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In order to meet the requirements in the stringent emission regulations, more and more research work has been focused on homogeneous charge compression ignition (HCCI) and partially premixed combustion (PPC) or partially premixed compression ignition (PCCI) as they have the potential to produce low NOx and soot emissions without adverse effects on engine efficiency. The mixture formation and charge stratification influence the combustion behavior and emissions for PPC/PCCI, significantly. An ultra-high speed burst-mode laser is used to capture the mixture formation process from the start of injection until several CADs after the start of combustion in a single cycle. To the authors’ best knowledge, this is the first time that such a high temporal resolution, i.e. 0.2 CAD, PLIF could be accomplished for imaging of the in-cylinder mixing process. The capability of resolving single cycles allows for the influence of cycle-to-cycle variations to be eliminated.

A phosphor thermometry, for measurements of two-dimensional gas-phase temperature was examined in turbulent combustion in an engine. The reasonable temperature deviation and the agreement with calculated data within 5% precision were achieved by single-shot images in the ignition process of compression ignition engine. Focusing on the local flame kernel, the flame structure could be quantitatively given by the temperature. It became evident that the HCCI flame kernels had 1-3 mm diameter and the isolated island structures. Subsequently, the HTR zone consisted of the combined flame kernels near TDC.

Phosphor thermometry was used during fuel injection in an optical engine with the glass piston of reentrant type. SiO2 coated phosphor particle was used for the gas-phase temperature measurements, which gave much less background signal. The measurements were performed in motored mode, in combustion mode with injection of n-heptane and in non-combustion mode with injection of iso-octane. In the beginning of injection period, the mean temperature of each injection cases was lower than that of the motored case, and temperature of iso-octane injection cases was even lower than that of n-heptane injection cases. This indicates, even if vaporization effect seemed to be the same at both injection cases, the effect of temperature decrease changed due to the chemical reaction effect for the n-heptane cases. Chemical reaction seems to be initiated outside of the fuel liquid spray and the position was moving towards the fuel rich area as the time proceeds.

In a previous study, in order to investigate the effect of charge stratification on combustion behavior such as combustion efficiency and combustion phasing which also largely affects the emissions, an experiment was conducted in a heavy-duty compression ignition (CI) metal engine. The engine behavior and emission characteristics were studied in the transition from HCCI mode to PPC mode by varying the start of injection (SOI) timing. To gain more detailed information of the mixing process, in-cylinder laser diagnostic measurements, namely fuel-tracer planar laser induced fluorescence (PLIF) imaging, were conducted in an optical version of the heavy-duty CI engine mentioned above. To the authors’ best knowledge, this is the first time to perform fuel-tracer PLIF measurements in an optical engine with a close to production bowl in piston combustion chamber, under transition conditions from HCCI to PPC mode.

The Homogeneous Charge Compression Ignition (HCCI) combustion progress has been characterized by means of high-speed fuel tracer Planar Laser Induced Fluorescence (PLIF) combined with simultaneous chemiluminescence imaging. Imaging has been conducted using a high-speed laser and detector system. The system can acquire a sequence of eight images within less than one crank angle. The engine was run at 1200 rpm on iso-octane or ethanol and a slight amount of acetone was added as a fuel tracer, providing a marker for the unburned areas. The PLIF sequences showed that, during the first stage of combustion, a well distributed decay of fuel concentration occurs. During the later parts of the combustion process the fuel concentration images present much more structure, with distinct edges between islands of unburned fuel and products.

Under the borderline autoignition conditions experienced during cold-starting of diesel engines, the amount and composition of residual gases may play a deterministic role. Among the intermediate species produced by misfiring and partially firing cycles, formaldehyde (HCHO) is produced in significant enough amounts and is sufficiently stable to persist through the exhaust and intake strokes to kinetically affect autoignition of the following engine cycle. In this work, the effect of HCHO addition at various phases of autoignition of n-heptane-air mixtures is kinetically modeled. Results show that HCHO has a retarding effect on the earliest low-temperature heat release (LTHR) phase, largely by competition for hydroxyl (OH) radicals which inhibits fuel decomposition. Conversely, post-LTHR, the presence of HCHO accelerates the occurrence of high-temperature ignition.

Simultaneous formaldehyde and OH PLIF have been applied in a direct-injected HCCI engine. The engine is a 0.5 l single-cylinder optical engine equipped with EGR system. PLIF measurements were performed with the engine run with two different fuels of low and high volatility, respectively. Different ratios of EGR were also examined. The aim of the study was to investigate how fuels with different volatility and EGR affect the HCCI combustion and measurements were performed for early and late injection timings. Measurements are presented for different injection timings showing formaldehyde and OH from start of injection until late in the expansion stroke. Also, formaldehyde distributions obtained from after the low temperature regime and before the high temperature regime are studied for different tuning of the start of injection from 300CAD to 20CAD before top dead center.

