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The behaviour of a NOx storage catalyst in powdered form and containing a storage component based on alkaline metal was investigated under rich conditions. Experiments were conducted in a fixed-bed flow reactor with the space velocity set at 45,000 h-1. From these experiments it was possible to extract the fractional NOx reduction and the efficiency of use of the reductant. With 0.9% CO as a reductant at 350°C, complete utilisation of CO was achieved up to 70% NOx conversion as treatment time was increased. To obtain 90% NOx conversion required longer times, and 23% of the CO did not participate in the reduction of NOX. A reductant balance shows that about 40% of the CO added is used to reduce the catalyst surface when the flow is switched from lean to rich. The ranking of efficiencies of different reductant gases at 350°C gave the following sequence: 0.9% H2 ≈ 0.9% CO > 1285 ppm toluene > 3000 ppm propene ≈ 1125 ppm i-octane > 3000 ppm propane.

A new method has been designed to examine car seats by technical means only, whether they fit summer conditions or not. Test procedures start with the application of a carefully wetted cloth onto the seat to be examined. The test area is then covered by a temperature controlled, electrically heated solid body bloc. This simulates the body temperature and the seat pressure of a real seat user. During test periods of standard three hours, temperature and humidity is measured beneath the test device and in the surrounding air. As an effect of the water impulse the humidity increases under the body bloc. It has been proved that good summer suitability of a car seat is characterised by moderate amount and moderate duration of increased humidity readings. Poor suitability results in higher amount and longer duration of raised humidity. The method is shown to be useful to examine full scale car seats, child safety seats and single design characteristics of car seats as well.

In one-dimensional engine simulation programs the simulation of engine performance is mostly done by parameter fitting in order to match simulations with experimental data. The extensive fitting procedure is especially needed for emissions formation - CO, HC, NO, soot - simulations. An alternative to this approach is, to calculate the emissions based on detailed kinetic models. This however demands that the in-cylinder combustion-flow interaction can be modeled accurately, and that the CPU time needed for the model is still acceptable. PDF based stochastic reactor models offer one possible solution. They usually introduce only one (time dependent) parameter - the mixing time - to model the influence of flow on the chemistry. They offer the prediction of the heat release, together with all emission formation, if the optimum mixing time is given.

The California LEV1 II program will be introduced in the year 2003 and requires a further reduction of the exhaust emissions of passenger cars. The cold start emissions represent the main part of the total emissions of the FTP2-Cycle. Cold start emissions can be efficiently reduced by injecting secondary air (SA) in the exhaust port making compliance with the most stringent standards possible. The thermochemical conditions (mixing rate and temperature of secondary air and exhaust gas, exhaust gas composition, etc) prevailing in the exhaust system are described in this paper. This provides knowledge of the conditions for auto ignition of the mixture within the exhaust manifold. The thus established exothermal reaction (exhaust gas post-combustion) results in a shorter time to light-off temperature of the catalyst. The mechanisms of this combustion are studied at different engine idle conditions.

The vehicle fleet differs in mass, geometry, stiffness and many other parameters. These differences are consequences of different design objectives for these vehicles and result from consumer demand, environmental and safety considerations etc. Accident research shows that the injury outcome differs in some cases, when two vehicles collide. Scientists often discuss a list of features that are assumed to be relevant for compatibility of vehicles. The relevance of these potentially important compatibility features and expected compatibility measures is examined from the perspective of accident analysis. An overview of this accident research is given and crash tests and measures are discussed that correspond with these findings.

The lifetime of the new technologies of after-treatment devices is influenced by the composition of engine oil, making it necessary to study the compatibility of lubricants with these devices. These compatibility tests usually evaluate parameters such as the long-term performance of after-treatment systems, the quantity and nature of accumulated residues due to the lubricant used, back-pressure increase, etc. This paper presents a novel, non-destructive radionuclide technique based on labeling the different elements in the engine oil (e.g. zinc and calcium), that provides additional information to after-treatment system compatibility tests: on-line measurement in the after-treatment device of the accumulation of elements from oil additives, and visualization of their distribution inside the device (inlet/outlet). Most of the work presented here focuses on the accumulation of zinc and calcium from the lubricant in a Diesel Particulate Filter (DPF).

