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Emissions from light duty vehicles have traditionally been measured using a chassis dynamometer, while heavy duty testing has been based on engine dynamometers. However, the need for in-use vehicle emissions data has led to the development of two transportable heavy duty chassis dynamometers capable of testing buses and heavy trucks. A test cycle has been developed for Class 8 trucks, which typically have unsyncronized transmissions. This test cycle has five peaks, each consisting of an acceleration, cruise period, and deceleration, with speeds and acceleration requirements that can be met by virtually all vehicles in common service. Termed the “WVU 5 peak truck test”, this 8 km (5 mile) cycle has been used to evaluate the emissions from diesel and ethanol powered over-the-road tractors and from diesel and ethanol powered snow plows, all with Detroit Diesel 6V92 engines.

A bi-fuel engine capable of operating either on compressed natural gas (CNG) or gasoline is being developed for the transition to alternative fuel usage. A Saturn 1.9 liter 4-cylinder engine was selected as a base powerplant. A control system that allows closed-loop optimization of both fuel delivery and spark timing was developed. Stock performance and emissions of the engine, as well as performance and emissions with the new controller on gasoline and CNG, have been documented. CNG operation in an engine designed for gasoline results in power loss because of the lower volumetric efficiency with gaseous fuel use, yet such an engine does not take advantage of the higher knock resistance of CNG. It is the goal of this research to use the knock resistance of CNG to recover the associated power loss. The two methods considered for this include turbocharging with a variable boost wastegate and raising the compression ratio while employing variable valve timing.

The effects of fuel composition on emissions levels from compression ignition engines can be profound, and this understanding has led to mandated reductions in both sulfur and aromatic content of automotive diesel fuels. A Navistar T444E (V8, 7.3 liter) engine was installed on an engine dynamometer and subjected to transient emissions measurement using a variety of fuels, namely federal low sulfur pump diesel; California pump diesel; Malaysian Fischer-Tropsch fuel with very low sulfur and aromatic content; various blends of soy-derived biodiesel; a Fischer-Tropsch fuel with very low sulfur and 10% aromatics; and the same Fischer-Tropsch fuel with 10% isobutanol by volume. The biodiesel blends showed their ability to reduce particulate matter, but at the expense of increasing oxides of nitrogen (NOx), following the simple argument that cetane enhancement led to earlier ignition. However, the Fischer-Tropsch fuels showed their ability to reduce all of the regulated emissions.

Regulated emissions (THC, CO, NOx, and PM) and particulate SOF and sulfate fractions were determined for a 1995 Detroit Diesel Series 50 urban bus engine at varying fuel sulfur levels, with and without catalytic converters. When tested on EPA certification fuel without an oxidation catalyst this engine does not appear to meet the 1994 emissions standards for heavy duty trucks, when operating at high altitude. An ultra-low (5 ppm) sulfur diesel base stock with 23% aromatics and 42.4 cetane number was used to examine the effect of fuel sulfur. Sulfur was adjusted above the 5 ppm level to 50, 100, 200, 315 and 500 ppm using tert-butyl disulfide. Current EPA regulations limit the sulfur content to 500 ppm for on highway fuel. A low Pt diesel oxidation catalyst (DOC) was tested with all fuels and a high Pt diesel oxidation catalyst was tested with the 5 and 50 ppm sulfur fuels.

An alternative fuel that has demonstrated considerable potential in reducing emissions and crude oil dependence is compressed natural gas (CNG). A dedicated CNG vehicle suffers from the lack of an adequate number of fueling stations and the poor range limited by CNG storage technology. A vehicle capable of operating on either gasoline or natural gas allows alternative fuel usage without sacrificing vehicle range and mobility. Although many such bi-fuel vehicles are in existence, historically they have employed older engine designs and made compromises in engine control parameters that can degrade performance relative to gasoline and increase emissions. A modern production engine, a 1992 Saturn 1.9 liter 16 valve powerplant, is being optimized for operation on each fuel to realize the full potential of CNG in a bi-fuel system. CNG operation in an engine designed for gasoline typically suffers from reduced power, due in part to displacement of air by gaseous fuel.

