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Vegetable oils are candidates for alternative fuels in diesel engines. These oils, such as soybean, sunflower, rapeseed, cottonseed, and peanut, consist of various triglycerides. The chemistry of the degradation of vegetable oils when used as alternate diesel fuels thus corresponds to that of triglycerides. To study the chemistry occurring during the precombustion phase of a vegetable oil injected into a diesel engine, a reactor simulating a diesel engine was constructed. Pure triglycerides were injected into the reactor in order to determine differences in the precombustion behavior of the various triglycerides. The reactor allowed motion pictures to be prepared of the injection event as the important reaction parameters, such as pressure, temperature, and atmosphere were varied. Furthermore, samples of the degradation products of precombusted triglycerides were collected and analyzed (gas chromatography / mass spectrometry).

One of the major problems created by the use of methanol fuels in SI engines is the high cylinder bore and ring wear rates observed during operation at low engine temperatures. The objective of the work reported in this paper was to identify the processes controlling the corrosion/wear mechanism in methanol-fueled, spark-ignition engines. Basically, three different types of experiments were performed during this project. The experiments consisted of: 1. Combustion experiments designed to identify the combustion products of methanol at various locations within a confined methanol flame; 2. Exposure studies designed to define the specific role of each of the combustion products on the corrosion mechanism; 3. Lubricant screening experiments designed to identify the mode of penetration of the oil film, and the location, in the microscale, of the surface attack. Performic acid was identified as the corrosive agent.

Comparative emission measurements were made in two dynamometer-based diesel engines using protocol specified by the U.S. Environmental Protection Agency (EPA) and the California Air Resources Board (CARB). A single JP-8 fuel with a sulfur level of 0.06 weight percent (wt%) was adjusted to sulfur levels of 0.11 and 0.26 wt%. The emission characteristics of the three fuels were compared to the 1994 EPA certification low-sulfur diesel fuel (sulfur level equal to 0.035 wt%) in the Detroit Diesel Corporation (DDC) 1991 prototype Series 60 diesel engine and in the General Motors (GM) 6.2L diesel engine. Comparisons were made using the hot-start transient portion of the heavy-duty diesel engine Federal Test Procedure. Results from the Army study show that the gaseous emissions for the DDC Series 60 engine using kerosene-based JP-8 fuel are equivalent to values obtained with the 0.035 wt% sulfur EPA certification diesel fuel.

Hybrids are fuels derived from combinations of different energy sources and which are generally formulated as solutions, emulsions, or slurries. The underlying objective of this program is to reduce the use of petroleum-derived fuels and/or to minimize the processing requirements of the finished hybrid fuels. Several hybrid fuel formulations have been developed and tested in a direct injection single-cylinder diesel engine. The formulations included solutions of ethanol and vegetable oils in diesel fuel, emulsions of methanol and of ethanol in diesel fuel; and slurries of starch, cellulose, and “carbon” in diesel fuel. Based on the progress to date, the solutions and emulsions appear to be viable diesel engine fuels if the economic factors are favorable and the storage and handling problems are not too severe. The slurries, on the other hand, are not to the same point of development as the solutions and emulsions.

It is now a fairly well established fact that excessive ring and cylinder bore wear can result from the operation of an S. I. engine on neat methanol. The mechanism leading to the excessive wear were investigated using both engine and bench tests. Engine tests using prevaporized superheated methanol indicated that the wear results from reactions between the combustion products and the cast iron cylinder liner, where the presence of liquid methanol in the combustion chamber appears to be an important part of the mechanism. These reactions were investigated using a spinning disc combustor. The spinning disc combustor was used to provide a source of burning methanol droplets which were subsequently quenched on a water-cooled cast iron surface. The condensate formed on the cast iron surface was collected and analyzed for chemical composition. Infrared analysis indicated the presence of large quantities of iron formate, a reaction product of iron and formic acid.

The purpose of this work was to develop a series of octane reference fuels for road testing methanol fueled vehicles. Preliminary attempts to measure the research octane number of neat methanol by the standard ASTM test procedure produced anomalous results. This led to a more basic method of measuring the octane number based on the incipient knock compression ratio. The incipient knock method gave research and motor octane numbers of 112 and 88, respectively, for neat methanol. Research octane numbers of several methanol reference fuel blends prepared by adding octane enhancers and depressors were determined. The effects of spark timing and air/fuel mixture temperature on the incipient knock compression ratio of neat methanol were also examined.

