for vibration induced noise. Requirements for a noise test are simplicity, robustness, repeatability, and independence of laboratory and test equipment. This paper reports on joint development activities for an alternative test procedure, involving three test laboratories with different equipment. In vehicle observation on parcel shelf mounted retractors, commercially available test equipment, and recent results from multi-axial component tests [1], set the frame for this work. Robustness and reliability of test results is being analyzed by means of sensitivity studies on several test parameters.

In a joint research project between industrial companies and a number of research institutes, nitrogen oxide conversion in oxygen containing exhaust gas has been investigated according to the following procedure Basic investigations of elementary steps of the chemical reaction Production and prescreening of different catalytic material on laboratory scale Application oriented screening of industrial catalyst material Catalyst testing on a lean bum gasoline engine, passenger car diesel engines (swirl chamber and DI) and on a DI truck engine Although a number of solid body structures show nitrogen oxide reduction by hydrocarbons, only noble metal containing catalysts and transition metal exchanged zeolites gave catalytic efficiencies of industrial relevance. A maximum of 25 % NOx reduction was found in the European driving cycle for passenger cars, about 40 % for truck engines in the respective European test.

BMW - the driving force for progress As we approach the new millenium, to ensure the continuation of the progress into the future, BMW uses leading edge approaches in its materials research and processing. Overview production sites all over the world - Plant Dingolfing Quality requirements for automobile painting The complex and wide-ranging demands that the outer skin of an automobile has to meet offered us the chance to advance with a technological leap from liquid clear coat to the potentials of powder clear coat. The new clear coat technology The clear coat creates the ultimate gloss effect - and powder-based clear coat makes the surface of the car even more brilliant. To achieve this effect the body is covered by microscopically small paint particles. A pioneer achievement A lot of challenges in both material development and systems-engineering had to be made. The automotive world was watching, many experts said it could not be successfully used as an OEM clear coat.

Current regulatory developments aim for stricter emission limits, increased environmental protection and purification of air on a local and global scale. In order to find solutions for a cleaner combustion process, it is necessary to identify the critical components and parameters responsible for the formation of emissions. This work provides an evaluation process for particle formation during combustion of a modern direct injection engine, which can help to create new aftertreatment techniques, such as a gasoline particle filter (GPF) system, that are fit for purpose. With the advent of “real driving emission” (RDE) regulations, which include market fuels for the particulate number testing procedure, the chemical composition and overall quality of the fuel cannot be neglected in order to yield a comparable emission test within the EU and worldwide.

For the NOx removal from diesel exhaust, the selective catalytic reduction (SCR) and lean NOx traps are established technologies. However, these procedures lack efficiency below 200 °C, which is of importance for city driving and cold start phases. Thus, the present paper deals with the development of a novel low-temperature deNOx strategy implying the catalytic NOx reduction by hydrogen. For the investigations, a highly active H2-deNOx catalyst, originally engineered for lean H2 combustion engines, was employed. This Pt-based catalyst reached peak NOx conversion of 95 % in synthetic diesel exhaust with N2 selectivities up to 80 %. Additionally, driving cycle tests on a diesel engine test bench were also performed to evaluate the H2-deNOx performance under practical conditions. For this purpose, a diesel oxidation catalyst, a diesel particulate filter and a H2 injection nozzle with mixing unit were placed upstream to the full size H2-deNOx catalyst.

Cars cause a lot of pollutants during the utilization phase. Within the last years environmental legislation tried to reduce the emissions by the introduction of very tight laws. The results are impressive: Most of the car exhaust emissions like carbonmonoxid and nitrous oxides have been reduced. At this stage new emission reduction limits in Europe as well as in the United States can only be achieved if the formulation of the catalyst system is significantly changed. An increased use of precious metals and rare earth materials is the result of such a modification which succeeds in a more expensive design of the total catalyst systems. More expensive means not only cost aspects but also the environmental burdens related to the increased production of precious metals and other catalyst components. The Life Cycle Engineering (LCE) of the catalyst system which achieves the new legislation is demonstrated as well as the effects to the usage phase.

