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Journal Article

Understanding the Chemical Effects of Increased Boost Pressure under HCCI Conditions

2008-04-14
2008-01-0019
One way to increase the load range in an HCCI engine is to increase boost pressure. In this modeling study, we investigate the effect of increased boost pressure on the fuel chemistry in an HCCI engine. Computed results of HCCI combustion are compared to experimental results in a HCCI engine. We examine the influence of boost pressure using a number of different detailed chemical kinetic models - representing both pure compounds (methylcyclohexane, cyclohexane, iso-octane and n-heptane) and multi-component models (primary reference fuel model and gasoline surrogate fuel model). We examine how the model predictions are altered by increased fueling, as well as reaction rate variation, and the inclusion of residuals in our calculations. In this study, we probe the low temperature chemistry (LTC) region and examine the chemistry responsible for the low-temperature heat release (LTHR) for wide ranges of intake boost pressure.
Technical Paper

Thermodynamic and Chemical Effects of EGR and Its Constituents on HCCI Autoignition

2007-04-16
2007-01-0207
EGR can be used beneficially to control combustion phasing in HCCI engines. To better understand the function of EGR, this study experimentally investigates the thermodynamic and chemical effects of real EGR, simulated EGR, dry EGR, and individual EGR constituents (N2, CO2, and H2O) on the autoignition processes. This was done for gasoline and various PRF blends. The data show that addition of real EGR retards the autoignition timing for all fuels. However, the amount of retard is dependent on the specific fuel type. This can be explained by identifying and quantifying the various underlying mechanisms, which are: 1) Thermodynamic cooling effect due to increased specific-heat capacity, 2) [O2] reduction effect, 3) Enhancement of autoignition due to the presence of H2O, 4) Enhancement or suppression of autoignition due to the presence of trace species such as unburned or partially-oxidized hydrocarbons.
Technical Paper

The Prediction of Autoignition in a DME Direct Injection Diesel Engine

2000-06-19
2000-01-1827
The ignition delay under various temperature and pressure conditions considering volumetric change is investigated both by experiments and simulation to give some basic data of ignition delay for a DME DI diesel engine. The combustion process in a DME direct injected diesel engine was also observed to help understanding of the difference between DME combustion and that of a diesel fuel. For DME fuel, it was clear that the luminous flame duration is much shorter than that of diesel fuel. The calculated results of ignition delay for high equivalence(ϕ =0.4 in this study) showed good accord qualitatively to those of measured at wide range of temperature and pressure conditions investigated in this work. There exists the negative temperature coefficient region near the temperature of 800K. This study shows basic guideline for optimal injection timing for DME fueled compression ignition engines.
Technical Paper

The Potential of HCCI Combustion for High Efficiency and Low Emissions

2002-06-03
2002-01-1923
Homogeneous Charge Compression Ignition (HCCI) engines can have efficiencies as high as compression-ignition, direct-injection (CIDI) engines (an advanced version of the commonly known diesel engine), while producing ultra-low emissions of oxides of nitrogen (NOx) and particulate matter (PM). HCCI engines can operate on gasoline, diesel fuel, and most alternative fuels. While HCCI has been demonstrated and known for quite some time, only the recent advent of electronic sensors and controls has made HCCI engines a potential practical reality. This paper provides a comprehensive overview of the current state-of-the-art in HCCI technology, estimates the potential benefits HCCI engines could bring to U.S. transportation vehicles, and lists the R&D barriers that need to be overcome before HCCI engines might be considered for commercial application.
Technical Paper

The Possibility of Gas to Liquid (GTL) as a Fuel of Direct Injection Diesel Engine

2002-05-06
2002-01-1706
In this study, engine performances and exhaust emissions characteristics of compression ignition engine fueled with GTL were investigated by comparison with diesel fuel. Diesel engine could be operated fueled with GTL without any special modify for the test engine. With the high cetane number of GTL, the ignition lag was shorter, and the combustion started earlier than that of diesel fuel. Brake thermal efficiency operated with GTL increased at middle load conditions due to incomplete combustion emission such as CO and THC were lower than that of diesel fuel operation. NOx emission with GTL was comparable to diesel fuel, and there was a little decrease at high load. With GTL, soot emission was lower than with diesel fuel at above middle load condition. It seemed to be a reason of soot reduction that there was little sulphur contained in GTL.
Journal Article