The free piston engine combined with a linear electric alternator has the potential to be a highly efficient converter from fossil fuel energy to electrical power. With only a single major moving part (the translating rod), mechanical friction is reduced compared to conventional crankshaft technology. Instead of crankshaft linkages, the motion of the translator is driven by the force balance between the engine cylinder, alternator, damping losses, and springs. Focusing primarily on mechanical springs, this paper explores the use of springs to increase engine speed and reduce cyclic variability. A numeric model has been constructed in MATLAB®/Simulink to represent the various subsystems, including the engine, alternator, and springs. Within the simulation is a controller that forces the engine to operate at a constant compression ratio by affecting the alternator load.

Oxidative degradation of biodiesel under accelerated conditions has been examined by Fourier transform infrared (FTIR), nuclear magnetic resonance (NMR), and gravimetric measurement of deposit formation. The formation of gums and deposits caused by oxidation in storage or in an engine fuel system is a significant issue because of the potential for fuel pump and injector fouling. The results of this study indicate several important pathways for degradation and two pathways leading to formation of oligomers and, ultimately, deposits. Peroxides formed in the initial stage of oxidation can decompose to form aldehydes, ketones, and acids. These can react further in aldol condensation to form oligomers. Additionally, peroxides can react with fatty acid chains to form dimers and higher oligomers. Deposits form when the polarity and molecular weight of these oligomers is high enough.

Growing concern over ground-level ozone and its role in smog formation has resulted in extensive investigation into identifying ozone sources. Motor vehicle exhaust, specifically oxides of nitrogen and hydrocarbons, have been identified as major ozone precursors in urban areas. Past research has concentrated on assessing the impact of emissions from gasoline fueled light duty vehicles. However, little work has been done on identifying ozone precursors from medium and heavy duty diesel fueled vehicles. This paper presents the results of testing performed on a Navistar T 444E 190 horsepower diesel engine which is certified as a light/heavy-duty emissions classification and is used in medium duty trucks up to 11,800 kg (26,000 lb) GVW. Regulated emissions and speciated hydrocarbon emissions were collected using a filter, bag and Tenax adsorption cartridges for both steady state and transient engine operation.

We describe a study to identify potential biofuels that enable advanced spark ignition (SI) engine efficiency strategies to be pursued more aggressively. A list of potential biomass-derived blendstocks was developed. An online database of properties and characteristics of these bioblendstocks was created and populated. Fuel properties were determined by measurement, model prediction, or literature review. Screening criteria were developed to determine if a bioblendstock met the requirements for advanced SI engines. Criteria included melting point (or cloud point) < -10°C and boiling point (or T90) <165°C. Compounds insoluble or poorly soluble in hydrocarbon were eliminated from consideration, as were those known to cause corrosion (carboxylic acids or high acid number mixtures) and those with hazard classification as known or suspected carcinogens or reproductive toxins.

Spark-ignition engine fuel standards have been put in place to ensure acceptable hot and cold weather driveability (HWD and CWD). Vehicle manufacturers and fuel suppliers have developed systems that meet our driveability requirements so effectively that drivers overwhelmingly find that their vehicles reliably start up and operate smoothly and consistently throughout the year. For HWD, fuels that are too volatile perform more poorly than those that are less volatile. Vapor lock is the apparent cause of poor HWD, but there is conflicting evidence in the literature as to where in the fuel system it occurs. Most studies have found a correlation between degraded driveability and higher dry vapor pressure equivalent or lower TV/L = 20, and less consistently with a minimum T50. For CWD, fuels with inadequate volatility can cause difficulty in starting and rough operation during engine warmup.