There is a growing need for low-emissions concepts due to stricter emission regulations, more stringent homologation cycles, and the possibility of a ban on new engines by 2035. Of particular concern are the conditions during a cold start, when the Three-Way Catalyst is not yet heated to its light-off temperature. During this period, the catalyst remains inactive, thereby failing to convert pollutants. Reducing the time needed to reach this temperature is crucial to comply with the more stringent emissions standards. The post oxidation by means of secondary air injection, illustrated in this work, is a possible solution to reduce the time needed to reach the above-mentioned temperature. The strategy consists of injecting air into the exhaust manifold via secondary air injectors to oxidize unburned fuel that comes from a rich combustion within the cylinder.

Apart from the reduction of engine-out emissions from the powerplant, the development of an efficient and reliable catalytic converter heating system is an important task of automotive engineering in the future to meet standards that will require reduction of cold start emissions. Carrying out a comprehensive study in this field, BMW has tested and evaluated possible solutions to this challenge. In additon to the electrically heated catalytic converter (E-cat) and the afterburner chamber, an incorporated burner system would meet the requirement for fast catalyst light-off in the future, particularly in the case of larger engines.

Although hydrogen ICE engines have existed in one sort or another for many years, the testing of fuel consumption by way of exhaust emissions is not yet a proven method. The current consumption method for gasoline- and diesel-fueled vehicles is called the Carbon-Balance method, and it works by testing the vehicle exhaust for all carbon-containing components. Through conservation of mass, the carbon that comes out as exhaust must have gone in as fuel. Just like the Carbon-Balance method for gas and diesel engines, the new Hydrogen-Balance equation works on the principle that what goes into the engine must come out as exhaust components. This allows for fuel consumption measurements without direct contact with the fuel. This means increased accuracy and simplicity. This new method requires some modifications to the testing procedures and CVS (Constant Volume Sampling) system.

The production of the BMW ALPINA B12 5.7 with Switch-Tronic transmission provides the markets of Europe and Japan with an exclusive, luxury-orientated, high performance limited series limousine. This is the first vehicle worldwide to be fitted with the progressive exhaust gas aftertreatment technology known as the Electrically Heated Catalyst (EHC), in which the effectiveness of the power utilized is increased significantly by an alternating heating process for both catalytic converters. Only since this achievement has the implementation of the EHC been viable without extensive modification to the battery and alternator. With this exhaust gas aftertreatment concept, the emissions of this high performance vehicle will fall to less than half the maximum permissible for compliance with 1996 emission standards.

Test of autonomous systems is mostly brute force and ad-hoc thus being neither efficient nor transparent. Though requirements invite for a situational transparency, a framework is missing to judge quality of requirements and derived test-cases. Practical challenges are state explosion, difficulty to derive corner cases, no systematic safety of the intended functionality as specified, lack of accepted KPI, etc. Maintaining a valid safety case is hardly possible with such adaptive systems and continuous software updates. To achieve trusted autonomous vehicles, test cases must be generated automatically while at same time providing coverage (e.g., indicating progress with KPI), efficiency (e.g., limiting the amount of regression testing) and transparency (e.g., showing how specific corner cases are tested in case of accidents). This paper provides a method for automatically generating test cases for AI-based autonomous systems and compares it with existing testing methods.

External Exhaust Gas Recirculation (EGR) provides an opportunity to increase the efficiency of turbocharged spark-ignition engines. Of the competing technologies and configurations, Low-Pressure EGR (LP-EGR) is the most challenging in terms of its dynamic behavior. Only some of the stationary feasible potential can be used during dynamic engine operation. To guarantee fuel consumption-optimized engine operation with no instabilities, a load point-dependent limitation of the EGR rate or alternatively an adaptation of the operating point to the actual EGR rate is crucial. For this purpose, a precise knowledge of efficiency and combustion variance is necessary. Since the operating state includes the actual EGR rate, it has an additional dimension, which usually results in an immense measuring effort.