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Technologies for the recycling of water are a primary goal of NASA’s advanced life support programs. Biological processes have been identified as an attractive method for wastewater processing. A fundamental new bioreactor based on a traditional activated sludge process is demonstrated that treats hygiene wastewater using magnetic iron oxide particles agglomerated with microbial cells. In this bioreactor, microbes are suspended in magnetic flocs in a wastewater medium. Instead of a traditional gravity separator used in activated sludge operations, a magnetic separator removes the microbial flocs from the outlet stream. The reactor separation operates continuously, independent of gravitational influences. The reactor has been able to simultaneously remove 98% of high levels of both nitrogenous and organic carbon impurities from the wastewater as well as achieve acceptably low levels of total suspended solids.

The Spacesuit Water Membrane Evaporator (SWME) is the baseline heat rejection technology selected for development for the Constellation lunar suit. The first SWME prototype, designed, built, and tested at Johnson Space Center in 1999 used a Teflon hydrophobic porous membrane sheet shaped into an annulus to provide cooling to the coolant loop through water evaporation to the vacuum of space. This present study describes the test methodology and planning to compare the test performance of three commercially available hollow fiber materials as alternatives to the sheet membrane prototype for SWME, in particular, a porous hydrophobic polypropylene, and two variants that employ ion exchange through non-porous hydrophilic modified Nafion. Contamination tests will be performed to probe for sensitivities of the candidate SWME elements to ordinary constituents that are expected to be found in the potable water provided by the vehicle, the target feedwater source.

A Total Organic Carbon (TOC) Analyzer has been developed for a Life Sciences Risk Mitigation Flight Experiment to be conducted on Spacehab and the Russian space station, Mir. Initial launch is scheduled for December 1996 (flight STS-81). The analyzer will be tested on the Orbiter in the Spacehab module, including when the Orbiter is docked at the Mir space station. The analyzer is scheduled to be launched again in May 1997 (STS-84) when it will be transferred to Mir. During both flights the analyzer will measure the quality of recycled and ground-supplied potable water on the space station. Samples will be archived for later return to the ground, where they will be analyzed for comparison to in-flight results. Water test samples of known composition, brought up with the analyzer, also will be used to test its performance in microgravity. Ground-based analyses of duplicates of those test samples will be conducted concurrently with the in-flight analyses.

A generalized computer program for analysis of pressure and composition in multiple volume systems has been under development by the National Aeronautics and Space Administration (NASA) since 1976. This paper describes the most recent developments in the program. These improvements include the expansion of the program to nine volumes, improvements to the model of the International Space Station (ISS) carbon dioxide removal system, and addition of a detailed Sabatier carbon dioxide reduction mode. An evaluation of the feasibility of adding of trace contaminant tracking was also performed. This paper will also present the results of an analysis that compares model predictions with ISS flight data for carbon dioxide (CO2) maintenance.

Removal of low-molecular weight, polar, non-ionic contaminants such as urea and alcohols from aqueous solution is being accomplished using immobilized enzyme technology. Immobilized urease is used to catalyze urea hydrolysis for subsequent removal as ammonia. An alcohol oxidase enzyme-based catalyst is used to catalyze oxidation of alcohols, aldehydes, and similar compounds to organic acids, which are removed by ion exchange. Fixed bed reactors were successfully developed and delivered to NASA-MSFC for a segment of the Phase III Core Module Integrated Facility (CMIF) Water Recovery Test. Wastewater generated in the End-use Equipment Facility (EEF) was purified using a combination of Multifiltration Unibeds and Enzyme Unibeds. The enzyme beds effectively removed the targeted organics to levels below detection limits (<100-400 ppb). Also, based on the amount of TOC removed, the enzyme beds removed unidentified organic contaminants beyond those specifically targeted.

A computer interfaced instrument designed to quantify ammonia and other nitrogenous species that are important regenerative life support water quality parameters is described in this paper. Measurements can be made either discretely by Flow Injection Analysis (FIA) or continuously using a split stream from a process flow. The monitor exhibits a predictable quadratic response for ammonia injections between 10 μg/L to 20 mg/L with a response time less than six minutes. A full description of the ammonia monitor's response to a variety of challenge solutions including real sewage treatment plant effluent is given. In addition, the response time characteristics, the effects of temperature, and interferences are described.

