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The autoignition characteristics of methanol, ethanol and MTBE (methyl tert-butyl ether) have been investigated in a rapid compression machine at pressures in the range 20-40 atm and temperatures within 750-1000 K. All three oxygenated fuels tested show higher autoignition temperatures than paraffins, a trend consistent with the high octane number of these fuels. The autoignition delay time for methanol was slightly lower than predicted values using reported reaction mechanisms. However, the experimental and measured values for the activation energy are in very good agreement around 44 kcal/mol. The measured activation energy for ethanol autoignition is in good agreement with previous shock tube results (31 kcal/mol), although ignition times predicted by the shock tube correlation are a factor of three lower than the measured values. The measured activation energy for MTBE, 41.4 kcal/mol, was significantly higher than the value previously observed in shock tubes (28.1 kcal/mol).

Knock in gasoline engines at higher loads is a significant constraint on torque and efficiency. The anti-knock property of a fuel is closely related to its research octane number (RON). Ethanol has superior RON compared to gasoline and thus has been commonly used to blend with gasoline in commercial gasolines. However, as the RON of a fuel is constant, it has not been used as needed in a vehicle. To wisely use the RON, an On-Board Separation (OBS) unit that separates commercial gasoline with ethanol content into high-octane fuel with high ethanol fraction and a lower octane remainder has been developed. Then an onboard Octane-on-demand (OOD) concept uses both fuels in varying proportion to provide to the engine a fuel blend with just enough RON to meet the ever changing octane requirement that depends on driving pattern.

Spark-ignition engine knock was characterized in terms of when during the engine cycle and combustion process knock occurred and its magnitude or intensity. Cylinder pressure data from a large number of successive individual cycles were generated from a single-cylinder engine of hemispherical chamber design over a range of operating conditions where knock occurred in some or all of these cycles. Mean values and distributions of following parameters were quantified: knock occurrence crank angle, knock intensity, combustion rate and the end-gas thermodynamic state. These parameters were determined from the cylinder pressure data on an individual cycle basis using a mass-burn-rate analysis. The effects of engine operating variables on these parameters were studied, and correlations between these parameters were examined.

Long-haul and other heavy-duty trucks, presently almost entirely powered by diesel fuel, face challenges meeting worldwide needs for greatly reducing nitrogen oxide (NOx) emissions. Dual-fuel gasoline-alcohol engines could potentially provide a means to cost-effectively meet this need at large scale in the relatively near term. They could also provide reductions in greenhouse gas emissions. These spark ignition (SI) flexible fuel engines can provide operation over a wide fuel range from mainly gasoline use to 100% alcohol use. The alcohol can be ethanol or methanol. Use of stoichiometric operation and a three-way catalytic converter can reduce NOx by around 90% relative to emissions from diesel engines with state of the art exhaust treatment.

The effects of cooled exhaust gas recirculation (EGR) on a boosted direct-injection (DI) spark ignition (SI) engine operating at stoichiometric equivalence ratio, gross indicated mean effective pressure of 14-18 bar, and speed of 1500-2500 rpm, are studied under constant fuel condition at each operating point. In the presence of EGR, burn durations are longer and combustion is more retard. At the same combustion phasing, the indicated specific fuel consumption improves because of a decrease in heat loss and an increase in the specific heat ratio. The knock limited spark advance increases substantially with EGR. This increase is due partly to a slower combustion which is equivalent to a spark retard, as manifested by a retarded value of the 50% burn point (CA50), and due partly to a slower ignition chemistry of the diluted charge, as manifested by the knock limited spark advance to beyond the value offered by the retarded CA50.

High boost and direct injection are effective ways for energy saving in gasoline engines. However, the occurrence of super-knock at high load has become a main obstacle for further improving power density and fuel economy. It has been known that super-knock can be induced by pre-ignition, and oil droplet auto-ignition is found to be one of the possible mechanisms. In this study, experiments were conducted in a single-cylinder thermal research engine (TRE), in which different types of oil and surrogates were directly injected into the cylinder and then led to pre-ignition and super-knock. The effect of oil injection timing, oil injection quantity, different gasoline and different oil were tested. All the oil in this work could induce pre-ignition, even though their combustion phasing was much later than that in the case of n-hexadecane.

Compression ratio and specific heat ratio are two dominant factors influencing engine thermal efficiency. Therefore, ultra-lean burn may be one method to deal with increasingly stringent fuel consumption and emission regulations in the approaching future. To achieve high efficiency and clean combustion, innovative combustion modes have been applied on research engines including homogeneous charge compression ignition (HCCI), spark-assisted compression ignition (SACI), and gasoline direct-injection compression ignition (GDCI), etc. Compared to HCCI, SACI can extend the load range and more easily control combustion phase while it is constrained by the limit of flame propagation. For SACI with ultra-lean burn in engines, equivalence ratio (φ), rich-fuel mixture around spark plug, and supercharging are three essentials for combustion stability.

