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The emission and flow restriction characteristics of three different ceramic substrates with varying wall thickness and cell density (400 cpsi/6.5 mil, 600/4.3, and 600/3.5) are compared. These 106mm diameter substrates were catalyzed with similar amounts of washcoat and fabricated into catalytic converters having a total volume of 2.0 liters. A Pd/Rh catalyst technology was applied at a concentration of 6.65 g/l and a ratio of 20/1. Three sets of converters (two of each type) were aged for 100 hours on an engine dynamometer stand. After aging, the FTP performance of these converters were evaluated on an auto-driver FTP stand using a 2.4L, four-cylinder prototype engine and on a 2.4L, four-cylinder prototype vehicle. A third set of unaged converters was used for cold flow restriction measurements and vehicle acceleration tests.

Numerical models of aftertreatment devices are increasingly becoming indispensable tools in the development of aftertreatment systems that enable modern diesel engines to comply with exhaust emissions regulations while minimizing the cost and development time involved. Such a numerical model was developed at Michigan Technological University (MTU) [1] and demonstrated to be able to simulate the experimental data [2] in predicting the characteristic pressure drop and PM mass retained during passive oxidation [3] and active regeneration [4] of a catalyzed diesel particulate filter (CPF) on a Cummins ISL engine. One of the critical aspects of a calibrated numerical model is its usability - in other words, how useful is the model in predicting the pressure drop and the PM mass retained in another particulate filter on a different engine without the need for extensive recalibration.

One-dimensional transient modeling techniques are adapted to analyze the thermal behavior of lean-burn after-treatment systems when active flow control schemes are applied. The active control schemes include parallel alternating flow, partial restricting flow, and periodic flow reversal (FR) that are found to be especially effective to treat engine exhausts that are difficult to cope with conventional passive flow converters. To diesel particulate filters (DPF), lean NOx traps (LNT), and oxidation converters (OC), the combined use of active flow control schemes are identified to be capable of shifting the exhaust gas temperature, flow rate, and oxygen concentration to more favorable windows for the filtration, conversion, and regeneration processes. Comparison analyses are made between active flow control and passive flow control schemes in investigating the influences of gas flow, heat transfer, chemical reaction, oxygen concentration, and converter properties.

Diesel fueling and exhaust flow strategies are investigated to control the substrate temperatures of diesel aftertreatment systems. The fueling control includes the common-rail post injection and the external supplemental fuel injection. The post injection pulses are further specified at the early, mid, or late stages of the engine expansion stroke. In comparison, the external fueling rates are moderated under various engine loads to evaluate the thermal impact. Additionally, the active-flow control schemes are implemented to improve the overall energy efficiency of the system. In parallel with the empirical work, the dynamic temperature characteristics of the exhaust system are simulated one-dimensionally with in-house and external codes. The dynamic thermal control, measurement, and modeling of this research intend to improve the performance of diesel particulate filters and diesel NOx absorbers.

This study describes a zero-dimensional algorithm for tracking the intake dilution in real-time. The inputs to the model are the oxygen concentration from the exhaust oxygen sensor, the manifold air pressure and temperature (MAP/MAT), the mass air flow (MAF) and the estimated fuel injected per cycle from the engine control module. The intake manifold, the exhaust manifold and EGR system are discretized into 3 volumes and the detailed concentrations of the gas species comprising the exhaust, EGR and intake streams are tracked at each time step (on a cycle-by-cycle basis). The model does not need the EGR ratio to be known in advance and is also applicable to oxygenated fuels such as ethanol. The model response is tuned to a multi-cylinder engine and the model output is empirically validated against a wide range of engine operations including load and EGR transients.

In an effort of providing better understanding of regeneration mechanisms of diesel particulate matter (PM), this experimental investigation focused on evaluating the amount of heat release generated during the thermal reaction of diesel PM and the concentrations of soluble organic compounds (SOCs) dissolved in PM emissions. Differences in oxidation behaviors were observed for two different diesel PM samples: a SOC-containing PM sample and a dry soot sample with no SOCs. Both samples were collected from a cordierite particulate filter membrane in a thermal reactor connected to the exhaust pipe of a light-duty diesel engine. A differential scanning calorimeter (DSC) and a thermogravimetric analyzer (TGA) were used to measure the amount of heat release during oxidation, along with subsequent oxidation rates and the concentrations of SOCs dissolved in particulate samples, respectively.

Close coupled catalysts and new ceramic catalyst substrates have significantly improved the light-off performance of automotive converters required to meet stringent emission requirements. The hotter environment of these catalytic converters and the lower structural strength of the ceramic substrates require the rethinking of converter designs. The development of new package requirements to accommodate the change in environment and new substrates are discussed. A historical perspective on converter durability is presented as reference. Development of durability test protocols is essential to verifying product durability performance to these new environments. Data collection and documentation of testing templates are shown to demonstrate the effectiveness of tests that represent real world environments. Design improvements to address failure modes are discussed along with durability improvement results.

