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The results of both theoretical and experimental studies on the self-ignition of single pure hydrocarbon drops are described. In this work single drops were subjected to air streams heated to such degrees that self-ignition of the drops would occur. Experimental heat and mass transfer parameters, as well as ignition delay data for different fuels and at different operating conditions were obtained. The experimental data were then used in conjunction with boundary layer correlations to evaluate the extent of the ignition delay that is physical (vaporization) and chemical (molecular interaction).

This paper describes a method for studying reactions of hydrocarbons in S.I. engine exhaust gases. The reaction of ethane is described using an Arrhenius model (experimentally E = 86,500 cal/mole) for the rate of ethane diappearance and empirical correlations for distributions of the products carbon monoxide, ethylene, formaldehyde, methane, acetylene, and propane as a function of the fraction of ethane reacted. The results show that the nature of partial oxidation products from a nonreactive hydrocarbon may be less desirable from an air pollution viewpoint than the initial hydrocarbon.

This study looks at the application of a titanium dioxide (TiO2) catalytic nanoparticle suspension to the surface of the combustion chamber as a coating, as well as the addition of hydrogen gas to a four-stroke spark-ignited carbureted engine as a possible technique for lowering engine-out emissions. The experiments were conducted on two identical Generac gasoline powered generators using two, four and six halogen work lamps to load the engine. One generator was used as a control and the second had key components of the combustion chamber coated with the catalytic suspension. In addition to the coating, both engines were fed a hydrogen and oxygen gas mixture and tested at low, medium and high loads. Using an unmodified engine as a control set, the following three conditions were tested and compared: addition of hydrogen only, addition of coating only, and addition of hydrogen to the coated engine.

The objective of this research was to investigate the effect of injection pressure on air entrainment into transient diesel sprays. The main application of interest was the direct injection diesel engine. Particle Image Velocimetry was used to make measurements of the air entrainment velocities into a spray plume as a function of time and space. A hydraulically actuated, electronically controlled unit injector (HEUI) system was used to supply the fuel into a pressurized spray chamber. The gas chamber density was maintained at 27 kg/m3. The injection pressures that were studied in this current research project were 117.6 MPa and 132.3 MPa. For different injection pressures, during the initial two-thirds of the spray plume there was little difference in the velocities normal to the spray surface. For the last third of the spray plume, the normal velocities were 125% higher for the high injection pressure case.

A correlation was developed to predict the ignition delay of PRF blends at a wide range of engine-relevant operating conditions. Constant volume simulations were performed using Cantera coupled with a reduced reaction mechanism at a range of initial temperatures from 570-1860K, initial pressures from 10-100atm, oxygen mole percent from 12.6% to 21%, equivalence ratios from 0.30-1.5, and PRF blends from PRF0 to PRF100. In total, 6,480 independent ignition delay simulations were performed. The correlation utilizes the traditional Arrhenius formulation; with equivalence ratio (φ), pressure (p), and oxygen mole percentage (xo2) dependencies. The exponents α, β, and γ were fitted to a third order polynomial with respect to temperature with an exponential roll-off to a constant value at low temperatures to capture the behavior expressed by the reaction mechanism. The location and rate of the roll-off functions were modified by linear functions of PRF.

Diesel fuels are complex mixtures of thousands of hydrocarbons. Since modeling their combustion characteristics with the inclusion of all hydrocarbon species is not feasible, a hybrid surrogate model approach is used in the present work to represent the physical and chemical properties of three different diesel fuels by using up to 13 and 4 separate hydrocarbon species, respectively. The surrogates are arrived at by matching their distillation profiles and important properties with the real fuel, while the chemistry surrogates are arrived at by using a Group Chemistry Representation (GCR) method wherein the hydrocarbon species in the physical property surrogates are grouped based on their chemical classes, and the chemistry of each class is represented by using up to two hydrocarbon species.

The purpose of the tests conducted on a single-cylinder laboratory engine was to determine the mechanism of combustion that affect exhaust emissions and the relationship of those mechanisms to engine design and operating variables. For the engine used in this study, the exhaust emissions were found to have the following dependence on various engine variables. Hydrocarbon emission was reduced by lean operation, increased manifold pressure, retarded spark, increased exhaust temperature, increased coolant temperature, increased exhaust back pressure, and decreased compression ratio. Carbon monoxide emission was affected by air-fuel ratio and premixing the charge. Oxides of nitrogen (NO + NO2 is called NOx) emission is primarily a function of the O2 available and the peak temperature attained during the cycle. Decreased manifold pressure and retarded spark decrease NOx emission. Hydrocarbons were found to react to some extent in the exhaust port and exhaust system.

