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Individual hydrocarbon conversion efficiencies of engine-out emissions have been measured for four different catalyst formulations (Pd-only, trimetallic, Pd/Rh, and Pt/Rh) during stoichiometric and rich operation. The measurements were carried out as a function of fuel-air equivalence ratio (Φ) using a dynamometer-controlled 1993 Ford V8 engine and capillary gas chromatography. HC conversion efficiency was examined in terms of mass conversion efficiency and also using three new definitions of catalyst conversion efficiency. The efficiencies across the four catalysts show similar trends with Φ for almost all HC species. The catalyst efficiencies for alkanes, alkenes, and aromatic species decrease as Φ increases above stoichiometric: alkane efficiencies decrease faster than alkenes which in turn decrease faster than aromatics. All efficiencies fall to zero near Φ = 1.08 except those of MTBE and acetylene, which remain near 100%.

A fundamental decision to be made in developing a motor vehicle Inspection and Maintenance (I&M) program is whether a “centralized” or “private garage” program will be used. Under the centralized approach, the state or a state contractor operates a network of single purpose “Inspection Centers” to inspect motor vehicles before the completion of the annual registration renewal process. After any repairs necessary to correct vehicles with excessive emissions are made at a facility of the owner's choosing, the vehicle must pass a reinspection at the Inspection Center. Under the private garage (decentralized) approach, both inspections and repairs are conducted by private repair facilities licensed by the state. A comparison of a centralized I&M program and a private garage I&M program currently operating in California indicates that the centralized program is providing over ten times greater emissions reductions.

In a gasoline engine, the unswept in-cylinder residual gas and introduction of external EGR is one of the important means of controlling engine raw NOx emissions and improving part load fuel economy via reduction of pumping losses. Since the trapped in-cylinder Residual Gas Fraction (RGF, comprised of both internal, and external) significantly affects the combustion process, on-line diagnosis and monitoring of in-cylinder RGF is very important to the understanding of the in-cylinder dilution condition. This is critical during the combustion system development testing and calibration processes. However, on-line measurement of in-cylinder RGF is difficult and requires an expensive exhaust gas analyzer, making it impractical for every application. Other existing methods, based on measured intake and exhaust pressures (steady state or dynamic traces) to calculate gas mass flowrate across the cylinder ports, provide a fast and economical solution to this problem.

California is considering adopting an enhanced Inspection and Maintenance (I&M) program (commonly referred to as Smog Check II) beginning with the 1996 calendar year. This program will utilize a targeting scheme to identify vehicles likely to be high emitters and send these vehicles to centralized testing facilities. The remaining fleet of vehicles will be sent to decentralized testing facilities. At these facilities, vehicles will be subjected to steady state loaded mode dynamometer based tests. Simultaneously, all 1996 and later model year passenger cars, light- and medium-duty trucks sold in California will be equipped with an On-Board Diagnostic (OBDII) system. This system is designed to monitor critical emission related components and activate a Malfunction Indicator Light (MIL) when a failure or a drift in calibration is likely to cause emissions to exceed 1.5 times the vehicle certification standards.

In recognizing the potential for large, damaging impacts from climate change, California enacted Executive Order S-03-05, requiring a reduction in statewide greenhouse gas (GHG) emissions to 80% below 1990 levels by 2050. Given that the transportation light-duty vehicle (LDV) segment accounts for 28% of the state's GHG emissions today, it will be difficult to meet the 2050 goal unless a portfolio of near-zero carbon transportation solutions is pursued. Because it takes decades for a new propulsion system to capture a large fraction of the passenger vehicle market due to vehicle fleet turn-over rates, it is important to accelerate the introduction of these alternatives to ensure markets enter into early commercial volumes (10,000s) between 2015 and 2020. This report summarizes the results and conclusions of a modeling exercise that simulated GHG emissions from the LDV sector to 2050 in California.

A novel ambient dilution tunnel has been designed, tested and employed to measure the emissions from active parked regenerations of Diesel Particulate Filters (DPFs) for 2007 and 2010 certified heavy duty diesel trucks (HDDTs). The 2007 certified engine had greater regulated emissions than the 2010 certified engine. For a fully loaded 2007 DPF there was an initial period of very large mass emissions, which was then followed by very large number of small particle emissions. The Particle Size Distribution, PSD, was distributed over a large range from 10 nm to 10 μm. The parked regenerations of the 2010 DPF had a much lower initial emission pattern, but the second phase of large numbers of small particles was very similar to the 2007 DPF. The emission results during regeneration have been compared to total emissions from recent engine dynamometer testing of 2007 and 2010 DPFs, and they are much larger.

This paper reports on DaimlerChrysler's participation in the Ad Hoc Diesel Fuels Test Program. This program was initiated by the U.S. Department of Energy and included major U.S. auto makers, major U.S. oil companies, and the Department of Energy. The purpose of this program was to identify diesel fuels and fuel properties that could facilitate the successful use of compression ignition engines in passenger cars and light-duty trucks in the United States at Tier 2 and LEV II tailpipe emissions standards. This portion of the program focused on minimizing engine-out particulates and NOx by using selected fuels, (not a matrix of fuel properties,) in steady state dynamometer tests on a modern, direct injection, common rail diesel engine.

