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In this work, the effects of ozone, hydrogen, carbon monoxide, and exhaust gas recirculation (EGR) addition to Haltermann gasoline combustion were investigated. For these additives, laminar and turbulent flame speeds were experimentally determined using spherically propagating premixed flames in a constant volume combustion vessel. Two initial mixture pressures of Po = 1 and 5 bar, two initial mixture temperatures of 358 and 373 K and a range of equivalence ratios (Ф) from 0.5 to 1 were investigated. The additives were added as single, binary and ternary mixtures to Haltermann gasoline over a wide range of concentrations. For the stoichiometric mixture, the addition of 10% H2, 5% CO and 1000 ppm O3 shows remarkable enhancement (80%) in SL0compared to neat Haltermann gasoline. In addition, for this same blend, increasing the mixture initial temperature and pressure results in a significant increase in SL0compared to the neat gasoline.

For several years there has been a great deal of effort made in researching ways to run a compression ignition engine with simultaneously high efficiency and low emissions. Recently much of this focus has been dedicated to using gasoline-like fuels that are more volatile and less reactive than conventional diesel fuel to allow the combustion to be more premixed. One of the key challenges to using fuels with such properties in a compression ignition engine is stable engine operation at low loads. This paper provides an analysis of how stable gasoline compression ignition (GCI) engine operation was achieved down to idle speed and load on a multi-cylinder compression ignition engine using only 87 anti-knock index (AKI) gasoline. The variables explored to extend stable engine operation to idle included: uncooled exhaust gas recirculation (EGR), injection timing, injection pressure, and injector nozzle geometry.

Gasoline compression ignition (GCI) offers improved efficiency by harnessing gasoline’s low reactivity to induce an extended ignition delay that promotes partial premixing of air and fuel before combustion occurs. However, enabling GCI across the full engine operating load map poses several challenges. At high load, due to the elevated pressures and temperatures of the charge mixture, the ignition delay time shrinks, leading to diminished GCI efficiency benefits. At low load, insufficient temperatures and pressures can lead to combustion instability. Variable valve actuation offers a practical solution to these challenges by enabling effective compression ratio (ECR) control. In this paper, the effects of variable intake valve closings were investigated for high load operations in a prototype heavy-duty GCI engine, using a research octane number 93 gasoline fuel. The study focused on the 50% (B50) and the 75% (B75) load conditions at 1375 RPM.

With an intention to improve the performance of reciprocating engines used for distributed generation US-Dept. of Energy has launched ARES program. Under this program, the performance targets for these natural gas-fuelled stationary engines are ≻ 50% efficiency and NOx emissions ≺ 0.1 g/bhp-hr by 2013. This paper presents two technologies developed under this program. Lean-burn operation is very popular with engine manufacturers as it offers simultaneous low-NOx emissions and high engine efficiencies, while not requiring the use of any aftertreatment devices. Though engines operating on lean-burn operation are capable of better performance, they are currently limited by the inability to sustain reliable ignition under lean conditions. Addressing such an issue, research has evaluated the use of laser ignition as an alternative to the conventional Capacitance Discharge Ignition (CDI).

The U.S. Renewable Fuel Standard (RFS2) requires an increase in the use of advanced biofuels up to 36 billion gallons by 2022. Longer chain alcohols, in addition to cellulosic ethanol and synthetic biofuels, could be used to meet this demand while adhering to the RFS2 corn-based ethanol limitation. Higher carbon number alcohols can be utilized to improve the energy content, knock resistance, and/or petroleum displacement of gasoline-alcohol blends compared to traditional ethanol blends such as E10 while maintaining desired and regulated fuel properties. Part I of this paper focuses on the development of scenarios by which to compare higher alcohol fuel blends to traditional ethanol blends. It also details the implementation of fuel property prediction methods adapted from literature. Possible combinations of eight alcohols mixed with a gasoline blendstock were calculated and the properties of the theoretical fuel blends were predicted.

Higher carbon number alcohols offer an opportunity to meet the Renewable Fuel Standard (RFS2) and improve the energy content, petroleum displacement, and/or knock resistance of gasoline-alcohol blends from traditional ethanol blends such as E10 while maintaining desired and regulated fuel properties. Part II of this paper builds upon the alcohol selection, fuel implementation scenarios, criteria target values, and property prediction methodologies detailed in Part I. For each scenario, optimization schemes include maximizing energy content, knock resistance, or petroleum displacement. Optimum blend composition is very sensitive to energy content, knock resistance, vapor pressure, and oxygen content criteria target values. Iso-propanol is favored in both scenarios' suitable blends because of its high RON value.

