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To comply with increasingly strict emission regulations, diesel vehicles are equipped with Diesel Particulate Filters (DPF) to capture fine particulate matter (PM) from exhaust gas. However, due to the limited capacity of DPF to capture soot, periodic regeneration processing is required to burn it off. The ash created by metal-based additives in engine oil accumulates in DPF, leading to issues such as increased regeneration frequency and decreased fuel efficiency. To solve this problem, researchers have developed diesel engine oil with reduced ash content. However, the authors are taking it a step further and developing a diesel engine oil without metal-based detergents and anti-wear additives, for even more significant environmental impact reduction. This paper describes the development of an ashless engine oil with DH-2 performance, the effects of the developed engine oil on DPF, and the results of engine and actual field tests.

Recently, deposition of ash derived from engine oil on the surface of a diesel particle filter (DPF) has been reported to worsen the performance of the DPF. It is generally known that phosphorus in engine oil is adsorbed on the surface of an automotive exhaust catalyst and reduces the performance of the catalyst. Thus, the amounts of ash and phosphorus in engine oil have been decreased. We have developed a non-phosphorus and non-ash engine oil (NPNA) that does not contain metal-based detergents and zinc dialkyldithiophosphate (ZnDTP). We performed a performance test for NPNA using an actual engine and reported that the piston detergency and anti-wear performance of NPNA were sufficiently high. However, the piston detergency of NPNA required further improvement when engine running conditions were more severe.

In order to clarify the relationship between the chemical structure of PAG (polyalkylene glycol) and the performance characteristics as the refrigeration lubricants used for HFC134a, performance tests were conducted using PAGs with different end groups and alkylene oxide chains in the presence of HFC134a. Newly developed dimethyl ether capped PAGs having more than 70 mol.% PO (propylene oxide) to less than 30 mol.% EO (ethylene oxide) as a monomer ratio were the most preferable of all PAGs tested. The refrigeration lubricants using these PAGs have been successfully introduced into the market for mobile air conditioning systems with refrigerant HFC134a.

In order to achieve the highest power output and lowest fuel consumption for the rotary engine in endurance race such as Le Mans, two types of lubricating oils were developed by conducting a single - rotor engine test at the rotational speed of 7500 rpm under full load. One was the engine oil for the lubrication of the combustion chamber. The other was a so - called system oil for lubrication of the engine system outside the combustion chamber. The conclusions obtained from the development are as follows: 1) Engine oil for the combustion chamber The engine oil greatly influences spitback phenomenon1) which can cause rotary engine trouble in an endurance race. The spitback phenomenon is decreased by the decrease of carbonaceous deposit and ash in the apex seal grooves.

Engine oils normally contain calcium detergents and ZnDTPs to have detergency and antiwear performance. However, it has been recently understood that these additives could deteriorate filter performance in catalyst and DPF. In this background this paper explains the study and the development about new type of engine oil excluding metal detergents and phosphorus compounds. The developed engine oil shows good durability in several JASO engine tests and a fleet test by formulating newly developed additives as substitute for calcium detergents and ZnDTPs.

1 Fuel savings by engine oil have been requested for two-wheeled vehicles from the viewpoint of environmental issues. In four-wheeled vehicles, reduction of oil viscosity and addition of friction modifiers have been effective in improving fuel efficiency. However, direct application of engine oil for four-wheeled vehicles to two-wheeled vehicles is difficult. In a four-cycle two-wheeled vehicle, the transmission, gears, and a wet clutch system are imbedded within the engine1). Engine oil must display a remarkable performance as it is required to function as transmission oil and to improve anti-metal fatigue life and clutch performance2), 3). If fuel efficiency is improved by reducing the viscosity of engine oil used in two-wheeled vehicles, the fatigue life tends to worsen. Therefore, reduction in oil viscosity is difficult to achieve.

Although it has been reported that the increase of base oil viscosity and the selection of suitable VII (Viscosity Index Improver) are key factors to improve metal fatigue life for the development of low viscosity ATF, the problem of gear fatigue life has not been perfectly solved. In this study, the effect of VII on gear fatigue life was evaluated by using EHD film thickness measurement and the block on ring friction tester. Based on the study, the low viscosity ATF that has good anti-pitting performance in gears can be proposed by optimizing the combination of base oil and VII.

Modern formulation in a wide variety of lubricants including engine oils and transmission fluids is designed to control friction through film-forming tribochemical reactions induced by the functional additives mixtures. Although many cases on the synergistic or antagonistic effects of additives on friction have been reported, their mechanisms are poorly understood. This study focused on the influences of metallic detergents on tribochemical reactions. We examined the mechanical properties of detergent-containing lubricants confined at a single-asperity contact and their contributions to tribochemical phenomena. We found that detergents enlarged the confinement space required for generating repulsive force and shear resistance. This means that these detergents provide steric effects under nanoconfinement at interfacial contacts.

