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Technical Paper

50,000 Mile Vehicle Road Test of Three-Way and NOx Reduction Catalyst Systems

1978-02-01
780608
The performance of three way and NOx catalysts was evaluated on vehicles utilizing non-feedback fuel control and electronic feedback fuel control. The vehicles accumulated 80,450 km (50,000 miles) using fuels representing the extremes in hydrogen-carbon ratio available for commercial use. Feedback carburetion compared to non-feedback carburetion improved highway fuel economy by about 0.4 km/l (1 mpg) and reduced deterioration of NOx with mileage accumulation. NOx emissions were higher with the low H/C fuel in the three way catalyst system; feedback reduced the fuel effect on NOx in these cars by improving conversion efficiency with the low H/C fuel. Feedback had no measureable effect on HC and CO catalyst efficiency. Hydrocarbon emissions were lower with the low H/C fuel in all cars. Unleaded gasoline octane improver, MMT, at 0.015g Mn/l (0.06 g/gal) increased tailpipe hydrocarbon emissions by 0.05 g/km (0.08 g/mile).
Technical Paper

A Catalytic NOX After-Treatment System for Heavy-Duty Trucks Using Diesel Fuel as Reducing Agent

1999-10-25
1999-01-3563
An advanced catalytic exhaust after-treatment system addresses the problem of NOX emissions from heavy-duty diesel trucks, relying on real-time catalyst modelling. The system consists of de-NOX catalysts, a device for injection of a reducing agent (diesel fuel) upstream the catalysts, and computer programmes to control the injection of the reducing agent and to model the engine and catalysts in real time. Experiments with 5 different air-assisted injectors were performed to determine the effect of injector design on the distribution of the injected diesel in the exhaust gas stream. A two-injector set-up was investigated to determine whether system efficiency could be increased without increasing the amount of catalyst or the amount of reducing agent necessary for the desired outcome. The results were verified by performing European standard transient cycle tests as well as stationary tests.
Journal Article

A Comparison of Combustion and Emissions of Diesel Fuels and Oxygenated Fuels in a Modern DI Diesel Engine

2012-09-10
2012-01-1695
Two oxygenated fuels were evaluated on a single-cylinder diesel engine and compared to three hydrocarbon diesel fuels. The oxygenated fuels included canola biodiesel (canola methyl esters, CME) and CME blended with dibutyl succinate (DBS), both of which are or have the potential to be bio-derived. DBS was added to improve the cold flow properties, but also reduced the cetane number and net heating value of the resulting blend. A 60-40 blend of the two (60% vol CME and 40% vol DBS) provided desirable cold flow benefits while staying above the U.S. minimum cetane number requirement. Contrary to prior vehicle test results and numerous literature reports, single-cylinder engine testing of both CME and the 60-40 blend showed no statistically discernable change in NOx emissions relative to diesel fuel, but only when constant intake oxygen was maintained.
Technical Paper

A Diesel Lean Nox Trap Model for Control Strategy Verification

2004-03-08
2004-01-0526
Lean NOx traps are considered as a possible means to reduce diesel powertrain tail pipe NOx emissions to future stringent limits. Several publications have proposed models for lean NOx traps [1, 2, 3 and 4]. This paper focuses on a lean NOx trap model that can be used for the verification of control strategies before these strategies are implemented in target microprocessors. Strategy verification in a simulation environment is a crucial tool for reducing control strategy development and implementation time.
Technical Paper

A Four Stroke Camless Engine, Operated in Homogeneous Charge Compression Ignition Mode with Commercial Gasoline

2001-09-24
2001-01-3610
A single cylinder, naturally aspirated, four-stroke and camless (Otto) engine was operated in homogeneous charge compression ignition (HCCI) mode with commercial gasoline. The valve timing could be adjusted during engine operation, which made it possible to optimize the HCCI engine operation for different speed and load points in the part-load regime of a 5-cylinder 2.4 liter engine. Several tests were made with differing combinations of speed and load conditions, while varying the valve timing and the inlet manifold air pressure. Starting with conventional SI combustion, the negative valve overlap was increased until HCCI combustion was obtained. Then the influences of the equivalence ratio and the exhaust valve opening were investigated. With the engine operating on HCCI combustion, unthrottled and without preheating, the exhaust valve opening, the exhaust valve closing and the intake valve closing were optimized next.
Technical Paper

A LNT+SCR System for Treating the NOx Emissions from a Diesel Engine

2006-04-03
2006-01-0210
An aftertreatment system involving a LNT followed by a SCR catalyst is proposed for treating the NOx emissions from a diesel engine. NH3 (or urea) is injected between the LNT and the SCR. The SCR is used exclusively below 400°C due to its high NOx activity at low temperatures and due to its ability to store and release NH3 below 400°C, which helps to minimize NH3 and NOx slip. Above 400°C, where the NH3 storage capacity of the SCR falls to low levels, the LNT is used to store the NOx. A potassium-based LNT is utilized due to its high temperature NOx storage capability. Periodically, hydrocarbons are oxidized on the LNT under net lean conditions to promote the thermal release of the NOx. NH3 is injected simultaneously to reduce the released NOx over the SCR. The majority of the hydrocarbons are oxidized on the front portion of the LNT, resulting in the rapid release of stored NOx from that portion of the LNT.
Journal Article

