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Heavy-duty diesel engine particulate matter (PM) emissions must be reduced from 0.1 to 0.01 grams per brake horsepower-hour by 2007 due to EPA regulations [1]. A catalyzed particulate filter (CPF) is used to capture PM in the exhaust stream, but as PM accumulates in the CPF, exhaust flow is restricted resulting in reduced horsepower and increased fuel consumption. PM must therefore be burned off, referred to as CPF regeneration. Unfortunately, nominal exhaust temperatures are not always high enough to cause stable self-regeneration when needed. One promising method for active CPF regeneration is to inject fuel into the exhaust stream upstream of an oxidation catalytic converter (OCC). The chemical energy released during the oxidation of the fuel in the OCC raises the exhaust temperature and allows regeneration.

A study of the sources of variability in particulate measurements using the Heavy-Duty Transient Test (40 CFR Subpart N) has been conducted. It consisted of several phases: a critical examination of the test procedures, visits to representative facilities to compare and contrast facility designs and test procedures, and development of a simplified model of the systems and procedures used for the Heavy-Duty Transient Test. Some of the sources of variability include; thermophoretic deposition of particulate matter onto walls of the sampling system followed by subsequent reentrainment in an unpredictable manner, the influence of dilution and cooling upon the soluble organic fraction, inconsistency among laboratories in the engine and dynamometer control strategies, and errors in measurements of flows into and out of the secondary dilution tunnel.

Gas concentrations, under different engine operating conditions, different locations relative to the fuel spray are presented. The gas that is sampled is “snatched” from a continuous flow sampling probe. The time of snatching is controlled. The concentrations of CO, CO2, NOx, and O2 are plotted against, crank position. The sampled gases were analyzed for concentration in the as taken state and after the sampled gas had passed through a heated catalytic oxidation converter. Analysis have been performed and plots are presented of the findings. The analytic procedure developed for the data analysis are presented in detail.

The Vehicle Engine Cooling System Simulation (VECSS) computer code has been developed at the Michigan Technological University to simulate the thermal response of a cooling system for an on-highway heavy duty diesel powered truck under steady and transient operation. In Part 1 of this research, the code development and verification has been presented. The revised and enhanced VECSS (version 8.1) software is capable of simulating in real-time a Freightliner FLD 120 truck with a Detroit Diesel Series 60 engine, Behr McCord radiator, Allied signal / Garrett Automotive charge air cooler and turbocharger, Kysor DST variable speed fan clutch, DDC oil and coolant thermostat. Other cooling system components were run and compared with experimental data provided by Kysor Cooling Systems. The experimental data were collected using the Detroit Diesel Electronic Control's (DDEC) Electronic Control Module (ECM) and the Hewlett Packard (HP) data acquisition system.

The Vehicle Engine Cooling System Simulation (VECSS) computer code has been developed at the Michigan Technological University to simulate the thermal response of the cooling system of an on-highway heavy duty diesel powered truck under steady and transient operation. This code includes an engine cycle analysis program along with various components for the four main fluid circuits for cooling air, cooling water, cooling oil, and intake air, all evaluated simultaneously. The code predicts the operation of the response of the cooling circuit, oil circuit, and the engine compartment air flow when the VECSS is operated using driving cycle data of vehicle speed, engine speed, and fuel flow rate for a given ambient temperature, pressure and relative humidity.

Enhanced VECSS simulation program was tested for use as a cooling system design tool. The design parameters indicated in the study were varying fan type, fan speed, engine power rating, radiator style and air conditioning condenser. The predicted temperature results were compared to the experimental data, and were found to follow the measured trends, and in cases when the exact parameters were simulated, were found to match the temperature amplitudes.

A one-dimensional incompressible flow model covering the mechanisms involved in the airflow through an automotive radiator-shroud-fan system with no heat transfer was developed. An analytical expression to approximate the experimentally determined fan performance characteristics was used in conjunction with an analytical approach for this simplified cooling airflow model, and the solution is discussed with illustrations. A major result of this model is a closed form equation relating the transient velocity of the air to the vehicle speed, pressure rise characteristics and speed of the fan, as well as the dimensions and resistance of the radiator. This provides a basis for calculating cooling airflow rate under various conditions. The results of the incompressible flow analysis were further compared with the computational results obtained with a previously developed one-dimensional, transient, compressible flow model.

