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The combustion processes in a compression-ignition engine of the direct-injection type are examined by the independent variation of the partial pressure of oxygen in the intake charge coupled with analyses of rates of heat release employing computer methods.

The effects of changes in the cetane number of diesel liquid pilot fuels on the ignition delay period in dual fuel engines were investigated experimentally. Different pilot fuel quantities were employed with commercially pure methane, propane and low heating value gaseous fuel mixtures of methane with nitrogen or carbon dioxide over a range of engine load. The ignition delay variation with increased gaseous fuel admission showed a strong dependance on both the quantity and the quality of the pilot fuel used. It was found that the use of high cetane number pilot liquid fuels permitted smaller pilot quantities to be used satisfactorily. Engine operation on propane and low heating value gaseous fuels improved in comparison with dual fuel engine operation employing common diesel fuels.

Operating characteristics including ignition limits, cyclic variability, and exhaust emissions were studied in the combustion of natural gas in a spark ignition, single-cylinder, variable compression ratio engine, operated at intake mixture temperatures ranging between 120 and -60 F. The work confirmed in general the feasibility of using natural gas in a spark ignition engine operated under extremely cold intake temperature conditions. It was learned that both the maximum peak cylinder pressures and the mass of mixture inducted by the engine increased as the intake mixture temperature was lowered, and that the emissions of pollutants were not significantly increased. These findings are thought to be particularly relevant to the use of natural gas in spark ignition engines, either as LNG or under very cold wintry conditions.

The effects of charge non-uniformity on autoignition of methane/air mixtures in a motored engine are investigated analytically using a varying global kinetic data model derived from the results of a detailed chemical kinetic scheme under similar conditions in a simple adiabatic constant volume reactor. These derived varying global kinetic data model was implemented in the CFD KIVA-3 code. The relative contribution of fluid motion generated by piston motion, heat transfer, chemical reactivity of the cylinder charge and swirl movement to the inhomogeneities in the properties of the cylinder charge and their consequent effects on the evolution of the autoignition process are presented and discussed.

The paper describes some of the operational and exhaust emission characteristics of a single-cylinder direct-injection diesel engine that was operated warm under a wide range of intake air temperatures extending down to -45°F and occasionally -60°F. The operating range considered included the no-load and partially motored regions.

A review is made of some of the main problems associated with the use of natural gas, notably methane, in dual fuel engines of the compression ignition diesel type. It is shown that such applications represent in principle a very attractive mode for the utilization of the fuel for the production of power generally at relatively high efficiencies and outputs with good exhaust emissions characteristics. Some relevant solutions to the problems outlined are then discussed. Moreover, some further research and development needed in this general area is also outlined.

The present contribution is mainly concerned with an investigation of the characteristics of dual fuel operation under cold intake temperatures, primarily from the viewpoint of engine performance and exhaust emissions. The gaseous fuels employed were methane, propane, hydrogen and ethylene. The addition of the inerts carbon dioxide and nitrogen were also considered. Comparison with the corresponding normal diesel operation was made throughout.

The total number of vehicles fuelled with compressed natural gas, CNG, is relatively very small in comparison to gasoline fuelled vehicles. Accordingly, because of the lack of statistics of accidents involving CNG fuelled vehicles, their safety aspects are evaluated in comparison to automobiles fuelled with gasoline or some other alternative fuels such as propane, hydrogen, LNG or LH2. It is suggested that methane, CNG, has some excellent physical, chemical and combustion characteristics that make it a safe automotive fuel. These characteristics are reviewed and the superior relative safety of methane in automotive applications in comparison to applications involving the other fuels is demonstrated where well designed conversion systems and operations are employed.

Cyclic variations in engines have been the subject of much investigation and there are some excellent reviews of this research. However, there is still a need to examine in an integrated manner the cyclic variation in performance parameters such as indicated power output, efficiency and cylinder pressure development in relation to the cyclic variation in some important combustion parameters notably those of the ignition lag, which is the time requirements to initiate a flame kernel following the passage of a spark and the duration to complete the combustion process particularly when gaseous fuels, notably methane are used. The paper describes the results of an investigation with these objectives using a single cylinder, variable compression ratio, spark ignition, CFR engine, run at constant speed, operating mainly on natural gas.

The presence of carbon dioxide with methane is often encountered to varying proportions in numerous natural, industrial and bio-gases. The paper discusses how such a presence modifies significantly the thermodynamic, kinetic and combustion characteristics of methane in air. Experimental results are presented showing how the performance of engines, both of the spark ignition and compression ignition dual fuel types is adversely affected by the increasing presence of carbon dioxide with the methane. The bases for these trends are discussed and some guidelines towards alleviating the adverse effects of the presence of carbon dioxide in such fuel mixtures are made.

Hydrogen is normally produced through the steam reforming of fossil fuels, notably natural gas or their partial oxidation in oxygenated air. The products of these processes would normally produce the H2 in the presence of a variety of concentrations of CO, CO2, H2O and N2. There is increasing interest in employing such mixtures whether on their own or in mixtures with traditional liquid or gaseous fuels in S.I. engine applications so as to improve the combustion process and engine performance. The combustion characteristics in S.I. engines of gas mixtures that contain H2 and CO need to be established to provide key operational information, such as the variations in the combustion duration and the knock limits. This paper presents experimental data obtained in a single cylinder, variable compression ratio, S.I., CFR engine when operated in turn on CH4, H2, CO and their binary mixtures.