Low temperature combustion engine technologies are being investigated for high efficiency and low emissions. However, such engine technologies often produce higher engine-out hydrocarbon (HC) and carbon monoxide (CO) emissions, and their operating range is limited by the fuel properties. In this study, two different fuels, a US market gasoline containing 10% ethanol (RON 92 E10) and a higher reactivity gasoline (RON 80 E0), were compared on Delphi’s second generation Gasoline Direct-Injection Compression Ignition (Gen 2.0 GDCI) multi-cylinder engine. The engine was evaluated at three operating points ranging from a light load condition (800 rpm/2 bar IMEPg) to medium load conditions (1500 rpm/6 bar and 2000 rpm/10 bar IMEPg). The engine was equipped with two oxidation catalysts, between which was located the exhaust gas recirculation (EGR) inlet. Samples were taken at engine-out, between the catalysts, and at tailpipe locations.

Preliminary research in our laboratory has demonstrated that boric acid is an effective lubricant with an unusual capacity to reduce the sliding friction (providing friction coefficients as low as 0.02) and wear of metallic and ceramic materials. More recent studies have revealed that water or methanol solutions of boric acid can be used to prepare strongly bonded layers of boric acid on aluminum surfaces. It appears that boric acid molecules have a strong tendency to bond chemically to the naturally oxidized surfaces of aluminum and its alloys and to make these surfaces very slippery. Recent metal-formability tests indicated that the boric acid films applied to aluminum surfaces worked quite well, improving draw scale performance by 58 to 75%.

Early in 2007 President Bush announced in his State of the Union Address a plan to off-set 20% of gasoline with alternative fuels in the next ten years. Ethanol, due to its excellent fuel properties for example, high octane number, renewable character, etc., appears to be a favorable alternative fuel from an engine perspective. Replacing gasoline with ethanol without any additional measures results in unacceptable disadvantages mainly in terms of vehicle range. This paper summarizes combustion studies performed with gasoline as well as blends of gasoline and ethanol. These tests were performed on a modern, 4-cylinder spark ignition engine with direct fuel injection and exhaust gas recirculation. To evaluate the influence of blending on the combustion behavior the engine was operated on the base gasoline calibration. Cylinder pressure data taken during the testing allowed for detailed analysis of rates of heat release and combustion stability.

The CFR F1 engine is the standard testing apparatus used for rating the research octane number (RON) of gasoline fuels. Unlike the motor octane number (MON) method, where the intake port temperature after the carburetor is controlled by an electric heater, the mixture temperature can vary during the RON test due to the heat of vaporization (HoV) of the fuel. Ethanol is receiving increasing attention as a high octane and high HoV fuel component. This work presents an analysis of the combustion characteristics during the RON rating of ethanol fuel blends according to the standard ASTM D2699 method, highlighting the effects of ethanol concentration and base fuel composition. All fuels were blended to a constant RON of 98. Ethanol levels varied from 0 to 50 vol% and the base fuels were surrogate blends composed of primary reference fuels (PRF), toluene standardization fuels (TSF), and a four component gasoline surrogate.

Dual-fuel combustion using port-injection of low reactivity fuel combined with direct injection of a higher reactivity fuel, otherwise known as Reactivity Controlled Compression Ignition (RCCI), has been shown as a method to achieve high efficiency combustion with moderate peak pressure rise rates, low engine-out soot and NOx emissions. A key requirement for extending to high-load operation is reduce the reactivity of the premixed charge prior to the diesel injection. One way to accomplish this is to use a very low reactivity fuel such as natural gas. In this work, experimental testing was conducted on a 13L multi-cylinder heavy-duty diesel engine modified to operate using RCCI combustion with port injection of natural gas and direct injection of diesel fuel. Natural gas/diesel RCCI engine operation is compared over the EPA Heavy-Duty 13 mode supplemental emissions test with and without EGR.

Detailed properties of particulate matter (PM) emissions from a gasoline direct injection (GDI) engine were analyzed in terms of size, morphology, and nanostructures, as gasoline and its ethanol blend E20 were used as a fuel. PM emissions were sampled from a 0.55L single-cylinder GDI engine by means of a scanning mobility particle sizer (SMPS) for size measurements and a self-designed thermophoretic sampling device for the subsequent analyses of size, morphology and nanostructures using a transmission electron microscope (TEM). The particle sizes were evaluated with variations of air-fuel equivalence ratio and fuel injection timing. The most important result from the SMPS measurements was that the number of nucleation-mode nanoparticles (particularly those smaller than 10 - 15 nm) increased significantly as the fuel injection timing was advanced to the end-of-injection angle of 310° bTDC.

Low temperature combustion through in-cylinder blending of fuels with different reactivity offers the potential to improve engine efficiency while yielding low engine-out NOx and soot emissions. A Navistar MaxxForce 13 heavy-duty compression ignition engine was modified to run with two separate fuel systems, aiming to utilize fuel reactivity to demonstrate a technical path towards high engine efficiency. The dual-fuel engine has a geometric compression ratio of 14 and uses sequential, multi-port-injection of a low reactivity fuel in combination with in-cylinder direct injection of diesel. Through control of in-cylinder charge reactivity and reactivity stratification, the engine combustion process can be tailored towards high efficiency and low engine-out emissions. Engine testing was conducted at 1200 rpm over a load sweep.