A new after-treatment system called DPNR (Diesel Particulate-NOx Reduction System) has been developed for simultaneous and continuous reduction of particulate matter (PM) and nitrogen oxides (NOx) in diesel exhaust gas. This system consists of both a new catalytic technology and a new diesel combustion technology which enables rich operating conditions in diesel engines. The catalytic converter for the DPNR has a newly developed porous ceramic structure coated with a NOx storage reduction catalyst. A fresh DPNR catalyst reduced more than 80 % of both PM and NOx. This paper describes the concept and performance of the system in detail. Especially, the details of the PM oxidation mechanism in DPNR are described.

A program with title of “Development of automobile and fuel technologies for air quality improvement (Japan Clean Air Program - abbreviated to JCAP) has been conducted as a five-year program. Under the program, an influence of fuel quality on automobile technology has been evaluated, and effect of air quality improvement due to implementation of automobile exhaust emission regulations has also been evaluated by using air quality models. Through the five years of JCAP activities from FY 1997 to FY 2001, following items have been evaluated: an influence of fuel properties and automobile exhaust emission reduction technologies, an evaluation of aftertreatment devices equipped on in-use vehicles, a detailed analysis of fuel properties and exhaust emissions, a prediction of air quality improvement effects due to the implementation of next stage stringent automobile exhaust emission regulations.

High viscosity index(HVI) petroleum base stock, with excellent temperature-viscosity characteristics, oxidation resistance, and low-evaporation properties, offers advantages as the base stock for high fuel economy engine oils, particularly because of its low-friction properties in the boundary and/or “E.H.L (Elastohydrodynamic Lubrication)” area due to its rheological characteristics. This research evaluated HVI base stock's low-friction properties. Upgrading the oil from 5W-30 to 5W-20 was also investigated. The friction properties of the HVI base stock were measured by a unit friction platform. The results show a 28% reduction in friction coefficient compared with the conventional, solvent refined oil, which is attributable to the high-pressure viscosity of the base oil.

The deposition of ash derived from engine oil on the surface of diesel particle filters (DPF) has recently been reported to degrade the performance of the DPF. It is generally known that phosphorus in engine oil is adsorbed on the surface of an automotive exhaust catalyst, reducing the performance of the catalyst. Thus, the amounts of ash and phosphorus in engine oil have been decreased. We have developed a non-phosphorus, non-ash engine oil (NPNA) that does not contain metal-based detergents or zinc dialkyldithiophosphate (ZnDTP). Various engine tests were performed, and we confirmed that under normal running conditions, the NPNA oil had a sufficiently high piston detergency and wear resistance-two important requirements for engine oil-to meet current American and Japanese standards. However, the piston detergency of NPNA required further improvement when engine running conditions were more severe.

As well as a four-wheeled vehicle, in the field of motorcycle, development of the CO2 reduction technology and practical use are required for global environment. Zinc dialkyldithiophosphate (Zn-DTP) type additives are widely used for engine oil formulations. However, phosphorus compounds are environmental load materials. The reduction of the quantity of phosphorus compounds in engine oils is required to reduce poisoning of three-way catalysts used to purify exhaust gases from internal combustion engines. Ito1) reported that they developed a sulfur-based additive as a substitute for Zn-DTP. Their non-phosphorus engine oil formulation for four-wheeled vehicles with a sulfur-based additive was examined to evaluate its anti-wear performance using the following test methods: JASO M328 for gasoline engines (KA24E) and JASO M354 for Diesel engine (4D34T4).

Just as CO2 reduction is required of four wheeled vehicles for environmental protection, similar environmental concerns drive the development of motorcycle oil technology. Zinc dialkyldithiophosphate (Zn-DTP) type additives are widely used for engine oil formulations. However, phosphorus compounds are environmental load materials. The reduction of the quantity of phosphorus compounds in engine oils is required to reduce poisoning of three-way catalysts used to purify exhaust gases from internal combustion engines. Mr. Ito and his co-authors1) reported that they developed a sulfur-based additive as a substitute for Zn-DTP. Their non-phosphorus engine oil formulation for four-wheeled vehicles with a sulfur-based additive was examined to evaluate its anti-wear performance using the following test methods:JASO M328 for gasoline engines (KA24E) and JASO M354 for Diesel engine (4D34T4).