The Microbial Check Valve (MCV) is a reloadable flow-through canister containing iodinated ion exchange resin, which is used aboard the Shuttle Orbiter as a disinfectant to maintain water potability. The MCV exhibits a significant contact kill and imparts a biocidal residual I2 concentration to the effluent. MCVs in current use have nominal 30 day lives. MCVs baselined for Space Station Freedom will have 90 day lives, and will require replacement 120 times over 30 years. Means to extend MCV life are desirable to minimize resupply penalties. New technology has been developed for fully autonomous in situ regeneration of an expended MCV canister. The Regenerative Microbial Check Valve (RMCV) consists of an MCV, a packed bed of crystalline I2, a flow diverter valve, an in-line iodine monitor and a microcontroller. During regeneration, flow is directed first through the packed I2 bed and then into the MCV where the resin is replenished.

The development of an optimum regenerative Advanced Life Support (ALS) system for future Mars missions has been a crucial issue in the space industry. Considering the numerous potential technologies for subsystems with the complexity of the Air Revitalization System (ARS), Water Reclamation System (WRS), and Waste Management System of the Environmental Control and Life Support System (ECLSS), it will be time-consuming and costly to determine the best combination of these technologies without a powerful sizing analysis tool. Johnson Space Center (JSC), therefore, initiated the development of ALSSAT using Microsoft® Excel for this purpose. ALSSAT has been developed based upon the ALS Requirement and Design Definition Document (Ref. 18). In 1999, a paper describing the development of ALSSAT with its built-in ARS mass balance model (Ref. 21) was published in ICES.

The aim of this study was to explore if fingernail delamination injury following EMU glove use may be caused by compression-induced blood flow occlusion in the finger. During compression tests, finger blood flow decreased more than 60%, however this occurred more rapidly for finger pad compression (4 N) than for fingertips (10 N). A pressure bulb compression test resulted in 50% and 45% decreased blood flow at 100 mmHg and 200 mmHg, respectively. These results indicate that the finger pad pressure required to articulate stiff gloves is more likely to contribute to injury than the fingertip pressure associated with tight fitting gloves.

Procedures that have been developed as part of the NASA JSC-sponsored pre-prototype Checkout, Servicing and Maintenance (COSM) program for pre- and post-EVA airlock operations are described. This paper addresses the accompanying pressure changes in the airlock and in the Advanced Extravehicular Mobility Unit (EMU). Additionally, the paper focuses on the components that are checked out, and includes the step-by-step sequences to be followed by the crew, the required screen displays and prompts that accompany each step, and a description of the automated processes that occur.

A new technology for controlling the partial pressure of CO2 (pCO2) in a plant growth chamber (PGC) has been demonstrated. CO2 is gathered from the source atmosphere across a membrane gas exchanger and stored in an alkanolamine solution. The CO2 loading of the alkanolamine reservoir is monitored using specific conductance and controlled by the exposure time and temperature. The PGC pCO2 is maintained using a second membrane exchanger through which the alkanolamine circulates, absorbing or releasing CO2 to maintain equilibrium. The equilibrium pCO2 is determined by the CO2 loading and the temperature. Constant PGC feed pCO2 levels of roughly 1000 ppm have been maintained using sources with pCO2 both above and below this value.

Recovery of potable water from wastewater is essential for the success of long-term manned missions to the moon and Mars. Honeywell International and the team consisting of Thermodistillation Company (Kyiv, Ukraine) and NASA Johnson Space Center (JSC) Crew and Thermal Systems Division are developing a wastewater processing subsystem that is based on centrifugal vacuum distillation. The Wastewater Processing Cascade Distillation Subsystem (CDS) utilizes an innovative and efficient multi-stage thermodynamic process to produce purified water. The rotary centrifugal design of the system also provides gas/liquid phase separation and liquid transport under microgravity conditions. A five-stage prototype of the subsystem was built, delivered and integrated into the NASA JSC Advanced Water Recovery Systems Development Facility for development testing.

The Shuttle Orbiter humidity control and carbon dioxide removal system for extended duration missions presently uses a solid amine called HS-C. This August, on board STS-62, a new solid amine called HS-C+ will be used. HS-C+ uses the same amine and the substrate material, but a different preparation process. Forty-seven breakthrough tests have been conducted to characterize the performance of HS-C+. CO2 partial pressure, bed temperature, and H2O partial pressure were varied. Eleven HS-C breakthrough tests were also run to provide a direct comparison. Under all conditions tested, HS-C+ outperformed HS-C. Both materials adsorb all CO2 and H2O available at the start of a test when the beds are fully desorbed. As the bed becomes partially loaded, the CO2 and H2O adsorption rates decrease rapidly. HS-C+ continues adsorbing all CO2 and H2O available for a longer time. Greater surface area on HS-C+ may cause the improved performance.

