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The aim of this research was to investigate the mechanism causing autoignition and the effect of exhaust gas recirculation (EGR) on combustion by detecting the behavior of the OH radical and other excited molecules present in the flame in a spark ignition engine. The test equipment used was a 2-cycle engine equipped with a Schnürle scavenging system. Using emission spectroscopy, the behavior of the OH radical was measured at four locations in the end zone of the combustion chamber. The OH radical plays an important role in the elemental reactions of hydrocarbon fuels. When a certain level of EGR was applied according to the engine operating conditions, the unburned gas became active owing to heat transfer from residual gas near the measurement positions on the exhaust port side and the influence of excited species in the residual gas, and autoignition tended to occur.

There is an urgent need today to improve the thermal efficiency of spark- ignition (SI) engines in order to reduce carbon dioxide emission and conserve energy in an effort to prevent global warming. However, a major obstacle to improving thermal efficiency by raising the compression ratio of SI engine is the easily occurrence of engine knocking. The result of studies done by numerous researchers have shown that knocking is an abnormal combustion in which the unburned gas in the end zone of the combustion chamber autoignites. However, the combustion reaction mechanism from autoignition to the occurrence of knocking is still not fully understood. The study deals with the light absorption and emission behavior in the preflame reaction interval before hot flame reactions.

Using absorption spectroscopy, simultaneous measurements were made of the behavior of the OH (characteristic spectrum of 306.4 nm), CH (431.5 nm) and C2(516.5 nm) radicals in the end-gas region and center of the combustion chamber of a spark-ignition engine during preflame reactions with four types of fuel having different octane numbers. The results of this research show that the behavior of the OH, CH and C2 radicals in preflame reactions differed significantly in both the center and end-gas region of the combustion chamber depending on the octane number of the fuel and also between normal and knocking combustion conditions.

Homogeneous Charge Compression Ignition (HCCI) combustion has attracted widespread interest as a combustion system that offers the advantages of high efficiency and low exhaust emissions. However, it is difficult to control the ignition timing in an HCCI combustion system owing to the lack of a physical means of initiating ignition like the spark plug in a gasoline engine or fuel injection in a diesel engine. Moreover, because the mixture ignites simultaneously at multiple locations in the cylinder, it produces an enormous amount of heat in a short period of time, which causes greater engine noise, abnormal combustion and other problems in the high load region. The purpose of this study was to expand the region of stable HCCI engine operation by finding a solution to these issues of HCCI combustion.

Homogeneous Charge Compression Ignition (HCCI) engines have attracted much attention and are being widely researched as engines characterized by low emissions and high efficiency. However, one issue of HCCI engines is their limited operating range because of the occurrence of rapid combustion at high loads and misfiring at low loads. It is known that knocking accompanied by in-cylinder pressure oscillations also occurs in HCCI engines at high loads, similar to knocking seen in spark-ignition engines. In this study, HCCI combustion accompanied by in-cylinder pressure oscillations was visualized by taking high-speed photographs of the entire bore area. In addition, the influence of internal exhaust gas circulation (EGR) on HCCI knocking was also investigated. The visualized combustion images revealed that rapid autoignition occurred in the end-gas region during the latter half of the HCCI combustion process when accompanied by in-cylinder pressure oscillations.

This study was conducted to investigate the influence of cooled recirculated exhaust gas (EGR) on abnormal combustion in a Homogenous Charge Compression Ignition (HCCI) engine. The condition of abnormal HCCI combustion accompanied by cylinder pressure oscillations was photographed with a high-speed camera using a 2-stroke optically accessible engine that enabled visualization of the entire bore area. Exhaust gas was cooled with a water-cooled intercooler for introducing cooled EGR. Experiments were conducted in which the quantity of cooled EGR introduced was varied and a comparison was made of the autoignition behavior obtained under each condition in order to investigate the influence of cooled EGR on abnormal HCCI combustion. The results revealed that cylinder pressure oscillations were reduced when cooled EGR was introduced. That reduction was found to be mainly ascribable to the effect of cooled EGR on changing the ignition timing.

One issue of downsized and supercharged engines is low-speed pre-ignition (LSPI) that occurs in the low-speed and high-load operating region. One proposed cause of LSPI is the influence of the engine oil and its additives. However, the effect of engine oil additives on pre-ignition and the mechanism involved are still not fully understood. This study investigated the influence of engine oil additives on abnormal combustion in a spark-ignition engine. A four-stroke air-cooled single-cylinder engine with a side valve arrangement was used in conducting combustion experiments. The research methods used were in-cylinder pressure analysis, in-cylinder visualization and absorption spectroscopic analysis. Engine oil additives were mixed individually at a fixed concentration into a primary reference fuel with an octane number of 50 and their effect on knocking was investigated.

