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Technical Paper

The Effects of Thermal Degradation on the Performance of a NOX Storage/Reduction Catalyst

2009-04-20
2009-01-0631
The performance characteristics of a commercial lean-NOX trap catalyst were evaluated between 200 and 500°C, using H2, CO, and a mixture of both H2 and CO as reductants before and after different high-temperature aging steps, from 600 to 750°C. Tests included NOX reduction efficiency during cycling, NOX storage capacity (NSC), oxygen storage capacity (OSC), and water-gas-shift (WGS) and NO oxidation reaction extents. The WGS reaction extent at 200 and 300°C was negatively affected by thermal degradation, but at 400 and 500°C no significant change was observed. Changes in the extent of NO oxidation did not show a consistent trend as a function of thermal degradation. The total NSC was tested at 200, 350 and 500°C. Little change was observed at 500°C with thermal degradation but a steady decrease was observed at 350°C as the thermal degradation temperature was increased.
Technical Paper

Sulfur Impact on Methane Steam Reforming over the Stoichiometric Natural Gas Three-Way Catalyst

2024-04-09
2024-01-2633
The steam reforming of CH4 plays a crucial role in the high-temperature activity of natural gas three-way catalysts. Despite existing reports on sulfur inhibition in CH4 steam reforming, there is a limited understanding of sulfur storage and removal dynamics under various lambda conditions. In this study, we utilize a 4-Mode sulfur testing approach to elucidate the dynamics of sulfur storage and removal and their impact on three-way catalyst performance. We also investigate the influence of sulfur on CH4 steam reforming by analyzing CH4 conversions under dithering, rich, and lean reactor conditions. In the 4-Mode sulfur test, saturating the TWC with sulfur at low temperatures emerges as the primary cause of significant three-way catalyst performance degradation. After undergoing a deSOx treatment at 600 °C, NOx conversions were fully restored, while CH4 conversions did not fully recover.
Technical Paper

Round Robin Noise Measurement System Analysis Using Light Duty Diesel Engine

2015-06-15
2015-01-2299
NVH development of light duty diesel engines require significant collaboration with the OEM as compared to medium duty and heavy duty diesel engines. Typically, competitive benchmark studies and customer expectations define the NVH targets at the vehicle level and are subsequently cascaded down to the powertrain level. For engine manufacturing companies like Cummins Inc., it is imperative to work closely with OEM to deliver on the NVH expectations. In certain situations, engine level NVH targets needs to be demonstrated in the OEM or 3rd party acoustic test facility for customer satisfaction or commercial purposes. Engine noise tests across different noise test facilities may introduce some variation due to differences in the acoustic test facilities, test hardware, instrumentation differences, etc. In addition, the engine itself is a major source of variation.
Journal Article

Perception of Diesel Engine Gear Rattle Noise

2015-06-15
2015-01-2333
Component sound quality is an important factor in the design of competitive diesel engines. One component noise that causes complaints is the gear rattle that originates in the front-of-engine gear train which drives the fuel pump and other accessories. The rattle is caused by repeated tooth impacts resulting from fluctuations in differential torsional acceleration of the driving gears. These impacts generate a broadband, impulsive noise that is often perceived as annoying. In most previous work, the overall sound quality of diesel engines has been considered without specifically focusing on predicting the perception of gear rattle. Gear rattle level has been quantified based on angular acceleration measurements, but those measurements can be difficult to perform. Here, the emphasis was on developing a metric based on subjective testing of the perception of gear rattle.
Technical Paper

New Insights into the Unique Operation of Small Pore Cu-Zeolite SCR Catalyst: Overlapping NH3 Desorption and Oxidation Characteristics for Minimizing Undesired Products

2014-04-01
2014-01-1542
An operational challenge associated with SCR catalysts is the NH3 slip control, particularly for commercial small pore Cu-zeolite formulations as a consequence of their significant ammonia storage capacity. The desorption of NH3 during increasing temperature transients is one example of this challenge. Ammonia slipping from SCR catalyst typically passes through a platinum based ammonia oxidation catalyst (AMOx), leading to the formation of the undesired byproducts NOx and N2O. We have discovered a distinctive characteristic, an overlapping NH3 desorption and oxidation, in a state-of-the-art Cu-zeolite SCR catalyst that can minimize NH3 slip during temperature transients encountered in real-world operation of a vehicle.
Journal Article

Measurement of Dioxin and Furan Emissions during Transient and Multi-Mode Engine Operation