Misfiring or partial combustion during diesel engine operation results in the production of partial oxidation products such as ethylene (C₂H₄), carbon monoxide and aldehydes, in particular formaldehyde (HCHO). These compounds remain in the cylinder as residual gases to participate in the following engine cycle. Carbon monoxide and formaldehyde have been shown to exhibit a dual nature, retarding ignition in one temperature regime, yet decreasing ignition delay periods of hydrocarbon mixtures as temperatures exceed 1000°K. Largely unknown is the synergistic effects of such species. In this work, varying amounts of C₂H₄ and HCHO are added to the intake air of a naturally aspirated optical diesel engine and their combined effect on autoignition and subsequent combustion is examined. To observe the effect of these dopants on the low-temperature heat release (LTHR), ultraviolet chemiluminescent images are recorded using intensified CCD cameras.

In-cylinder heat losses in diesel engines decrease engine efficiency significantly and account for approximately 14-19% [1, 2, 3] of the injected fuel energy. A great part of the heat losses during diesel combustion presumably arises from the flame impingement onto the piston. Therefore, the present study investigates the heat losses during flame impingement onto the piston bowl wall experimentally. The measurements were performed on a full metal heavy-duty diesel engine with a small optical access through a removed exhaust valve. The surface temperature at the impingement point of the flame was determined by evaluating a phosphor’s temperature dependent emission decay. Simultaneous cylinder pressure measurements and high-speed videos are associated to the surface temperature measurements in each cycle. Thus, surface temperature readings could be linked to specific impingement and combustion events.

In this work the pre- to main chamber ignition process is studied in a Wärtsilä 34SG spark-ignited lean burn four-stroke large bore optical engine (bore 340 mm) operating on natural gas. Unburnt and burnt gas regions in planar cross-sections of the combustion chamber are identified by means of planar laser induced fluorescence (PLIF) from acetone seeded to the fuel. The emerging jets from the pre-chamber, the ignition process and early flame propagation are studied. Measurements reveal the presence of a significant temporal delay between the occurrence of a pressure difference across the pre-chamber holes and the appearance of hot burnt/burning gases at the nozzle exit. Variations in the delay affect the combustion timing and duration. The combustion rate in the pre-chamber does not influence the jet propagation speed, although it still has an effect on the overall combustion duration.

Simultaneous laser induced fluorescence (LIF) imaging of formaldehyde and a fuel-tracer have been performed in a direct-injection HCCI engine. A mix of N-heptane and iso-octane was used as fuel and Toluene as fluorescent tracer. The experimental setup involves two pulsed Nd:YAG lasers and two ICCD cameras. Frequency quadrupled laser radiation at 266 nm from one of the Nd:YAG lasers was used for excitation of the fuel tracer. The resulting fluorescence was detected with one of the ICCD cameras in the spectral region 270-320 nm. The second laser system provided frequency tripled radiation at 355 nm for excitation of Formaldehyde. Detection in the range 395-500 nm was achieved with the second ICCD. The aim of the presented work is to investigate the applicability of utilizing formaldehyde as a naturally occurring fuel marker. Formaldehyde is formed in the low temperature reactions (LTR) prior to the main combustion and should thus be present were fuel is located until it is consumed.

The effects of injection pressure and swirl ratio on the in-cylinder soot oxidation are studied using simultaneous PLIF imaging of OH and LII imaging of soot in an optical diesel engine. Images are acquired after the end of injection in the recirculation zone between two adjacent diesel jets. Scalars are extracted from the images and compared with trends in engine-out soot emissions. The soot emissions decrease monotonically with increasing injection pressure but show a non-linear dependence on swirl ratio. The total amount of OH in the images is negatively correlated with the soot emissions, as is the spatial proximity between the OH and soot regions. This indicates that OH is an important soot oxidizer and that it needs to be located close to the soot to perform this function. The total amount of soot in the images shows no apparent correlation with the soot emissions, indicating that the amount of soot formed is a poor predictor of the emission trends.

Simultaneous OH- and formaldehyde LIF measurements have been performed in an HCCI engine using two laser sources working on 283 and 355 nm, respectively. Two ICCD camera systems, equipped with long-pass filters, were used to collect the LIF signals. The simultaneous images of OH and formaldehyde were compared with heat-release calculated from the pressure-trace matching the cycle for the LIF measurements. The measurements were performed on a 0.5 l single-cylinder optical engine equipped with port-fuel injection system. A blend of iso-octane and n-heptane was used as fuel and the compression ratio was set to 12:1. The width of the laser sheet was 40 mm and hence covered approximately half of the cylinder bore. At some 20 CAD BTDC low temperature reactions is present and formaldehyde is formed. The formaldehyde signal is then rather constant until the main heat-release starts just before TDC, where the signal decreases rapidly to low values.

