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The adoption of lithium-ion batteries in vehicle electrification is fast growing due to high power and energy demand on hybrid and electric vehicles. However, the battery overall performance changes with time through the vehicle life. This paper investigates the electric vehicle battery cell aging under different usages. Battery cell experimental data including open circuit voltage and internal resistance is utilized to build a typical electric vehicle model in the AVL-Cruise platform. Four driving cycles (WLTP, UDDS, HWFET, and US06) with different ambient temperatures are simulated to acquire the battery cell terminal currents. These battery cell terminal current data are inputs to the MATLAB/Simulink battery aging model. Simulation results show that battery degrades quickly in high ambient temperatures. After 15,000 hours usage in 50 degrees Celsius ambient temperature, the usable cell capacity is reduced up to 25%.

A methodology for evaluating life cycle cost of electric vehicles (EVs) to their buyers is presented. The methodology is based on an analysis of conventional vehicle costs, costs of drivetrain and auxiliary components unique to EVs, and battery costs. The conventional vehicle's costs are allocated to such subsystems as body, chassis, and powertrain. In electric vehicles, an electric drive is substituted for the conventional powertrain. The current status of the electric drive components and battery costs is evaluated. Battery costs are estimated by evaluating the material requirements and production costs at different production levels; battery costs are also collected from other sources. Costs of auxiliary components, such as those for heating and cooling the passenger compartment, are also estimated. Here, the methodology is applied to two vehicle types: subcompact car and minivan.

Use of ethanol as gasoline replacement can contribute to the reduction of nitrogen oxide (NOx) and carbon oxide (CO) emissions. Depending on ethanol production, significant reduction of greenhouse-gas emissions is possible. Concentration of certain species, such as unburned ethanol and acetaldehyde in the engine-out emissions are known to rise when ratio of ethanol to gasoline increases in the fuel. This research explores on hydrous ethanol fueled port-fuel injection (PFI) spark ignition (SI) engine emissions that contribute to photochemical formation of ozone, or so-called ozone precursors and the precursor of peroxyacetyl nitrates (PANs). The results are compared to engine operation on gasoline. Concentration obtained by FTIR gas analyzer, and mass-specific emissions of formaldehyde (HCHO), acetaldehyde (MeCHO) and methane (CH4) under two engine speed, four load and two spark advance settings are analyzed and presented.

Ammonia is a promising carbon-free alternative fuel for use in combustion systems. The main associated challenges are its relatively low reactivity and high NOx emissions compared to conventional fuels. Therefore, the combustion behaviour of ammonia and ammonia blends still needs to be better understood over a wide range of conditions. To this end, a comprehensive chemical kinetic mechanism C3MechV3.4, which is an update of C3MechV3.3, has been developed for improved predictions of the combustion of ammonia and ammonia blends. C3MechV3.4 has been validated using a wide range of experimental results for pure ammonia and ammonia/hydrogen, ammonia/methanol and ammonia/n-heptane blends. These validations target different data sets including ignition delay times, species profiles measured as a function of time, and/or temperature and laminar flame speeds over a wide range of conditions.

The Battery Performance and Cost Model (BatPaC), developed by Argonne National Laboratory, is a versatile tool designed for lithium-ion battery (LIB) pack engineering. It accommodates user-defined specifications, generating detailed bill-of-materials calculations and insights into cell dimensions and pack characteristics. Pre-loaded with default data sets, BatPaC aids in estimating production costs for battery packs produced at scale (5 to 50 GWh annually). Acknowledging inherent uncertainties in parameters, the tool remains accessible and valuable for designers and engineers. BatPaC plays a crucial role in National Highway Transportation Traffic Safety Administration (NHTSA) regulatory assessments, providing estimated battery pack manufacturing costs and weight metrics for electric vehicles. Integrated with Argonne's Autonomie simulations, BatPaC streamlines large-scale processes, replacing traditional models with lookup tables.

To reduce development time and introduce technologies faster to the market, many companies have been turning more and more to Model Based Design. In Model Based Design, the development process centers around a system model, from requirements capture and design to implementation and test. Engineers can skip over a generation of system design processes on the basis of hand coding and use graphical models to design, analyze, and implement the software that determines machine performance and behavior. This paper describes the process implemented in Autonomie, a Plug-and-Play Software Environment, to design and evaluate component hardware in an emulated environment. We will discuss best practices and provide an example through evaluation of advanced high-energy battery pack within an emulated Plug-in Hybrid Electric Vehicle.