2011-04-12
2011-01-1158
This study analyzed the impact of transient and multi-mode engine conditions on emissions of dioxins and furans from a variety of diesel aftertreatment configurations. Exhaust aftertreatment systems included combinations of diesel oxidation catalyst, diesel particulate filter, and either Cu/zeolite or Fe/zeolite selective catalytic reduction catalyst. EPA method TO-9A was modified for proportional exhaust gas sampling, whereas EPA method 0023A was modified for raw exhaust gas sampling. Dioxin and furan emissions were first measured with modified method TO-9A during Federal Test Procedure transient cycles, but no toxic dioxins or furans were detected. Measurements were then taken with modified method 0023A during Ramped Mode Cycles-Supplemental Emissions Test experiments. Because more rigorous pre-cleaning and sample extraction procedures were used with this method and lower detection limits were achieved by the analytical laboratory, some dioxin and furan congeners were detected.
Technical Paper

Lean Breakthrough Phenomena Analysis for TWC OBD on a Natural Gas Engine using a Dual-Site Dynamic Oxygen Storage Capacity Model

2017-03-28
2017-01-0962
Oxygen storage capacity (OSC) is one of the most critical characteristics of a three-way catalyst (TWC) and is closely related to the catalyst aging and performance. In this study, a dynamic OSC model involving two oxygen storage sites with distinct kinetics was developed. The dual-site OSC model was validated on a bench reactor and a natural gas engine. The model was capable of predicting temperature dependence on OSC with H2, CO and CH4 as reductants. Also, the effects of oxygen concentration and space velocity on the amount of OSC were captured by the model. The validated OSC model was applied to simulate lean breakthrough phenomena with varied space velocities and oxygen concentrations. It is found that OSC during lean breakthrough is not a constant for a particular TWC catalyst and is dependent on space velocity and oxygen concentration. Specifically, breakthrough time exhibits a non-linear, inverse correlation to oxygen flux.
Technical Paper

Impact of Using Low Thermal Mass Turbine Housing on Exhaust Temperature with Implication on Aftertreatment Warm-Up Benefit for Emissions Reduction

2020-09-02
2020-01-5083
The present study examines the impact of using low thermal mass (LTM) turbine housing designs on the transient characteristics of the turbine outlet temperature for a light-duty diesel standard certification cycle (FTP75). For a controlled exhaust flow, the turbine outlet temperature will directly determine the impact on an aftertreatment system warm-up from a cold state, typical of engine-off and engine idling conditions. The performance of the aftertreatment system such as a Selective Catalytic Reduction (SCR) system is highly dependent on how quickly it warms up to its desirable temperature to be able to convert the harmful oxides of Nitrogen (NOx) to gaseous Nitrogen. Previous works have focused on mostly insulating the exhaust manifold and turbine housing to conserve the heat going into the aftertreatment system. The use of LTM turbine housing has not been previously considered as a means for addressing this requirement.
Technical Paper

Gear Whine Noise Due to Deformation- A Case Study

2017-03-28
2017-01-1122
Vehicle noise has reduced over the years due to the customer demand for quieter vehicles. As the background noises such as combustion noise, pumping noise, etc. have reduced, mechanical noises such as gear noise have become prominent and a major cause of customer complaints. Engine timing gear train uses gears for transferring torque to cam and accessory gears. As engines have become quieter by efforts to reduce the combustion noise, as well as, by moving away from mechanical fuel pumps to common rail fuel pumps, the gear train noise has come under increased scrutiny. Gear whine could be a result of multiple factors. Gear profile distortion is one of the factors. Gear torque variation also has a significant effect on gear whine. Operation of the accessory drives such as hydraulic pumps under variable loads and speeds, is one of the major challenges for resolving a gear whine issue in the engine gear train.
Journal Article

Gear Train Mesh Efficiency Study: The Effects of an Anti-Backlash Gear

2014-04-01
2014-01-1769
In recent years, the focus on engine parasitic losses has increased as a result of the efforts to increase engine efficiency and reduce greenhouse gasses. The engine gear train, used to time the valve system and drive auxiliary loads, contributes to the overall engine parasitic losses. Anti-backlash gears are often used in engine gear trains to reduce gear rattle noise resulting from the torsional excitation of the gear train by the engine output torque. Friction between sliding surfaces at the gear tooth is a major source of power loss in gear trains. The effect of using anti-backlash gears on the gear friction power loss is not well known. As a part of the effort to reduce parasitic losses, the increase in friction power loss in the Cummins ISX 15 gear train due to the anti-backlash gear was quantitatively determined by modifying the methods given in ISO 14179-2 to fit the anti-backlash gear sub-assembly.
Technical Paper

