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The emission and flow restriction characteristics of three different ceramic substrates with varying wall thickness and cell density (400 cpsi/6.5 mil, 600/4.3, and 600/3.5) are compared. These 106mm diameter substrates were catalyzed with similar amounts of washcoat and fabricated into catalytic converters having a total volume of 2.0 liters. A Pd/Rh catalyst technology was applied at a concentration of 6.65 g/l and a ratio of 20/1. Three sets of converters (two of each type) were aged for 100 hours on an engine dynamometer stand. After aging, the FTP performance of these converters were evaluated on an auto-driver FTP stand using a 2.4L, four-cylinder prototype engine and on a 2.4L, four-cylinder prototype vehicle. A third set of unaged converters was used for cold flow restriction measurements and vehicle acceleration tests.

Modeling tailpipe NOx emissions has always been difficult due to the complexity of the numerous factors involved in the catalytic conversion of the pollutant. Most emissions modeling has been based on steady state driving. A parameterized algebraic model for second-by-second tailpipe emissions of NOx for a composite Tier 1 car is presented employing data from the Federal Test Procedure Revision Project (FTPRP). Calculating fuel rate from measured engine out values, the catalytic converter is physically modeled based on the fuel rate history and a few fitted parameters. Under certain conditions, the changes in fuel rate are related to trends in the air to fuel ratio. The model accurately predicts the time dependence of hot stabilized tailpipe NOx emissions in the FTP bag 3 and US06 driving cycles. Modeling of low power driving, as in bag 2, is not as successful.

A global, systems-level model which characterizes the thermal behavior of internal combustion engines is described in this paper. Based on resistor-capacitor thermal networks, either steady-state or transient thermal simulations can be performed. A two-zone, quasi-dimensional spark-ignition engine simulation is used to determine in-cylinder gas temperature and convection coefficients. Engine heat fluxes and component temperatures can subsequently be predicted from specification of general engine dimensions, materials, and operating conditions. Emphasis has been placed on minimizing the number of model inputs and keeping them as simple as possible to make the model practical and useful as an early design tool. The success of the global model depends on properly scaling the general engine inputs to accurately model engine heat flow paths across families of engine designs. The development and validation of suitable, scalable submodels is described in detail in this paper.

An aftertreatment system involving a LNT followed by a SCR catalyst is proposed for treating the NOx emissions from a diesel engine. NH3 (or urea) is injected between the LNT and the SCR. The SCR is used exclusively below 400°C due to its high NOx activity at low temperatures and due to its ability to store and release NH3 below 400°C, which helps to minimize NH3 and NOx slip. Above 400°C, where the NH3 storage capacity of the SCR falls to low levels, the LNT is used to store the NOx. A potassium-based LNT is utilized due to its high temperature NOx storage capability. Periodically, hydrocarbons are oxidized on the LNT under net lean conditions to promote the thermal release of the NOx. NH3 is injected simultaneously to reduce the released NOx over the SCR. The majority of the hydrocarbons are oxidized on the front portion of the LNT, resulting in the rapid release of stored NOx from that portion of the LNT.

Urea water solution-based Selective Catalytic Reduction (SCR) of NOx emissions from vehicular diesel engines is now widely used world-wide to meet strict health and environmental protection regulations. While urea-based SCR is proven effective, urea-derived deposits often form near injectors, on mixers and pipes, and on the SCR catalyst face. Further understanding of these deposit-formation processes is needed to design aftertreatment system hardware and control systems capable of avoiding severe urea-derived deposits. Computational Fluid Dynamics (CFD) is widely used in SCR aftertreatment design. Film formation, movement, solid wall cooling and deposit initiation/growth time-scales are in the range of minutes to hours, but traditional CFD simulations take too long to reach these time-scales. Here, we propose and demonstrate the frozen flow approach for pulsed sprays and conjugate heat transfer to reduce computation time while maintaining accuracy of key physics.

In an effort of providing better understanding of regeneration mechanisms of diesel particulate matter (PM), this experimental investigation focused on evaluating the amount of heat release generated during the thermal reaction of diesel PM and the concentrations of soluble organic compounds (SOCs) dissolved in PM emissions. Differences in oxidation behaviors were observed for two different diesel PM samples: a SOC-containing PM sample and a dry soot sample with no SOCs. Both samples were collected from a cordierite particulate filter membrane in a thermal reactor connected to the exhaust pipe of a light-duty diesel engine. A differential scanning calorimeter (DSC) and a thermogravimetric analyzer (TGA) were used to measure the amount of heat release during oxidation, along with subsequent oxidation rates and the concentrations of SOCs dissolved in particulate samples, respectively.

Close coupled catalysts and new ceramic catalyst substrates have significantly improved the light-off performance of automotive converters required to meet stringent emission requirements. The hotter environment of these catalytic converters and the lower structural strength of the ceramic substrates require the rethinking of converter designs. The development of new package requirements to accommodate the change in environment and new substrates are discussed. A historical perspective on converter durability is presented as reference. Development of durability test protocols is essential to verifying product durability performance to these new environments. Data collection and documentation of testing templates are shown to demonstrate the effectiveness of tests that represent real world environments. Design improvements to address failure modes are discussed along with durability improvement results.

