Search Results

Exhaust gas recirculation (EGR) can be used to mitigate knock in SI engines. However, experiments have shown that the effectiveness of various EGR constituents to suppress knock varies with fuel type and compression ratio (CR). To understand some of the underlying mechanisms by which fuel composition, octane sensitivity (S), and CR affect the knock-mitigation effectiveness of EGR constituents, the current paper presents results from a chemical-kinetics modeling study. The numerical study was conducted with CHEMKIN, imposing experimentally acquired pressure traces on a closed reactor model. Simulated conditions include combinations of three RON-98 (Research Octane Number) fuels with two octane sensitivities and distinctive compositions, three EGR diluents, and two CRs (12:1 and 10:1). The experimental results point to the important role of thermal stratification in the end-gas to smooth peak heat-release rate (HRR) and prevent acoustic noise.

In order to clarify future automobile technologies and fuel qualities to improve air quality, second phase of Japan Clean Air Program (JCAPII) had been conducted from 2002 to 2007. Predicting improvement in air quality that might be attained by introducing new emission control technologies and determining fuel qualities required for the technologies is one of the main issues of this program. Unregulated material WG of JCAPII had studied unregulated emissions from gasoline and diesel engines. Eight gaseous hydrocarbons (HC), four Aldehydes and three polycyclic aromatic hydrocarbons (PAHs) were evaluated as unregulated emissions. Specifically, emissions of the following components were measured: 1,3-Butadiene, Benzene, Toluene, Xylene, Ethylbenzene, 1,3,5-Trimethyl-benzene, n-Hexane, Styrene as gaseous HCs, Formaldehyde, Acetaldehyde, Acrolein, Benzaldehyde as Aldehydes, and Benzo(a)pyrene, Benzo(b)fluoranthene, Benzo(k)fluoranthene as PAHs.

We have developed a novel engine cycle simulation program (UniDES: universal diesel engine simulator) to reproduce the diesel combustion process over a wide range of engine operating parameters, such as the amount of injected fuel, the injection timing, and the EGR ratio. The approach described in this paper employs a zoning model, where the in-cylinder region is divided into up to five zones. We also applied a probability density function (PDF) concept to each zone to consider the effect of spatial non-homogeneities, such as local equivalence ratios and temperature, on the combustion characteristics. We linked this program to the commonly used commercial GT-Power® software (UniDES+GT). As a result, we were able to reproduce transient engine behavior very accurately.

The aim of this research is to develop the diesel combustion simulation (UniDES: Universal Diesel Engine Simulator) that incorporates multiple-injection strategies and in-cylinder composition changes due to exhaust gas recirculation (EGR), and that is capable of high speed calculation. The model is based on a zero-dimensional (0D) cycle simulation, and represents a multiple-injection strategy using a multi-zone model and inhomogeneity using a probability density function (PDF) model. Therefore, the 0D cycle simulation also enables both high accuracy and high speed. This research considers application to actual development. To expand the applicability of the simulation, a model that accurately estimates nozzle sac pressure with various injection quantities and common rail pressures, a model that accounts for the effects of adjacent spray interaction, and a model that considers the NOx reduction phenomenon under high load conditions were added.

One of the main causes of the inadequate transient response of a 4-valve engine was established as being partition wall-wetting. The possibility of resolving this problem by improving fuel atomization was investigated. An air-mix type injector, although producing finer droplets with more uniform distribution, was not found effective in improving transient response. The development of a two-hole injector is described. This new injector produces twin sprays which are directed into the siamese intake ports without wetting the partition wall. As a consequence, the lean A/F ratio excursion is reduced, torque stumble is eliminated and the conversion efficiency of a three-way catalyst is increased.

To prevent global warming, further reductions in carbon dioxide are required. It is therefore important to promote the spread of electric vehicles powered by internal combustion engines and electric vehicles without internal combustion engines. As a result, emissions from hybrid electric vehicles equipped with internal combustion engines should be further reduced. Interest in catalytic reactions in an electric field with a higher catalytic activity compared to conventional catalysts has increased because this technology consumes less energy than other electrical heating devices. This study was therefore undertaken to apply a catalytic reaction in an electric field to an exhaust emission control. First, the original experimental equipment was built with a high voltage system used to conduct catalytic activity tests.

At the engine restart, when the temperature of the catalytic converter is low, additional fuel consumption would be required to warm up the catalyst for controlling exhaust emission.The aim of this study is to find a thermally optimal way to reduce fuel consumption for the catalyst warm up at the engine restart, by improving the thermal retention of the catalytic converter in the cool down process after the previous trip. To make analysis of the thermal flow around the catalytic converter, a 2-D thermal flow model was constructed using the thermal network method. This model simulates the following processes: 1) heat conduction between the substrate and the stainless steel case, 2) heat convection between the stainless steel case and the ambient air, 3) heat convection between the substrate and the gas inside the substrate, 4) heat generation due to chemical reactions.