Electrically assisted turbochargers are a promising technology for improving boost response of turbocharged engines. These systems include a turbocharger shaft mounted electric motor/generator. In the assist mode, electrical energy is applied to the turbocharger shaft via the motor function, while in the regenerative mode energy can be extracted from the shaft via the generator function, hence these systems are also referred to as regenerative electrically assisted turbochargers (REAT). REAT allows simultaneous improvement of boost response and fuel economy of boosted engines. This is achieved by optimally scheduling the electrical assist and regeneration actions. REAT also allows the exhaust turbine to operate within a narrow range of optimal vane positions relative to the unassisted variable geometry turbocharger (VGT). The ability to operate within a narrow range of VGT vane positions allows an opportunity for a more optimal turbine design for a REAT system.

Charge motion is known to accelerate and stabilize combustion through its influence on turbulence intensity and flame propagation. The present work investigates the effect of charge motion generated by intake runner blockages on combustion characteristics and emissions under part-load conditions in SI engines. Firing experiments have been conducted on a DaimlerChrysler (DC) 2.4L 4-valve I4 engine, with spark range extending around the Maximum Brake Torque (MBT) timing. Three blockages with 20% open area are compared to the fully open baseline case under two operating conditions: 2.41 bar brake mean effective pressure (bmep) at 1600 rpm, and 0.78 bar bmep at 1200 rpm. The blocked areas are shaped to create different levels of swirl, tumble, and cross-tumble. Crank-angle resolved pressures have been acquired, including cylinders 1 and 4, intake runners 1 and 4 upstream and downstream of the blockage, and exhaust runners 1 and 4.

Diesel vehicles have significant advantages over their gasoline counterparts including a more efficient engine, higher fuel economy, and lower emissions of HC, CO, and CO2. However, NOx control is more difficult on a diesel because of the high O2 concentration in the exhaust, making conventional three-way catalysts ineffective. The most promising technology for continuous NOx reduction onboard diesel vehicles is Selective Catalytic Reduction (SCR) using aqueous urea. Recent work with urea SCR has involved aftertreatment for the 1.2L DIATA common-rail diesel engine. This engine was used in Ford's hybrid-electric vehicle, the Prodigy, which was developed under the PNGV (Partnership for a New Generation of Vehicles) program. An emission control system consisting of a diesel particulate filter followed by an underbody SCR system was used successfully to meet ULEV emission standards (0.2 g/mi NOx, 0.04 g/mi particulate matter (PM)).

In order to assess the amount of airborne particulate matter (PM) attributable to vehicle disk brakes, a system was devised for collecting brake wear debris on a laboratory brake dynamometer. The brake dynamometer test hardware was enclosed and vented through a duct in which the airflow was controlled to ensure isokinetic sampling. Two brake dynamometer simulations were implemented: urban driving (low velocity, low g) and the Auto Motor und Sport (AMS, high velocity, high g). These test procedures were performed repeatedly on the brake system hardware of vehicles utilizing three different friction material types: low-metallic, semi-metallic, and non-asbestos organic (NAO). Airborne brake wear was collected on filters and via other airborne PM sampling techniques. Larger, non-airborne wear debris was collected from the wheel, below the brake, and brushed off the hardware. Considering the effect of the wheel, 50-70% of the collected wear debris was airborne PM.

Emissions of particulate matter, or PM, due to brake wear, are not well quantified in current air pollutant emission inventories. Current emission factor models need to be updated to reflect new technologies and materials and to incorporate the effects of changing driving habits and speeds. While emission regulations drive technical innovations that are significantly reducing PM emissions in vehicle exhaust, non-exhaust automotive emissions remain unregulated. Current emission factor models need to be updated to reflect the changes caused by new technologies, materials, and speed-dependent vehicle usage. Most research regarding brake emissions relies on a laboratory setting. Laboratory testing has allowed researchers, application engineers, data modeling engineers, and environmental agencies to generate large datasets for multiple vehicle configurations and friction couple designs.

In 1997 and 1998, the California Air Resources Board (CARB) conducted an extensive evaporative emissions test program to assess the feasibility of reducing evaporative emissions standards from the current 2 gram per test total hydrocarbon (THC) standard. Seven vehicles were tested and five modified in order to determine what emissions levels would be feasible. Emissions reductions of approximately 40% resulted from these modifications. The ARB also conducted studies of non-fuel background emissions and of emissions test variability.

