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A program has been completed to evaluate ultra-low sulfur diesel fuels and passive diesel particulate filters (DPFs) in truck and bus fleets operating in southern California. The fuels, ECD and ECD-1, are produced by ARCO (a BP Company) and have less than 15 ppm sulfur content. Vehicles were retrofitted with two types of catalyzed DPFs, and operated on ultra-low sulfur diesel fuel for over one year. Exhaust emissions, fuel economy and operating cost data were collected for the test vehicles, and compared with baseline control vehicles. Regulated emissions are presented from two rounds of tests. The first round emissions tests were conducted shortly after the vehicles were retrofitted with the DPFs. The second round emissions tests were conducted following approximately one year of operation. Several of the vehicles retrofitted with DPFs accumulated well over 100,000 miles of operation between test rounds.

In April 2003, a small field study was initiated to evaluate the effect of lube oil formulations on ash accumulation in heavy-duty diesel DPFs. Nine (9) Fuel Delivery Trucks were retrofitted with passive diesel particulate filters and fueled with ultra low sulfur diesel which contains less than 15 ppm sulfur. Each vehicle operated in the field for 18 months or approximately 160,000 miles (241,401 km) using one of three lube oil formulations. Ash accumulation was determined for each vehicle and compared between the three differing lube oil formulations. Ash analyses, used lube oil analysis and filter substrate evaluations were performed to provide a complete picture of DPF operations. The evaluation also examined some of the key parameters that allows for the successful implementation of the passive DPF in this heavy-duty application.

In urban areas, particulate emission from diesel engines is one of the pollutants of most concern. As a result, particulate emission control from urban bus diesel engines using particle filter technology is being evaluated at several locations in the US. A project entitled, “Clean Diesel Vehicle Air Quality Project” has been initiated by NY City Transit under the supervision of NYSDEC and with active participation from several industry partners. Under this program, 25 NY City transit buses with DDC Series 50 engines have been equipped with continuously regenerating diesel particulate filter systems and have been operating with ultra low sulfur diesel (< 30 ppm S) in transit service in Manhattan since February 2000. These buses were evaluated over a 9 month period for operations, maintainability and durability of the particulate filter.

Particulate emission from diesel engines is one of the most important pollutants in urban areas. As a result, particulate emission control from urban bus diesel engines using particle filter technology is being evaluated at several locations in the US. A project entitled “Clean Diesel Demonstration Program” has been initiated by NY City Transit under the supervision of NY State DEC and with active participation from several industrial partners. Under this program, several NY City transit buses with DDC Series 50 engines have been equipped with continuously regenerating diesel particulate filter system and are operating with ultra low sulfur diesel (< 30 ppm S) in transit service in Manhattan since February 2000. These buses are being evaluated over a 8-9 month period for operations, maintainability and durability of the particulate filter.

The temporary deactivation of the selective catalytic reduction (SCR) device due to malfunction requires the engine control to engage multiple engine-out calibrations. Further, it is expected that emitted particles will be different in composition, size and morphology when an engine, which meets the 2010 particulate matter (PM) gravimetric limits, is programmed with multiple maps. This study investigated the correlation between SCR-out/engine-out PM emissions from an 11-liter Volvo engine. Measurement of PM concentrations and size distributions were conducted under steady state and transient cycles. Ion Chromatograph analysis on gravimetric filters at the SCR-out has revealed the presence of sulfates. Two different PM size-distributions were generated over a single engine test mode in the accumulation mode region with the aid of a design of experiment (DOE) tool. The SCR-out PM size distributions were found to correlate with the two engine-out distributions.

Recently, the California Air Resources Board (CARB) has reported that tailpipe emission samples from a compressed natural gas (CNG)-fueled transit bus without aftertreatment had measurable levels of toxic compounds such as formaldehyde (HCHO) and nanoparticle (=50 nm) and mutagen emissions (Ames assay) that in some cases were greater than that of a similar diesel transit bus equipped with either a diesel oxidation catalyst (DOC) or a diesel particulate filter (DPF) and fueled by ultra-low sulfur diesel (ULSD) [1, 2, 3]. Therefore, CARB has investigated the effectiveness of oxidation catalyst (OC) control for CNG bus applications. This study includes results for regulated gaseous and non-methane hydrocarbon (NMHC) emissions, non-regulated hydrocarbon emissions of toxic risk significance, and total particulate matter (PM). Two driving cycles were investigated: the Central Business District (CBD) cycle and Steady-State (SS) cruise condition at 55 mph.

Alternative compression ignition engine fuels are of interest both to reduce emissions and to reduce U.S. petroleum fuel demand. A Malaysian Fischer-Tropsch gas-to-liquid fuel was compared with California #2 diesel by characterizing emissions from over the road Class 8 tractors with Caterpillar 3176 engines, using a chassis dynamometer and full scale dilution tunnel. The 5-Mile route was employed as the test schedule, with a test weight of 42,000 lb. Levels of oxides of nitrogen (NOx) were reduced by an average of 12% and particulate matter (PM) by 25% for the Fischer-Tropsch fuel over the California diesel fuel. Another distillate fuel produced catalytically from Fischer-Tropsch products originally derived from natural gas by Mossgas was also compared with 49-state #2 diesel by characterizing emissions from Detroit Diesel 6V-92 powered transit buses, three of them equipped with catalytic converters and rebuilt engines, and three without.