The uniform lean methanol-air mixture was provided to the diesel engine and was ignited by the direct diesel fuel injection. The internal EGR is added to this ignition method in order to activate the fuel in the mixture and to increase the mixture temperature. The test engine was a 4-stroke, single- cylinder direct-injection diesel engine. The cooling system was forced-air cooling and displacement volume was about 211 (cm3). The compression ratio was about 19.9:1. The experiment was made under constant engine speed of 3000 (r/min). The boost pressure was maintained at 101.3 (kPa). Five values of mass flow rate of diesel fuel injection were selected from 0.060 (g/s) to 0.167 (g/s) and five levels of back pressure: 0), 26.7, 53.3, 80.0 and 106.6 (kPa) were selected for the experiment. The effect of internal EGR is varied by the back pressure level.

Unresolved issues of Homogeneous Charge Compression Ignition (HCCI) combustion include an extremely rapid pressure rise on the high load side and resultant knocking. Studies conducted to date have examined ways of expanding the region of stable HCCI combustion on the high load side such as by applying supercharging or recirculating exhaust gas (EGR). However, the effect of applying EGR gas to supercharged HCCI combustion and the mechanisms involved are not fully understood. In this study, the effect of EGR gas components on HCCI combustion was investigated by conducting experiments in which external EGR gas was applied to supercharged HCCI combustion and also experiments in which nitrogen (N2) and carbon dioxide (CO2) were individually injected into the intake air pipe to simulate EGR gas components. In addition, HCCI combustion reactions were analyzed by conducting chemical kinetic simulations under the same conditions as those of the experiments.

The uniform lean methanol-air mixture was provided to the diesel engine and was ignited by direct diesel fuel injection. In this study, the internal EGR is added to this ignition method in order to activate the fuel in the mixture and to increase the temperature of the mixture before the ignition. It is confirmed that the lean methanol-air mixture of air-fuel ratio between 130 and 18 could be ignited and burned when the back pressure of 80 [kPa] is added. The ignition and combustion characteristics can be improved by the internal EGR, however the engine performance and NOx emission deteriorated.

Homogeneous Charge Compression Ignition (HCCI) combustion has attracted widespread interest in recent years as a clean, high-efficiency combustion system. However, it is difficult to control the ignition timing in HCCI engines because they lack a physical means of inducing ignition. Another issue of HCCI engines is their narrow operating range because of misfiring that occurs at low loads and abnormal combustion at high loads. As a possible solution to these issues, this study focused on the application of a streamer discharge in the form of non-equilibrium plasma as a technique for assisting HCCI combustion. Experiments were conducted with a four-stroke single-cylinder engine fitted with an ignition electrode in the combustion chamber. A streamer discharge was continuously generated in the cylinder during a 720-degree interval from the intake stroke to the exhaust stroke.

In this research, the effect of high-temperature residual gas, resulting from the application of a certain level of EGR, on combustion was investigated using a two-stroke engine and alcohol fuels (ethanol and methanol) and gasoline as the test fuels. Measurements were made of the light emission intensity of the OH radical on the intake and exhaust port sides of the combustion chamber and of the combustion chamber wall temperature (spark plug washer temperature) and the exhaust gas temperature. Data were measured and analyzed in a progression from normal combustion to autoignited combustion to preignition and to knocking operation.

The uniform lean gasoline-air mixture was provided to the diesel engine and was ignited by the direct diesel fuel injection. In this study, the internal EGR is add to this ignition method in order to activate the fuel in the mixture before the ignition. It is confirmed that the lean mixture of air-fuel ratio between 150 and 40 could be ignited and burned by this ignition method when the back pressure of 80 [kPa] is added, and the burning period is shorted by internal EGR. However, as the back pressure increases, NOx concentration is increased by the high temperature residual gas.

Homogeneous Charge Compression Ignition (HCCI) combustion has attracted considerable interest in recent years as a new combustion concept for internal combustion engines. On the other hand, two combustion concepts proposed for two-cycle spark-ignition (SI) engines are Active Thermo-Atmosphere Combustion (ATAC) and Activated Radical (AR) combustion. The authors undertook this study to examine the similarities and differences between HCCI combustion and ATAC (AR) combustion. Differences in the low-temperature oxidation reaction behavior between these two combustion processes were made clear using one test engine.