Natural gas is one of the promising alternative fuels due to the low cost, worldwide availability, high knock resistance and low carbon content. Ignition quality is a key factor influencing the combustion performance in natural gas engines. In this study, the effect of pre-chamber geometry on the ignition process and flame propagation was studied under varied initial mixture temperatures and equivalence ratios. The pre-chambers with orifices in different shapes (circular and slit) were investigated. Schlieren method was adopted to acquire the flame propagation. The results show that under the same cross-section area, the slit pre-chamber can accelerate the flame propagation in the early stages. In the most of the cases, the penetration length of the flame jet and flame area development are higher in the early stages of combustion.

The NOx emission and knock characteristics of a PFI engine operating on ethanol/gasoline mixtures were assessed at 1500 and 2000 rpm with λ =1 under Wide-Open-Throttle condition. There was no significant charge cooling due to fuel evaporation. The decrease in NOx emission and exhaust temperature could be explained by the change in adiabatic flame temperature of the mixture. The fuel knock resistance improved significantly with the gasohol so that ignition could be timed at a value much closer or at MBT timing. Changing from 0% to 100% ethanol in the fuel, this combustion phasing improvement led to a 20% increase in NIMEP and 8 percentage points in fuel conversion efficiency at 1500 rpm. At 2000 rpm, where knocking was less severe, the improvement was about half (10% increase in NIMEP and 4 percentage points in fuel conversion efficiency).

Octane number (ON) and octane sensitivity (S), the fuel anti-knock indices, are critical for the design of advanced jet ignition engines. In this study, ten fuels with different research octane number (RON) and varying S were formulated based on ethanol reference fuels (ERFs) to investigate the effect of S on combustion of jet ignition engine. To fully understand S effects, the combustion characteristics under EGR dilution and lean burn were further investigated. The results indicated that increasing S resulted in higher reactivity with shorter ignition delay and combustion duration. The increase of reactivity led to heavier knocking intensity. The competition between the flame speed and the reactivity of the mixture determined the auto-ignition fraction of mixture and the knocking onset crank angle as S varied. Medium S (S=3) was helpful to improve the combustion speed, reduce the auto-ignition fraction of mixture and retard the knocking onset crank angle.

Super-knock has been a significant obstacle for the development of highly turbocharged (downsized) gasoline engines with spark ignition, due to the catastrophic damage super-knock can cause to the engine. According to previous research by the authors, one combustion process leading to super-knock may be described as hot-spot induced pre-ignition followed by deflagration which can induce detonation from another hot spot followed by high pressure oscillation. The sources of the hot spots which lead to pre-ignition (including oil films, deposits, gas-dynamics, etc.) may occur sporadically, which leads to super-knock occurring randomly at practical engine operating conditions. In this study, a spark plasma was used to induce preignition and the correlation between super-knock combustion and the thermodynamic state of the reactant mixture was investigated in a four-cylinder production gasoline engine.

THE autoignition characteristics of several fuels under various conditions of mixture strength, compression ratio, and temperature have been studied by means of a rapid-compression machine. The behaviors of a knock inhibitor, tetraethyl lead, and a knock inducer, ethyl nitrite, have also been studied. Simultaneous records of pressure, volume, and the inflammation have been obtained. These records show the diverse aspects of the autoignition phenomenon and indicate, among other things, according to the authors, that a comparison of the detonating tendencies of fuels must include not only a consideration of the length of the delay period but also an evaluation of the rate of pressure rise during autoignition. Physical interpretations of the data are presented but chemical interpretations have been avoided. The work was exploratory in nature. The authors hope that the results will stimulate activity in this important branch of combustion research.

A novel non-destroy repeatable-use impact theory based total cylinder sampling system has been established. This system is mainly composed of a knocking body and a sampling valve. The knocking body impacts the sampling valve with certain velocity resulting in huge force to open the sampling valve and most of the in-cylinder gas has been dumped to one sampling bag for after-treatment. The feasibility and sampling response characteristics of this impact theory based total cylinder sampling system were investigated by engine bench testing. Within 0 to 35°CA ATDC (Crank Angle After Top Dead Center) sample timing 50 percent to 80 percent of in-cylinder mass would be sampled, which was a little less compared with the traditional system. The half decay period of pressure drop was 10 to 20 degrees crank angle within 0 to 60°CA ATDC sample timing, which was about 2-3 times of the traditional system.