As engine efficiency targets continue to rise, additional improvements must consider reduction of heat transfer losses. The development of advanced heat transfer models and realistic boundary conditions for simulation based engine design both require accurate in-cylinder wall temperature measurements. A novel dual wavelength infrared diagnostic has been developed to measure in-cylinder surface temperatures with high temporal resolution. The diagnostic has the capability to measure low amplitude, high frequency temperature variations, such as those occurring during the gas exchange process. The dual wavelength ratio method has the benefit of correcting for background scattering reflections and the emission from the optical window itself. The assumption that background effects are relatively constant during an engine cycle is shown to be valid over a range of intake conditions during motoring.

Simultaneous laser-induced fluorescence (LIF) imaging of formaldehyde and a fuel-tracer have been performed in a high-speed diesel engine. N-heptane and isooctane were used as fuel and toluene was used as a tracer. This arrangement made it possible to make simultaneous measurements of toluene by exciting at 266 nm and detecting at 270-320 nm while exciting formaldehyde at 355 nm and detecting at 400-500 nm. The aim of this study is to investigate how traditional fuel tracer and natural-occurring formaldehyde formed in the cool chemistry are transported in the piston bowl. A range of ignition delays were created by running the engine with different amounts of EGR. During this sweep the area where the low-temperature reactions take place were studied. The measurements were performed in a 0.5-l, single-cylinder optical engine running under conditions simulating a cruise-point, i.e., about 2.2 bar imep.

With increasing interest to reduce the dependency on gasoline and diesel, alternative energy source like compressed natural gas (CNG) is a viable option for internal combustion engines. Spark-ignited (SI) CNG engine is the simplest way to utilize CNG in engines, but direct injection (DI) Diesel-CNG dual-fuel engine is known to offer improvement in combustion efficiency and reduction in exhaust gases. Dual-fuel engine has characteristics similar to both SI engine and diesel engine which makes the combustion process more complex. This paper reports the computational fluid dynamics simulation of both DI dual-fuel compression ignition (CI) and SI CNG engines. In diesel-CNG dual-fuel engine simulations and comparison to experiments, attention was on ignition delay, transition from auto-ignition to flame propagation and heat released from the combustion of diesel and gaseous fuel, as well as relevant pollutants emissions.

A means of validating numerical simulations has been developed which utilizes chemiluminescence measurements from an internal combustion engine. By incorporating OH*, CH2O* and CO2* chemiluminescence sub-mechanisms into a detailed n-heptane reaction mechanism, excited species concentration and chemiluminescence light emission were calculated. The modeled line-of-sight chemiluminescence emission allows a direct comparison of simulation results to experimentally measured chemiluminescence images obtained during combustion in an optically accessible compression ignition engine using neat n-heptane fuel. The spray model was calibrated using in-cylinder liquid penetration length Mie scattering measurements taken from the jets of the high-pressure piezo injector.

This study evaluates the performance of an indirect injection (IDI) diesel engine fueled with cotton seed biodiesel while assessing the engine's multi-fuel capability. Millions of tons of cotton seeds are available in the south of the US every year and approximately 10% of oil contained in the seeds can be extracted and transesterified. An investigation of combustion, emissions, and efficiency was performed using mass ratios of 20-50% cotton seed biodiesel (CS20 and CS50) in ultra-low sulfur diesel #2 (ULSD#2). Each investigation was run at 2400 rpm with loads of 4.2 - 6.3 IMEP and compared to the reference fuel ULDS#2. The ignition delay ranged in a narrow interval of 0.8-0.97ms across the blends and the heat release rate showed comparable values and trends for all fuel blends. The maximum volume averaged cylinder temperature increased by approximately 100K with each increase in 1 bar IMEP load but the maximum remained constants across the blends.

Recent legislation entitled “The Single Fuel Forward Policy” mandates that all vehicles deployed by the US military be operable with aviation fuel (JP-8). Therefore, the authors are conducting an investigation into the influence of JP-8 on a diesel engine's performance. The injection, combustion, and performance of JP-8, 20-50% by weight in ULSD (diesel no.2) mixtures (J20-J50) produced at room temperature, were investigated in a small indirect injection, high compression ratio (24.5), 77mm separate combustion chamber diesel engine. The effectiveness of JP8 for application in an auxiliary power unit (APU) at continuous operation (100% load) of 4.78bar bmep/2400rpm was investigated. The blends had an ignition delay of approximately 1.02ms that increased slightly in relation to the amount of JP-8 introduced. J50 and diesel no.2 exhibited similar characteristics of heat release, the premixed phase being combined with the diffusion combustion.

Ultraviolet chemiluminescence has been observed in a diesel engine cyclinder during compression, but prior to fuel injection under engine starting conditions. During a portion of the warm-up sequence, the intensity of this emission exhibits a strong correlation to the phasing of the subsequent combustion. Engine exhaust measurements taken from a continuously misfiring, motored engine confirm the generation of formaldehyde (HCHO) in such processes. Fractions of this compound are expected to be recycled as residual to participate in the following combustion cycle. Spectral measurements taken during the compression period prior to fuel injection match the features of Emeleus' cool flame HCHO bands that have been observed during low temperature heat release reactions occurring in lean HCCI combustion. That the signal from the OH* bands is weak implies a buildup of HCHO during compression.