The present study introduces a modeling approach for investigating the effects of valve events and gas exchange processes in the framework of a full-cycle HCCI engine simulation. A multi-dimensional fluid mechanics code, KIVA-3V, is used to simulate exhaust, intake and compression up to a transition point, before which chemical reactions become important. The results are then used to initialize the zones of a multi-zone, thermo-kinetic code, which computes the combustion event and part of the expansion. After the description and the validation of the model against experimental data, the application of the method is illustrated in the context of variable valve actuation. It has been shown that early exhaust valve closing, accompanied by late intake valve opening, has the potential to provide effective control of HCCI combustion.

The current paper describes a methodology for combustion bowl assessment for diesel engines. The methodology is based on the application of Computational Fluid Dynamics (CFD) following a Design of Experiments (DoE) procedure. In this work the 3D CFD simulation was performed by the commercial CFD code AVL-FIRE for different combustion bowls from intake valve closing (IVC) to exhaust valve opening (EVO). The initial conditions (at IVC) and boundary conditions were obtained from 1D simulation. Since the work was concentrated on the spray injection, mixing, combustion as well as bowl aerodynamics only a sector mesh was employed for the calculations. A DoE procedure was also used for this simulation work in order to minimize the number of simulation runs and at the same time maintaining the accuracy required assessing the influences of different bowl geometry, spray and intake air motion parameters.

Emissions from CI engines fueled with dimethyl ether (DME) were discussed in this paper. Thanks to its high content of fuel oxygen, DME combustion is virtually soot free. This characteristic of DME combustion indicates that the particulate filter will not be needed in the aftertreatment system for engines fueled with DME. NOx emissions from a CI engine fueled with DME can meet the US 2007 regulation with a high EGR rate. Because 49% more fuel mass must be delivered in each DME injection than the corresponding diesel-fuel injection, and the DME injection pressure is lower than 500 bar under the current fuel-system technology, the DME injection duration is generally longer than that of diesel-fuel injection. This is unfavorable to further NOx reduction. A multiple-injection strategy with timing for the primary injection determined by the cylinder temperature was proposed.

At the current stage of engine technology, diesel engines typically require diesel particulate filter (DPF) systems to meet recent particulate emissions standards. To assure the performance and reliability of DPF systems, profound understanding of filtration and regeneration mechanisms is required. Among extensive efforts for developing advanced DPF systems, the development of effective thermal management strategies, which control the thermal runaway taking place in oxidation of an excess amount of soot deposit in DPF, is quite challenging. This difficulty stems mainly from lack of sufficient knowledge and understanding about DPF regeneration mechanisms, which need detailed information about oxidation of diesel particulate matter (PM). Therefore, this work carried out a series of oxidation experiments of diesel particulates collected from a DPF on a diesel engine, and evaluated the oxidation rates of the samples using a thermo-gravimetric analyzer (TGA).

Gas-to-Liquids (GTL) is a liquid diesel fuel produced from natural gas, which may have certain attributes different from conventional ultra low sulfur diesel (ULSD). In this investigation, GTL, ULSD, and their blends of 20% and 50% GTL in ULSD were tested in an older Mercedes C Class (MY1999, Euro 2) and a newer Opel Astra (MY2006, Euro 4) diesel vehicle to evaluate the performance in terms of fuel consumption and emissions. Each vehicle was pre-conditioned on-road with one tank full of test fuel before actual testing in a chassis dynamometer facility. Both vehicles were calibrated for European emission standards and operation, and they were not re-calibrated for the fuel tests at Argonne National Laboratory (ANL). In the two-vehicle EPA FTP-75, US06, and Highway drive-cycle tests, the emissions of carbon dioxide on a per-mile basis (g/mi) from all GTL-containing fuels were significantly lower than those from the ULSD.

Dual-fuel combustion using port-injection of low reactivity fuel combined with direct injection of a higher reactivity fuel, otherwise known as Reactivity Controlled Compression Ignition (RCCI), has been shown as a method to achieve high efficiency combustion with moderate peak pressure rise rates, low engine-out soot and NOx emissions. A key requirement for extending to high-load operation is reduce the reactivity of the premixed charge prior to the diesel injection. One way to accomplish this is to use a very low reactivity fuel such as natural gas. In this work, experimental testing was conducted on a 13L multi-cylinder heavy-duty diesel engine modified to operate using RCCI combustion with port injection of natural gas and direct injection of diesel fuel. Natural gas/diesel RCCI engine operation is compared over the EPA Heavy-Duty 13 mode supplemental emissions test with and without EGR.