With the increasing demand of emission reductions from the automotive industry, advanced after-treatment strategies have been investigated to overcome the challenges associated with meeting increasingly stringent emission regulations. Ongoing investigations on low temperature combustion (LTC) strategies are being researched to meet future emission regulations, however, the lowered exhaust temperature presents an even greater issue for exhaust after-treatment due to the change in combustion modes. Catalyst temperature is critical for the catalytic ability to maintain effective conversion efficiency of regulated emissions. The use of periodic flow reversal has shown benefits of maintaining catalyst temperature by alternating the exhaust flow direction through the catalytic converter, reducing the catalyst sensitivity to inlet gas temperature fluctuations.

The ever-stringent emission regulations are major challenges for the diesel fueled engines in automotive industry. The applications of advanced after-treatment technologies as well as alternative fuels [1] are considered as promising methodology to reduce exhaust emission from compression ignition (CI) engines. Using dimethyl ether (DME) as an alternative fuel has been extensively studied by many researchers and automotive manufactures since DME has demonstrated enormous potential in terms of emission reduction, such as low CO emission, and soot and sulfur free. However, the effect of employing DME in a lean NOX trap (LNT) based after-treatment system has not been fully addressed yet. In this work, investigations of the long breathing LNT system using DME as a reductant were performed on a heated after-treatment flow bench with simulated engine exhaust condition.

Reduction of nitrogen oxides (NOx) in lean burn and diesel fueled Compression Ignition (CI) engines is one of the major challenges faced by automotive manufacturers. Lean NOx Trap (LNT) and urea-based Selective Catalytic Reduction (SCR) exhaust after-treatment systems are well established technologies to reduce NOx emissions. However, each of these technologies has associated advantages and disadvantages for use over a wide range of engine operating conditions. In order to meet future ultra-low NOx emission norms, the use of both alternative fuels and advanced after-treatment technology may be required. The use of an alcohol fuel such as n-butanol or ethanol in a CI engine can reduce the engine-out NOx and soot emissions. In CI engines using LNTs for NOx reduction, the fuel such as diesel is utilized as a reductant for LNT regeneration.

The current paper describes a methodology for combustion bowl assessment for diesel engines. The methodology is based on the application of Computational Fluid Dynamics (CFD) following a Design of Experiments (DoE) procedure. In this work the 3D CFD simulation was performed by the commercial CFD code AVL-FIRE for different combustion bowls from intake valve closing (IVC) to exhaust valve opening (EVO). The initial conditions (at IVC) and boundary conditions were obtained from 1D simulation. Since the work was concentrated on the spray injection, mixing, combustion as well as bowl aerodynamics only a sector mesh was employed for the calculations. A DoE procedure was also used for this simulation work in order to minimize the number of simulation runs and at the same time maintaining the accuracy required assessing the influences of different bowl geometry, spray and intake air motion parameters.

Diesel Particulate Filters (DPF) are viable to reduce smoke from diesel engines. An oxidation process is usually required to remove the Particulate Matter (PM) loading from the DPF substrates. In cases when the engine exhaust temperature is insufficient to initiate a thermal regeneration, supplemental energy is commonly applied to raise the exhaust gas and/or the DPF substrate temperatures. A flow reversal (FR) mechanism that traps a high temperature region in the DPF substrate by periodically altering the gas flow directions has been identified to be capable of reducing the supplemental energy and thus to improve the overall thermal efficiency of the engine. However, extended operations with low exhaust temperature lowers the DPF boundary temperatures that defers the regeneration processes. Furthermore, the temperature fluctuations caused by the periodic FR operation also increase the thermal stress in the DPF.

Emissions from CI engines fueled with dimethyl ether (DME) were discussed in this paper. Thanks to its high content of fuel oxygen, DME combustion is virtually soot free. This characteristic of DME combustion indicates that the particulate filter will not be needed in the aftertreatment system for engines fueled with DME. NOx emissions from a CI engine fueled with DME can meet the US 2007 regulation with a high EGR rate. Because 49% more fuel mass must be delivered in each DME injection than the corresponding diesel-fuel injection, and the DME injection pressure is lower than 500 bar under the current fuel-system technology, the DME injection duration is generally longer than that of diesel-fuel injection. This is unfavorable to further NOx reduction. A multiple-injection strategy with timing for the primary injection determined by the cylinder temperature was proposed.

At the current stage of engine technology, diesel engines typically require diesel particulate filter (DPF) systems to meet recent particulate emissions standards. To assure the performance and reliability of DPF systems, profound understanding of filtration and regeneration mechanisms is required. Among extensive efforts for developing advanced DPF systems, the development of effective thermal management strategies, which control the thermal runaway taking place in oxidation of an excess amount of soot deposit in DPF, is quite challenging. This difficulty stems mainly from lack of sufficient knowledge and understanding about DPF regeneration mechanisms, which need detailed information about oxidation of diesel particulate matter (PM). Therefore, this work carried out a series of oxidation experiments of diesel particulates collected from a DPF on a diesel engine, and evaluated the oxidation rates of the samples using a thermo-gravimetric analyzer (TGA).

