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A zero-dimension model of spray development and particulate emissions for direct-injection combustion was developed. The model describes the major characteristics of the injection plume including: spray angle, liquid penetration, lift-off length, and temperatures of regions within the spray. The model also predicts particulate mass output over a span of combustion cycles, as well as a particulate mass-history over a single combustion event. The model was developed by applying established conceptual models for direct injection combustion to numerical relations, to develop a mathematical description of events. The model was developed in a Matlab Simulink environment to promote modularity and ease of use.

Cu- and Fe-zeolite SCR catalysts emerged in recent years as the primary candidates for meeting the increasingly stringent lean exhaust emission regulations, due to their outstanding activity and durability characteristics. It is commonly known that Cu-zeolite catalysts possess superior activity to Fe-zeolites, in particular at low temperatures and sub-optimal NO₂/NOx ratios. In this work, we elucidate some underlying mechanistic differences between these two classes of catalysts, first based on their NO oxidation abilities, and then based on the relative properties of the two types of exchanged metal sites. Finally, by using the ammonia coverage-dependent NOx performance, we illustrate that state-of-the-art Fe-zeolites can perform better under certain transient conditions than in steady-state.

Nitrous oxide (N2O), with a global warming potential (GWP) of 297 and an average atmospheric residence time of over 100 years, is an important greenhouse gas (GHG). In recognition of this, N2O emissions from on-highway medium- and heavy-duty diesel engines were recently regulated by the US Environmental Protection Agency (EPA) and National Highway Traffic Safety Administration’s (NHTSA) GHG Emission Standards. Unlike NO and NO2, collectively referred to as NOx, N2O is not a major byproduct of diesel combustion. However, N2O can be formed as a result of unselective catalytic reactions in diesel aftertreatment systems, and the mitigation of this unintended N2O formation is a topic of active research. In this study, a nonroad Tier 4 Final/Stage IV engine was equipped with a vanadium-based selective catalytic reduction (SCR) aftertreatment system. Experiments were conducted over nonroad steady and both cold and hot transient cycles (NRSC and NRTC, respectively).

A detailed thermodynamic analysis was performed to demonstrate the fundamental efficiency advantage of an opposed-piston two-stroke engine over a standard four-stroke engine. Three engine configurations were considered: a baseline six-cylinder four-stroke engine, a hypothetical three-cylinder opposed-piston four-stroke engine, and a three-cylinder opposed-piston two-stroke engine. The bore and stroke per piston were held constant for all engine configurations to minimize any potential differences in friction. The closed-cycle performance of the engine configurations were compared using a custom analysis tool that allowed the sources of thermal efficiency differences to be identified and quantified.

Cu/CHA catalysts have been widely used in the industry, due to their desirable performance characteristics including the unmatched hydrothermal stability. While broadly recognized for their outstanding activity at or above 200°C, these catalysts may not show desired levels of NOx conversion at lower temperatures. To achieve high NOx conversions it is desirable to have NO2/NOx close to 0.5 for fast SCR. However even under such optimal gas feed conditions, sustained use of Cu/CHA below 200°C leads to ammonium nitrate formation and accumulation, resulting in the inhibition of NOx conversion. In this contribution, the formation and decomposition of NH4NO3 on a commercial Cu/CHA catalyst have been investigated systematically. First, the impact of NH4NO3 self-inhibition on SCR activity as a function of temperature and NO2/NOx ratios was investigated through reactor testing.

The performance characteristics of a commercial lean-NOX trap catalyst were evaluated between 200 and 500°C, using H2, CO, and a mixture of both H2 and CO as reductants before and after different high-temperature aging steps, from 600 to 750°C. Tests included NOX reduction efficiency during cycling, NOX storage capacity (NSC), oxygen storage capacity (OSC), and water-gas-shift (WGS) and NO oxidation reaction extents. The WGS reaction extent at 200 and 300°C was negatively affected by thermal degradation, but at 400 and 500°C no significant change was observed. Changes in the extent of NO oxidation did not show a consistent trend as a function of thermal degradation. The total NSC was tested at 200, 350 and 500°C. Little change was observed at 500°C with thermal degradation but a steady decrease was observed at 350°C as the thermal degradation temperature was increased.

A study was performed in which the effects on the regulated emissions from a commercial small DI diesel engine were measured for different refinery-derived fuel blends. Seven different fuel blends were tested, of which two were deemed to merit more detailed evaluation. To investigate the effects of fuel properties on the combustion processes with these fuel blends, two-color pyrometry was used via optically accessible cylinderheads. Additional data were obtained with one of the fuel blends with a heavy-duty DI diesel engine. California diesel fuel was used as a baseline. The fuel blends were made by mixing the components typically found in gasoline, such as methyl tertiary-butyl ether (MTBE) and whole fluid catalytic cracking gasoline (WH-FCC). The mixing was performed on a volume basis. Cetane improver (CI) was added to maintain the same cetane number (CN) of the fuel blends as that of the baseline fuel.

