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Optimising an engine specification to improve cold start performance has been investigated. Taguchi methods were used to define a test programme to assess the effect of seven build factors. Experiments were conducted to measure mixture ratio at the spark plug location after a short period of engine cranking at test conditions covering ± 15°C and three fuel-mass-supplied values. The analysis of the results identified build modifications which improved start quality and reduced HC and CO emissions substantially compared to a reference, base-line build. Injector design and location, and inlet valve timing were found to have most influence on robustness to uncontrolled variations in mixture preparation during starts.

A method of predicting brake specific fuel consumption characteristics from limited specifications of engine design has been investigated. For spark ignition engines operating on homogeneous mixtures, indicated specific fuel consumption based on gross indicated power is related to compression ratio and spark timing relative to optimum values. The influence of burn rate is approximately accounted for by the differences in spark timings required to correctly phase combustion. Data from engines of contemporary design shows that indicated specific fuel consumption can be defined as a generic function of relative spark timing, mixture air/fuel ratio and exhaust gas recirculation rate. The additional information required to generate brake specific performance maps is cylinder volumetric efficiency, rubbing friction, auxiliary loads, and exhaust back pressure characteristics.

The determination of size distribution of soot particles and agglomerates in oil samples using a Nanosight LM14 to perform Nanoparticle Tracking Analysis (NTA) is described. This is the first application of the technique to sizing soot-in-oil agglomerates and offers the advantages of relatively high rates of sample analysis and low cost compared to Transmission Electron Microscopy (TEM). Lubricating oil samples were drawn from the sump of automotive diesel engines run under a mix of light duty operating conditions. The oil samples were diluted with heptane before analysing. Results from NTA analysis were compared with the outputs of a more conventional analysis based on Dynamic Light Scattering (DLS). This work shows that soot-in-oil exists as agglomerates with average size of 115 nm. This is also in good agreement with TEM analysis carried out in a previous work. NTA can measure soot particles in polydisperse oil solutions and report the size distribution of soot-in-oil aggregates.

Asymmetric particulate filters (PF), where the inlet channel is wider than the outlet channel, are commonly used because of their greater capacity for ash. Somewhat surprisingly, very few models for asymmetric PFs have been published and none of these gives a correct/detailed description of the geometry. For example, octahedral channels may be treated as if they were square or the tapering walls between the inlet and outlet channels treated as if they were rectangular in cross section. Alternatively, the equations may be presented in generic form in terms of channel cross-sectional areas and perimeters, but without giving any indication of how to calculate these. This paper aims to address these deficiencies with a model that correctly describes the geometry of square and octo-square asymmetric PFs. Expressions for the solid fraction of the PF (which affects thermal mass) and channel cross section and perimeter (both when clean and soot/ash loaded) are presented.

Reduction of nitrogen oxides in Diesel exhaust gas is a challenging task. This paper reports results from an extensive study using Pt-based catalysts involving synthetic gas activity testing (SCAT), engine bench testing and tests on passenger cars. Preliminary SCAT work highlighted the importance of Pt-dispersion, and both SCAT and bench engine testing yielded comparable NOx conversions under steady state conditions at high HC:NOx ratios. On passenger cars in the European cycle without secondary fuel injection NOx conversion was lower than obtained in the steady state tests. Better conversion was obtained in the FTP cycle, where secondary injection was employed. Higher HC:NOx, ratios and more favourable temperature conditions which were present in the exhaust contributed to this higher conversion.

The development of a leanburn engine is described, in which optimized engine design, innovative engine management and exhaust gas aftertreatment using a special NOx-storage catalyst were combined to yield a significant improvement in fuel economy with reduced NOx emissions. To achieve stable combustion near the lean limit a swirl system was used and the appropriate parameters of the 2.2 I 4-cyIinder 4-valve SI engine were optimized. As a result, the mixture formation was improved and the lean limit was extended to higher air-fuel ratios. An adaptive lambda controller which was based on the evaluation of engine-smoothness calculated from the RPM-sensor was implemented to control each cylinder individually close to the lean limit. A model-based control system was developed to achieve extremely accurate air-fuel ratio control during transients.

Enhancements in the thermal stability of three-way catalysts have been achieved by: 1) developing improved methods for the incorporation of ceria into catalyst formulations and 2) identifying a proprietary stabilizer which reduces the rate of ceria sintering at high temperature. Improvements in thermal stability are demonstrated by comparing the FTP and engine dynamometer performance of new formulations with a standard formulation after aging on several high temperature engine dynamometer cycles.

