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The common realization of the necessity to reduce the use of mineral sources is promoting the use of alternative fuels. Big efforts are being made to replace petroleum derivatives in the internal combustion engines (ICEs). For this purpose it is mandatory to evaluate the behavior of non-conventional fuels in the ICEs. The optical diagnostics have proven to be a powerful tool to analyze the processes that take place inside the engine. In particular, 2d imaging in the infrared range can reveal new details about the effect of the fuel properties since this technique is still not very common. In this work, a comparison between commercial diesel fuel and two non-conventional fuels has been made in an optically accessible diesel engine. The non-conventional fuels are: the first generation biofuel Rapeseed Methyl Ester (RME) and an experimental blend of diesel and a fuel with high glycerol content (HG).

The use of oxygenated and renewable fuels is nowadays a widespread means to reduce regulated pollutant emissions produced by internal combustion engines, as well as to reduce the greenhouse impact of transportation. Besides PM, NOx and HC emissions, also the size distribution of particles emitted at the engine exhaust represent meaningful information, considering its adverse effects on the environment and human health. In this work, the results of a comprehensive investigation on the combustion characteristics and the exhaust emissions of a GDI high performance engine, fuelled with pure bio-ethanol and European gasoline, are shown. The engine is a 4-cylinder, 4-stroke, 1750 cm₃ displacement, and turbocharged. The engine was operated at different speed/load conditions and two fuel injection strategies were investigated: homogeneous charge mode and stratified charge mode.

In order to meet the requirements in the stringent emission regulations, more and more research work has been focused on homogeneous charge compression ignition (HCCI) and partially premixed combustion (PPC) or partially premixed compression ignition (PCCI) as they have the potential to produce low NOx and soot emissions without adverse effects on engine efficiency. The mixture formation and charge stratification influence the combustion behavior and emissions for PPC/PCCI, significantly. An ultra-high speed burst-mode laser is used to capture the mixture formation process from the start of injection until several CADs after the start of combustion in a single cycle. To the authors’ best knowledge, this is the first time that such a high temporal resolution, i.e. 0.2 CAD, PLIF could be accomplished for imaging of the in-cylinder mixing process. The capability of resolving single cycles allows for the influence of cycle-to-cycle variations to be eliminated.

Premixed charge compression ignition (PCCI) has been shown to be a promising strategy to simultaneously reduce emissions while realizing improved fuel economy. PCCI combustion uses high levels of pre-combustion mixing to lower both NOx and soot emissions by ensuring low equivalence ratio and low flame temperatures. The high level of pre-combustion mixing results in a primarily kinetics controlled combustion process. In this work, optical diagnostics have been applied in a transparent DI diesel engine equipped with the head of Euro5 commercial engine and the last generation CR injection system. In order to realize the PCCI combustion the injection of neat ethanol has been performed in the intake manifold. The engine run in continuous way at 1500 rpm engine speed and commercial diesel fuel has been injected into the cylinder. The PCCI combustion has been analyzed by means of UV- Visible digital imaging and the mixing process, the autoignition of the charge have been investigated.

Phosphor thermometry was used during fuel injection in an optical engine with the glass piston of reentrant type. SiO2 coated phosphor particle was used for the gas-phase temperature measurements, which gave much less background signal. The measurements were performed in motored mode, in combustion mode with injection of n-heptane and in non-combustion mode with injection of iso-octane. In the beginning of injection period, the mean temperature of each injection cases was lower than that of the motored case, and temperature of iso-octane injection cases was even lower than that of n-heptane injection cases. This indicates, even if vaporization effect seemed to be the same at both injection cases, the effect of temperature decrease changed due to the chemical reaction effect for the n-heptane cases. Chemical reaction seems to be initiated outside of the fuel liquid spray and the position was moving towards the fuel rich area as the time proceeds.

Spectral flame emissivity and absorption measurements with high temporal and spatial resolution were performed in an optically accessible high-swirl divided-chamber Diesel system. Simultaneous determination of soot temperature, soot volume fraction and the OH radical concentration were made from the start to the end of the combustion in 153 locations equally distributed in the chamber. The engine was run at 2000 rpm and at fixed air-fuel ratio realizing 200 consecutive combustion cycles. To visualize the spatial and temporal spray and flame evolution, direct high-speed photographic sequences were taken at 8000 frames/s. The photographic sequences showed that the spray is strongly distorted and mixed by very high swirl resulting in a well premixed region where the combustion starts. The OH radicals were detected in the fuel reaction zone. Moreover OH concentration and soot volume fraction are well correlated with soot temperature.

Pollutant emission of vehicle cars is nowadays a fundamental aspect to take into account. In the last decays, the company have been forced to study new solutions, such as alternative fuel and learn burn mixture strategy, to reduce the vehicle’s pollutants below the limits imposed by emission regulations. Pre-chamber ignition system presents potential reductions in emission levels and fuel consumption, operating with lean burn mixtures and alternative fuels. As alternative fuels, methane is considered one of the most interesting. It has wider flammable limits and better anti-knock properties than gasoline. Moreover, it is characterized by lower CO2 emissions. The aim of this work is to study the evolution of the plasma jets in a different in-cylinder conditions. The activity was carried out in a research optical small spark ignition engine equipped alternatively with standard ignition system and per-chamber.