The effects of diesel fuel properties (aromatic content, cetane index and T90), cetane improver, oxygenates, high boiling point hydrocarbons and aromatics distribution on diesel exhaust emissions were studied under the Japanese 10-15 test cycle and the ECE+EUDC test cycle. The test vehicle was a TOYOTA COROLLA with a natural aspirated, 2.0L displacement, IDI diesel engine. It was demonstrated that particulate emissions are highly correlated with T90 and that NOx is affected by the aromatic content of fuel. A reduction in particulates emissions was observed in fuel with a lower cetane number by adding cetane improver, but this reduction was limited. Cetane improver had no effect on NOx emissions in the 45 # 60 cetane number range. Oxygenates reduced particulate emissions remarkably but had little effect on NOx emissions. A decrease in the soot in particulates was particularly observed.

To improve urban air pollution, stringent emissions regulations for heavy-duty diesel engines have been proposed and will become effective in Japan, the EU, and the United States in a few years. To comply with such future regulations, it is critical to investigate the effects of intake and injection parameters and fuel properties on engine performance, efficiency and emissions characteristics, associated with the use of aftertreatment systems. An experimental study was carried out to identify such effects. In addition, the KIVA-3 code was used to gain insight into cylinder events. The results showed improvements in NOx-Smoke and BSFC trade-offs at high-pressure injection in conjunction with EGR and supercharging.

Polymer electrolyte membrane fuel cell (PEFC) systems for fuel cell vehicles (FCVs) require both performance and durability. Carbon is the typical support material used for PEFC catalysts. However, hydrogen starvation at the anode causes high electrode potential states (e.g., 1.3 V with respect to the reversible hydrogen electrode) that result in severe carbon support corrosion. Serious damage to the carbon support due to hydrogen starvation can lead to irreversible performance loss in PEFC systems. To avoid such high electrode potentials, FCV PEFC systems often utilize cell voltage monitor systems (CVMs) that are expensive to use and install. Simplifying PEFC systems by removing these CVMs would help reduce costs, which is a vital part of popularizing FCVs. However, one precondition for removing CVMs is the adoption of a durable support material to replace carbon.

Three-way catalyst shows high performance under stoichiometric atmosphere. The CeO2-ZrO2 based materials (CZ) are added as a buffer of O2 concentration. To improve the catalyst performance the larger O2 storage capacity (OSC) are needed. Theoretically, the sulfur oxidation-reduction reaction moves oxygen 8 times larger than cerium. We focused on this phenomenon and synthesized Ln2O2SO4 as a new OSC material. The experimental result under model gas shows that the OSC of Ln2O2SO4 is 5 times lager than CZ.

Performance improvements were studied for the diesel particulate and NOx reduction system (DPNR), a system that simultaneously reduces NOx and Particulate Matter (PM) from diesel engine exhaust gas. The experimental system (hereinafter called the “dual DPNR”) consists of two DPNR catalysts arranged in parallel, each provided with an exhaust throttle valve downstream to control the exhaust gas flow to the catalyst, plus a fuel injector that precisely controls the air-fuel ratio and the catalyst bed temperature. The fuel injector is used to supply a rich mixture to the DPNR catalyst, and the flow of exhaust gas is switched between the two catalysts by operating the exhaust throttle valves alternately. Tests were conducted with the engine running at steady state. The results indicated that the NOx reduction performance dramatically improved and the loss of fuel economy from the NOx reduction reduced.

Catalyst specifications and converter layouts were studied to identify the high conversion performance under various in-use driving conditions, high mileage intervals and extended life cycle. The effects of volumes, configuration, selection and loading distribution of precious metals, additive components and substrate type for catalyst were studied on engine dynamometers and vehicle tests to optimize a catalyst converter system. Moreover, model gas experiments were conducted to analyze deterioration mechanisms and conversion characteristics of catalysts. As a result, the concept of a divided catalyst converter system, which provides separate functions for a close-coupled and an under-floor catalyst, was found to be effective for the future exhaust system. For reducing HC emissions, the close-coupled catalyst should warm up quickly and resist a high temperature. The under-floor catalyst, located at a rather low temperature position, is durable and maintains high NOx conversion.