Gas-to-Liquids (GTL) is a liquid diesel fuel produced from natural gas, which may have certain attributes different from conventional ultra low sulfur diesel (ULSD). In this investigation, GTL, ULSD, and their blends of 20% and 50% GTL in ULSD were tested in an older Mercedes C Class (MY1999, Euro 2) and a newer Opel Astra (MY2006, Euro 4) diesel vehicle to evaluate the performance in terms of fuel consumption and emissions. Each vehicle was pre-conditioned on-road with one tank full of test fuel before actual testing in a chassis dynamometer facility. Both vehicles were calibrated for European emission standards and operation, and they were not re-calibrated for the fuel tests at Argonne National Laboratory (ANL). In the two-vehicle EPA FTP-75, US06, and Highway drive-cycle tests, the emissions of carbon dioxide on a per-mile basis (g/mi) from all GTL-containing fuels were significantly lower than those from the ULSD.

Dual-fuel combustion using port-injection of low reactivity fuel combined with direct injection of a higher reactivity fuel, otherwise known as Reactivity Controlled Compression Ignition (RCCI), has been shown as a method to achieve high efficiency combustion with moderate peak pressure rise rates, low engine-out soot and NOx emissions. A key requirement for extending to high-load operation is reduce the reactivity of the premixed charge prior to the diesel injection. One way to accomplish this is to use a very low reactivity fuel such as natural gas. In this work, experimental testing was conducted on a 13L multi-cylinder heavy-duty diesel engine modified to operate using RCCI combustion with port injection of natural gas and direct injection of diesel fuel. Natural gas/diesel RCCI engine operation is compared over the EPA Heavy-Duty 13 mode supplemental emissions test with and without EGR.

Similar to single-brick SCR architectures, the multi-brick SCR systems described in this paper require urea injection control software that meets the NOx conversion performance target while maintaining the tailpipe NH3 slip below a given threshold, under all driving conditions. The SCR architectures containing a close-coupled SCRoF and underfloor SCR are temperature-wise more favorable than the under-floor location and lead to significant improvement of the global NOx conversion, compared to a single-brick system. But in order to maximize the benefit of close-coupling, the urea injection control must maximize the NH3 stored in the SCRoF. The under-floor SCR catalyst can be used as an NH3 slip buffer, lowering the risk of NH3 slip at the tailpipe with some benefit on the global NOx conversion of the system. With this approach, the urea injection strategy has a limited control on the NH3 coverage of the under-floor SCR catalyst.

Detailed soot deposition and oxidation characteristics in a diesel particulate filter (DPF) have been experimentally examined on a unique bench-scale DPF test system that has a visualization window. The filtration and regeneration processes were visualized to examine soot deposition and oxidation behaviors on the filter channel surfaces, along with measurements of pressure drop across the filter. The pressure drop caused by trapped soot was separated from the measured total pressure drop by subtracting the pressure drop caused by the clean filter itself. Then, the soot-derived pressure-drop data, normalized (non-dimensionalized) by the volumetric flow rate, exhaust gas viscosity, and DPF volume, were used to compare filtration and regeneration characteristics at different experimental conditions, independently of flow conditions.

A three-dimensional (3-D) computational fluid dynamics (CFD) code has been developed to predict flow dynamics and pressure drop characteristics in geometry-modified filters in which the normalized distance of the outlet channel plugs from the inlet has been varied at 0.25, 0.50, and 0.75. In clean filter simulations, the pressure drop in geometry-modified filters showed higher values than for conventional filters because of the significant change in the pressure field formed inside the channel that determines the amount of flow entering the modified channel. This flow through the modified channel depends on plug position initially but has a maximum limit when pressure difference and geometrical change are compromised. For soot loading simulations, a Lagrangian multiphase flow model was used to interpret the hydrodynamics of particle-laden flow with realistic inputs.

The objective of this paper is to present the results of diesel exhaust aftertreatment testing and analysis done under the FreedomCAR program. Nitrogen Oxides (NOx) adsorber technology was selected based on a previous investigation of various NOx aftertreatment technologies including non-thermal plasma, NOx adsorber and active lean NOx. Particulate Matter (PM) emissions were addressed by developing a catalyzed particulate filter. After various iterations of the catalyst formulation, the aftertreatment components were integrated and optimized for a light duty vehicle application. This compact exhaust aftertreatment system is dual leg and consists of a sulfur trap, NOx adsorbers, and catalyzed particulate filters (CPF). During regeneration, supplementary ARCO ECD low-sulfur diesel fuel is injected upstream of the adsorber and CPF in the exhaust. Steady state and transient emission test results with and without the exhaust aftertreatment system (EAS) are presented.