The two major problems of diesel emission control are the reduction of nitrogen oxides and particulates. This paper describes experimental investigations to achieve both a separation of soot particles as well as a catalytic NOx reduction with hydrocarbons under lean diesel exhaust gas conditions. For that purpose a diesel particle trap is coated with a catalyst based on a Pt containing zeolite. Preliminary studies have been performed on the catalytic NOx reduction to evaluate the efficiency of a Pt/zeolite system as well as to establish the impact of operation conditions on the catalyst performance. The activity of the prepared samples (catalytic coating on particle trap) has been determined under model gas test conditions. Much attention has been focussed on the steady-state kinetics of the surface processes. Another aspect considered is the N2O formation which can be reduced, when alkali-earth or rare-earth oxides are added to the catalyst system.

It has long been recognized that the key to achieving stringent emission standards such as ULEV is the control of cold-start hydrocarbons. This paper describes a new approach for achieving excellent cold-start hydrocarbon control. The most important component in the system is a catalyst that is highly active at ambient temperature for the exothermic CO oxidation reaction in an exhaust stream under net lean conditions. This catalyst has positive order kinetics with respect to CO for CO oxidation. Thus, as the concentration of CO in the exhaust is increased, the rate of this reaction is increased, resulting in a faster temperature rise over the catalyst.

A test programme has been conducted to study any potential long term effects of gasoline sulphur on catalyst performance, using a newly developed transient engine-bed ageing cycle. The ageing cycle, which was based on repeated European Extra Urban Drive Cycles, was chosen to ensure that the catalyst experienced a realistically wide range of temperatures and space velocities, together with transients, idle and periods of overrun. Two nominally identical platinum/rhodium catalysts (manufactured from the same batch) with matched lambda sensors, were aged for a period of 80,000 km each, one being aged using a gasoline containing 50 mg/kg (ppm wt) sulphur, the other being aged on the same fuel doped to 450 ppm wt S. The emissions performance of both catalysts was measured after 6,000, 40,000 and 80,000 km ageing, by fitting the catalysts to a test vehicle, and performing emissions tests over the European test cycle at both sulphur levels.

An adsorber system for reducing cold start hydrocarbon (HC) emissions has been developed combining existing catalyst technologies with a zeolite-based HC adsorber. The series flow in-line concept offers a passive and simplified alternative to other technologies by incorporating one additional adsorber substrate into existing converters without any additional valving, purging lines, or special substrates. This contribution describes the current development status of hydrocarbon adsorber aftertreatment technologies. We report results obtained with a variety of adsorber, start-up, and underfloor catalyst system combinations. In each case, it was possible to achieve HC emission levels in compliance with the ULEV standards, and in the best cases, demonstrating HC emissions substantially below the legislated standard.

Morphology plays an important role in determining behaviour and impact of soot nanoparticles, including effect on human health, atmospheric optical properties, contribution to engine wear, and role in marine ecology. However, its nanoscopic size has limited the ability to directly measure useful morphological parameters such as surface area and effective volume. Recently, 3D morphology characterization of soot nanoparticles via electron tomography has been the subject of several introductory studies. So-called ‘3D-TEM’ has been posited as an improvement over traditional 2D-TEM characterization due to the elimination of the error-inducing information gap that exists between 3-dimensional soot structures and 2-dimensional TEM projections. Little follow-up work has been performed due to difficulties with developing methodologies into robust high-throughput techniques.

Experimental studies of fuel utilisation during the early stages of engine warm-up after cold-starts are reported. The investigation has been carried out on a 1.81, 4 cylinder spark-ignition engine with port electronic fuel injection. The relationship between fuel supplied and fuel accounted for by the analysis of exhaust gas composition shows that a significant mass of fuel supplied is temporarily stored or permanently lost. An interpretation of data is made which allows time-dependent variations of these to be separately resolved and estimates of fuel quantities made. The data covers a range of cold-start conditions down to -5°C at which, on a per cylinder basis, fuel stored peaks typically at around 0.75g and a total of 1g is returned over 100 seconds of engine running. Fuel lost past the piston typically accounts for 2g over 200 to 300 seconds of running.