THE present work uses the hot-motored technique to compare a hot, motored pressure diagram with a fired, pressure-time diagram. This technique is applied to a diesel engine to study the small pressure changes after injection and before rapid inflammation. The data resulting from these studies show a relationship between the magnitude of these pressure changes and cetane number of the fuel. Data for selected fuels are presented to show the relative magnitude of different phenomena causing ignition delay.

A computational, three-dimensional approach to investigate the behavior of diesel soot particles in the micro-channels of wall-flow Diesel Particulate Filters is presented. The KIVA3V CFD code, already extended to solve the 2D conservation equations for porous media materials [1], has been enhanced to solve in 2-D and 3-D the governing equations for reacting and compressible flows through porous media in non axes-symmetric geometries. With respect to previous work [1], a different mathematical approach has been followed in the implementation of the numerical solver for porous media, in order to achieve a faster convergency as source terms were added to the governing equations. The Darcy pressure drop has been included in the Navier-Stokes equations and the energy equation has been extended to account for the thermal exchange between the gas flow and the porous wall.

3-D Computational Fluid Dynamics (CFD) simulations have been performed to study particulate formation in a Spark-Ignition (SI) engine under premixed conditions. A semi-detailed soot model and a chemical kinetic model, including poly-aromatic hydrocarbon (PAH) formation, were coupled with a spark ignition model and the G equation flame propagation model for SI engine simulations and for predictions of soot mass and particulate number density. The simulation results for in-cylinder pressure and particle size distribution (PSDs) are compared to available experimental studies of equivalence ratio effects during premixed operation. Good predictions are observed with regard to cylinder pressure, combustion phasing and engine load. Qualitative agreements of in-cylinder particle distributions were also obtained and the results are helpful to understand particulate formation processes.

Engine experiments and multi-dimensional modeling were used to explore the effects of isobutanol as both the high and low reactivity fuels in Reactivity Controlled Compression Ignition (RCCI) Combustion. Three fuel combinations were examined; EEE/diesel, isobutanol/diesel, and isobutanol/isobutanol+DTBP (di-tert butyl peroxide). In order to assess the relative performance of the fuel combinations of interest under RCCI operation, the engine was operated under conditions representative of typical low temperature combustion (LTC). A net load of 6 bar indicated mean effective pressure (IMEP) was chosen because it provides a wide operable range of equivalence ratios and combustion phasings without excessively high peak pressure rise rates (PPRR). The engine was operated under various intake pressures with global equivalence ratios from 0.28-0.36, and various combustion phasings (defined by 50% mass fraction burned-CA50) from about 1.5 to about 10 deg after top dead center (ATDC).

The tradeoff between NOx emissions and combustion instability in an engine operating in the dual-fuel Reactivity Controlled Compression Ignition (RCCI) combustion mode was investigated using a combination of engine experiments and detailed CFD modeling. Experiments were performed on a single cylinder version of a General Motors/Fiat JTD 1.9L four-cylinder diesel engine. Gasoline was injected far upstream of the intake valve using an air assisted injector and fuel vaporization system and diesel was injected directly into the cylinder using a common rail injector. The timing of the diesel injection was swept from −70° ATDC to −20° ATDC while the gasoline percentage was adjusted to hold the average combustion phasing (CA50) and load (IMEPg) constant at 0.5° ATDC and 7 bar, respectively. At each operating point the variation in IMEP, peak PRR, and CA50 was calculated from the measured cylinder pressure trace and NOx, CO, soot and UHC were recorded.

Engine experiments have revealed the importance of fuel condensation on the emission characteristics of low temperature combustion. However, direct in-cylinder experimental evidence has not been reported in the literature. In this paper, the in-cylinder condensation processes observed in optically accessible engine experiments are first illustrated. The observed condensation processes are then simulated using state-of-the-art multidimensional engine CFD simulations with a phase transition model that incorporates a well-validated phase equilibrium numerical solver, in which a thermodynamically consistent phase equilibrium analysis is applied to determine when mixtures become unstable and a new phase is formed. The model utilizes fundamental thermodynamics principles to judge the occurrence of phase separation or combination by minimizing the system Gibbs free energy.

The present experimental engine efficiency study explores the effects of intake pressure and temperature, and premixed and global equivalence ratios on gross thermal efficiency (GTE) using the reactivity controlled compression ignition (RCCI) combustion strategy. Experiments were conducted in a heavy-duty single-cylinder engine at constant net load (IMEPn) of 8.45 bar, 1300 rev/min engine speed, with 0% EGR, and a 50% mass fraction burned combustion phasing (CA50) of 0.5°CA ATDC. The engine was port fueled with E85 for the low reactivity fuel and direct injected with 3.5% 2-ethylhexyl nitrate (EHN) doped into 91 anti-knock index (AKI) gasoline for the high-reactivity fuel. The resulting reactivity of the enhanced fuel corresponds to an AKI of approximately 56 and a cetane number of approximately 28. The engine was operated with a wide range of intake pressures and temperatures, and the ratio of low- to high-reactivity fuel was adjusted to maintain a fixed speed-phasing-load condition.