This study investigated the effects of recirculated exhaust gas (EGR) and its principal components of N2, CO2 and H2O on moderating Homogeneous Charge Compression Ignition (HCCI) combustion. Experiments were conducted using two types of gaseous fuel blends of DME/propane and DME/methane as the test fuels. The addition rates of EGR, N2, CO2 and H2O were varied and the effects of each condition on HCCI combustion of propane and methane were investigated. The results revealed that the addition of CO2 and H2O had the effect of substantially delaying and moderating rapid combustion. The addition of N2 showed only a slight delaying and moderating effect. The addition of EGR had the effect of optimally delaying the combustion timing, while either maintaining or increasing the indicated mean effective pressure and indicated thermal efficiency ηi.

There are strong demands today to further improve the thermal efficiency of internal combustion engines against a backdrop of various environmental issues, including rising carbon dioxide (CO2) emissions and global warming. One factor that impedes efforts to improve the thermal efficiency of spark ignition engines is the occurrence of knocking. The aim of this study was to elucidate the details of knocking based on spectroscopic measurements and visualization of phenomena in the combustion chamber of a test engine that was operated on three primary reference fuels with different octane ratings (0 RON, 30 RON, and 50 RON). The ignition timing was retarded in the experiments to delay the progress of flame propagation, making it easier to capture the behavior of low-temperature oxidation reactions at the time knocking occurred.

The use of a higher compression ratio is desirable for improving the thermal efficiency and specific power of spark-ignition engines, but it gives rise to a problem of engine knock. In the present research, an investigation was made of the role of the preflame reaction region of a spark-ignition engine in the occurrence of autoignition. Emission spectroscopy was used to measure the behavior of formaldehyde (HCHO) in a cool flame. In addition, measure the behavior of the faint light attributed to the HCO radical in a blue flame with the concurrent measurement of the OH radical. The emission waveforms measurements obtained for HCHO when n-heptane (ORON) was used as the fuel, It is thought that these tendencies correspond to the passage and degeneracy of a cool flame. Further, the emission waveforms measured for the HCO radical when blended fuels (6ORON, 8ORON) were correspond to that of a blue flame.

Engine knock is the one of the main issues to be addressed in developing high-efficiency spark-ignition (SI) engines. In order to improve the thermal efficiency of SI engines, it is necessary to develop effective means of suppressing knock. For that purpose, it is necessary to clarify the mechanism generating pressure waves in the end-gas region. This study examined the mechanism producing pressure waves in the end-gas autoignition process during SI engine knock by using an optically accessible engine. Occurrence of local autoignition and its development process to the generation of pressures waves were analyzed under several levels of knock intensity. The results made the following points clear. It was observed that end-gas autoignition seemingly progressed in a manner resembling propagation due to the temperature distribution that naturally formed in the combustion chamber. Stronger knock tended to occur as the apparent propagation speed of autoignition increased.

Although metallic compounds are widely known to affect combustion in internal combustion engines, the potential of metallic additives in engine oils to initiate abnormal combustion has been unclear. In this study, we investigated the influence of combustion chamber deposits derived from engine oil additives on combustion in a spark-ignited engine. We used a single-cylinder four-stroke engine, and measured several combustion characteristics (e.g., cylinder pressure, in-cylinder ultraviolet absorbance in the end-gas region, and visualized flame propagation) to evaluate combustion anomalies. To clarify the effects of individual additive components, we formed combustion products of individual additives in a combustion chamber prior to measuring combustion characteristics. We tested three types of metallic additives: a calcium-based detergent, a zinc-based antiwear agent, and a molybdenum-based friction modifier.

Supercharged direct-injection engines are known to have a tendency toward abnormal combustion such as spontaneous low-speed pre-ignition and strong knock because they operate under low-speed, high-load conditions conducive to the occurrence of irregular combustion. It has been hypothesized that one cause of such abnormal combustion is the intrusion of engine oil droplets into the combustion chamber where they become a source of ignition. It has also been reported that varying the composition of engine oil additives can change susceptibility to abnormal combustion. However, the mechanisms involved are not well understood, and it is not clear how the individual components of engine oil additives affect autoignition. In this study, abnormal combustion experiments were conducted to investigate the effect on autoignition of a calcium-based additive that is typically mixed into engine oil to act as a detergent.