Synthetic fuels are expected to play an important role for future mobility, because they can be introduced seamlessly alongside conventional fuels without the need for new infrastructure. Thus, understanding the interaction of GTL fuels with modern engines, and aftertreatment systems, is important. The current study investigates potential benefits of GTL fuel in respect of diesel particulate filters (DPF). Experiments were conducted on a Euro 4 TDI engine, comparing the DPF response to two different fuels, normal diesel and GTL fuel. The investigation focused on the accumulation and regeneration behavior of the DPF. Results indicated that GTL fuel reduced particulate formation to such an extent that the regeneration cycle was significantly elongated, by ∼70% compared with conventional diesel. Thus, the engine could operate for this increased time before the DPF reached maximum load and regeneration was needed.

Several different possibilities will be described and discussed on the processes of reducing NOx in lean-burn gasoline and diesel engines. In-company studies were conducted on zeolitic catalysts. With lean-burn spark-ignition engines, hydrocarbons in the exhaust gas act as a reducing agent. In stationary conditions at λ = 1.2, NOx conversion rates of approx. 45 % were achieved. With diesel engines, the only promising variant is SCR technology using urea as a reducing agent. The remaining problems are still the low space velocity and the narrow temperature window of the catalyst. The production of reaction products and secondary reactions of urea with other components in the diesel exhaust gas are still unclarified.

Accident studies conducted during the last twenty-five years clearly show that car to car head-on collision is a major impact configuration to take into account in order to improve safety on the roads. With new self protection ratings all cars offer equivalent behaviour against a fixed obstacle. So, in the future, the main progress will have to be made in car to car compatibility. Recent studies have shown the feasibility of designing compatible cars for both structure behaviour and occupant protection. However, some requirements on front unit design could make this aim more difficult to achieve. We suggest developping a more comprehensive approach in order to better take into account all the constraints.

The regulations for mobile applications will become stricter in Euro 6 and further emission levels and require the use of active aftertreatment methods for NOX and particulate matter. SCR and LNT have been both used commercially for mobile NOX removal. An alternative system is based on the combination of these two technologies. Developments of catalysts and whole systems as well as final vehicle demonstrations are discussed in this study. The small and full-size catalyst development experiments resulted in PtRh/LNT with optimized noble metal loadings and Cu-SCR catalyst having a high durability and ammonia adsorption capacity. For this study, an aftertreatment system consisting of LNT plus exhaust bypass, passive SCR and engine independent reductant supply by on-board exhaust fuel reforming was developed and investigated. The concept definition considers NOX conversion, CO2 drawback and system complexity.

This paper summarizes the development of a wireless message from infrastructure-to-vehicle (I2V) for safety applications based on Dedicated Short-Range Communications (DSRC) under a cooperative agreement between the Crash Avoidance Metrics Partners LLC (CAMP) and the Federal Highway Administration (FHWA). During the development of the Curve Speed Warning (CSW) and Reduced Speed Zone Warning with Lane Closure (RSZW/LC) safety applications [1], the Basic Information Message (BIM) was developed to wirelessly transmit infrastructure-centric information. The Traveler Information Message (TIM) structure, as described in the SAE J2735, provides a mechanism for the infrastructure to issue and display in-vehicle signage of various types of advisory and road sign information. This approach, though effective in communicating traffic advisories, is limited by the type of information that can be broadcast from infrastructures.

Based an extensive preparatory work and analyses, suggestions have been drawn up with regard to solutions for front door frames in the following regions:- door hinge mountings, seat belt anchorage mountings of B pillars, cross sections for the top of A pillars. At the same time as the design work, FEM calculations should be carried out to ensure optimization of the concepts. Economy reasons and experiences in production runs point towards a very strong fibre glass-reinforced door frames manufacutred in the SMC procress. The complete door frame is examined in comparison with geometrically similar sheet metal parts on a test frame and in the vehicle.

Generally, safety belt effectiveness is spoken of as a single value which is applied to all types of accidents and injuries. This study analyzes the makeup of safety belt effectiveness and compares the overall effectiveness to the effectiveness for different levels of injury, different areas of the body and for different types of accidents at different speeds. These comparisons show the wide range of effectiveness of safety belts and the relative effectiveness for different specific situations.

Meeting current exhaust emission standards requires rapid catalyst light-off. Closed-coupled catalysts are commonly used to reduce light-off time by minimizing exhaust heat loss between the engine and catalyst. However, this exhaust gas system design leads to a coupling of catalyst heating and engine operation. An engine-independent exhaust gas aftertreatment can be realized by combining a burner heated catalyst system (BHC) with an underfloor catalyst located far away from the engine. This paper describes some basic characteristics of such a BHC system and the results of fitting this system into a Volkswagen Touareg where a single catalyst was located about 1.8 m downstream of the engine. Nevertheless, it was possible to reach about 50% of the current European emission standard EU 4 without additional fuel consumption caused by the BHC system.