Emissions from heavy-duty vehicles are a major contributor to California's air quality problems. Emissions from these vehicles account for approximately 30% of the nitrogen oxide and 75% of the particulate matter emissions from the entire on-road vehicle fleet. Additionally, excessive exhaust smoke from in-use heavy-duty diesel vehicles is a target of numerous public complaints. In response to these concerns, California has adopted an in-use Heavy-Duty Vehicle Smoke and Tampering Inspection Program (HDVIP) designed to significantly reduce emissions from these vehicles. Pending promulgation of HDVIP regulations, vehicles falling prescribed test procedures and emission standards will be issued citations. These citations mandate expedient repair of the vehicle and carry civil penalties ranging from $300 to $1800. Failure to clear citations can result in the vehicle being removed from service.

Heavy-duty vehicles account for approximately 30 percent of the oxides of nitrogen (NOx) and 65 percent of the particulate matter (PM) emissions from the entire California on-road fleet, despite the fact that these vehicles comprise only 2 percent of the same. To meet legislative mandates to reduce excess smoke emissions from in-use heavy-duty diesel-powered vehicles, the Air Resources Board (ARB or Board) adopted, in December 1997, amendments to the regulations governing the operation and enforcement of the Heavy-Duty Vehicle Inspection Program (HDVIP or the “roadside” program) and the Periodic Smoke Inspection Program (PSIP or the “fleet” program). The initial roadside program was adopted in November 1990 in response to Senate Bill (SB) 1997 (stat. 1988, ch. 1544, Presley), and enforced from 1991 to 1993. It was suspended in October 1993, when the Board redirected staff to investigate reformulated fuels issues.

Cam-phasing is increasingly considered as a feasible Variable Valve Timing (VVT) technology for production engines. Additional independent control variables in a dual-independent VVT engine increase the complexity of the system, and achieving its full benefit depends critically on devising an optimum control strategy. A traditional approach relying on hardware experiments to generate set-point maps for all independent control variables leads to an exponential increase in the number of required tests and prohibitive cost. Instead, this work formulates the task of defining actuator set-points as an optimization problem. In our previous study, an optimization framework was developed and demonstrated with the objective of maximizing torque at full load. This study extends the technique and uses the optimization framework to minimize fuel consumption of a VVT engine at part load.

The direct injection gasoline spray-wall interaction was characterized inside a heated pressurized chamber using various visualization techniques, including high-speed laser-sheet macroscopic and microscopic movies up to 25,000 frames per second, shadowgraph, and doublespark particle image velocimetry. Two hollow cone high-pressure swirl injectors having different cone angles were used to inject gasoline onto a heated plate at two different impingement angles. Based on the visualization results, the overall transient spray impingement structure, fuel film formation, and preliminary droplet size and velocity were analyzed. The results show that upward spray vortex inside the spray is more obvious at elevated temperature condition, particularly for the wide-cone-angle injector, due to the vaporization of small droplets and decreased air density. Film build-up on the surface is clearly observed at both ambient and elevated temperature, especially for narrow cone spray.

There is a distinct difference between plug-in hybrid electric vehicles in the market today. One key distinction that can be made is to classify a plug-in hybrid electric vehicle (PHEV) according to its operational behavior in charge depleting (CD) mode. Some PHEVs are capable of using the electric-only propulsion system to achieve all-electric operation for all driving conditions in CD mode, including full power performance. In contrast, some PHEVs, henceforth termed “blended PHEVs”, cannot satisfy the power requirements of all driving conditions with the electric-only propulsion system and occasionally utilize blended CD operation whereby it is necessary to blend the use of the internal combustion (IC) engine with the use of the electric motor(s) to help power the vehicle.

Two additive blends proposed for improving the flame luminosity in neat methanol fuel were investigated to determine the effect of these additives on the exhaust emissions in a dual-fueled Volkswagen Jetta. The two blends contained 4 percent toluene plus 2 percent indan in methanol and 5 percent cyclopentene plus 5 percent indan in methanol. Each blend was tested for regulated and unregulated emissions as well as a speciation of the exhaust hydrocarbons resulting from use of each fuel. The vehicle exhaust emissions from these two fuel blends were compared to the Coordinating Research Council Auto-Oil national average gasoline (RF-A), M100, and M85 blended from RF-A. Carter Maximum Incremental Reactivity Factors were applied to the speciated hydrocarbon emission results to determine the potential ozone formation for each fuel. Toxic emissions as defined in the 1990 Clean Air Act were also compared for each fuel.

Projected NOx and fuel costs are compared for a plasma-catalyst system and an active lean NOx catalyst system. Comparisons are based on modeling of FTP cycle performance. The model uses steady state laboratory device characteristics, combined with measured vehicle exhaust data to predict NOx conversion efficiency and fuel economy penalties. The plasma system uses a proprietary catalyst downstream of a plasma discharge. The active lean NOx catalyst uses a catalyst along with addition of hydrocarbons to the exhaust. For the plasma catalyst system, NOx conversion is available over a wide temperature range. Increased electrical power improves conversion but degrades vehicle fuel economy; 10 J/L energy deposition costs roughly 3% fuel economy. Improved efficiency is also available with larger catalyst size or increased exhaust hydrocarbon content. For the active lean NOx system, NOx conversion is available only in a narrow temperature range.