This paper describes the use of advanced three-way catalysts to meet future European and California low emissions legislation. Firstly, it describes the performance of these catalysts tested using the European Stage II test cycle and contrasts their emissions performance over the proposed European Stage III test. The future legislation requires fast catalyst light-off for the low emissions standards to be achieved, therefore the performance of close-coupled catalysts was investigated. The close-coupled catalyst systems gave very low emissions. Space constraints often preclude the use of large volume close-coupled catalysts, and the combination of a small starter catalyst with an underfloor catalyst was tested. This gave performance levels better than the close-coupled configuration. The effect of reducing the underfloor catalyst volume is also described. The work was carried out on a 1.2 litre European Vehicle, the conclusions were verified on a 1.6 litre European vehicle.

Various types of after-treatment system for BS VI Stage 1 are being assessed for the Light Duty Diesel (LDD) segment. For BS VI Stage 2, Real Driving Emission (RDE) assessment will be newly introduced, which will require more robustness in emission control system capability. Although the detailed requirements for India BS VI stage 2 are still being discussed, a reasonable assumption is that similar systems to those being developed for Euro 6d, will work for India BS VI. This paper describes typical system designs for Euro 6d and also reveals newly developed SCRF® (Selective Catalytic Reduction Filter) based systems, which demonstrate excellent RDE emissions. In addition, newly developed Lean NOx Trap (NSC) coatings, which focus on low temperature NOx control used with SCRF® (NSC + SCRF®) also show excellent emission control capability as demonstrated in this case on the ARTEMIS Cycle. These systems have potential as promising LDD solutions for India BS VI stage 2.

The awareness concerning environmental issues and the economical need for fuel savings leads to the introduction of new, highly efficient Diesel engines for passenger cars. An engine with common rail injection system could meet this target and, with the help of an advanced diesel exhaust aftertreatment system also fulfilled the new legislative emission regulations. Besides the efficient oxidation of carbon monoxide (CO), hydrocarbons (HC) and diesel particulates, such a system also requires a moderate reduction efficiency for nitrogen oxides (NOx) under excess oxygen conditions. The present paper illustrates the further progress in catalytic NOx-reduction under excess of oxygen by hydrocarbon enrichment using the common rail injection system.

An experimental study of the performance of a reverse tumble, DISI engine is reported. Specific fuel consumption and engine-out emissions have been investigated for both homogeneous and stratified modes of fuel injection. Trends in performance with varying AFR, EGR, spark and injection timings have been explored. It is shown that neural networks can be trained to describe these trends accurately for even the most complex case of stratified charge operation with exhaust gas recirculation.

Chemiluminescence imaging has been applied to a parametric investigation of diesel autoignition. Time-resolved images of the natural light emission were made in an optically accessible DI diesel engine of the heavy-duty size class using an intensified CCD video camera. Measurements were obtained at a base operating condition, corresponding to a motored TDC temperature and density of 992 K and 16.6 kg/m3, and for TDC temperatures and densities above and below these values. Data were taken with a 42.5 cetane number blend of the diesel reference fuels for all conditions, and measurements were also made with no. 2 diesel fuel (D2) at the base condition. For each condition, temporal sequences of images were acquired from the time of first detectable chemiluminescence up through fully sooting combustion, and the images were analyzed to obtain quantitative measurements of the average emission intensity.

A comparison of two different types of NOx reducing catalysts will be worked out. The potential of two De-NOx catalysts using engine out hydrocarbon emissions for NOx conversion will be shown by variation of different engine parameters. An analysis of the hydrocarbon species upstream and downstream catalyst will demonstrate, which components are responsible for the NOx reduction in the exhaust gas of a lean burn engine. By variation of different parameters during adsorbtion and regeneration phases of the adsorber catalyst the efficiency in NOx reduction will be optimized. An assessment of the suitability for lean burn engines will consider the emission reduction efficiency as well as the influence on engine fuel consumption.

The experience which has been gained in more than ten years with vehicles for the U.S.A. and Japan forms the basis of the catalytic converter systems for application in Europe. We are talking about the improvement of the mechanical and chemical endurance of catalytic converters and oxygen sensors. Special attention is paid to various substrate materials (e.g. steel) and coatings concerning their properties with regard to high-temperature stability and power loss. Moreover we are dealing with the increased application of electronics in the engine. The paper mainly refers to the Mercedes-Benz 190 E 2.3-16. This vehicle is used as an example to show the development of an emission concept for European requirements.