This research focused on the effects of split injection on combustion in a diesel environment. It was done in a specially designed engine-fed combustion chamber (swirl ratio of 5) with full field optical access through a quartz window. The simulated engine combustion chamber used a special backwards spraying injector (105°). The electronically controlled injector could control the size and position of it's, two injections. Both injections were through the same nozzle and it produced very rapid injections (1.5 ms) with a maximum injection pressure of 130 MPa. Experimental data included: rate of injection, injector pressure, combustion chamber dumping (NO & NOx concentrations), flame temperature, KL factor (soot concentration) combustion pressure, and rate of pressure rise. Injection rates indicate that the UCORS injection system creates very rapid injections with the ability to produce controllable split injections.

To date there is no universal agreement as to the interaction between fuel type, fuel-air mixture preparation and combustion chamber flow characteristics and their effect on soot formation. A propane fueled modified conical back-mixed steady flow reactor was built in which the fuel and air could be mixed together in varying degrees and reacted in at different mixing intensities. The onset of soot and soot loading were determined qualitatively by a photomultiplier focused on the volume inside the reactor. Increasing the degree of premix from a diffusion flame to a distribution of Φmax/Φavg = 5.0 resulted in increases of 3 to 17 percent of the soot-onset equivalence ratio and decreases in soot loading down to zero. Changes in the mixing intensity from 32.5 sec−1 to 75.7 sec−1 resulted in a change in the soot-onset equivalence ratio from 1.26 to 1.52. Soot loading was found to depend on both the mixing intensity, β, and the average number of mixes per mean residence time, β/α.

A single cylinder, Cummins NH, direct-injection, diesel engine has been operated in order to evaluate the effects of aromatic content and aromatic structure on diesel engine particulates. Results from three fuels are shown. The first fuel, a low sulfur Chevron diesel fuel was used as a base fuel for comparison. The other fuels consisted of the base fuel and 10% by volume of 1-2-3-4 tetrahydronaphthalene (tetralin) a single-ring aromatic and naphthalene, a double-ring aromatic. The fuels were chosen to vary aromatic content and structure while minimizing differences in boiling points and cetane number. Measurements included exhaust particulates using a mini-dilution tunnel, exhaust emissions including THC, CO2, NO/NOx, O2, injection timing, two-color radiation, soluble organic fraction, and cylinder pressure. Particulate measurements were found to be sensitive to temperature and flow conditions in the mini-dilution tunnel and exhaust system.

Sustained NOx reduction at low temperatures, especially in the 150-200 °C range, shares some similarities with the more commonly discussed cold-start challenge, however, poses a number of additional and distinct technical problems. In this project, we set a bold target of achieving and maintaining 90% NOx conversion at the SCR catalyst inlet temperature of 150 °C. This project is intended to push the boundaries of the existing technologies, while staying within the realm of realistic future practical implementation. In order to meet the resulting challenges at the levels of catalyst fundamentals, system components, and system integration, Cummins has partnered with the DOE, Johnson Matthey, and Pacific Northwest National Lab and initiated the Sustained Low-Temperature NOx Reduction program at the beginning of 2015 and completed in 2017.

Gasoline fueled Homogeneous Charge Compression Ignition (HCCI) combustion with internal exhaust gas re-circulation using Negative Valve Overlap (NOL) was investigated by means of calculation and experiment in order to apply this technology to practical use with sufficient operating range and with acceptable emission and fuel consumption. In this paper we discuss the basic characteristics of NOL-HCCI with emphasis on the influence of intake valve timing on load range, residual gas fraction and induction air flow rate. Emission and fuel consumption under various operation conditions are also discussed. A water-cooled 250cc single cylinder engine with a direct injection system was used for this study. Three sets of valve timing were selected to investigate the effect of intake valve opening duration. Experimental results demonstrated that an engine speed of approximately 2000rpm yields an NMEP (Net Mean Effective Pressure) range from 200kPa to 400kPa.

An investigation of high speed direct injection (DI) compression ignition (CI) engine combustion fueled with gasoline (termed GDICI for Gasoline Direct-Injection Compression Ignition) in the low temperature combustion (LTC) regime is presented. As an aid to plan engine experiments at full load (16 bar IMEP, 2500 rev/min), exploration of operating conditions was first performed numerically employing a multi-dimensional CFD code, KIVA-ERC-Chemkin, that features improved sub-models and the Chemkin library. The oxidation chemistry of the fuel was calculated using a reduced mechanism for primary reference fuel combustion. Operation ranges of a light-duty diesel engine operating with GDICI combustion with constraints of combustion efficiency, noise level (pressure rise rate) and emissions were identified as functions of injection timings, exhaust gas recirculation rate and the fuel split ratio of double-pulse injections.