Regulated and unregulated emissions (individual hydrocarbons, ethanol, aldehydes and ketones, polynuclear aromatic hydrocarbons (PAH), nitro-PAH, and soluble organic fraction of particulate matter) were characterized in engines utilizing duplicate ISO 8178-C1 eight-mode tests and FTP smoke tests. Certification No. 2 diesel (400 ppm sulfur) and three ethanol/diesel blends, containing 7.7 percent, 10 percent, and 15 percent ethanol, respectively, were used. The three, Tier II, off-road engines were 6.8-L, 8.1-L, and 12.5-L in displacement and each had differing fuel injection system designs. It was found that smoke and particulate matter emissions decreased with increasing ethanol content. Changes to the emissions of carbon monoxide and oxides of nitrogen varied with engine design, with some increases and some decreases. As expected, increasing ethanol concentration led to higher emissions of acetaldehyde (increases ranging from 27 to 139 percent).

Biodiesel produced from soybean oil, canola oil, yellow grease, and beef tallow was tested in two heavy-duty engines. The biodiesels were tested neat and as 20% by volume blends with a 15 ppm sulfur petroleum-derived diesel fuel. The test engines were a 2002 Cummins ISB and 2003 DDC Series 60. Both engines met the 2004 U.S. emission standard of 2.5 g/bhp-h NOx+HC (3.35 g/kW-h) and utilized exhaust gas recirculation (EGR). All emission tests employed the heavy-duty transient procedure as specified in the U.S. Code of Federal Regulations. Reduction in PM emissions and increase in NOx emissions were observed for all biodiesels in all engines, confirming observations made in older engines. On average PM was reduced by 25% and NOx increased by 3% for the two engines tested for a variety of B20 blends. These changes are slightly larger in magnitude, but in the same range as observed in older engines.

Methane emissions from lean-burn natural gas engines can be relatively high. As natural gas fueled vehicles become more prevalent, future regulations may restrict these emissions. Preliminary reports indicated that conventional, precious metal oxidation catalysts rapidly deactivate (in less than 50 hours) in lean-burn natural gas engine exhaust. This investigation is directed at quantifying this catalyst deactivation and understanding its cause. The results may also be relevant to oxidation of lean-burn propane and gasoline engine exhaust. A platinum/palladium on alumina catalyst and a palladium on alumina catalyst were aged in the exhaust of a lean-burn natural gas engine (Cummins B5.9G). The engine was fueled with compressed natural gas. Catalyst aging was accomplished through a series of steady state cycles and heavy-duty transient tests (CFR 40 Part 86 Subpart N) lasting 10 hours. Hydrocarbons in the exhaust were speciated by gas chromatography.

The use of biodiesel requires the development of proper quantification procedures for biodiesel content in blends and in lubricants (fuel dilution in oil). Although the ester carbonyl stretch at 1746 wavenumbers (cm-1) is the most prominent band in the IR spectrum of biodiesel, it is difficult to use for quantification purposes due to a severe fluctuation of absorption strength from sample to sample, even at the same biodiesel content. We have demonstrated that the ester carbonyl fluctuation is not caused by variation in the ester alkyl chain length; but is most likely caused by the degree of hydrogen bonding of the ester functional group with water in the sample. Water molecules can form complexes with the ester compound affecting the strength of the ester carbonyl band. The impact of water on quantification of the biodiesel content of blends was significant, even for B100 samples that met the proposed ASTM D6751 water limit of 500 ppm by D6304 (Karl Fischer Methdod).

In a recent study the present authors showed that piston motion in a compression ignition engine can have a small yet significant effect on ignition delay of diesel fuel. In particular, sinusoidal piston motion, or a motion with high dwell near top-dead-center, promotes reduced delay and improved cold starting relative to conventional slider-crank piston motion. This paper extends the analysis to the case of coal-diesel and coal-methanol blends, using experimental data from the thesis available in the literature. Ignition delay was shown again to be reduced with sinusoidal motion. In addition, the effect of piston motion on mass loss was considered. As expected, higher dwell near top-dead-center caused more mass loss, but there is still benefit to ignition delay of unusual piston motions unless the coefficient of leakage past the rings is very large.