A constant volume bomb was used to determine basic combustion characteristics of isooctane, n-heptane, methanol, propane and methane. Results show that the laminar flame velocity of a quiescent homogeneous air/fuel mixture can be derived from pressure-time data in the bomb. The effects of pressure, temperature, and charge dilution on flame velocity and ignition are presented. A thermo-chemical kinetic model accurately predicted concentrations of nitric oxide during combustion and in the burned gas.

A technology path has been identified for development of a high efficiency, durable, gasoline engine, targeted at achieving performance and emissions levels necessary to meet heavy-duty, on-road standards of the foreseeable future. Initial experimental and numerical results for the proposed technology concept are presented. This work summarizes internal research efforts conducted at Southwest Research Institute. An alternative combustion system has been numerically and experimentally examined. The engine utilizes gasoline as the fuel, with a combination of enabling technologies to provide high efficiency operation at ultra-low emissions levels. The concept is based upon very highly-dilute combustion of gasoline at high compression ratio and boost levels. Results from the experimental program have demonstrated engine-out NOx emissions of 0.06 g/hp/hr, at single-cylinder brake thermal efficiencies (BTE) above thirty-four percent.

SwRI has developed a new technology concept involving the use of high EGR rates coupled with a high-energy ignition system in a gasoline engine to improve fuel economy and emissions. Based on a single-cylinder study [1], this study extends the concept of a high compression ratio gasoline engine with EGR rates > 30% and a high-energy ignition system to a multi-cylinder engine. A 2000 MY Isuzu Duramax 6.6 L 8-cylinder engine was converted to run on gasoline with a diesel pilot ignition system. The engine was run at two compression ratios, 17.5:1 and 12.5:1 and with two different EGR systems - a low-pressure loop and a high pressure loop. A high cetane number (CN) diesel fuel (CN=76) was used as the ignition source and two different octane number (ON) gasolines were investigated - a pump grade 91 ON ((R+M)/2) and a 103 ON ((R+M)/2) racing fuel.

The engine selected for this work was a Caterpillar 3176 engine. Engine exhaust emissions, performance, and heat release rates were measured as functions of engine configuration, engine speed and load. Two engine configurations were used, a standard 1994 design and a 1994 configuration with EGR designed to achieve a NOx emissions level of 2.5 gm/hp-hr. Measurements were performed at 7 different steady-state, speed-load conditions on thirteen different test fuels. The fuel matrix was statistically designed to independently examine the effects of the targeted fuel properties. Cetane number was varied from 40 to 55, using both natural cetane number and cetane percent improver additives. Aromatic content ranged from 10 to 30 percent in two different forms, one in which the aromatics were predominantly mono-aromatic species and the other, where a significant fraction of the aromatics were either di- or tri-aromatics.

Due to the cost and mobility advantages of diesel-powered mine vehicles over electric vehicles, it is anticipated that the diesel engine will become more widely used in underground mines in this country. Concern has arisen, however, over the impact of diesel exhaust emissions on the air quality in the underground mine environment. A literature search has been conducted to identify known effects of fuel properties on the reduction of diesel exhaust emissions. Reductions can be obtained by optimizing fuel properties and by considering alternative fuels to standard diesel fuel. However, the data base is relatively small and the results highly dependent on engine type and operating conditions. Engine studies on a typical mine diesel are necessary to draw quantitative conclusions regarding the reduction of emissions, especially particulates and NO2 which have not been generally addressed in previous studies.

Diesel exhaust emission levels have been measured during discrete transients in speed and load, and with changes made to the engine and fuel. Particulate, oxides of nitrogen, unburned hydrocarbon, and carbon monoxide measurements were made for two fuels, DF2 and 5 percent water-in-fuel microemulsion, for both a standard Caterpillar 3304 and a modified 3304 engine. Engine modifications included increasing compression ratio and retarding injection timing. This paper examines the effects of the water addition and engine modification on the steady-state and transient emission levels. In general, the addition of water decreased the particulate and oxides of nitrogen emission levels for the standard engine, but increased the levels of hydrocarbons and carbon monoxide. For the modified engine, the water addition resulted in a slight decrease in oxides of nitrogen and particulate matter at high speed and load conditions.

The responses of diesel engine exhaust emissions to transients in speed and torque are examined. Particulate matter, hydrocarbons, carbon monoxide, and oxides of nitrogen were sampled for discrete segments of various transient cycles. Each cycle consisted of four distinct segments, two of which were steady state, in general, each segment was defined by choosing the beginning and ending values for speed and torque, and the segment length. Using regression techniques, prediction equations were obtained for each emission. The equations relate the emission levels to engine parameters, which describe each segment. Speed and torque were found to be important variables as were the rates at which speed and torque changed. Transients in torque were found to increase particulate and carbon monoxide emissions.

