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All the experimental investigations performed in the last years on newly sold motorcycles, equipped with a three-way catalyst and electronic mixture control, clearly indicate that CO and HC cold additional emissions, if compared with those exhausted in hot conditions, represent an important proportion of total emissions. Consequently, calculation programs for estimating emissions from road transports for air quality modeling in dedicated local areas should take into consideration this effect. From this motivation, an experimental activity on motorcycles cold emissive behavior is being jointly conducted by Istituto Motori of the National Research Council (IM-CNR) and the Department of Mechanic and Energetic (DiME) of the University of Naples.

In this paper the low temperature reduction process of nitrates stored at high temperatures over model Pt-Ba/Al2O3 LNT catalysts using both H2 and C3H6 is analyzed. The results indicate that over the Pt-Ba/Al2O3 catalyst the reduction of stored NOx with both H2 and C3H6 occurs at temperature below those corresponding to their thermal stability. Accordingly, the reduction process occurs through a Pt-catalyzed surface reaction, which does not involve, as a preliminary step, the thermal decomposition of the adsorbed NOx species. The occurrence of such a pathway also requires the co-presence of the storage element and of the noble metal on the same support.

The accurate prediction of pollutant emissions generated by IC engines is a key aspect to guarantee the respect of the emission regulation legislation. This paper describes the approach followed by the authors to achieve a strict numerical coupling of two different 1D modeling tools in a co-simulation environment, aiming at a reliable calculation of engine-out and tailpipe emissions. The main idea is to allow an accurate 1D simulation of the unsteady flows and wave motion inside the intake and exhaust systems, without resorting to an over-simplified geometrical discretization, and to rely on advanced thermodynamic combustion models and kinetic sub-models for the calculation of cylinder-out emissions. A specific fluid dynamic approach is then used to track the chemical composition along the exhaust duct-system, in order to evaluate the conversion efficiency of after-treatment devices, such as TWC, GPF, DPF, DOC, SCR and so on.

Increasing demands on the capabilities of engine simulation and the ability to accurately predict both performance and acoustics has lead to the development of several numerical tools to help engine manufacturers during the prototyping stage. The aid of CFD tools (3D and 1D) can remarkably reduce the duration and the costs of this stage. The need of achieving good accuracy, along with acceptable computational runtime, has given the spur to the development of a geometry based quasi-3D approach. This is designed to model the acoustics and the fluid dynamics of both intake and exhaust system components used in internal combustion engines. Models of components are built using a network of quasi-3D cells based primarily on the geometry of the system. The solution procedure is based on an explicitly time marching staggered grid approach making use of a flux limiter to prevent numerical instabilities.

Low back pain is more frequently present in patients involved in occupations that are related to driving automobiles, motorcycles, buses, tractors, trucks and heavy construction and agriculture machinery. Furthermore, low back pain is the leading major cause of disability in those younger than 45 years. The EU co-funded project SAFEGUARD aims at developing a new seat that will improve comfort, while decreasing the risk for health damage. In addition, it aims at developing in a broader sense a methodology, to evaluate seating comfort. This paper presents the results of the user needs analysis study and the plans towards the later phases within the overall SAFEGUARD concept and framework.

The tightening trend of regulations on the levels of admitted pollutant emissions has given a great spur to the research work in the field of combustion and after-treatment devices. Despite the improvements that can be applied to the development of the combustion process, pollutant emissions cannot be reduced to zero; for this reason, the aftertreatment system will become a key component in the path to achieving near-zero emission levels. This study focuses on the numerical analysis and optimization of different metallic substrates, specifically developed for three-way catalyst (TWC) and Diesel oxidation catalyst (DOC) applications, to improve their thermal efficiency by reducing radial thermal losses through the outer mantle. The optimization process relies on computational fluid dynamics (CFD) simulations supported by experimental measurements to validate the numerical models carried out under uncoated conditions, where chemical reactions do not occur.

This paper is based on a Research Project of the Department of Mechanical Engineering (DiME) in collaboration with Aprilia, the Italian motorbike manufacturer. In an attempt to simulate the functioning of the cooling plant of the Aprilia RSV-4 motorbike a numerical model was constructed using mono-dimensional and three-dimensional simulation codes. Our ultimate aim was to create a simulation model which could be of assistance to engine designers to improve cooling plant performance, thereby reducing research and development costs. The model allows to simulate the running conditions of the whole cooling circuit upon variations in environmental and running conditions. In particular, the centrifugal pump of the cooling plant was simulated by a 3D commercial software, while the whole circuit was built by a 1D commercial code which allows simulation of all the thermal exchanges and pressure drops in the cooling circuit.