The University of Wisconsin-Madison Snowmobile Team has designed and constructed a clean, quiet, high performance snowmobile for entry in the 2008 Society of Automotive Engineers' Clean Snowmobile Challenge. Built on a 2003 cross-country touring chassis, this machine features a 750 cc fuel-injected four-stroke engine equipped with a fuel sensor which allows operation ranging from regular gasoline to an 85% blend of ethanol and gasoline (E85). The engine has been customized with a Mototron control system which allows for full engine optimization using a range of fuels from E00 to E85. Utilizing a heated oxygen sensor and a 3-way catalyst customized for this engine by W.C. Heraeus-GmbH, this sled reduces NOx, HC and CO emissions by up to 89% to an average specific mass of 0.484, 0.154, 4.94 g/kW-hr respectively. Finally, the Mototron system also allowed Wisconsin to extract another 4 kW from the Weber 750cc engine; producing 45 kW and 65 Nm of torque.

In the current work, a series-hybrid vehicle has been constructed that utilizes a dual-fuel, Reactivity Controlled Compression Ignition (RCCI) engine. The vehicle is a 2009 Saturn Vue chassis and a 1.9L turbo-diesel engine converted to operate with low temperature RCCI combustion. The engine is coupled to a 90 kW AC motor, acting as an electrical generator to charge a 14.1 kW-hr lithium-ion traction battery pack, which powers the rear wheels by a 75 kW drive motor. Full vehicle testing was conducted on chassis dynamometers at the Vehicle Emissions Research Laboratory at Ford Motor Company and at the Vehicle Research Laboratory at Oak Ridge National Laboratory. For this work, the US Environmental Protection Agency Highway Fuel Economy Test was performed using commercially available gasoline and ultra-low sulfur diesel. Fuel economy and emissions data were recorded over the specified test cycle and calculated based on the fuel properties and the high-voltage battery energy usage.

In recent years society's demand and interest in clean and efficient internal combustion engines has grown significantly. Several ideas have been proposed and tested to meet this demand. In particular, dual-fuel Reactivity Controlled Compression Ignition (RCCI) combustion has demonstrated high thermal efficiency, and low engine-out NOx, and soot emissions. Unlike homogeneous charge compression ignition (HCCI) combustion, which solely relies on the chemical kinetics of the fuel for ignition control, RCCI combustion has proven to provide superior combustion controllability while retaining the known benefits of low emissions and high thermal efficiency of HCCI combustion. However, in order for RCCI combustion to be adopted as a high efficiency and low engine-out emission solution, it is important to achieve high-power operation that is comparable to conventional diesel combustion (CDC).

The per cylinder displacement in cubic centimeters (PCDICC) vs. brake specific fuel consumption (BSFC) have been plotted for both DI and IDI diesel engines. The smallest and largest PCDICC are 25.7 to 2,000,000. It was found for the DI engines that the lowest to the highest (BSFC) ranged from approximately 155 to 450. In terms of ratios these turn out to be about 2.9. Reasons for the increase in BSFC with decrease in PCDICC are presented. Background material are presented to help in explaining the trends experienced. Boundary conditions of the injected fuel as to duration, drop size, and their effect on BSFC, emissions are postulated.

Low-temperature combustion (LTC) strategies have been an active area of research due to their ability to achieve high thermal efficiency while avoiding the formation of NOx and particulate matter. One of the largest challenges with LTC is the relative lack of authority over the heat release rate profile, which, depending on the particular injection strategy, either limits the maximum attainable load, or creates a tradeoff between noise and efficiency at high load conditions. We have shown previously that control over heat release can be dramatically improved through a combination of reactivity stratification in the premixed charge and a diffusion-limited injection that occurs after the conclusion of the low-temperature heat release, in a strategy called direct dual fuel stratification (DDFS).

The transient response of an engine with both High Pressure (HP) and Low Pressure (LP) EGR loops was compared by conducting step changes in EGR fraction at a constant engine speed and load. The HP EGR loop performance was shown to be closely linked to turbocharger performance, whereas the LP EGR loop was relatively independent of turbocharger performance and vice versa. The same experiment was repeated with the variable geometry turbine vanes completely open to reduce turbocharger action and achieve similar EGR rate changes with the HP and LP EGR loops. Under these conditions, the increased loop volume of the LP EGR loop prolonged the response of intake O2 concentration following the change in air-fuel ratio. The prolonged change of intake O2 concentration caused emissions to require more time to reach steady state as well. Strong coupling between the HP EGR loop and turbochargers was again observed using a hybrid EGR strategy.