A preliminary investigation was made into the use of hydrogen-oxygen mixtures in spark ignition engines. This appeared to be attractive in view of the serious air pollution problem. Furthermore, hydrogen has been considered by others as a possible alternative fuel to replace depleting petroleum resources. Following a literature survey regarding the combustion characteristics of hydrogen, a computer program based on a constant-volume combustion engine cycle was used to evaluate the overall performance of an engine. Another program, which considered chemical reaction kinetics, was used to predict the onset of autoignition in mixtures undergoing compression in an engine. Results of the program indicated that an attractive and safe way to use hydrogen-oxygen mixtures in an engine involved the recycling of exhaust gases. Such a system would be fed with a stoichiometric mixture, while excess hydrogen would be circulated within to control combustion in the engine.

The paper describes the computational and experimental approach of deriving gross chemical kinetic data of the combustion of common fuels using a motored engine. The approach is based on the accurate calculation of the rate of heat release due to autoignition reactions. Kinetic data of the combustion of n-heptane, propane, and methane in air together with the role of the presence of a higher hydrocarbon vapour such as n-heptane with methane and propane are presented and discussed mainly in relation to dual-fuel engine phenomena.

The observed lean and rich operational limits in a spark ignition engine of the variable compression ratio type fuelled with either methane or propane are shown to be amenable to correlation in terms of a calculated mean mixture temperature at the time of passing the spark. Moreover, using a detailed chemical kinetics model for the oxidation of lean methane-air mixtures in a compression ignition engine, the autoignition of methane-air mixtures is examined. It is shown that these autoignition limits are also influenced by the mean charge temperature and the kinetic and thermal sensitizing of the charge through mixing with residual gases.

An examination of the combustion phenomena and associated engine performance is made for a dual fuel engine of the compression ignition type when additional auxiliary fuels and inerts were introduced with the main intake charge. This was considered to have direct relevance to operation of diesel engines on low heating value gaseous fuel mixtures. A single cylinder direct injection diesel engine was employed throughout. H2, CH4, CO2 and N? were the gas constituents used. Operation on gaseous fuel mixtures containing significant amounts of diluent inerts showed a marked deterioration of the already inefficient combustion of lean fuel-air mixtures. Of the two inert gases (CO2 and N2) introduced in turn, CO2 has a comparatively greater influence in narrowing the operating range of the engine. Both diesel and dual fuel operations were also considered when a spray of water was introduced into the intake of the engine.

There are distinct operational mixture limits beyond which satisfactory spark ignition engine performance can not be maintained. The values of these limit mixtures which depend on the mode of their determination, are affected by numerous operational and design factors that include the type of engine and fuel used. Simple approximate methods are presented for predicting these limits. Good agreement is shown to exist between the calculated and the corresponding experimental values over a range of operating conditions while operating on the gaseous fuels: methane, propane and hydrogen. The experimentally observed operational limits deviate very substantially from the corresponding accepted flammability limit values for quiescent conditions evaluated at the average temperature and pressure prevailing at the instant of the spark passage.

The paper reviews the combustion characteristics of the two fuels and sets out to consider their respective performance in both spark ignition and compression ignition engines. Results of comparative tests involving spark ignition engines over a wide range of operating conditions are presented and discussed. Some of the performance characteristics considered are those relating to power output, efficiency, tendency to knock, cyclic variations, optimum spark requirements and exhaust emissions. Similarly, some of the performance characteristics in compression ignition engines considered include power output, efficiency, tendency towards knock and autoignition, exhaust emissions and low operational temperature problems. Finally, the relative operational safety aspects of the two fuels are evaluated. It is then suggested that in this regard, methane has some excellent physical, chemical and combustion characteristics that makes it a particularly safe fuel.

One of the main features of methane fueled spark ignition engines is their relatively slow flame propagation rates in comparison to liquid fuel applications which may lead to relatively lower power output and efficiency with increased emissions and cyclic variations. This is especially pronounced at operational equivalence ratios that are much leaner than the stoichiometric value. The addition of some hydrogen and oxygen to the methane may contribute towards speeding the combustion process and bring about significant improvements in performance and emissions. It has been suggested that the addition to the methane of products of water electrolysis generated in situ on board of a vehicle may produce such improvements.

The ignition delay period occurring in dual fuel engines operating on a wide range of gaseous fuels and in diesel engines with various inert diluents added to the intake charge is examined. The observed differences in the delay period between dual fuel and diesel operations are then attributed mainly to changes in the oxygen concentration of the charge, the charge effective temperature and the chemical kinetic processes.

Examination is made of the changes that take place in the major parameters of the combustion process and engine performance when using three different designs of plasma jet igniters of the open cavity type in a methane fuelled single cylinder engine. The characteristics of the combustion process were analysed employing a two-zone diagnostic model based on cylinder pressure-time development data. The use of plasma jet igniters with methane as a fuel enhanced the rates of burning in the initial stages of combustion, especially with very lean mixtures. The lean limit of engine operation was also extended. Their use for near stoichiometric fast burning mixtures tends in comparison to contribute little towards enhancing engine performance.