Sources of unburned hydrocarbon (UHC) emissions are examined for a highly dilute (10% oxygen concentration), moderately boosted (1.5 bar), low load (3.0 bar IMEP) operating condition in a single-cylinder, light-duty, optically accessible diesel engine undergoing partially-premixed low-temperature combustion (LTC). The evolution of the in-cylinder spatial distribution of UHC is observed throughout the combustion event through measurement of liquid fuel distributions via elastic light scattering, vapor and liquid fuel distributions via laser-induced fluorescence, and velocity fields via particle image velocimetry (PIV). The measurements are complemented by and contrasted with the predictions of multi-dimensional simulations employing a realistic, though reduced, chemical mechanism to describe the combustion process.

An analysis of the soot formation and oxidation process in a conventional direct-injection (DI) diesel flame was conducted using numerical simulations. An improved multi-step phenomenological soot model that includes particle inception, particle coagulation, surface growth and oxidation was used to describe the soot formation and oxidation process. The soot model has been implemented into the KIVA-3V code. Other model Improvements include a piston-ring crevice model, a KH/RT spray breakup model, a droplet wall impingement model, a wall-temperature heat transfer model, and the RNG k-ε turbulence model. The Shell model was used to simulate the ignition process, and a laminar-and-turbulent characteristic time combustion model was used for the post-ignition combustion process. Experimental data from a heavy-duty, Cummins N14, research DI diesel engine operated with conventional injection under low-load conditions were selected as a benchmark.

A modeling study has been conducted in order to characterize the heat transfer in an automotive diesel exhaust system. The exhaust system model, focusing on 2 exhaust pipes, has been created using a transient 1-D engine flow network simulation program. Model results are in excellent agreement with experimental data gathered before commencement of the modeling study. Predicted pipe exit stream temperatures are generally within one percent of experimental values. Sensitivity analysis of the model was the major focus of this study. Four separate variables were chosen for the sensitivity analysis. These being the external convective heat transfer coefficient, external emissivity, mass flow rate of exhaust gases, and amplitude of incoming pressure fluctuations. These variables were independently studied to determine their contribution to changes in exhaust gas stream temperature and system heat flux. There are two primary benefits obtained from conducting this analysis.

The high global warming potential of nitrous oxide (N2O) led to its inclusion in the list of regulated greenhouse gas (GHG) pollutants [1, 2]. The mitigation of N2O on aftertreatment catalysts was shown to be ineffective as its formation and decomposition temperatures do not overlap. Therefore, the root causes for N2O formation were investigated to enable the catalyst architectures and controls development for minimizing its formation. In a typical heavy-duty diesel exhaust aftertreatment system based on selective catalytic reduction of NOx by ammonia derived from urea (SCR), the main contributors to tailpipe N2O are expected to be the undesired reaction between NOx and NH3 over SCR catalyst and NH3 slip in to ammonia slip catalyst (ASC), part of which gets oxidized to N2O.

Plug flow reactors, simulating engine exhaust gas, are widely used in emissions control research to gain insight into the reaction mechanisms and engineering aspects that controls activity, selectivity, and durability of catalyst components. The choice of relevant hydrocarbon (HC) species is one of the most challenging factor in such laboratory studies, given the variety of compositions that can be encountered in different application scenarios. Furthermore, this challenge is amplified by the experimental difficulties related to introducing heavier and multi-component HCs and analyzing the reaction products.

Advanced flow-reactor capabilities created at Cummins were applied to the study of the diesel particulate matter (soot) oxidation process. This approach complemented the on-engine studies with a number of important features, including accurate control of gas composition and soot layer temperature. Using the developed methodology for quantitative soot oxidation studies in a broad range of temperatures (200-700°C), an initial set of experiments was performed to compare the behavior of the real and model soot samples under the identical conditions (10%vol. of O2, 0-15%vol. of H2O). It was found that presence of H2O vapor synergistically enhances the rate of oxidation by O2 of the diesel soot sample. However, the behavior of the model soot sample (carbon black) was virtually not affected by H2O. Kinetic analysis of the obtained results revealed an unusual type of behavior, with the activation energy of soot oxidation increasing in the course of the experiment.

This paper investigates flow and combustion in a full-cycle simulation of a four-stroke, three-valve HCCI engine by visualizing the flow with pathlines. Pathlines trace massless particles in a transient flow field. In addition to visualization, pathlines are used here to trace the history, or evolution, of flow fields and species. In this study evolution is followed from the intake port through combustion. Pathline analysis follows packets of intake charge in time and space from induction through combustion. The local scalar fields traversed by the individual packets in terms of velocity magnitude, turbulence, species concentration and temperatures are extracted from the simulation results. The results show how the intake event establishes local chemical and thermal environments in-cylinder and how the species respond (chemically react) to the local field.