Humidity condensate collected and processed in-flight is an important component of a space station drinking water supply. Water recovery systems in general are designed to handle finite concentrations of specific chemical components. Previous analyses of condensate derived from spacecraft and ground sources showed considerable variation in composition. Consequently, an investigation was conducted to collect condensate on the Shuttle while the vehicle was docked to Mir, and return the condensate to Earth for testing. This scenario emulates an early ISS configuration during a Shuttle docking, because the atmospheres intermix during docking and the condensate composition should reflect that. During the STS-89 and STS-91 flights, a total volume of 50 liters of condensate was collected and returned. Inorganic and organic chemical analyses were performed on aliquots of the fluid.

Twenty-nine recycled water, eight stored (ground-supplied) water, and twenty-eight humidity condensate samples were collected on board the Mir Space Station during the Phase One Program (1995-1998). These samples were analyzed to determine potability of the recycled and ground-supplied water, to support the development of water quality monitoring procedures and standards, and to assist in the development of water reclamation hardware. This paper describes and summarizes the results of these analyses and lists the lessons learned from this project. Results show that the recycled water and stored water on board Mir, in general, met NASA, Russian Space Agency (RSA), and U.S. Environmental Protection Agency (EPA) standards.

Potable- and hygiene-quality water will be supplied to crews on the International Space Station through the recovery and purification of spacecraft wastewaters, including humidity condensate, urine, and wash water. Contaminants released into the cabin air from human metabolism, hardware offgassing, flight experiments, and routine operations will be present in spacecraft humidity condensate; normal constituents of urine and bathing water will be present in urine and untreated wash water. This report describes results from detailed analyses of Mir reclaimed potable water, ground-supplied water, and humidity condensate. These results are being used to develop and test water recycling and monitoring systems for the International Space Station (ISS); to evaluate the efficiency of the Mir water processors; and to determine the potability of the recycled water on board.

The Early Human Testing Initiative (EHTI) Phase I Human Test, performed by the Crew and Thermal Systems Division at Johnson Space Center, demonstrated the ability of a crop of wheat to provide air revitalization for a human test subject for a 15-day period. The test demonstrated three different methods for control of oxygen and carbon dioxide concentrations for the human/plant system and obtained data on trace contaminants generated by both the human and plants during the test and their effects on each other. The crop was planted in the Variable Pressure Growth Chamber (VPGC) on July 24, 1995 and the test subject entered the adjoining airlock on day 17 of the wheat's growth cycle. The test subject stayed in the chamber for a total of 15 days, 1 hour and 20 minutes. Air was mixed between the plant chamber and airlock to provide oxygen to the test subject and carbon dioxide to the plants by an interchamber ventilation system.

The incidence of decompression sickness (DCS) in space appears to be less than that predicted to occur on the basis of ground based altitude chamber trials. Our current work uses six hours of chair rest adynamia and likewise produces fewer gas bubbles when compared to standing in a cross over study. Mild exercise during oxygen prebreathe is also very efficacious in reducing DCS and bubble formation (measured by Doppler ultrasound). The effect is postulated to be the result of the alteration in the populations of tissue micronuclei such that the radii are reduced. Surface tension then becomes too great for bubble growth from the existing inert gas partial pressures.

Supply of oxygen (O2) and hydrogen (H2) by electrolyzing water in space will play an important role in meeting the National Aeronautics and Space Administration's (NASA's) needs and goals for future space missions. Both O2 and H2 are envisioned to be used in a variety of processes including crew life support, spacecraft propulsion, extravehicular activity, electrical power generation/storage as well as in scientific experiment and manufacturing processes. Life Systems, Inc., in conjunction with NASA, has been developing an alkaline-based Static Feed Electrolyzer (SFE). During the development of the water electrolysis technology over the past 23 years, an extensive engineering and scientific data base has been assembled.

The purification of waste water is a critical element of any long-duration space mission. The Vapor Phase Catalytic Ammonia Removal (VPCAR) system offers the promise of a technology requiring low quantities of expendable material that is suitable for exploration missions. NASA has funded an effort to produce an engineering development unit specifically targeted for integration into the NASA Johnson Space Center's Integrated Human Exploration Mission Simulation Facility (INTEGRITY) formally known in part as the Bioregenerative Planetary Life Support Test Complex (Bio-Plex) and the Advanced Water Recovery System Development Facility. The system includes a Wiped-Film Rotating-Disk (WFRD) evaporator redesigned with micro-gravity operation enhancements, which evaporates wastewater and produces water vapor with only volatile components as contaminants. Volatile contaminants, including organics and ammonia, are oxidized in a catalytic reactor while they are in the vapor phase.