Similar to single-brick SCR architectures, the multi-brick SCR systems described in this paper require urea injection control software that meets the NOx conversion performance target while maintaining the tailpipe NH3 slip below a given threshold, under all driving conditions. The SCR architectures containing a close-coupled SCRoF and underfloor SCR are temperature-wise more favorable than the under-floor location and lead to significant improvement of the global NOx conversion, compared to a single-brick system. But in order to maximize the benefit of close-coupling, the urea injection control must maximize the NH3 stored in the SCRoF. The under-floor SCR catalyst can be used as an NH3 slip buffer, lowering the risk of NH3 slip at the tailpipe with some benefit on the global NOx conversion of the system. With this approach, the urea injection strategy has a limited control on the NH3 coverage of the under-floor SCR catalyst.

This study presents an efficient process to optimize the transmission loss of a vehicle muffler by using both experimental and analytical methods. Two production mufflers were selected for this study. Both mufflers have complex partitions and one of them was filled with absorbent fiberglass. CAD files of the mufflers were established for developing FEA models in ANSYS and another commercial software program (CFEA). FEA models were validated by experimental measurements using a two-source method. After the models were verified, sensitivity studies of design parameters were performed to optimize the transmission loss (TL) of both mufflers. The sensitivity study includes the perforated hole variations, partition variations and absorbent material insertion. The experimental and sensitivity analysis results are included in the paper.

Detailed soot deposition and oxidation characteristics in a diesel particulate filter (DPF) have been experimentally examined on a unique bench-scale DPF test system that has a visualization window. The filtration and regeneration processes were visualized to examine soot deposition and oxidation behaviors on the filter channel surfaces, along with measurements of pressure drop across the filter. The pressure drop caused by trapped soot was separated from the measured total pressure drop by subtracting the pressure drop caused by the clean filter itself. Then, the soot-derived pressure-drop data, normalized (non-dimensionalized) by the volumetric flow rate, exhaust gas viscosity, and DPF volume, were used to compare filtration and regeneration characteristics at different experimental conditions, independently of flow conditions.

A three-dimensional (3-D) computational fluid dynamics (CFD) code has been developed to predict flow dynamics and pressure drop characteristics in geometry-modified filters in which the normalized distance of the outlet channel plugs from the inlet has been varied at 0.25, 0.50, and 0.75. In clean filter simulations, the pressure drop in geometry-modified filters showed higher values than for conventional filters because of the significant change in the pressure field formed inside the channel that determines the amount of flow entering the modified channel. This flow through the modified channel depends on plug position initially but has a maximum limit when pressure difference and geometrical change are compromised. For soot loading simulations, a Lagrangian multiphase flow model was used to interpret the hydrodynamics of particle-laden flow with realistic inputs.

The objective of this paper is to present the results of diesel exhaust aftertreatment testing and analysis done under the FreedomCAR program. Nitrogen Oxides (NOx) adsorber technology was selected based on a previous investigation of various NOx aftertreatment technologies including non-thermal plasma, NOx adsorber and active lean NOx. Particulate Matter (PM) emissions were addressed by developing a catalyzed particulate filter. After various iterations of the catalyst formulation, the aftertreatment components were integrated and optimized for a light duty vehicle application. This compact exhaust aftertreatment system is dual leg and consists of a sulfur trap, NOx adsorbers, and catalyzed particulate filters (CPF). During regeneration, supplementary ARCO ECD low-sulfur diesel fuel is injected upstream of the adsorber and CPF in the exhaust. Steady state and transient emission test results with and without the exhaust aftertreatment system (EAS) are presented.

FTP emissions from a 2.2L four cylinder vehicle are measured from six different converters. These converters have been designed to have both similar flow restriction and to have similar platinum group metals. The durability of these six converters is evaluated after dynamometer aging of both 125 and 250 hours of RATsm aging. These catalytic converters use various combinations of 400/3.5 (400 cells/in2/3.5mil wall), 400/4.5, 400/6.5, 600/3.5, 600/4.5, and 900/2.5 ceramic substrates in order to meet a restriction target and to maximize converter geometric surface area. Total catalyst volume of the converters varies from 1.9 to 0.82 liters. Catalyst frontal area varies from 68 cm2 to 88 cm2. Five of the six converters use two catalyst bricks. The front catalyst brick uses either a three-way Pd washcoat technology containing ceria or a non-ceria Pd washcoat technology. To minimize dependence on palladium the rear brick uses a Pt/Rh washcoat at a loading of 0.06 Toz and a ratio of 5/0/1.

Despite remarkable progress made over the past 30 years, automobiles continue to be a major source of hydrocarbon emissions. The objective of this study is to evaluate whether variable exhaust valve opening (EVO) and exhaust valve closing (EVC) can be used to reduce hydrocarbon emissions. An automotive gasoline engine was tested with different EVO and EVC timings under steady-state and start-up conditions. The first strategy that was evaluated uses early EVO with standard EVC. Although exhaust gas temperature is increased and catalyst light-off time is reduced, the rapid drop in cylinder temperature increases cylinder-out hydrocarbons to such a degree that a net increase in hydrocarbon emissions results. The second strategy that was evaluated uses early EVO with early EVC. Early EVO reduces catalyst light-off time by increasing exhaust gas temperature and early EVC keeps the hydrocarbon-rich exhaust gas from the piston crevice from leaving the cylinder.