Five different diesel fuel feedstocks were processed to two levels of aromatic (0.05 sulfur, and then 10 percent) content. These materials were distilled into 6 to 8 narrow boiling range fractions that were each characterized in terms of the properties and composition. The fractions were also tested at five different speed load conditions in a single cylinder engine where high speed combustion data and emissions measurements were obtained. Linear regression analysis was used to develop relationships between the properties and composition, and the combustion and emissions characteristics as determined in the engine. The results are presented in the form of the regression equations and discussed in terms of the relative importance of the various properties in controlling the combustion and emissions characteristics. The results of these analysis confirm the importance of aromatic content on the cetane number, the smoke and the NOx emissions.

Southwest Research Institute (SwRI) is exploring the feasibility of extending the performance and fuel efficiency of the spark ignition (SI) engine to match that of the emission constrained compression (CI) engine, whilst retaining the cost effective 3-way stoichiometric aftertreatment systems associated with traditional SI light duty engines. The engine concept, which has a relatively high compression ratio and uses heavy EGR, is called “HEDGE”, i.e. High Efficiency Durable Gasoline Engine. Whereas previous SwRI papers have been medium and heavy duty development focused, this paper uses results from simulations, with some test bed correlations, to predict multicylinder torque curves, brake thermal efficiency and NOx emissions as well as knock limit for light and medium duty applications.

An experimental investigation of the effects of partial premixed charge compression ignition (PCCI) combustion and EGR temperature was conducted on a Caterpillar C-12 heavy-duty diesel engine (HDDE). The addition of EGR and PCCI combustion resulted in significant NOx reductions over the AVL 8-mode test. The lowest weighted BSNOx achieved was 2.55 g/kW-hr (1.90 g/hp-hr) using cooled EGR and 20% port fuel injection (PFI). This represents a 54% reduction compared to the stock engine. BSHC and BSCO emissions increased by a factor of 8 and 10, respectively, compared to the stock engine. BSFC also increased by 7.7%. In general, BSHC, BSCO, BSPM, and BSFC increased linearly with the amount of port-injected fuel.

Two different laboratory fuel-injection-pump durability-tests were conducted with four advanced technology test fuels. The first test used a relatively low pressure rotary, opposed piston fuel injection pump similar to those used on some current North American engines. The second test used a relatively high pressure common rail injection pump such as those used currently on some European engines. The tests were scheduled to operate for 500 hours under severe load conditions. It can be concluded that the common-rail, high-pressure fuel pump is more sensitive to the advanced fuels than is the rotary pump in this severe duty-cycle test. Although the laboratory high frequency reciprocating rig (HFRR) tests were able to distinguish between those fuels that contained lubricity additives and those that did not, there was little correlation with pump durability results.

This paper explores the possibility of on-board fuel classification for fuel property adaptive compression-ignition engine control system. The fuel classifier is designed to on-board classify the fuel that a diesel engine is running, including alternative and renewable fuels such as bio-diesel. Based on this classification, the key fuel properties are provided to the engine control system for optimal control of in-cylinder combustion and exhaust treatment system management with respect to the fuel. The fuel classifier employs engine input-output response characteristics measured from standard engine sensors to classify the fuel. For proof-of-concept purposes, engine input-output responses were measured for three different fuels at three different engine operating conditions. Two neural-network-based fuel classifiers were developed for different classification scenarios. Of the three engine operating conditions tested, two conditions were selected for the fuel classifier to be active.

Methods to reduce direct injected diesel engine emissions in the combustion chamber will be discussed in this paper. The following NOx emission reduction technologies will be reviewed: charge air chilling, water injection, and exhaust gas recirculation (EGR). Emphasis will be placed on the development of an EGR system and the effect of EGR on NOx and particulates. The lower limit of NOx that can be obtained using conventional diesel engine combustion will be discussed. Further reductions in NOx may require changing the combustion process from a diffusion flame to a homogeneous charge combustion system.

High-speed movie films, and laser-diffraction drop sizing were used to evaluate the structure, penetration rate, cone angle, and drop size distribution of diesel sprays in a constant volume pressure vessel. As further means of evaluating the data, comparisons are made between the film measurements, and calculations from a dense gas jet model. In addition to the high-speed film data that describes the overall structure of the spray as a function of time, a laser diffraction instrument was used to measure drop size distribution through a cross-section of the spray. In terms of the growth of the total spray volume (a rough measure of the amount of air entrained in the spray), spray impingement causes an initial delay, but generally the same overall growth rate as an equivalent unimpeded spray. Agreement between measurements and calculations is excellent for a diesel spray with a 0.15 mm D orifice and relatively high injection pressures.