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A 3-dimensional numerical study has been conducted investigating the combustion process in a VW 1.9l TDI Diesel engine. Simulations were performed modeling the spray injection of a 5-hole Diesel injector in a pressure chamber. A graphical methodology was utilized to match the spray resulting from the widely used Discrete Droplet Spray model to pressure chamber spray images. Satisfactory agreement has been obtained regarding the simulated and experimental spray penetration and cone angles. Thereafter, the combustion process in the engine was simulated. Using engine measurements to initialize the combustion chamber conditions, the compression stroke, the spray injection and the combustion simulation was performed. The novel RTZF two-zone flamelet combustion model was used for the combustion simulation and was tested for partial load operating conditions. An objective analysis of the model is presented including the results of a numerical parameter study.

Renewable fuels, such as bio- and e-fuels, are of great interest for the defossilization of the transport sector. Among these fuels, methanol represents a promising candidate for emission reduction and efficiency increase due to its very high knock resistance and its production pathway as e-fuel. In general, reliable simulation tools are mandatory for evaluating a specific fuel potential and optimizing combustion systems. In this work, a previously presented methodology (Esposito et al., Energies, 2020) has been refined and applied to a different engine and different fuels. Experimental data measured with a single cylinder engine (SCE) are used to validate RANS 3D-CFD simulations of gaseous engine-out emissions. The RANS 3D-CFD model has been used for operation with a toluene reference fuel (TRF) gasoline surrogate and methanol. Varying operating conditions with exhaust gas recirculation (EGR) and air dilution are considered for the two fuels.

Catalyst systems utilizing ceramic and metallic substrates were compared to assess the influence of various substrate parameters on the exhaust gas conversion efficiency and flow restriction. In particular, the substrate surface area, substrate specific heat capacity, and substrate volume were all evaluated for their importance in estimating the conversion efficiency of the catalyst system. Additionally, substrate open frontal area and cell hydraulic diameter were compared against exhaust restriction performance.

On-Board Diagnostics for emissions-related components require the monitoring of the catalytic converter performance. Currently, the dual Exhaust Gas Oxygen (EGO) sensor method is the only proven method for monitoring the catalyst performance for hydrocarbons (HC). The premise for using the dual oxygen sensor method is that a catalyst with good oxygen storage capacity (OSC) will perform better than a catalyst with lower OSC. A statistical relationship has been developed to correlate HC performance with changes in OSC. The current algorithms are susceptible to false illumination of the Malfunction Indication Light (MIL) due to: 1. The accuracy with which the diagnostic algorithm can predict a catalyst malfunction condition, and 2. The precision with which the algorithm can consistently predict a malfunction. A new algorithm has been developed that provides a significant improvement in correlation between the EGO sensor signals and hydrocarbon emissions.

An overview is given on the state of the art of a new catalytic exhaust gas aftertreatment device for diesel engines. The function of a precious metal based, flow-through type diesel oxidation catalyst is explained. Much attention is paid to the durability of the diesel oxidation catalyst and especially to the influence of poisoning elements on the catalytic activity. Detailed data on the interaction of poisoning elements such as sulfur, zinc and phosphorus with the catalytic active sites are given. Finally it is demonstrated that it is possible to meet the stringent emission standards for diesel passenger cars in Europe with a new catalyst generation over 80.000 km AMA aging.

Three-way catalysts (TWC) to remove the HC, CO, and NOx pollutants from the exhaust of gasoline powered vehicles employ rhodium in combination with platinum and palladium. Of these precious metals, rhodium is by far the most expensive. Since it is so heavily used for its NOx reduction capabilities, the amount per vehicle approaches and sometimes exceeds the naturally occurring mine ratio. A program was conducted to determine the feasibility of a non-rhodium TWC catalyst. It showed that Pt and Pd in conjunction with other washcoat support materials exhibited relatively good TWC characteristics compared to a Pt/Rh catalyst after engine dynamometer aging. In FTP evaluations this new REDOX type catalyst gave comparable HC and CO efficiency and 85% of the NOx efficiency of a Pt/Rh-containing catalyst. Presently the operating window is being defined but comparisons to conventional Pt/Pd and Pt/Rh catalysts have been made under a number of conditions.

Simultaneous reduction of engine pollutants (e.g., CO, THC, NOx, and soot) is one of the main challenges in the development of new combustion systems. Low-temperature combustion (LTC) concepts in compression ignition (CI) engines like premixed charged compression ignition (PCCI) make use of pre-injections to create a partly homogenous mixture. In the PCCI combustion regime, a direct correlation between injection and pollutant formation is no longer present because of long ignition delay times. In LTC combustion systems, the in-cylinder pressure sensor is normally used to help the combustion control. However, to allow the control of PCCI engines, new sensor concepts are investigated to obtain additional information about the PCCI combustion for advanced controller structures. In LTC combustion systems like gasoline-controlled autoignition (GCAI) concepts, the application of ion current sensors enables additional monitoring of the combustion process with real-time capability.

