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Engine experiments were carried out in order to investigate the mechanisms involved in connection with the emission of lubricant related polyaromatic hydrocarbons (PAH) from a D.I. diesel engine. In the experiments only the mechanisms related to pyrene emissions were investigated, since synthetic fuels and lubricants containing pyrene as the only aromatic compond were used. Particulate matter (PM) and the soluble organic fraction (SOF) of PM as well as PAH emissions were measured for different engine conditions at different levels of pyrene in the lubricant and the fuel. Possible mechanisms of PAH transportation from the lubricant to the exhaust gas are discussed based on the experimental results, as well as the importance of fuel and lubricant to SOF and PAH emissions.

A simple real-time measurement system for the components of volatile organic compounds (VOCs) and polyaromatic hydrocarbons (PAHs) in automobile exhaust gas using a laser ionization method was developed. This method was used to detect VOCs and PAHs in the exhaust gas of a diesel truck while idling, at 60 km/h, and in the Japanese driving mode JE05. As a result, various VOCs and PAHs, such as xylene and naphthalene, were simultaneously detected, and real-time changes in their concentration were obtained at 1 s intervals.

The engine in the research is a single cylinder DI diesel using the emission reduction techniques such as high boost, high injection pressure and broad range and high quantity of exhaust gas recirculation (EGR). The study especially focuses on the reduction of particulate matter (PM) under the engine operating conditions. In the experiment the authors measured engine performance, exhaust gases and mass of PM by low sulfur fuel such as 3 ppm and low sulfur lubricant oil such as 0.26%. Then the PM components were divided into soluble organic fraction (SOF) and insoluble organic fraction (ISOF) and they were measured at each engine condition. The mass of SOF was measured from the fuel fraction and lubricant oil fraction by gas chromatography. Also each mass of soot fraction and sulfate fraction was measured as components of ISOF. The experiment was conducted at BMEP = 2.0 MPa as full load condition of the engine and changing EGR rate from 0% to 40 %.

Exhaust emissions and particulate matter (PM) from an engine with a conventional continuous regeneration diesel particulate filter (DPF) were measured to evaluate DPF performance under the Japan 13-mode cycle, European Stationary Cycle and various transient cycles: U.S. transient cycle, Japan Automobile Research Institute cycle, and World-wide Heavy Duty Cycle. The emission tendencies with and without DPF under these conditions were clarified. According to these experiments, accumulated PM in the DPF under the driving modes mentioned above has influence on measurement errors. It is necessary to estimate the amount of accumulated PM in the DPF to evaluate the PM reduction rate correctly. This study also measured particle size distribution of diesel exhaust particulates (DEP) downstream of the DPF using an electrical low-pressure impactor (ELPI). As a result, we determined that most of the particles not trapped by the DPF are less than 110nm.

To clarify the effect of fuel properties on diesel exhaust emissions, direct injection of two component fuels with approximately zero aromatic content and sulfur were attempted in a diesel engine. Fuels were prepared using paraffins having different cetane numbers and boiling points. Parameters considered are the Average Boiling Point (ABP) by volume and the difference of component characteristics for the same ABP. The results indicate that the trade off relation between NOx and particulate matter (PM) emissions depends significantly on ABP or density and is independent of the fuel component. On the other hand, components of the mixed fuels have significant influence on SOF and THC emissions. Fuels having higher amount of low boiling point components emit higher THC. Mixtures of low boiling point-high cetane number fuel and high boiling point-low cetane number fuel or fuel that contains normal paraffins only emit higher SOF.

A prototype CNG engine for heavy-duty trucks has been developed. The engine had sufficient output in practical use, and the green-house gas emission rate was below that of the base diesel engine. Furthermore, the NOx emission rate was reduced to 0.16 g/kWh in the JE05 mode as results of having fully adjusted air fuel ratio control. The measured emission characteristics of particles from the prototype CNG engine demonstrated that oil consumption was related to the number of particles. Moreover, when oil consumption is at an appropriate level, the accumulation mode particles are significantly reduced, and the nuclei mode particles are fewer than those of diesel-fueled engines.

Recently, after-treatment techniques for diesel engine emission have made remarkable progress with the development of suitable De-NOx catalysts. The urea-injection SCR system is one of the candidates for a high efficiency De-NOx method for diesel engine emissions. This system reduces NOx through a reaction with ammonia (NH3) that is generated from injected urea. In this system, it is very important to control the amount and timing of the urea injection so as to minimize the NH3 gas slip. Therefore, NH3 gas measurement is becoming important during the development of NOx after-treatment systems even though NH3 is not a target component of the current emission regulations. In this paper, a new NH3 gas analyzer utilizing a chemi-luminescence detection (CLD) method has been developed. The new NH3 analyzer consists of dual detectors (DCLDs) and a furnace for a NH3 oxidization catalyst. Real-time concentration of NH3 can be calculated from the difference of NOx readings of two detectors.