The electrochemical performance of a lithium-ion battery is strongly affected by the temperature. During charge and discharge cycles, batteries are subjected to an increment of temperature that can accelerate aging and loss of efficiency if critical values are reached. Knowing the thermal parameters that affect the heat exchange between the battery surface and the surrounding environment (air, cooling fins, plates, etc…) is fundamental to their thermal management. In this work, thermal imaging is applied to a laminated lithium-polymers battery as a non-invasive temperature-indication method. Measurements are taken during the discharge phase and the following cooling down until the battery reaches the ambient temperature. The 2d images are used to analyze the homogeneity of the temperature distribution on the battery surface. Then, experimental results are coupled with mathematical correlations.

Electrification of transport, together with the decarbonization of energy production are suggested by the European Union for the future quality of air. However, in the medium period, propulsion systems will continue to dominate urban mobility, making mandatory the retrofitting of thermal engines by applying combustion modes able to reduce NOx and PM emissions while maintaining engine performances. Low Temperature Combustion (LTC) is an attractive process to meet this target. This mode relies on premixed mixture and fuel lean in-cylinder charge whatever the fuel type: from conventional through alternative fuels with a minimum carbon footprint. This combustion mode has been subject of numerous modelling approaches in the engine research community. This study provides a theoretical comparative analysis between multi-zone (MZ) and Transported probability density function (TPDF) models applied to LTC combustion process.

Simultaneous formaldehyde and OH PLIF have been applied in a direct-injected HCCI engine. The engine is a 0.5 l single-cylinder optical engine equipped with EGR system. PLIF measurements were performed with the engine run with two different fuels of low and high volatility, respectively. Different ratios of EGR were also examined. The aim of the study was to investigate how fuels with different volatility and EGR affect the HCCI combustion and measurements were performed for early and late injection timings. Measurements are presented for different injection timings showing formaldehyde and OH from start of injection until late in the expansion stroke. Also, formaldehyde distributions obtained from after the low temperature regime and before the high temperature regime are studied for different tuning of the start of injection from 300CAD to 20CAD before top dead center.

Direct injection spark ignition engines represent an effective technology to achieve the goal of carbon dioxide emission reduction. Further reduction of the carbon footprint can be achieved by using carbon-neutral fuels. Oxygenated alcohols are well consolidated fuels for spark ignition engines providing also the advantages of knock resistance and low soot tendency production. Methanol and ethanol are possible candidates as alternative fuels to gasoline due to their similar properties. In this study a blend at 25 % v/v of ethanol in gasoline (E25) and a blend with 80% gasoline, 5 % v/v ethanol and 15% v/v of methanol (GEM) were tested. These blends were considered since E25 is already available at fuel pump in some countries. The GEM blend, instead, could represent a valid alternative in the next future. Experiments were carried out on a high performance, turbocharged 1.8 L direct injection spark ignition engine over the Worldwide Harmonized Light Vehicles Test Cycle.

Internal combustion engines are characterized by high pressure and thermal loads on pistons and in cylinders. The heat generated by the combustion process is dissipated by means of water and oil cooling systems. For the best design and optimization of the engine components it is necessary to know the components temperature in order to estimate the thermal flows. The purpose of this work is to measure the piston sapphire window temperature in a research optically accessible engine by combining two different techniques: measurements with templugs and with thermography. The method is very simple and can provide a reliable value of temperature within a small interval. It fits well for applications inside the engine because of its low technical level requirements. It consists of application of temperature sensitive stickers on the target component that makes it a very robust method, not affected by piston movement.

In view of the new emission regulations seeking to lower the particle cut-off size down to the current 23 nm, an extensive comprehension on the nature of sub-23 nm particles is crucial. In this regard, a new challenge lies ahead considering an even more massive use of biofuels. The objective of this research study was to characterize the sub-23 nm particles and to evaluate their volatile organic fraction (VOF) from a high performance, 1.8 L gasoline direct injection (GDI) engine under the Worldwide harmonized Light vehicles Test Cycle (WLTC). Particle emissions were measured through an Engine Exhaust Particle Sizer (EEPS) capable of particle sizing and counting in the range 5.6 - 560 nm. The sampling and conditioning were performed by both a single diluter and the Dekati Engine Exhaust Diluter (DEED) a Particle Measurement Programme (PMP) compliant sample conditioning system.