The Performance of Multi-Cylinder Hydrogen / Diesel Dual Fuel Engine

2015-09-06
2015-24-2458
Hydrogen can be produced by electrolyzation with renewable electricity and the combustion products of hydrogen mixture include no CO, CO2 and hydrocarbons. In this study, engine performance with hydrogen / diesel dual fuel (hydrogen DDF) operation in a multi-cylinder diesel engine is investigated due to clarify advantages and disadvantages of hydrogen DDF operation. Hydrogen DDF operation under several brake power conditions are evaluated by changing a rate of hydrogen to total input energy (H2 rate). As H2 rate is increased, an amount of diesel fuel is decreased to keep a given torque constant. When the hydrogen DDF engine is operated with EGR, Exhaust gas components including carbon are improved or suppressed to same level as conventional diesel combustion. In addition, brake thermal efficiency is improved to 40% by increase in H2 rate that advances combustion phasing under higher power condition. On the other hand, NOx emission is much higher than one of conventional diesel engine.
Technical Paper

The Influence of Fuel Volatility on the Liquid-Phase Fuel Penetration in a Heavy-Duty D.I. Diesel Engine

1998-02-23
980510
The objective of this investigation is to verify and characterize the influence of fuel volatility on maximum liquid-phase fuel penetration for a variety of actual Diesel fuels under realistic Diesel engine operating conditions. To do so, liquid-phase fuel penetration was measured for a total of eight Diesel fuels using laser elastic-scatter imaging. The experiments were carried out in an optically accessible Diesel engine of the “heavy-duty” size class at a representative medium speed (1200 rpm) operating condition. In addition to liquid-phase fuel penetration, ignition delay was assessed for each fuel based on pressure-derived apparent heat release rate and needle lift data. For all fuels examined, it was observed that initially the liquid fuel penetrates almost linearly with increasing crank angle until reaching a maximum characteristic length. Beyond this characteristic length, the fuel is entirely vapor phase and not just smaller fuel droplets.
Technical Paper

The Effects of Injection Timing and Diluent Addition on Late-Combustion Soot Burnout in a DI Diesel Engine Based on Simultaneous 2-D Imaging of OH and Soot

2000-03-06
2000-01-0238
The effects of injection timing and diluent addition on the late-combustion soot burnout in a direct-injection (DI) diesel engine have been investigated using simultaneous planar imaging of the OH-radical and soot distributions. Measurements were made in an optically accessible DI diesel engine of the heavy-duty size class at a 1680 rpm, high-load operating condition. A dual-laser, dual-camera system was used to obtain the simultaneous “single-shot” images using planar laser-induced fluorescence (PLIF) and planar laser-induced incandescence (PLII) for the OH and soot, respectively. The two laser beams were combined into overlapping laser sheets before being directed into the combustion chamber, and the optical signal was separated into the two cameras by means of an edge filter.
Technical Paper

The Effect of TDC Temperature and Density on the Liquid-Phase Fuel Penetration in a D. I. Diesel Engine*

1995-10-01
952456
A parametric study of the liquid-phase fuel penetration of evaporating Diesel fuel jets has been conducted in a direct-injection Diesel engine using laser elastic-scatter imaging. The experiments were conducted in an optically accessible Diesel engine of the “heavy-duty” size class at a representative medium speed (1200 rpm) operating condition. The density and temperature at TDC were varied systematically by adjusting the intake temperature and pressure. At all operating conditions the measurements show that initially the liquid fuel penetrates almost linearly with increasing crank angle until reaching a maximum length. Then, the liquid-fuel penetration length remains fairly constant although fuel injection continues. At a TDC density of 16.6 kg/m3 and a temperature of about 1000 K the maximum penetration length is approximately 23 mm. However, it varies significantly as TDC conditions are changed, with the liquid-length being less at higher temperatures and at higher densities.
Technical Paper

The Effect of Platinum Catalysts on Propane Oxidation at Elevated Pressure

1988-10-01
881614
The potential for catalytically enhanced ignition in low-heat rejection Diesel engines has been experimentally studied under engine simulated conditions in a high pressure chemical flow reactor. Results are presented for propane oxidation on platinum at 6 and 10 atmospheres, at temperatures from 800K to 1050K, and at equivalence ratios from 0.5 to 4.0. For turbulent transport rates which are typical of those in an engine, as much as 20% of the fuel was found to react on the catalyst before the onset of the gas-phase ignition reactions. Depending on the adiabaticity of the combustion chamber walls, this could lead to significant thermal enhancement of the gas-phase ignition process. Evidence of chemical enhancement was also observed, at 10 atm under very fuel rich conditions, in terms of a change in the concentration and distribution of the hydrocarbon intermediate species. Possible mechanisms for the observed chemical enhancement due to surface generated species are discussed.
Technical Paper