Gear Interference-Fit Joint Considerations and Design for the Resultant Tooth Distortion

2018-04-03
2018-01-1293
Automotive timing gear trains, transmission gearboxes, and wind turbine gearboxes are some of the application examples known to use interference-fit to attach the gear to the rotating shaft. This paper discusses the interference-fit joint design and the finite element analysis to demonstrate the distortion. The mechanism of tooth profile distortion due to the interference-fit assembly in gear trains is discussed by demonstrating the before and after assembly gear profile measurements. An algorithm to calculate the profile slope deviation change is presented. The effectiveness of the computational algorithm to predict the distortion is demonstrated by comparing with measurements. Finally, steps to mitigate the interference assembly effects are discussed.
Technical Paper

FEM Simulation Methodology for Accurately Capturing the Experimental Vibration Response of ECM Assembly on a Commercial Vehicle

2018-04-03
2018-01-0467
This paper presents an experimental setup and an equivalent FEM simulation methodology to accurately predict the response of Engine Control Module (ECM) assembly mounted on a commercial vehicle subjected to road vibrations. Comprehensive vibration study is carried out. It involved Modal characteristics determination followed by random vibration characterization of the ECM assembly. A hammer impact experiment is first performed in lab to estimate the natural frequencies and mode shapes of ECM assembly. Mounting conditions in test specimen are kept similar to the actual mounting settings on vehicle. Natural frequencies and mode shapes predicted from free vibration experiment are compared with finite element (FE) based modal analysis. The importance of capturing the assembly stiffness more accurately by incorporating pre-stress effects like bolt-pretension and gravity, is emphasized.
Technical Paper

Experimental and Kinetic Modeling of Degreened and Aged Three-way Catalysts: Aging Impact on Oxygen Storage Capacity and Catalyst Performance

2018-04-03
2018-01-0950
The aging impact on oxygen storage capacity (OSC) and catalyst performance was investigated on one degreened and one aged (hydrothermally aged at 955 °C for 50 h) commercial three-way catalyst (TWC) by experiments and modeling. The difference of OSC between the degreened and aged TWCs was dependent on catalyst temperature. The largest difference was found at 600 °C, at which the amount of OSC decreased by 45.5%. Catalyst performance was evaluated through lightoff tests at two simulated engine exhaust conditions (lean and rich) on a micro-reactor. The aging impact on the catalyst performance was different under lean and rich environments and investigated separately. At the lean condition, oxidation of CO and C3H6 was significantly suppressed while oxidation of C3H8 was relatively less degraded. At the rich condition, the inhibition effect was more pronounced on the aged TWC and inhibiting hydrocarbon species from C3H6 partial oxidation can survive at temperatures up to 450 °C.
Journal Article

Effect of Transition Metal Ion Properties on the Catalytic Functions and Sulfation Behavior of Zeolite-Based SCR Catalysts

2017-03-28
2017-01-0939
Copper- and Iron- based metal-zeolite SCR catalysts are widely used in US and European diesel aftertreatment systems to achieve drastic reduction in NOx emission. These catalysts are highly selective to N2 under wide range of operating conditions. Nevertheless, the type of transition metal has a significant impact on the key performance and durability parameters such as NOx conversion, selectivity towards N2O, hydrothermal stability, and sensitivity to fuel sulfur content. In this study, we explained the differences in the performance characteristics of these catalysts based on their relative acidic-basic nature of transition metal present in these catalysts using practically relevant gas species present in diesel exhaust such as NO2, SOx, and NH3. These experiments show that Fe-zeolite has relatively acidic nature as compared to Cu-zeolite that causes NH3 inhibition and hence explains low NOx conversion on Fe-zeolite at low temperature under standard SCR conditions.
Technical Paper

Durability Test Suite Optimization Based on Physics of Failure

2018-04-03
2018-01-0792
Dynamometer (dyno) durability testing plays a significant role in reliability and durability assessment of commercial engines. Frequently, durability test procedures are based on warranty history and corresponding component failure modes. Evolution of engine designs, operating conditions, electronic control features, and diagnostic limits have created challenges to historical-based testing approaches. A physics-based methodology, known as Load Matrix, is described to counteract these challenges. The technique, developed by AVL, is based on damage factor models for subsystem and component failure modes (e.g. fatigue, wear, degradation, deposits) and knowledge of customer duty cycles. By correlating dyno test to field conditions in quantifiable terms, such as customer equivalent miles, more effective and efficient durability test suites and test procedures can be utilized. To this end, application of Load Matrix to a heavy-duty diesel engine is presented.
Journal Article