Low Speed Pre-Ignition (LSPI), also referred to as superknock or mega-knock is an undesirable turbocharged engine combustion phenomenon limiting fuel economy, drivability, emissions and durability performance. Numerous researchers have previously reported that the frequency of Superknock is sensitive to engine oil and fuel composition as well as engine conditions in controlled laboratory and engine-based studies. Recent studies by Toyota and Tsinghua University have demonstrated that controlled induction of particles into the combustion chamber can induce pre-ignition and superknock. Afton and Tsinghua recently developed a multi-physics approach which was able to realistically model all of the elementary processes known to be involved in deposit induced pre-ignition. The approach was able to successfully simulate deposit induced pre-ignition at conditions where the phenomenon has been experimentally observed.

This paper presents the analysis and design of a variable compression-ratio and displacement engine concept - the Alvar Cycle using a four-stroke engine-performance simulation. The Alvar-Cycle engine uses secondary pistons which reciprocate in auxiliary chambers housed in the cylinder head, at adjustable phase-angle differences from the primary pistons. The phase difference provides both the variable total engine displacement and compression ratio. Results indicate that the Alvar engine can operate at higher power density via a combination of higher intake boost and lower compression ratio to avoid knock at high loads, and capture the better thermal efficiency at higher compression ratios at part loads.

The ignition of lubricating oil droplet has been proved to be the main factor for pre-ignition and the following super-knock in turbocharged gasoline direct injection engine. In this paper, the ignition process of lubricating oil droplet in combustible ambient gaseous mixture was investigated in a rapid compression machine (RCM). The pre-ignition induction by oil droplet of the ambient gaseous mixture was analyzed under different initial droplet volume and effective temperature conditions. The oil droplet was suspended on a tungsten fiber in the combustion chamber and the ignition process was recorded by a high-speed camera through the quartz window mounted at the end of the combustion chamber. The pressure traces were also obtained by a sensor in order to get the ignition delay and analyze the combustion process in detail.

The knocking characteristics of several fuels are studied using a single cylinder test engine with variations in key engine operating parameters. Compression ratio, spark advance, fuel equivalence ratio, exhaust gas recirculation, engine speed, charge inlet pressure and charge inlet temperature were varied to yield a range of engine cylinder pressure-temperature histories as the base for this study. The fuels studied include three reference fuels containing isooctane and heptane with isooctane volume percents of 80, 90 and 100. Two wide boiling range gasolines were also studied. A number of empirical relationships for autoignition times of isooctane and heptane blends are employed in conjunction with the experimentally obtained pressure-temperature histories to predict onset of knock. The accuracies of the predictions with respect to the experimentally determined knock points are discussed.

In internal combustion engines, a portion of liquid fuel spray may directly land on the liner and mix with oil (lubricant), forming a fuel-oil film (~10μm) that is much thicker than the original oil film (~0.1μm). When the piston retracts in the compression stroke, the fuel-oil mixture may have not been fully vaporized and can be scraped by the top ring into the 1st land crevice and eventually enter the combustion chamber in the format of droplets. Studies have shown that this mechanism is possibly a leading cause for low-speed pre-ignition (LSPI) as the droplets contain oil that has a much lower self-ignition temperature than pure fuel. In this interest, this work aims to study the oil-fuel interactions on the liner during an engine cycle, addressing molecular diffusion (in the liquid film) and vaporization (at the liquid-gas interface) to quantify the amount of fuel and oil that are subject to scraping by the top ring, thereby exploring their implications on LSPI and friction.

The performance of an extended stroke spark ignition engine has been assessed by cycle simulation. The base engine is a modern turbo-charged 4-stroke passenger car spark-ignition engine with 10:1 compression ratio. A complex crank mechanism is used so that the intake stroke remains the same while the expansion-to-intake stroke ratio (SR) is varied by changing the crank geometry. The study is limited to the thermodynamic aspect of the extended stroke; the changes in friction, combustion characteristic, and other factors are not included. When the combustion is not knock limited, an efficiency gain of more than 10 percent is obtained for SR = 1.5. At low load, however, there is an efficiency lost due to over-expansion. At the same NIMEP, the extended stroke renders the engine more resistant to knock. At SR of 1.8, the engine is free from knock up to 14 bar NIMEP at 2000 rpm. Under knocking condition, the required spark retard to prevent knocking is less with the extended stroke.

1 Downsizing and turbocharging a spark-ignited engine is becoming an important strategy in the engine industry for improving the efficiency of gasoline engines. Through boosting the air flow, the torque is increased, the engine can thus be downsized, engine friction is reduced in both absolute and relative terms, and engine efficiency is increased. However knock onset with a given octane rating fuel limits both compression ratio and boost levels. This paper explores the operating limits of a turbocharged engine, with various gasoline-ethanol blends, and the interaction between compression ratio, boost levels, and spark retard, to achieve significant increases in maximum engine mean effective pressure and efficiency.