The U.S. Renewable Fuel Standard (RFS2) requires an increase in the use of advanced biofuels up to 36 billion gallons by 2022. Longer chain alcohols, in addition to cellulosic ethanol and synthetic biofuels, could be used to meet this demand while adhering to the RFS2 corn-based ethanol limitation. Higher carbon number alcohols can be utilized to improve the energy content, knock resistance, and/or petroleum displacement of gasoline-alcohol blends compared to traditional ethanol blends such as E10 while maintaining desired and regulated fuel properties. Part I of this paper focuses on the development of scenarios by which to compare higher alcohol fuel blends to traditional ethanol blends. It also details the implementation of fuel property prediction methods adapted from literature. Possible combinations of eight alcohols mixed with a gasoline blendstock were calculated and the properties of the theoretical fuel blends were predicted.

Higher carbon number alcohols offer an opportunity to meet the Renewable Fuel Standard (RFS2) and improve the energy content, petroleum displacement, and/or knock resistance of gasoline-alcohol blends from traditional ethanol blends such as E10 while maintaining desired and regulated fuel properties. Part II of this paper builds upon the alcohol selection, fuel implementation scenarios, criteria target values, and property prediction methodologies detailed in Part I. For each scenario, optimization schemes include maximizing energy content, knock resistance, or petroleum displacement. Optimum blend composition is very sensitive to energy content, knock resistance, vapor pressure, and oxygen content criteria target values. Iso-propanol is favored in both scenarios' suitable blends because of its high RON value.

Emissions from CI engines fueled with dimethyl ether (DME) were discussed in this paper. Thanks to its high content of fuel oxygen, DME combustion is virtually soot free. This characteristic of DME combustion indicates that the particulate filter will not be needed in the aftertreatment system for engines fueled with DME. NOx emissions from a CI engine fueled with DME can meet the US 2007 regulation with a high EGR rate. Because 49% more fuel mass must be delivered in each DME injection than the corresponding diesel-fuel injection, and the DME injection pressure is lower than 500 bar under the current fuel-system technology, the DME injection duration is generally longer than that of diesel-fuel injection. This is unfavorable to further NOx reduction. A multiple-injection strategy with timing for the primary injection determined by the cylinder temperature was proposed.

Preliminary research in our laboratory has demonstrated that boric acid is an effective lubricant with an unusual capacity to reduce the sliding friction (providing friction coefficients as low as 0.02) and wear of metallic and ceramic materials. More recent studies have revealed that water or methanol solutions of boric acid can be used to prepare strongly bonded layers of boric acid on aluminum surfaces. It appears that boric acid molecules have a strong tendency to bond chemically to the naturally oxidized surfaces of aluminum and its alloys and to make these surfaces very slippery. Recent metal-formability tests indicated that the boric acid films applied to aluminum surfaces worked quite well, improving draw scale performance by 58 to 75%.

The CFR F1 engine is the standard testing apparatus used for rating the research octane number (RON) of gasoline fuels. Unlike the motor octane number (MON) method, where the intake port temperature after the carburetor is controlled by an electric heater, the mixture temperature can vary during the RON test due to the heat of vaporization (HoV) of the fuel. Ethanol is receiving increasing attention as a high octane and high HoV fuel component. This work presents an analysis of the combustion characteristics during the RON rating of ethanol fuel blends according to the standard ASTM D2699 method, highlighting the effects of ethanol concentration and base fuel composition. All fuels were blended to a constant RON of 98. Ethanol levels varied from 0 to 50 vol% and the base fuels were surrogate blends composed of primary reference fuels (PRF), toluene standardization fuels (TSF), and a four component gasoline surrogate.

The correlations between the physical properties and autoignition parameters of several alternate fuels have been examined. The fuels are DF-2 and its blends with petroleum derived fuels, coal derived fuels, shale derived fuels, high aromatic naphtha sun-flower oils, methanol and ethanol. A total of eighteen existing correlations are discussed. An emphasis is made on the suitability of each of the correlations for the development of electronic controls for diesel engines when run on alternate fuels. A new correlation has been developed between the cetane number of the fuels and its kinematic viscosity and specific gravity.

Most current flex-fuel vehicles are capable of operating on gasoline/ethanol blends from E0 to E85. The presence of gasoline in the fuel enables cold startability because some of its more volatile components can still vaporize at cold temperatures and produce an ignitable mixture. However when E100 is used, other means are required for cold starting because of ethanol's relatively low vapor pressure at low temperatures. A common technique is to employ an auxiliary gasoline fuel system for use only when temperatures are too low for the vehicle to start on E100 alone. But the added cost, complexity and maintenance of such systems have driven the search for a simpler approach. One such technique is to heat the fuel prior to injection. Fuel systems currently exist where heating occurs within the main conduit of the fuel rail. Another method is to heat the fuel within each fuel injector.