Durability Study of a High Pressure Common Rail Fuel Injection System Using Lubricity Additive Dosed Gasoline-Like Fuel - Additional Cycle Runtime and Teardown Analysis

2019-04-02
2019-01-0263
This study is a continuation of previous work assessing the robustness of a Cummins XPI common rail injection system operating with gasoline-like fuel. All the hardware from the original study was retained except for the high pressure pump head and check valves which were replaced due to cavitation damage. An additional 400 hour NATO cycle was run on the refurbished fuel system to achieve a total exposure time of 800 hours and detect any other significant failure modes. As in the initial investigation, fuel system parameters including pressures, temperatures and flow rates were logged on a test bench to monitor performance over time. Fuel and lubricant samples were taken every 50 hours to assess fuel consistency, metallic wear, and interaction between fuel and oil. High fidelity driving torque and flow measurements were made to compare overall system performance when operating with both diesel and light distillate fuel.
Technical Paper

Diesel Engines Gear Whine: Production Plant Perspective

2017-06-05
2017-01-1809
Engine noise is one of the significant aspects of product quality for light and medium duty diesel engine market applications. Gear whine is one of those noise issues, which is considered objectionable and impacts the customer’s perception of the product quality. Gear whine could result due to defects in the gear manufacturing process and/or due to inaccurate design of the gear macro and micro geometry. The focus of this technical paper is to discuss gear whine considerations from the production plant perspective. This includes quick overview of the measurement process, test cell environment, noise acceptance criteria considerations. A gear whine case study is presented based on the data collected in the test cell at the engine plant. Gear whine data acquired on current product and next generation of prototype engines is analyzed and presented. This paper concludes by highlighting the lessons learned from the case study.
Technical Paper

Diesel Engine Cylinder Deactivation for Improved System Performance over Transient Real-World Drive Cycles

2018-04-03
2018-01-0880
Effective control of exhaust emissions from modern diesel engines requires the use of aftertreatment systems. Elevated aftertreatment component temperatures are required for engine-out emissions reductions to acceptable tailpipe limits. Maintaining elevated aftertreatment components temperatures is particularly problematic during prolonged low speed, low load operation of the engine (i.e. idle, creep, stop and go traffic), on account of low engine-outlet temperatures during these operating conditions. Conventional techniques to achieve elevated aftertreatment component temperatures include delayed fuel injections and over-squeezing the turbocharger, both of which result in a significant fuel consumption penalty. Cylinder deactivation (CDA) has been studied as a candidate strategy to maintain favorable aftertreatment temperatures, in a fuel efficient manner, via reduced airflow through the engine.
Technical Paper

Development of a New 13L Heavy-Duty Diesel Engine Using Analysis-Led Design

2008-06-23
2008-01-1515
The paper covers the design and development of a new 13L heavy-duty diesel engine intended primarily for heavy truck applications in China. It provides information on the specific characteristics of the engine that make it particularly suitable for operation in China, and describes in detail some of the design techniques that were used. To meet these exacting requirements, extensive use was made of Analysis-Led Design, which allows components, sub-systems and the entire engine, aftertreatment and vehicle system to be modeled before designs are taken to prototype hardware. This enables a level of system and sub-system optimization not previously available. The paper describes the emissions strategy for China, and the physical design strategy for the new engine, and provides some engine performance robustness details. The engine architecture is discussed and the paper details the analysis of the major components - cylinder block, head, head seal, power cylinder and bearings.
Technical Paper

Development of a Kinetic Model to Evaluate Water Storage on Commercial Cu-Zeolite SCR Catalysts during Cold Start

2017-03-28
2017-01-0968
Commercial Cu-Zeolite SCR catalyst can store and subsequently release significant amount of H2O. The process is accompanied by large heat effects. It is critical to model this phenomenon to design aftertreatment systems and to provide robust tuning strategies to meet cold start emissions and low temperature operation. The complex reaction mechanism of water adsorption and desorption over a Cu-exchanged SAPO-34 catalyst at low temperature was studied through steady state and transient experiments. Steady state isotherms were generated using a gravimetric method and then utilized to predict water storage interactions with respect to feed concentration and catalyst temperature. Transient temperature programmed desorption (TPD) experiments provided the kinetic information required to develop a global kinetic model from the experimental data. The model captures fundamental characteristics of water adsorption and desorption accompanied by the heat effects.
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