A study was undertaken to investigate the affect of exhaust gas recirculation (EGR) on engine wear and lubricating oil degradation in a heavy duty diesel engine using a newly developed methodology that uses analytical ferrography in conjunction with short term tests. Laboratory engine testing was carried out on a Cummins NTC-300 Big Cam II diesel engine at rated speed (1800 RPM) and 75% rated load with EGR rates of 0, 5, and 15% using a SAE 15W40 CD/SF/EO-K oil. Dynamometer engine testing involved collecting oil samples from the engine sump at specified time intervals through each engine test. These oil samples were analyzed using a number of different oil analysis techniques that provide information on the metal wear debris and also on the lubricating oil properties. The results from these oil analysis techniques are the basis of determining the effect of EGR on engine wear and lubricating oil degradation, rather than an actual engine tear down between engine tests.

This paper describes a method for studying reactions of hydrocarbons in S.I. engine exhaust gases. The reaction of ethane is described using an Arrhenius model (experimentally E = 86,500 cal/mole) for the rate of ethane diappearance and empirical correlations for distributions of the products carbon monoxide, ethylene, formaldehyde, methane, acetylene, and propane as a function of the fraction of ethane reacted. The results show that the nature of partial oxidation products from a nonreactive hydrocarbon may be less desirable from an air pollution viewpoint than the initial hydrocarbon.

The ratio of two temperature gradients across the combustion-chamber wall in a diesel engine is used to provide a heat flow ratio showing the radiant heat transfer as a per cent of local total heat transfer. The temperature gradients were obtained with a thermocouple junction on each side of the combustion-chamber wall. The first temperature gradient was obtained by covering the thermocouple at the cylinder gas-wall interface with a thin sapphire window, while the second was obtained without the window. Results show that the time-average radiant heat transfer is of significant magnitude in a diesel engine, and is probably even more significant in heat transfer during combustion and expansion.

The techniques used to characterize the chemical and physical nature of particulates in diesel exhaust emissions are reviewed. The emphasis is on understanding the broader aspects of the fundamental nature of not only diesel particulates, but particulate systems in general. Consideration is given to the special nature of particulates which make them significant pollutants and to the relative place of the diesel in the formation of man-made particles. The underlying combustion processes leading to carbon and sulfur based particulates are reviewed. The important variables in steps of the combustion processes which lead to particulate formation are considered, as well as major fuel and engine factors. Collection methods are examined with examples given from current diesel dilution techniques. Probes, sampling lines, and instrumentation are considered.

A diesel exhaust sampling system was specially designed to measure and collect emissions from a ceramic wall-flow particulate trap during periods of controlled electric regeneration with the exhaust emissions bypassing the trap. This resulted in the regeneration emissions being independent of those produced during either baseline (no control) or trap (exhaust filtration) sampling conditions. This system provided data regarding the physical, chemical, and biological character of regeneration emissions relative to baseline and trap emissions. Selected emission levels measured continuously during the regeneration process were also used to define the particle combustion process in the trap core. Variations in hydrocarbons (HC), oxides of nitrogen (NOx), and particulate volume concentrations during the regeneration process were used to define four stages of the combustion process: preheat; combustion wave formation; combustion wave propagation; and combustion wave extinction.

One of the more objectionable aspects of the use of the diesel engine is its emission of particulate matter. Methods for collecting particulate matter samples in the undiluted exhaust gases with an Andersen Impactor for gravimetric and electron microscopy analysis are developed. A direct injection Vee-eight naturally aspirated diesel engine was used in the study. This paper presents the results of an in-depth study of the physical characteristics of diesel particles. The size distribution of the particulate matter was obtained using an Andersen Inertial Impactor for the engine conditions applicable to the SAE 13-mode cycle. The particulate matter was analyzed using both scanning and transmission electron microscopes and was found to be comprised of individual spherical particles ranging from 100 ņ to 800 Å with a mean size of approximately 260 Å. The particulate matter was analyzed for carbon, hydrogen and nitrogen.

A study was conducted to assess the effects of controlling filter face temperatures and two differently sized collection systems on diesel total particulate matter (TPM) and vapor phase hydrocarbon levels from a diesel engine. The results were used to revise sampling protocols so that variability associated with quantitation of polynuclear aromatic hydrocarbons (PAH) is minimized. Particulate soluble organic fraction (SOF) levels (%) were compared 1) for tests where the dilute exhaust filter face temperature was held constant by varying dilution ratio (DR) to account for day to day variations in inlet air temperature to the tunnel and 2) for tests in earlier studies where the DR was held constant and the filter face temperature then varied because of varying tunnel inlet air temperature. Between date variations in %SOF were reduced by about 60% due to holding filter face temperatures constant, compared to holding DR constant.