The California LEV1 II program will be introduced in the year 2003 and requires a further reduction of the exhaust emissions of passenger cars. The cold start emissions represent the main part of the total emissions of the FTP2-Cycle. Cold start emissions can be efficiently reduced by injecting secondary air (SA) in the exhaust port making compliance with the most stringent standards possible. The thermochemical conditions (mixing rate and temperature of secondary air and exhaust gas, exhaust gas composition, etc) prevailing in the exhaust system are described in this paper. This provides knowledge of the conditions for auto ignition of the mixture within the exhaust manifold. The thus established exothermal reaction (exhaust gas post-combustion) results in a shorter time to light-off temperature of the catalyst. The mechanisms of this combustion are studied at different engine idle conditions.

The technical issues related to NOx abatement for diesel applications are summarized. Data on improved catalysts and a novel approach which involves temporarily trapping of NOx before reduction are presented. New high temperature lean NOx materials have been identified which have better hydrothermal stability than the state of the art Cu/ZSM-5. One of these materials, Catalyst A, was shown to reduce the NOx emitted from a 2.5 L diesel engine at temperatures ≥ 350°C using injected diesel fuel as a reductant. Catalyst A also showed reasonably good durability after aging for 500 h at ca. 500°C on a 14 L diesel truck engine. Pt/Al2O3, a low temperature lean NOx reduction catalyst (200-300°C), demonstrated fairly good performance after 125 h of aging on a 4 L diesel truck engine, however sulfate make and N2O formation are high on this material. New low temperature NOx traps show promise for transient removal of NOx below 200-400°C.

The plasma assisted catalytic reactor (PACR) approach to lean NOx abatement is a two step process. The non-thermal plasma oxidizes the engine out NO to NO2, which is then reduced to N2 over a catalyst using a hydrocarbon reductant. Whereas it was once believed that the plasma itself directly reduces NOx to N2, it has been shown that the plasma's principle function is to oxidize NO to NO2. This is accomplished without oxidizing SO2 to SO3, resulting in lower sulfate particulate when compared to standard lean NOx catalysis using platinum or reducible oxide catalysts. We have performed reactor studies comparing the relative reducibility of NO2 and NO in a synthetic diesel exhaust using diesel fuel as the hydrocarbon reductant, with attention to time-on stream behavior and determination of NOx reversibly adsorbed on the catalyst. We find that at 200°C, 50% of the NO2 disappearance over Na-ZSM5 is attributable to reversible adsorption on the catalyst.

To achieve the strict legislative restrictions for emissions from combustion engines, vast improvements in engine emissions and efficiency are required. Two major impacting factors for emissions and efficiency are the reliable generation of an effective mixture before ignition and a fast, stable combustion process. While the mixture of air and injected fuel is generated by highly three-dimensional, time-dependent flow phenomena during the intake and compression stroke, the turbulent flame propagation is directly affected by the turbulence level in the flow close to the advancing flame front. However, the flow field in the combustion chamber is highly turbulent and subject to cycle-to-cycle variations (CCV). To understand the fundamental mechanisms and interactions, 3D flow measurements with combined high spatial and temporal resolution are required.

Gasoline particulate filters (GPF) recently entered the market, and are already regarded a state-of-the-art solution for gasoline exhaust aftertreatment systems to enable EU6d-TEMP fulfilment and beyond. Especially for coated GPF applications, the prognosis of the emission conversion performance over lifetime poses an ambitious challenge, which significantly influences future catalyst diagnosis calibrations. The paper presents key-findings for the different GPF application variants. In the first part, experimental GPF ash loading results are presented. Ash accumulates as thin wall layers and short plugs, but does not penetrate into the wall. However, it suppresses deep bed filtration of soot, initially decreasing the soot-loaded backpressure. For the emission calibration, the non-linear backpressure development complicates the soot load monitoring, eventually leading to compromises between high safety against soot overloading and a low number of active regenerations.