The application of oxidation catalyst and particulate filter technology for the reduction of particulate matter (PM), hydrocarbons (HC) and carbon monoxide (CO) emissions from heavy duty diesel engines has become an established practice. The design and performance of such systems have been commercially proven to the point that the application of these technologies is cost effective and durable. The application of an effective NOx reduction technology in heavy duty diesel applications is more complicated since there are no passive NOx reduction technologies that can be fit onto HDD vehicles. However, Selective Catalytic Reduction (SCR) systems using Urea injection to achieve NOx reduction have become the technology of choice in Europe and have been applied to achieve Euro IV emissions levels on new HDD vehicles. In addition, retrofit SCR emission control systems have also been developed that can provide high NOx reduction when applied on existing HDD vehicles.

A multi-year technology validation program was completed in 2001 to evaluate ultra-low sulfur diesel fuels and passive diesel particle filters (DPF) in several different diesel fleets operating in Southern California. The fuels used throughout the validation program were diesel fuels with less than 15-ppm sulfur content. Trucks and buses were retrofitted with two types of passive DPFs. Two rounds of emissions testing were performed to determine if there was any degradation in the emissions reduction. The results demonstrated robust emissions performance for each of the DPF technologies over a one-year period. Detailed descriptions of the overall program and results have been described in previous SAE publications [2, 3, 4, 5]. In 2002, a third round of emission testing was performed by NREL on a small subset of vehicles in the Ralphs Grocery Truck fleet that demonstrated continued robust emissions performance after two years of operation and over 220,000 miles.

The next generation advanced emission regulations have been proposed for the Indian heavy duty automotive industry for implementation from 2020. These BS VI emission regulations will require both advanced NOx control as well as advanced PM (Particulate Matter) control along with Particle Number limitations. This will require implementation of full DPF (Diesel Particulate Filter) and simultaneous NOx control using SCR technologies. DPF technologies have already been successfully implemented in Euro VI and US 10 HDD systems. These systems use low temperature NO2 based passive DPF regeneration as well as high temperature oxygen based active DPF regeneration. Effective DPF and DOC designs are essential to enable successful DPF regeneration (minimize soot loading in the DPF) while operating HDD vehicles under transient conditions. DOC designs are optimized to oxidize engine out NO into NO2, which helps with passive DPF regeneration.

The study was aimed at assessing in-use emissions of a USEPA 2010 emissions-compliant heavy-duty diesel vehicle powered by a model year (MY) 2011 engine using West Virginia University's Transportable Emissions Measurement System (TEMS). The TEMS houses full-scale CVS dilution tunnel and laboratory-grade emissions measurement systems, which are compliant with the Code of Federal Regulation (CFR), Title 40, Part 1065 [1] emissions measurement specifications. One of the specific objectives of the study, and the key topic of this paper, is the quantification of greenhouse gas (GHG) emissions (CO2, N2O and CH4) along with ammonia (NH3) and regulated emissions during real-world operation of a long-haul heavy-duty vehicle, equipped with a diesel particulate filter (DPF) and urea based selective catalytic reduction (SCR) aftertreatment system for PM and NOx reduction, respectively.

A fleet of six 2001 International Class 6 trucks operating in southern California was selected for an operability and emissions study using gas-to-liquid (GTL) fuel and catalyzed diesel particle filters (CDPF). Three vehicles were fueled with CARB specification diesel fuel and no emission control devices (current technology), and three vehicles were fueled with GTL fuel and retrofit with Johnson Matthey's CCRT™ diesel particulate filter. No engine modifications were made. Bench scale fuel-engine compatibility testing showed the GTL fuel had cold flow properties suitable for year-round use in southern California and was additized to meet current lubricity standards. Bench scale elastomer compatibility testing returned results similar to those of CARB specification diesel fuel. The GTL fuel met or exceeded ASTM D975 fuel properties. Researchers used a chassis dynamometer to test emissions over the City Suburban Heavy Vehicle Route (CSHVR) and New York City Bus (NYCB) cycles.

In order to comply with stringent 2010 US-Environmental Protection Agency (EPA) on-road, Heavy-Duty Diesel (HDD) emissions regulations, the Selective Catalytic Reduction (SCR) aftertreatment system has been judged by a multitude of engine manufacturers as the primary technology for mitigating emissions of oxides of nitrogen (NOx). As virtually stand-alone aftertreatment systems, SCR technology further represents a very flexible and efficient solution for retrofitting legacy diesel engines as the most straightforward means of cost-effective compliance attainment. However, the addition of a reducing agent injection system as well as the inherent operation limitations of the SCR system due to required catalyst bed temperatures introduce new, unique problems, most notably that of ammonia (NH₃) slip.