The Combustion Improvements of Hydrogen / Diesel Dual Fuel Engine

2015-09-01
2015-01-1939
Hydrogen can be produced by electrolyzation with renewable electricity and reduce the combustion products from hydrogen mixture don't include CO, CO2 and unburned hydrocarbon components. We focused on these characteristics of hydrogen and high thermal efficiency of diesel engine and acquired the performance of hydrogen diesel dual fuel (DDF) engine. We changed proportion of hydrogen to total input energy and studied basic combustion and exhaust gas emission performance of hydrogen DDF operation. In addition, we studied the effects of advancement of diesel fuel injection timing and EGR on combustion behavior and improvement of NOx emission. Especially, EGR improved NOx emission from hydrogen DDF operation drastically without a decrease in thermal efficiency. Under hydrogen DDF operation with EGR, diesel fuel injection timing was advanced for stable combustion and it inhibited the degradation of thermal efficiency.
Technical Paper

Study on Removal of PM and NOx in Diesel Exhaust by Using DC Corona Discharge

2002-05-06
2002-01-1660
In order to remove the diesel particulate matter (PM) and nitrogen oxides (NOx) from diesel exhaust, the gas is passed through a corona discharge collector for PM and another corona discharge device for NOx oxidation. With the PM collector, PM is accumulated on the central electrode, after that, it is removed by incineration technique. NOx concentration is decreased by oxidation to HNO3. In this study, these corona discharge reactors were coupled for removal of PM and NOx in progression, and attempted to remove these emissions in a slipstream of 14 liters/min of an experimental diesel engine and an actual vehicle, respectively. In case of the experimental test engine, it is found that nearly 100% and 15% of the PM and NOx emissions were removed even at a low input power of 26W (1560 J/L specific energy deposition). In the vehicle tests 1) a PM removal rate of 60% is obtained at an input power of over 40W, 2) a NOx removal rate of 97% is obtained at an input power of over 100W.
Technical Paper

Study on Improvement of Combustion and Effect of Fuel Property in Advanced Diesel Engine

2010-04-12
2010-01-1117
The tasks to improve diesel emissions and fuel consumption must be accomplished with urgency. However, due to the trade-off relationship between NOx emissions, soot emissions and fuel consumption, clean diesel combustion should be achieved by both innovative combustion and fuel technologies. The objective of this study is to extend the clean diesel combustion operating range (Engine-out emission: NOx ≺ 0.2 g/kWh, Soot ≺ 0.02 g/kWh). In this study, performance of a single-cylinder test engine equipped with a hydraulic valve actuation system and an ultra-high pressure fuel injection system was investigated. Also evaluated, were the effects of fuel properties such as auto-ignitability, volatility and aromatic hydrocarbon components, on combustion performance. The results show that applying a high EGR (Exhaust gas recirculation) rate can significantly reduce NOx emission with an increase in soot emission.
Technical Paper

Study on Characteristics of Auto-Ignition and Combustion of Unsteady Synthetic Gas Jet

2007-04-16
2007-01-0629
It is thought that the synthetic gas, including hydrogen and carbon monoxide, has a potential to be an alternative fuel for internal combustion engines, because a heating value of the synthetic gas is higher than one of hydrogen or natural gas. A purpose of this study is to acquire stable auto-ignition and combustion of the synthetic gas which is supposed to be applied into a direct-injection compression ignition engine. In this study, the effects of ambient gas temperatures and oxygen concentrations on auto-ignition characteristics of the synthetic gas with changing percentage of hydrogen (H2) or carbon monoxide (CO) concentrations in the synthetic gas. An electronically-controlled, hydraulically-actuated gas injector was used to control a precise injection timing and period of gaseous fuels, and the experiments were conducted in an optically accessible, constant-volume combustion chamber under simulated quiescent diesel engine conditions.
Technical Paper

Spray and Exhaust Emission Characteristics of a Biodiesel Engine Operating with the Blend of Plant Oil and DME