For compliance with legislative regulations as well as restricted resources of fossil fuel, it is essential to further reduce engine-out emissions and increase engine efficiency. As a result of lower peak temperatures and increased homogeneity, premixed Low-Temperature Combustion (LTC) has the potential to simultaneously reduce nitrogen oxides (BSNOx) and soot. However, LTC can lead to higher emissions of unburnt total hydrocarbons (BSTHC) and carbon monoxide (BSCO). Furthermore, losses in efficiency are often observed, due to early combustion phasing (CA50) before top dead center (bTDC). Various studies have shown possibilities to counteract these drawbacks, such as split-injection strategies or different nozzle geometries. In this work, the combination of both is investigated. Three different nozzle geometries with included spray angles of 100°, 120°, and 148° and four injection strategies are applied to investigate the engine performance.

The desire for improved fuel economy, and lower emissions of green house gases, such as CO2, is projected to increase the demand for diesel and lean-burn gasoline engines throughout the world. Several commercial diesel oxidation catalysts (DOCs) were developed in the last 3-4 years to reduce hydrocarbon, CO, and particulates emitted from the exhaust of diesel passenger cars and trucks. To meet future U.S. and European NOx standards, it is essential to develop catalyst technology that will allow NOx reduction in addition to the other three pollutants. Two materials that attracted great attention as lean NOx catalysts are the Cu/ZSM-5 and Pt based. Cu containing ZSM-5 are active for lean-NOx reduction at temperatures above 350°C, provided sufficient hydrocarbons are present as reductants.

Several different possibilities will be described and discussed on the processes of reducing NOx in lean-burn gasoline and diesel engines. In-company studies were conducted on zeolitic catalysts. With lean-burn spark-ignition engines, hydrocarbons in the exhaust gas act as a reducing agent. In stationary conditions at λ = 1.2, NOx conversion rates of approx. 45 % were achieved. With diesel engines, the only promising variant is SCR technology using urea as a reducing agent. The remaining problems are still the low space velocity and the narrow temperature window of the catalyst. The production of reaction products and secondary reactions of urea with other components in the diesel exhaust gas are still unclarified.

Close coupled catalysts represent a solution being pursued by automotive engineers to meet stringent LEV and ULEV emission standards. Close coupled systems provide fast light-off by utilizing the energy in the exhaust gas rather than energy supplied by an auxiliary source such as an electrically heated catalyst or a burner in the exhaust. Previous close coupled catalyst designs were limited by the temperature capability of the catalyst coatings. A successful close coupled catalyst technology has been developed 'that is resistant to higher temperature deactivation. This technology is able to function well at low temperature during the vehicle cold start when light-off is critical. The close coupled catalyst technology has approached ULEV emission levels after aging at 1050°C for 24 hours. This study will present experimental results for a close coupled catalyst including the selection of catalyst volume, cross sectional area and combination of catalyst technologies.

A new method for the analysis of the gas flow in an internal combustion engine has been developed. It is based on the interactive coupling between commercially available three (STAR-CD) and one dimensional (PROMO) fluid dynamics codes. With this method the detailed transient flow distribution for any engine component of interest can be calculated taking into account the overall gas dynamic interaction with other engine components. The underlying physics and numerics are outlined. A description of the coupling procedure ensuring proper communication between the two computer codes is given. Also addressed is the averaging procedure adopted at the 3D boundaries, including the influence of the 1D/3D interface placement. A first application of this new method is presented, in which the gas flow in a turbo-charged DI-diesel-engine is simulated.

The revisions in the United States Clean Air Act of 1990 and recent regulatory actions taken by the California Air Resources Board and European Economic Community require the development of automobiles with much lower tailpipe emissions. A significant portion of the total pollutants emitted to the atmosphere by motor vehicles occurs immediately following the startup of the engine when the engine block and exhaust manifold are cold, and the catalytic converter has not yet reached high conversion efficiencies. An effective, energy efficient strategy for dealing with cold start hydrocarbon using carbon-free hydrocarbon traps and heat exchange related TWC catalyst beds has been successfully tested on a wide variety of current model vehicles. In each case U.S. FTP 75 total hydrocarbon emissions were reduced between 45 - 75% versus the vehicle's stock exhaust system.

Deposits on engine parts, and in particular in combustion chambers of modern engines are causing increasing concern in the automobile industry. Highly sophisticated engine management systems make effects on emissions or performance obvious as outgassing of unburned hydrocarbons or variation of spark advance. Reduced mean heat flux away from the cylinder influences engine thermodynamics. Extreme deposits may cause noise increase by carbon rap. A special form of combustion chamber deposits, well known under the synonym spark plug fouling, is a carbon needle on spark plugs, which can cause the total damage of the catalysts (Japanese Industrial Standard D 1606: Adaptability Test Code of Spark Plug for Automobiles) The Co-ordinating European Council for the development of performance tests for transportation fuels, lubricants, and other fluids (CEC) started the development of a new performance test in 1994.