Air Quality Modeling Working Group developed two models to evaluate effects of automobile emission reduction measures on air quality improvement: Urban Air Quality Simulation Model in which secondary aerosol formation processes have been incorporated, and Roadside Air Quality Simulation Model in which micro-scale traffic flow has been taken into consideration. Concretely, a model has been built up for estimating SPM concentration in ambient air in which high concentrated air pollutants have been contained during summer and winter. The model has been built up by using UAM (Urban Airshed Model) as base model, and the following modification has been made to the base model. First, ISSOROPIA (secondary inorganic aerosol equilibrium model) has been added to the base model, and a secondary organic aerosol formation/reaction model (SOA model) has been incorporated into the model.

The use of Automatic Transmission Fluids (ATFs) with lower viscosity and excellent anti-shudder durability for wet clutch system will be effective for improving fuel saving performance in automatic transmissions. In this study, two ATF formulation techniques were examined. The first trial formulation is to improve fatigue life in gear components even if a lower viscosity ATF is used. The second one is to improve anti-shudder durability for wet lock-up clutch system in AT units. As to fatigue life performance, the relation between molecular weight of Viscosity Index Improver (VII) and film formation property in EHL contact regions were experimentally investigated. ATFs containing VIIs with lower molecular weight tend to increasing EHL film thickness, resulting in a longer gear pitting fatigue life. Calcium detergents and ashless friction modifiers in ATFs were found to give a great impact on the anti-shudder performance.

Crosscheck tests of fast electrical mobility spectrometers, Differential Mobility Spectroscopy (DMS) and Engine Exhaust Particle Sizer(EEPS), were conducted to evaluate the accuracy of fine particle measurement. Two kinds of particles were used as test particles for the crosscheck test of instruments: particles emitted from diesel vehicles and diluted in a full dilution tunnel, and particles generated by CAST. In the steady state tests, it was confirmed that the average concentration of each instrument was within the range of ±2σ from the average concentration of all the same type of instruments. In the transient tests, it is verified that the instruments have almost equal sensitivity. For application of the fast electrical mobility spectrometers to evaluation of particle number and size distributions, it is essential to develop a calibration method using reference particle counters and sizers (CPC, SMPS, etc.) and maintenance methods appropriate for each model.

The study of 10% ethanol blended gasoline (E10 gasoline) utilization has been conducted in the Japan Auto-Oil Program (JATOP). In order to clarify the impact of E10 gasoline on vehicle performances, exhaust emissions, evaporative emissions, driveability and material compatibility have been investigated by using domestic gasoline vehicles including mini motor vehicles which are particular to Japan. The test results reveal that E10 gasoline has no impact on exhaust emissions, engine startup time and acceleration period under the hot start condition, but a slight deterioration is observed in some test cases under the cold start condition using E10 gasolines with 50% distillation temperature (T50) level set to the upper limit of Japanese Industrial Standards (JIS) K 2202. Regarding evaporative emissions, the tested vehicles shows no remarkable increase in the hot soak loss (HSL), diurnal breathing loss (DBL) and running loss (RL) testing with E10 gasolines.

Due to increasing demands for further CO2 reduction and tighter exhaust emissions regulations, automakers are increasingly downsizing turbo-charged diesel engines by raising specific power, or adopting low-pressure loop exhaust gas recirculation (LPL-EGR) systems to improve the EGR rate. However, adopting a higher boost pressure to increase the specific power, or introducing hot exhaust gas before the turbocharger compressor with the LPL-EGR system creates higher gas temperatures in the compressor, which results in soot-containing deposits derived from the engine oil in the compressor. This phenomenon causes significant deterioration of turbocharger efficiency. Therefore, countermeasures such as restricting boost pressure or limiting EGR usage in the operational map are necessary to prevent engine performance deterioration. Increasing the gas temperature in the compressor while preventing deposit formation should enable further improvements in fuel consumption and engine power.

One issue of downsized and supercharged engines is low-speed pre-ignition (LSPI) that occurs in the low-speed and high-load operating region. One proposed cause of LSPI is the influence of the engine oil and its additives. However, the effect of engine oil additives on pre-ignition and the mechanism involved are still not fully understood. This study investigated the influence of engine oil additives on abnormal combustion in a spark-ignition engine. A four-stroke air-cooled single-cylinder engine with a side valve arrangement was used in conducting combustion experiments. The research methods used were in-cylinder pressure analysis, in-cylinder visualization and absorption spectroscopic analysis. Engine oil additives were mixed individually at a fixed concentration into a primary reference fuel with an octane number of 50 and their effect on knocking was investigated.