Concern over dwindling oil supplies has led to the adoption of alternate fuels to power fleet vehicles. However, during the interim period when alternate fuel supply stations are few and far between, dual fuel engines prove a necessity. In the light duty arena, these engines are typically gasoline engines modified to accommodate compressed natural gas (CNG) as an alternate fuel, but they are seldom optimized with both fuels in mind. A Saturn 1.9 liter 4 cylinder dual overhead cam engine was selected as a base for developing an optimized gasoline/CNG powerplant. Baseline data on power and steady state emissions (CO2, CO, NOx, HC) were found using the standard Saturn controller. In addition to monitoring standard sensor measurements, real-time pressure traces were taken for up to 256 cycles using a modified head with embedded PCB piezoelectric pressure transducers.

Dual fuel engines employing pilot diesel injection to ignite premixed natural gas provide an opportunity for liquid petroleum fuel replacement and for reduced emissions of oxides of nitrogen (NOx) and particulate matter (PM). A Navistar T444E turbocharged V8 engine was converted to operate in dual fuel mode by metering the compressed natural gas (CNG) with an IMPCO Technologies, Inc. regulator and electronic valve while retaining the stock Navistar Hydraulically-Actuated Electronically-Controlled Unit Injection (HEUI) system for diesel pilot injection. A dedicated controller was designed and constructed to allow manual control of diesel fuel injection pulsewidth (FIPW), diesel injection advance (ADV), hydraulic injection control pressure (ICP) and natural gas mass flow. The controller employed two Microchip, Inc. PIC-based microcontrollers: one to perform initialization of a Silicon Systems, Inc. 67F867 engine interface peripheral, and the other to perform the runtime algorithms.

Biodiesel has been used to reduce petroleum consumption and pollutant emissions. B20, a 20% blend of biodiesel with 80% petroleum diesel, has become the most common blend used in the United States. Little quantitative information is available on the impact of biodiesel on engine operating costs and durability. In this study, eight engines and fuel systems were removed from trucks that had operated on B20 or diesel, including four 1993 Ford cargo vans and four 1996 Mack tractors (two of each running on B20 and two on diesel). The engines and fuel system components were disassembled, inspected, and evaluated to compare wear characteristics after 4 years of operation and more than 600,000 miles accumulated on B20. The vehicle case history-including mileage accumulation, fuel use, and maintenance costs-was also documented. The results indicate that there was little difference that could be attributed to fuel in operational and maintenance costs between the B20- and diesel-fueled groups.

Dedicated natural gas engines suffer the disadvantages of limited vehicle range and relatively few refueling stations. A vehicle capable of operating on either gasoline or natural gas allows alternative fuel usage without sacrificing vehicle range and mobility. However, the bi-fuel engine must be made to provide equal performance on both fuels. Although bi-fuel conversions have existed for a number of years, historically natural gas performance is degraded relative to gasoline due to reduced volumetric efficiency and lower power density of CNG. Much of the performance losses associated with CNG can be overcome by increasing the compression ratio. However, in a bi-fuel application, high compression ratios can result in severe engine knock during gasoline operation. Variable intake valve timing, increased exhaust gas recirculation and retarded ignition timing were explored as a means of controlling knock during gasoline operation of a bi-fuel engine.

Natural Gas engines are viewed as an alternative to diesel power in the quest to reduce heavy duty vehicle emissions in polluted urban areas. In particular, it is acknowledged that natural gas has the potential to reduce the inventory of particulate matter, and this has encouraged the use of natural gas engines in transit bus applications. Extensive data on natural gas and diesel bus emissions have been gathered using two Transportable Heavy Duty Vehicle Emissions Testing Laboratories, that employ chassis dynamometers to simulate bus inertia and road load. Most of the natural gas buses tested prior to 1997 were powered by Cummins L-10 engines, which were lean-burn and employed a mechanical mixer for fuel introduction. The Central Business District (CBD) cycle was used as the test schedule.