In this study, we combined a diesel engine with the Toyota Hybrid System (THS). Utilizing the functions of the THS, reducing engine friction, lowering the compression ratio, and adopting a low pressure loop exhaust gas recirculation system (LPL-EGR) were examined to achieve both low fuel consumption and low nitrogen oxides (NOx) emissions over a wide operating range. After applying this system to a test vehicle it was verified that the fuel economy greatly surpassed that of a conventional diesel engine vehicle and that NOx emissions could be reduced below the value specified in the Euro 6 regulations without DeNOx catalysts.

The development of an alternative oxygen reduction electrocatalyst to platinum based electrocatalysts is critical for practical use of the polymer electrolyte membrane fuel cell (PEMFC). Transition metal sulfide chalcogenides have recently been reported as a possible candidate for Pt replacement. Our work focused on chalcogenides composed of ruthenium, molybdenum, and sulfur (RuMoS). We elucidate the factors affecting electrocatalytic activity of carbon supported RuXMoY SZ catalyst. This was demonstrated through a correlation of oxygen reduction reaction (ORR) activity of the catalysts with structural changes resulting from designed changes in sulfur composition in the catalysts.

Recently, the California Air Resources Board (CARB) has proposed a new set of evaporative emissions and “Useful Life” standards, called LEVII EVAP regulations, which are more stringent than those of the enhanced EVAP emissions regulations. If the new regulations are enforced, it will become increasingly important for the carbon canister to reduce Diurnal Breathing Loss (DBL) and to prevent deterioration of the canister. Therefore, careful studies have been made on the techniques to meet these regulations by clarifying the working capacity deterioration mechanism and the phenomenon of DBL in a carbon canister. It has been found that the deterioration of working capacity would occur if high boiling hydrocarbons, which are difficult to purge, fill up the micropores of the activated carbon, and Useful Life could be estimated more accurately according to the saturated adsorption mass of the activated carbon and the canister purge volume.

The emission characteristics of hydrocarbons during the cold start and the warm-up have been investigated. Timed sampling of hydrocarbon emissions upstream and downstream of a close-coupled catalytic converter have been carried out. The experimental results show that the emission characteristics of hydrocarbons are influenced by both the engine operating conditions and the heating characteristics of the catalytic converter. In the case of engine-out hydrocarbons, the total amount of hydrocarbons drastically decreases but the percentage contribution of the C2-C4 olefins to the engine-out hydrocarbons increases as the warm-up proceeds. Since these olefins have relatively high maximum incremental reactivity (MIR) factors, the specific reactivity (SR) of the engine-out hydrocarbons gradually increases during the warm-up. The adsorption and desorption processes of the engine-out hydrocarbons on the catalyst occur before the catalyst light-off.

A new after-treatment system called DPNR (Diesel Particulate-NOx Reduction System) has been developed for simultaneous and continuous reduction of particulate matter (PM) and nitrogen oxides (NOx) in diesel exhaust gas. This system consists of both a new catalytic technology and a new diesel combustion technology which enables rich operating conditions in diesel engines. The catalytic converter for the DPNR has a newly developed porous ceramic structure coated with a NOx storage reduction catalyst. A fresh DPNR catalyst reduced more than 80 % of both PM and NOx. This paper describes the concept and performance of the system in detail. Especially, the details of the PM oxidation mechanism in DPNR are described.

Improving vehicle fuel economy is a central part of efforts toward achieving a sustainable society. An effective way for accomplishing this aim is to enhance the engine thermal efficiency. Measures to mitigate knocking and reduce engine cooling heat loss are important aspects of enhancing the engine thermal efficiency. Cooled exhaust gas recirculation (EGR) is regarded as a key technology because it is capable of achieving both of these objectives. For this reason, it has been adopted in a wide range of both hybrid and conventional vehicles in recent years. Toyota has been introducing these technologies as ESTEC (Economy with Superior Thermal Efficient Combustion). Improving cycle-to-cycle variations in combustion, in addition to fast combustion is essential for achieving high engine thermal efficiency.

To correspond to the social requirements such as climate change, air pollution, and energy security, enhancing the engine thermal efficiency is strongly required in these days. As for the specific engine technologies to improve the engine thermal efficiency, Atkinson cycle, cooled EGR (Exhaust Gas Recirculation), and low friction technologies have been developed [1–4]. In regard to combustion technology, lean boosted concept has a potential to reduce CO2 emission because lean boosted concept is expected to enhance the engine thermal efficiency. Although expanding lean combustion limit is important for both increasing the engine thermal efficiency and reducing NOx emission, there is a limitation to realize stable lean combustion with SI (Spark Ignition) gasoline engine. In this study, fuel effects on the combustion characteristics from the viewpoint of chemical reaction capability are focused on.