Within the European research programme IDEA (Integrated Diesel European Action), detailed experimental and theoretical studies of the fundamental phenomena of the Diesel engine like flow, injection, mixture formation, auto-ignition, combustion and pollutant formation were carried out to improve knowledge and to set up models for a simulation code. Because this basic research of the Diesel combustion process is very complex and cost intensive, it was carried out jointly by the JRC (Joint Research Committee), an association of European car manufacturers (Fiat, Peugeot SA, Renault, Volvo and Volkswagen). The activities were also subsidized by the Commission of the European Communities and the Swedish National Board of Technical Development. The results of the research work will support the design of even more efficient engines and the further reduction of soot and NOx emissions and will also enable the companies to reduce time and cost in developing new engines.

Compatibility has been a research issue for many years now. It has gained more importance recently due to significant improvements in primary and secondary safety. Using a rigorous approach, combining accident research and theoretical scientific considerations, measures to improve vehicle-vehicle compatibility, with an emphasis on feasibility, were discussed. German accident research statistics showed that frontal impacts are of higher statistical significance than side impacts. Based on this and the high potential for improvement due high available deformation energy, the frontal impact configuration was identified as the most appropriate collision mode for addressing the compatibility issue. In side impacts, accident avoidance was identified as the most feasible and sensible measure. For frontal vehicle-vehicle impacts, both trucks and passenger cars were identified as opponents of high statistical significance.

One dimensional Spontaneous Raman Scattering measurements (RS) have been performed in a spray (standard gasoline, one-component and multi-component model fuels) which was operated in a high-temperature, high-pressure chamber, so that realistic engine conditions have been simulated. The present work investigates under what conditions 1D-RS can be employed for fuel/air-ratio measurements in realistic DI gasoline sprays. The distance from the spray axis has been determined, til that, coming from the outside, quantitative Raman measurement are possible. The equivalence ratio has been quantified for the one component fuel close to the spray. It turns out that the measurement error depends strongly on the type of fuel. These problems are caused by the PAH (polycyclic aromatic hydrocarbon) content of the fuel, which leads to interfering laser-induced fluorescence signals.

Cervical Spine Distortions (CSD) - sometimes called whiplash injuries - have turned out in passenger car accidents to be one of the most important types of injuries to occupants, according to the rate of occurences and to the significance of consequences as well. Many technical aspects of traffic accidents which in the past have led to CSD have been analysed and reported in a large number of publications. However human factors data are not as good represented in the literature. Particularly these parameters and their relationship to whiplash injuries have been analysed on the basis of the Volkswagen Accident Database. The significance of the items gender, age, body height and body weight of belted occupants in passenger cars involved in rear end collisions is presented in quantitative terms regarding frequencies of occurance and risk of suffering CSD respectively.

Sulfur content in gasoline is known to reduce the efficiency of the catalytic converters that are used to reduce pollutants in the exhaust gas of cars. There is some concern that nitrous oxide emissions (N2O) increase when fuel with a high sulfur content is used. The engine out and tailpipe mass emissions of two cars conforming to the California LEV-standard were analyzed. The influence of the fuel sulfur content on the emissions of the regulated and some unregulated pollutants during FTP test cycles was determined. Four fuels covering the range from less than 1 to 330 ppm sulfur content were used. Over that range of fuel sulfur concentration the engine out emissions of sulfur dioxide (SO2 ) of both cars increased. Tailpipe emissions of SO2 were only found at fuel sulfur concentrations of 150 and 330 ppm. For both vehicles a correlation between the N2O emissions and the fuel sulfur content was found.

VOLKSWAGEN has conducted a number of investigations on a Multi Fuel Vehicle (MFV), designed for variable fuel operation, to determine the influence of fuel composition and clean fuels on exhaust emissions, mainly on ozone forming potential. Results of the tests indicate a small advantage of Phase II Reformulated Gasoline and a greater one for for methanol fuel M85, compared to today's gasoline. For M85 there is an about 25 % lower ozone forming potential. The most critical components in the exhaust of methanol fueled vehicles (M85) are unburned methanol and formaldehyde, forming more than 60 % of the total ozone forming potential. Therefore improvement of cold start and warmup driving during the first two to three minutes is of great importance, because in this time about 90 % of the mentioned components are formed.