2002-03-04
2002-01-0864
As an effective method to solve the global warming and the energy crisis, the research has been carried out for the adaptability of plant oil as an alternative fuel for Diesel engine. But there are the problems of engine performance and exhaust emissions owing to the high viscosity and low volatility, when the plant oil is used as a fuel. In order to eliminate these problems, spray characteristics of the DME (Dimethyl ether) blended plant oil has been examined by using the image processing based on the shadowgraph methodology. Results show that the optimum mixing ratio of the blend is about 50:50 (by weight %). Thereafter, experiments have been conducted with a DI Diesel engine using the DME blended plant oil, and compared the exhaust emissions with Diesel, DME and transesterified fuel operation. From the results, it can be concluded that the combustion characteristics of DME blended plant oil are comparable to Diesel fuel.
Technical Paper

Spray Characteristics of LPG Direct Injection Diesel Engine

2003-03-03
2003-01-0764
In this study, spray images of LPG Blended Fuels (LBF) for DI diesel engines were observed using a constant volume chamber at high ambient temperature and pressure, and the spray characteristics of the fuel were investigated. The LBF spray started to vaporize at the injector tip and the outer downstream regions of the spray, like diesel fuel, because of the high temperature at these areas. There were more vaporized areas compared to diesel fuel. Sufficient fuel injection volume and volatility of LBF resulted in good fuel-air mixture, then, THC emissions decreased compared to diesel fuel at high load engine test conditions. Butane spray image could not be observed at the injector tip. It seems that the high temperature of the injector tip caused the butane spray to vaporize rapidly. Spray tip penetration with LBF and butane were equal or greater than with diesel fuel. The high volatility of LBF and butane had no noticeable effect on spray penetration.
Technical Paper

Spray Characteristics of DME Blended Biodiesel Oil

2001-09-24
2001-01-3636
Spray characteristics of biodiesel oil was investigated as it can be applied to industrial combustion systems, including internal combustion engines. Shadowgraph methodology using Greenfield system was used to take some images of the spray and to measure droplet size. A high speed video camera was also used to take a picture of spray penetration and its angle. From the results, it shows that DME blended biodiesel oil has almost the same droplet size as conventional diesel oil, when the blended DME ratio is over 50% by weight. It is also shown that there exists optimum fuel injection pressure that has minimum droplet size when the ambient gas pressure is constant.
Technical Paper

Spectroscopic Investigation of the Combustion Process in an LPG Lean-burn SI Engine

1999-10-25
1999-01-3510
Band spectrum images for CH, OH and CHO were taken in a heavy duty type LPG lean-burn SI engine, to investigate the combustion process as it pertains to the pollutant formation process in the post flame region. Full spectra and band spectrum flame images were observed with a bottom view single cylinder research engine and two high speed cameras. NOx emissions were also measured for excess air ratios ranging from 1.0 to 1.6. A thermodynamic model, including the detailed chemical kinetic mechanism for LPG and NOx formation reactions, was developed to predict the major reaction species in the post flame region, and NOx emissions during the combustion process. The model qualitatively described the flame images for each band spectrum and could predict the measured NOx emissions very well.
Technical Paper

Spectroscopic Investigation of the Combustion Process in DME Compression Ignition Engine

2002-05-06
2002-01-1707
For better understanding of the in-cylinder combustion characteristics of DME, combustion radicals of a direct injection DME-Fueled compression ignition engine were observed using a spectroscopic method. In this initial report, the emission intensity of OH, CH, CHO, C2 and NO radicals was measured using a photomultiplier. These radicals could be measured with wavelength resolution (half-width) as about 3.3 nm. OH and CHO radicals appeared first, and then CH radical emission was detected. After that, the combustion radicals were observed using a high-speed image intensified video camera with band-pass filter. All of radicals were able to observe as images with half-width as 6 or about 10 nm. Rich DME leaked from nozzle was burning at the end of combustion. Therefore, the second light emission of C2 radical after the main combustion was observed.
Technical Paper

Spectroscopic Analysis of Combustion in the DME Diesel Engine

2004-03-08
2004-01-0089
For better understanding of the combustion characteristics in a direct injection dimethyl ether (DME) engine, the chemiluminescences of a burner flame and in-cylinder flame were analyzed using the spectroscopic method. The emission intensities of chemiluminescences were measured by a photomultiplier after passing through a monochrome-spectrometer. For the burner flame, line spectra were found nearby the wave length of 310 nm, 430 nm and 515 nm, arising from OH, CH and C2 radicals, respectively. For the in-cylinder flame, a strong continuous spectrum was found from 340 nm wave length to 550 nm. Line spectra were also detected nearby 310 nm, 395 nm and 430 nm, arising from OH, HCHO, and C2 radicals, respectively, partially overlapping with the continuous spectrum. Of these line spectra, 310 nm of OH radical did not overlapped with the continuous spectrum.
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