A 1-D 2-layer model developed previously at MTU was used in this research to predict the pressure drop, filtration characteristics and various properties of the particulate filter and the particulate deposit layer. The model was calibrated and validated for this CPF with data obtained from steady state experiments conducted using a 1995 Cummins M11-330E heavy-duty diesel engine with manual EGR and using ULSF. The CPF used is a NGK filter having a cordierite substrate with NEX catalyst type formulation (54% porosity, 15.0 μm mean pore diameter and 50 gms/ft3 Pt). The filter was catalyzed using a wash coat process. The model was used to predict the pressure drop, particulate mass retained inside the CPF, particulate mass filtration efficiency and concentration downstream of the CPF with agreement between the experimental and simulated data.

The Vehicle Engine Cooling System Simulation (VECSS) developed at Michigan Technological University in 1982 was enhanced to the extent that it can be used as a cooling system design tool for a heavy duty diesel truck. The enhancements are described in the present paper, while the use of the VECSS as a cooling system design tool is presented in the companion paper, “The Use of the Vehicle Engine Cooling System Simulation as a Cooling System Design Tool.” The enhanced VECSS was validated by comparing predicted temperature results to data collected by the Cummin's Engine Company during Air-to-Boil (ATB) tests, and during an “over-the-road” dynamic run of a heavy duty diesel truck. The enhanced model provided results which compared very favorably to both, the steady state ATB data and the dynamic “over-the-road” data.

Physical, chemical, and biological characterization data for the particulate emissions from a Caterpillar 3208 diesel engine with and without Corning porous ceramic particulate traps are presented. Measurements made at EPA modes 3,4,5,9,lO and 11 include total hydrocarbon, oxides of nitrogen and total particulate matter emissions including the solid fraction (SOL), soluble organic fraction (SOF) and sulfate fraction (SO4), Chemical character was defined by fractionation of the SOF while biological character was defined by analysis of Ames Salmonella/ microsome bioassay data. The trap produced a wide range of total particulate reduction efficiencies (0-97%) depending on the character of the particulate. The chemical character of the SOF was significantly changed through the trap as was the biological character. The mutagenic specific activity of the SOF was generally increased through the trap but this was offset by a decrease in SOF mass emissions.

A 1-D 2-layer model developed previously at MTU was used in this research to predict the pressure drop, filtration characteristics and various properties of the particulate filter and the particulate deposit layer. The model was used along with dilute emission data to characterize two catalyzed particulate filters (CPFs) having different catalyst loading and catalyst application processes. The model was calibrated and validated with data obtained from steady state experiments conducted using a 1995 Cummins M11-330E heavy-duty diesel engine with manual EGR with different fuels for the two different CPFs. The two different catalyzed particulate filters were CPF III (5 gms/ft3 Pt) and CPF V (50 gms/ft3 Pt). Both the CPFs had cordierite substrates with CPF III and CPF V had MEX and NEX catalyst type formulation respectively. The CPF III filter was catalyzed using a solution-impregnated process while the CPF V filter was catalyzed using a wash coat process.

To determine the effects of knock in a spark-ignition, single-cylinder engine with cooled exhaust upon the exhaust composition, exhaust products (CO, CO2, and total hydrocarbons) were measured by non-dispersive infrared analyzers (NDIRA) and by a flame ionization detector (FID). Individual hydrocarbons were separated on a gas-liquid chromatograph. In fuel-rich mixtures, the FID indicated noticible decreases in the hydrocarbon concentrations in the presence of knock. The NDIRA did not indicate a decrease in the hydrocarbons at knock of lower intensities but showed decreases in hydrocarbons at knock of higher intensities. Chromatograms indicated a preferential decreases in acetylene at the time of knock, causing different responses at lower intensities. In fuel-lean mixtures, no apparent effect of knock on the hydrocarbons was indicated.

The effect of fuel changes on diesel oxidation catalyst performance was studied by comparing the physical, chemical and biological character of the particulate emissions using three different fuels. Baseline (uncatalyzed) emissions were also compared for these same fuels. The fuels used for this study were: a typical No. 2 fuel, a No. 1 fuel, and a shale oil-derived diesel fuel. Comparisons of NOX, NO, NO2, HC and particulate mass emissions using each fuel were made using selected modes from the EPA 13 mode cycle. Changes in the chemical and biological character of the soluble organic fraction (SOF) were also studied. Fuel properties, most notably fuel sulfur content, were found to affect the performance of the oxidation catalyst used. Fuel sulfur content should be kept as low as possible if catalytic converters are used on diesel powered equipment.