Nowadays, the regulation regards only the particles larger than 23 nm. The attention is shifting towards the sub-23 nm particles because of their large presence at the exhaust of the modern engines and their negative impact on human health. The main challenge of the regulation of these particles is the definition of a proper procedure for their measure. The nature of the sub-23 nm particles is not well understood, and their measure is strongly affected by the sampling conditions leading to not reliable measure. The aim of this paper is to provide information on the emissions of sub-23 nm particles from GDI vehicles/engines. At the same time, the presence of volatiles, which mainly contribute to the formation of sub-23 nm particles, was evaluated and the effect of sampling conditions was investigated. The analysis was performed on a 1.8L GDI powered vehicle, widely used both in North America and Europe, and a 4-cylinder GDI engine, whose features are similar to those of the vehicle.

An engine can be run in Homogenous Charge Compression Ignition (HCCI) mode by applying a negative valve overlap, thus trapping hot residuals so as to achieve an auto-ignition temperature. By employing spark assistance, the engine can be operated in what is here called Spark Assisted Compression Ignition (SACI) with ethanol as fuel. The influence of fuel stratification by means of port fuel injection as well as in combination with direct injection was investigated. A high-speed multi-YAG laser system and a framing camera were utilized to capture planar laser-induced fluorescence (PLIF) images of the fuel distribution. The charge homogeneity in terms of fuel distribution was evaluated using a homogeneity index calculated from the PLIF images. The homogeneity index showed a higher stratification for increased proportions of direct-injected fuel. It was found that charge stratification could be achieved through port fuel injection in a swirling combustion system.

The aim of the present work is the study of the combustion process in Gasoline Direct Injection (GDI) engine fuelled with ethanol mixed with gasoline at percentages of 10 and 85. The characterization has been made in terms of performance and emission for different injection pressure conditions and the results correlated to the unperturbed non-evaporating evolution of the fuel injected in a pressurized quiescent vessel. Measurements were performed in the optically accessible combustion chamber made by modifying a real 4-stroke, 4-cylinder, high performance GDI engine. The cylinder head was instrumented by using an endoscopic system coupled to high spatial and temporal resolution camera in order to allow the visualization of the fuel injection and the combustion process. The engine is equipped with solenoid-actuated six-hole GDI injectors, 0.14 mm hole diameter, 9.0 g/s @ 10 MPa static flow.

Present work investigates both experimentally and numerically the benefits deriving from the use of split injections in increasing the engine power output and reducing the tendency to knock of a gasoline direct injection (GDI) engine. The here considered system is characterized by an optical access to the combustion chamber. Imaging in the UV-visible range is carried out by means of a high spatial and temporal resolution camera through an endoscopic system and a transparent window placed in the piston head. This last is modified to allow the view of the whole combustion chamber almost until the cylinder walls, to include the so-called eng-gas zones of the mixture, where undesired self-ignition may occur under some circumstances. Optical data are correlated to in-cylinder pressure oscillations on a cycle resolved basis.

Simultaneous laser induced fluorescence (LIF) imaging of formaldehyde and a fuel-tracer have been performed in a direct-injection HCCI engine. A mix of N-heptane and iso-octane was used as fuel and Toluene as fluorescent tracer. The experimental setup involves two pulsed Nd:YAG lasers and two ICCD cameras. Frequency quadrupled laser radiation at 266 nm from one of the Nd:YAG lasers was used for excitation of the fuel tracer. The resulting fluorescence was detected with one of the ICCD cameras in the spectral region 270-320 nm. The second laser system provided frequency tripled radiation at 355 nm for excitation of Formaldehyde. Detection in the range 395-500 nm was achieved with the second ICCD. The aim of the presented work is to investigate the applicability of utilizing formaldehyde as a naturally occurring fuel marker. Formaldehyde is formed in the low temperature reactions (LTR) prior to the main combustion and should thus be present were fuel is located until it is consumed.

Simultaneous laser-induced fluorescence (LIF) imaging of formaldehyde and a fuel-tracer have been performed in a high-speed diesel engine. N-heptane and isooctane were used as fuel and toluene was used as a tracer. This arrangement made it possible to make simultaneous measurements of toluene by exciting at 266 nm and detecting at 270-320 nm while exciting formaldehyde at 355 nm and detecting at 400-500 nm. The aim of this study is to investigate how traditional fuel tracer and natural-occurring formaldehyde formed in the cool chemistry are transported in the piston bowl. A range of ignition delays were created by running the engine with different amounts of EGR. During this sweep the area where the low-temperature reactions take place were studied. The measurements were performed in a 0.5-l, single-cylinder optical engine running under conditions simulating a cruise-point, i.e., about 2.2 bar imep.

In order to meet the increasingly strict emission regulations, several solutions for NOx and PM emissions reduction have been studied. Exhaust gas recirculation (EGR) technology has become one of the more used methods to accomplish the NOx emissions reduction. However, actual control strategies do not consider, in the definition of optimal EGR, its effect on particle size and density. These latter have a great importance both for the optimal functioning of after-treatment systems, but also for the adverse effects that small particles have on human health. Epidemiological studies, in fact, highlighted that the toxicity of particulate particles increases as the particle size decreases. The aim of this paper is to present a Neural Network model able to provide real time information about the characteristics of exhaust particles emitted by a Diesel engine.