Two diagnostics were developed that are particularly suitable for use with natural gas-fuelled reciprocating engines that are used for power generation applications. The first diagnostic relates flame chemiluminescence to thermodynamic metrics relevant to engine combustion - Heat Release Rate (HRR) and in-cylinder bulk gas temperature. Studies were conducted in a single-cylinder natural gas-fired reciprocating engine that could simulate turbocharged conditions with Exhaust Gas Recirculation. Crank-angle-resolved spectra (266 to 795 nm) of flame luminosity were measured for various operational conditions by varying the ignition timing for MBT conditions and by holding the speed at 1800 rpm and Brake Mean Effective Pressure (BMEP) at 12 bar. The effect of dilution on CO₂* chemiluminescence intensities was studied, by varying the global equivalence ratio (0.6 - 1.0) and by varying the Exhaust Gas Recirculation rate.

Increasingly stringent exhaust and CO2 emissions regulations are driving advancements in combustion and after-treatment technologies in the passenger vehicle sector. One major challenge is to achieve low emissions over the full operating map as required by Real Driving Emissions (RDE) legislation. Gasoline Compression Ignition (GCI), an advanced combustion concept, has shown potential to increase fuel efficiency and reduce emissions. GCI harnesses gasoline’s low reactivity for longer ignition delay, thus promoting partially premixed air-fuel mixture for efficient combustion. To maintain low engine-out NOx over the load range, high Exhaust Gas Recirculation (EGR) is required that consequently elevates boost pressure requirements. To meet the high boost and EGR demands, while minimizing pumping losses require air-system optimization.

When compared with new oil, used diesel engine oils exhibited thermal conductivity that increases as the concentration of soot increases. The magnitude of the effect depends on the oil composition, and on the size and dispersion of the soot particles. Although soot in engine oil is generally deleterious to engine performance from the standpoint of wear and deposits, no negative effects were observed on the thermal performance of the oil itself; indeed, even slight positive effects are expected for oils that maintain soot in stable dispersion. Therefore, the thermal challenge for engine oils in diesel engines that use exhaust gas recirculation will be to prevent soot deposition on engine surfaces.

Particulate and nitrogen oxide emissions from a 1.9-liter Volkswagen diesel engine were measured for three different fuels: neat diesel fuel, a blend of diesel fuel with 10% ethanol, and a blend of diesel fuel with 15% ethanol. Engine-out emissions were measured on an engine dynamometer for five different speeds and five different torques using the standard engine-control unit. Results show that particulate emissions can be significantly reduced over approximately two-thirds of the engine map by using a diesel-ethanol blend. Nitrogen oxide emissions can also be significantly reduced over a smaller portion of the engine map by using a diesel-ethanol blend. Moreover, there is an overlap between the regions where particulate emissions can be reduced by up to 75% and nitrogen oxide emissions are reduced by up to 84% compared with neat diesel fuel.

Exhaust gas recirculation (EGR) is a commonly used technique for the reduction of Nitrogen oxide (NOx) emissions from internal combustion engines. However, it is generally known that the use of EGR will cause an increase in emissions of particulate matter (PM). The effects of EGR operating mode on particulate morphology were investigated for a 1.7-liter light-duty diesel engine. This engine was equipped with a turbocharged and inter-cooled air induction system, a common-rail direct fuel injection system, and an EGR system. A rapid prototyping electronic control system (RPECS) was developed to operate this engine at various EGR rates under different conditions (i.e. constant boost pressure, constant oxygen-to-fuel ratio (OFR)). A unique thermophoretic sampling system was employed to collect particulates directly from exhaust manifold after exhaust valves.

The detailed morphological properties of diesel particulate matter were analyzed along the exhaust system at various engine operating conditions (in a range of 1000 - 2500 rpm and 10 - 75 % loads of maximum torques). A 1.7-L turbocharged light-duty diesel engine was powered with California low-sulfur diesel fuel injected by a common-rail injection system, of which particulate emissions were controlled by an exhaust gas recirculation (EGR) system and two oxidation catalysts. A unique thermophoretic sampling system first developed for internal combustion engine research, a high-resolution transmission electron microscope (TEM), and a customized image processing/data acquisition system were key instruments that were used for the collection of particulate matter, subsequent imaging of particle morphology, and detailed analysis of particle dimensions and fractal geometry, respectively.

Previous studies have shown that fuels with higher laminar flame speed also have increased tolerance to EGR dilution. In this work, the effects of fuel laminar flame speed on both lean and EGR dilute spark ignition combustion stability were examined. Fuels blends of pure components (iso-octane, n-heptane, toluene, ethanol, and methanol) were derived at two levels of laminar flame speed. Each fuel blend was tested in a single-cylinder spark-ignition engine under both lean-out and EGR dilution sweeps until the coefficient of variance of indicated mean effective pressure increased above thresholds of 3% and 5%. The relative importance of fuel laminar flame speed to changes to engine design parameters (spark ignition energy, tumble ratio, and port vs. direct injection) was also assessed.