Due to the increasing pressure to develop small-size and low-cost after-treatment systems meeting the legislative demands it is desirable to integrate multiple functionalities and exploit any possible synergies. Typical examples include DPFs catalyzed with deNOx catalysts, as well as LNT-SCR combinations using layered coating technology. The present paper deals with the modeling challenges involved for the proper simulation of such advanced concepts. Key role in such advanced simulation attempts has the coupling between diffusion-reaction phenomena, which is captured through intra-layer modeling. All investigations in this paper deal with the application of possible combined LNT-SCR system configurations. The simulation results show that a dual bed LNT- passive SCR configuration offers substantial NOx emissions reductions compared to a single LNT catalyst and effectively controls secondary NH3 emissions produced during LNT regeneration phases.

The reduction of the catalyst light-off time at the engine cold start represents a key factor for the pollutant emissions control from vehicles tested on homologation cycles and real drive conditions. The adoption of heating strategies to increase the temperature of the catalytic substrate in the early phase of the engine start is regarded as a promising solution. The present study focuses on the application of electrical heated catalyst (EHC) in an after-treatment line for a spark-ignition gasoline engine. The analysis is carried out by means of an advanced CFD framework, which includes the modeling of catalytic reactions in the substrates and accounts for the thermal evolution of all the components included in the after-treatment system.

In the last years, as a response to the more and more restrictive emission legislation, new devices (SRC, DOC, NOx-trap, DPF) have been progressively introduced as standard components of modern after-treatment system for Diesel engines. In addition, the adoption of electrical heating is nowadays regarded with interest as an effective solution to promote the light-off of the catalyst at low temperature, especially at the start-up of the engine and during the low load operation of the engine typical of the urban drive. In this work, a state-of-the-art 48 V electrical heated catalyst is considered, in order to investigate its effect in increasing the abatement efficiency of a standard DOC. The electrical heating device considered is based on a metallic support, arranged in a spiral layout, and it is heated by the Joule effect due to the passage of the electrical current.

The rare occurrence during city driving of the exhaust temperature levels required for ceramic trap regeneration without catalytic aid, seems to be the main reason of delay in wide application of the trap. The use of catalysts seems to be more or less necessary. Study of the catalytic activity during trap regeneration had not been very effective so far. This holds equally true for the case of catalyzed trap as for the case of catalytic fuel additives. The lack of a satisfactory theory for the explanation and prediction of catalytic activity, directed international research and development towards the quest of the optimum catalyst, which could support a very simple and low-cost regeneration system. The new approach to the explanation of catalytic activity presented in this paper, denies the above assumption.

NH₃/urea SCR is a very effective and widely used technology for the abatement of NOx from diesel exhaust. The SCR mechanism is well understood and the catalyst behavior can be predicted by mathematical models - as long as operation above the temperature limit for AdBlue® injection is considered. The behavior below this level is less understood. During the first seconds up to minutes after cold start, complete NOx abatement can be observed over an SCR catalyst in test bench experiments, together with a significant increase in temperature after the converter (ca. 100 K). In this work these effects have been investigated over a monolith Cu-zeolite SCR catalyst. Concentration step experiments varying NO, NO₂ and H₂O have been carried out in lab scale, starting from room temperature. Further, the interaction of C₃H₆ and CO with NOx over the SCR has been investigated.

A growing interest towards heavy-duty engines powered with NG, dictated by stringent regulations in terms of emissions, has made it essential to study a specific Three-Way Catalyst (TWC). Oxygen storage phenomena characterize the catalytic converter efficiency under real world driving operating conditions and, consequently, during strong dynamics in Air-to-Fuel ratio (AFR). A numerical “quasi-steady” model has been set-up to simulate the chemical process inside the reactor. A dedicated experimental campaign has been performed in order to evaluate the catalyst response to a defined λ variation, thus providing the data necessary for the numerical model validation. In fact, goal of the present research activity was to investigate the effect of very fast composition transitions of the engine exhaust typical of the mentioned driving conditions (including fuel cutoffs etc.) on the catalyst performance and on related emissions.

Ethanol is the most promising alternative fuel for spark ignition (SI) engines, that is blended with gasoline, typically. Moreover, in the last years great attention is paid to the dual fueling, ethanol and gasoline are injected simultaneously. This paper aims to analyze the better methods, blending or dual fueling in order to best exploit the potential of ethanol in improving engine performance and reducing pollutant emissions. The experimental activity was carried out in a small displacement single cylinder engine, representative of 2-3 wheel vehicle engines or of 3-4 cylinder small displacement automotive engines. It was equipped with a prototype gasoline direct injection (GDI) head. The tests were carried out at 3000, 4000, and 5000 rpm full load. The investigated engine operating conditions are representative of the European homologation urban driving cycle.