Battery packs for plug-in hybrid electrical vehicle (PHEV) applications can be characterized as high-capacity and high-power packs. For PHEV battery packs, their power and electrical-energy capacities are determined by the range of the electrical-energy-driven operation and the required vehicle drive power. PHEV packs often employ high-power lithium-ion (Li-ion) pouch cells with large cell capacity in order to achieve high packing efficiency. Lithium-ion battery packs for PHEV applications generally have a 96SnP configuration, where S is for cells in series, P is for cells in parallel, and n = 1, 2 or 3. Two PHEV battery packs with 355V nominal voltage and 25-kWh nominal energy capacity are studied. The first pack is assembled with 96 70Ah high-power Li-ion pouch cells in 96S1P configuration. The second pack is assembled with 192 35Ah high-power Li-ion pouch cells in 96S2P configuration.

Detailed properties of particulate matter (PM) emissions from a gasoline direct injection (GDI) engine were analyzed in terms of size, morphology, and nanostructures, as gasoline and its ethanol blend E20 were used as a fuel. PM emissions were sampled from a 0.55L single-cylinder GDI engine by means of a scanning mobility particle sizer (SMPS) for size measurements and a self-designed thermophoretic sampling device for the subsequent analyses of size, morphology and nanostructures using a transmission electron microscope (TEM). The particle sizes were evaluated with variations of air-fuel equivalence ratio and fuel injection timing. The most important result from the SMPS measurements was that the number of nucleation-mode nanoparticles (particularly those smaller than 10 - 15 nm) increased significantly as the fuel injection timing was advanced to the end-of-injection angle of 310° bTDC.

Biodiesel has been widely accepted as an alternative for fossil-derived diesel fuel for use in compression ignition (CI) engines. Poor oxidative stability and cold flow properties restrict the use of biodiesel beyond current B20 blend levels (20% biodiesel in 80% ULSD) for vehicle applications. Maintaining the properties of B20 as specified by ASTM D7476-08 is important because, once out of spec, B20 may cause injector coke formation, fuel filter plugging, increased exhaust emissions, and overall loss of engine performance. While the properties of fresh B20 may be within the specifications, under engine operating and longer storage conditions B20 could deteriorate. In a diesel engine, the fuel that goes to the injector and does not enter the cylinder is recycled back to the fuel tank. The re-circulated fuel returns to the fuel tank at an elevate temperature, which can cause thermal oxidation.

This paper presents the vehicle model development and validation process for the Ford Focus battery electric vehicles (BEVs) using Autonomie and test results from Advanced Powertrain Research Facility in Argonne National Laboratory. The parameters or characteristic values for the important components such as the electric machine and battery pack system are estimated through analyzing the test data of the multi cycle test (MCT) procedure under the standard ambient condition. A novel process was used to import vehicle test data into Autonomie. Through this process, a complete vehicle model of the Ford Focus BEV is developed and validated under ambient temperature for different drive cycles (UDDS, HWFET, US06 and Steady-State). The simulation results of the developed vehicle model show coincident results with the test data within 0.5% ∼ 4% discrepancies for electrical consumption.

Low temperature combustion through in-cylinder blending of fuels with different reactivity offers the potential to improve engine efficiency while yielding low engine-out NOx and soot emissions. A Navistar MaxxForce 13 heavy-duty compression ignition engine was modified to run with two separate fuel systems, aiming to utilize fuel reactivity to demonstrate a technical path towards high engine efficiency. The dual-fuel engine has a geometric compression ratio of 14 and uses sequential, multi-port-injection of a low reactivity fuel in combination with in-cylinder direct injection of diesel. Through control of in-cylinder charge reactivity and reactivity stratification, the engine combustion process can be tailored towards high efficiency and low engine-out emissions. Engine testing was conducted at 1200 rpm over a load sweep.

A novel, electronically controlled, common rail fuel injection system has been designed and developed by the authors under a contract from the National Renewable Energy Laboratory (NREL). This system was specifically designed for direct injection of liquid dimethyl ether (DME) to achieve ultra-low emissions of NOx & particulate matter from conventional diesel engines. However, the system's basic characteristics also make it suitable for direct injection of ethanol & methanol in compression-ignition engines, and direct injection of liquid propane and gasoline in spark-ignition engines.

The focus of this study is to determine the effect of using B-20 (a blend of 20% soybean methyl ester biodiesel and 80% ultra low sulfur diesel fuel) on the combustion process, performance and exhaust emissions in a High Speed Direct Injection (HSDI) diesel engine equipped with a common rail injection system. The engine was operated under simulated turbocharged conditions with 3-bar indicated mean effective pressure and 1500 rpm engine speed. The experiments covered a wide range of injection pressures and EGR rates. The rate of heat release trace has been analyzed in details to determine the effect of the properties of biodiesel on auto ignition and combustion processes and their impact on engine out emissions. The results and the conclusions are supported by a statistical analysis of data that provides a quantitative significance of the effects of the two fuels on engine out emissions.