Diesel Particulate Filters (DPFs) are well assessed exhaust aftertreatment devices currently equipping almost every modern diesel engine to comply with the most stringent emission standards. However, an accurate estimation of soot content (loading) is critical to managing the regeneration of DPFs in order to attain optimal behavior of the whole engine-after-treatment assembly, and minimize fuel consumption. Real-time models can be used to address challenges posed by advanced control systems, such as the integration of the DPF with the engine or other critical aftertreatment components or to develop model-based OBD sensors. One of the major hurdles in such applications is the accurate estimation of engine Particulate Matter (PM) emissions as a function of time. Such data would be required as input data for any kind of accurate models. The most accurate way consists of employing soot sensors to gather the real transient soot emissions signal, which will serve as an input to the model.

Since early 2010, most new medium- and heavy-duty diesel vehicles in the US rely on urea-based Selective Catalytic Reduction (SCR) technology for meeting the most stringent regulations on nitrogen oxides (NOx) emissions in the world today. Catalyst technologies of choice include Copper (Cu)- and Iron (Fe)-based SCR. In this work, the performances of Fe-SCR and Cu-SCR were investigated in the most commonly used DOC + CSF + SCR system configuration. Cu-SCR offered advantages over Fe-SCR in terms of low temperature conversion, NO₂:NOx ratio tolerance and NH₃ slip, while Fe-SCR demonstrated superior performance under optimized NO₂:NOx ratio and at higher temperatures. The Cu-SCR catalyst displayed less tolerance to sulfur (S) exposure. Reactor testing has shown that Cu-SCR catalysts deactivate at low temperature when poisoned by sulfur.

For engine operations involving low load conditions for an extended amount of time, the exhaust temperature may be lower than that necessary to initiate the urea hydrolyzation. This would necessitate that the controller interrupt the urea supply to prevent catalyst fouling by products of ammonia decomposition. Therefore, it is necessary for the engine controller to have multiple calibrations available in regions of engine operation where the aftertreatment does not perform well, so that optimal exhaust conditions are guaranteed during the wide variety of engine operations. In this study the test engine was equipped with a catalyzed diesel particulate filter (DPF) and a selective catalytic reduction system (SCR), and programmed with two different engine calibrations, namely the low-NOx and the low fuel consumption (low-FC).

Particulate emission control from diesel engines is one of the major concerns in the urban areas in California. Recently, regulations have been proposed for stringent PM emission requirements from both existing and new diesel engines. As a result, particulate emission control from urban diesel engines using advanced particulate filter technology is being evaluated at several locations in California. Although ceramic based particle filters are well known for high PM reductions, the lack of effective and durable regeneration system has limited their applications. The continuously regenerated diesel particulate filter (CRDPF) technology discussed in this presentation, solves this problem by catalytically oxidizing NO present in the diesel exhaust to NO2 which is utilized to continuously combust the engine soot under the typical diesel engine operating condition.

Particulate emission from diesel engines is one of the most important pollutants in urban areas. With increasing worldwide regulatory requirements to lower particulate matter (PM) standards for heavy duty diesel powered vehicles, the interest in diesel particulate filter based emission control solutions such as the Continuously Regenerating Technology (CRT®) have significantly increased. This system has been applied to thousands of heavy-duty diesel vehicles in Europe over the last six years to meet various local and governmental requirements, while recently introduced in the US. Among the numerous demonstration programs taking place in the US, one important one is the evaluation of CRT filter systems on urban transit buses in NY City. Here, several NY City transit buses with DDC Series 50 engines have been equipped with CRT filters and operating on ultra low sulfur diesel (< 30 ppm S) in transit service in Manhattan since February 2000.

The modern Diesel engine is one of the most versatile power sources available for mobile applications. The high fuel economy and torque of the Diesel engine has long resulted in global application for heavy-duty applications. Moreover, the high power and excellent driveability of today's turbo-charged small high-speed Diesel engines, coupled with their low CO2 emissions, has resulted in an increasing demand for Diesel powered light-duty vehicles. However, the demand for Diesel vehicles can only be realised if their exhaust emissions meet the increasingly stringent emissions legislation being introduced around the world. In the USA, both HDD and LDD vehicles are meeting strict emissions legislations since 2007 with the introduction of particle filters which will be further restricted from 2010 with the use of additional NOx contr5ol systems. In Europe, similar strict requirements are being implemented with Euro IV, Euro V and finally through Euro VI legislations.

The Air Resources Board (ARB) led a multi-division, multi-agency research effort to collect emissions data from two late-model heavy-duty transit buses in three different configurations. The objectives of the study were 1) to assess driving cycle effects, 2) to evaluate toxicity between new and “clean” heavy duty engine technologies in use in California, and 3) to investigate total PM and ultrafine particle emissions. Chassis dynamometer testing was conducted at ARB's Heavy-duty Emissions Testing Laboratory (HDETL) in Los Angeles. The impetus behind this work was to compare the emissions from transit buses powered by similar engines and fueled by Emission Control Diesel (ECD-1) and compressed natural gas (CNG).