The aim of the paper is the comparison of the performance, gaseous and particle emissions from different injection configurations and fuels. The engine was operated in port fuel injection (PFI), direct injection (DI) and dual fuel (DF). For DF, ethanol DI-gasoline PFI and gasoline DI-gasoline PFI strategies were performed to discern the effect of injection strategy from the effect of the fuel. The experimental activity was carried out in a small displacement single cylinder engine, representative of 2-3 wheel vehicle engines or of 3-4 cylinder small displacement automotive engines. It was equipped with a prototype gasoline direct injection (GDI) head. The tests were carried out at 3000 rpm, 4000 rpm and 5000 rpm full load. The investigated engine operating conditions are representative of the homologation urban driving cycle. The gaseous and particle emissions were measured at the exhaust by means of a gas analyzer and a smoke meter.

In this work a multilevel CFD analysis have been applied for the design of an intake air-box with improved characteristics of noise reduction and fluid dynamic response. The approaches developed and applied for the optimization process range from the 1D to fully 3D CFD simulation, exploring hybrid approaches based on the integration of a 1D model with quasi-3D and 3D tools. In particular, the quasi-3D strategy is exploited to investigate several configurations, tailoring the best trade-off between noise abatement at frequencies below 1000 Hz and optimization of engine performances. Once the best configuration has been defined, the 1D-3D approach has been adopted to confirm the prediction carried out by means of the simplified approach, studying also the impact of the new configuration on the engine performances.

The small engine for two-wheel vehicles has generally high possibility to be optimized at low speeds and high loads. In these conditions fuel consumption and pollutants emission should be reduced maintaining the performance levels. This optimization can be realized only improving the basic knowledge of the thermo-fluid dynamic phenomena occurring during the combustion process. It is known that, during the fuel injection phase in PFI SI engines, thin films of liquid fuel can form on the valves surface and on the cylinder walls. Successively the fuel films interact with the intake manifold and the combustion chamber gas flow. During the normal combustion process, it is possible to achieve gas temperature and mixture strength conditions that lead to fuel film ignition. This phenomenon can create diffusion-controlled flames that can persist well after the normal combustion event. These flames induce the emission of soot and unburned hydrocarbons.

The transient heat transfer behavior of an automotive catalytic converter has been simulated with OpenFOAM in 1D. The model takes into consideration the gas-solid convective heat transfer, axial wall conduction and heat capacity effects in the solid phase, but also the chemical reactions of CO oxidation, based on simplified Arrhenius and Langmuir-Hinshelwood approaches. The associated parameters are the results of data in literature tuned by experiments. Simplified cases of constant flow rates and gas temperatures in the catalyst inflow have been chosen for a comprehensive analysis of the heat and mass transfer phenomena. The impact of inlet flow temperatures and inlet flow rates on the heat up characteristics as well as in the CO emissions have been quantified. A dimensional analysis is proposed and dimensionless temperature difference and space-time coordinates are introduced.

The match between the increasing performance demands and stringent requirements of emissions and fuel consumption reduction needs a strong evolution in the 2-wheel vehicle technology. In particular many steps forward should be taken for the optimization of modern small motorcycle and scooter at low engine speeds and low temperature start. To this aim, the detailed understandings of thermal and fluid-dynamic phenomena that occur in the combustion chamber are fundamental. In this work, experimental activities were realized in the combustion chamber of a single-cylinder 4-stroke optical engine. The engine was equipped with a four-valve head of a commercial scooter engine. High spatial resolution imaging was used to follow the flame kernel growth and flame front propagation. Moreover, the effects of an abnormal combustion due to firing of fuel deposition near the intake valves and on the piston surface were investigated.

A reason of the lack of agreement between measured pollutants concentration in the air of urban areas and vehicle pollutant emissions evaluated by available emission models is the fact that catalyst performance variability is not considered. In this paper, an experimental study on the effect of performance variability of catalyst on emissions is presented. Average emissions have been measured using driving cycles representative of different levels of urban traffic, determined by statistical methods on the basis of data detected on-road by an instrumented car. For each driving cycle, representative of a certain traffic level, different thermal starting conditions of catalyst have been tested. These conditions have been determined by the characterization of catalyst performance at steady state and are representative of real catalyst conditions experienced on the road.