A New Catalyzed HC Trap Technology that Enhances the Conversion of Gasoline Fuel Cold-Start Emissions

2018-04-03
2018-01-0938
Passive in-line catalyzed hydrocarbon (HC) traps have been used by some manufacturers in the automotive industry to reduce regulated tailpipe (TP) emissions of non-methane organic gas (NMOG) during engine cold-start conditions. However, most NMOG molecules produced during gasoline combustion are only weakly adsorbed via physisorption onto the zeolites typically used in a HC trap. As a consequence, NMOG desorption occurs at low temperatures resulting in the use of very high platinum group metal (PGM) loadings in an effort to combust NMOG before it escapes from a HC trap. In the current study, a 2.0 L direct-injection (DI) Ford Focus running on gasoline fuel was evaluated with full useful life aftertreatment where the underbody converter was either a three-way catalyst (TWC) or a HC trap. A new HC trap technology developed by Ford and Umicore demonstrated reduced TP NMOG emissions of 50% over the TWC-only system without any increase in oxides of oxygen (NOx) emissions.
Technical Paper

A Phenomenological Control Oriented Lean NOx Trap Model

2003-03-03
2003-01-1164
Lean NOx Trap (LNT) is an aftertreatment device typically used to reduce oxides of nitrogen (NOx) emissions for a lean burn engine. NOx is stored in the LNT during the lean operation of an engine. When the air-fuel ratio becomes rich, the stored NOx is released and catalytically reduced by the reductants such as CO, H2 and HC. Tailpipe NOx emissions can be significantly reduced by properly modulating the lean (storage) and rich (purge) periods. A control-oriented lumped parameter model is presented in this paper. The model captures the key steady state and transient characteristics of an LNT and includes the effects of the important engine operating parameters. The model can be used for system performance evaluation and control strategy development.
Technical Paper

AUREATE: An Augmented Reality Test Environment for Realistic Simulations

2018-04-03
2018-01-1080
Automated driving is currently one of the most active areas of research worldwide. While the general progress in developing specific algorithms for perception, planning and control tasks is very advanced, testing and validation of the resulting functions is still challenging due to the large number of possible scenarios and generation of ground-truth. Currently, real world testing and simulations are used in combination to overcome some of these challenges. While real world testing does not suffer from imperfect sensor models and environments, it is expensive, slow and not accurately repeatable and therefore unable to capture all possible scenarios. However, simulation models are not sophisticated enough to fully replace real world testing. In this paper, we propose a workflow that is capable of augmenting real sensor-level data with simulated sensor data.
Technical Paper

Advanced Predictive Diesel Combustion Simulation Using Turbulence Model and Stochastic Reactor Model

2017-03-28
2017-01-0516
Today numerical models are a major part of the diesel engine development. They are applied during several stages of the development process to perform extensive parameter studies and to investigate flow and combustion phenomena in detail. The models are divided by complexity and computational costs since one has to decide what the best choice for the task is. 0D models are suitable for problems with large parameter spaces and multiple operating points, e.g. engine map simulation and parameter sweeps. Therefore, it is necessary to incorporate physical models to improve the predictive capability of these models. This work focuses on turbulence and mixing modeling within a 0D direct injection stochastic reactor model. The model is based on a probability density function approach and incorporates submodels for direct fuel injection, vaporization, heat transfer, turbulent mixing and detailed chemistry.
Technical Paper

An On-Board Reductant Delivery System for Diesel Aftertreatment

2001-09-24
2001-01-3622
It has become evident that almost all diesel aftertreatment devices dealing with NOx and particulate matter (PM) controls require the addition of one or more reducing agents (reductants), such as diesel fuel, ammonia, or aqueous urea to enhance their efficiency and durability. These reductants can be used to catalytically convert NOx to N2, to enrich the air fuel ratio (A/F), or to increase temperatures for regenerating PM filters or for de-sulfating NOx traps. A number of injection methods have been developed recently to provide easy reductant addition. However, many of them may be cumbersome, costly, or ineffective. This paper describes a new reductant delivery system, which appears to minimize these shortcomings. To be effective, the manner of reductant injection into the exhaust is critical. First, the reductant must be added quickly to accommodate the fast transient operations.
Technical Paper

Analysis of Advanced Multiple Injection Strategies in a Heavy-Duty Diesel Engine Using Optical Measurements and CFD-Simulations

2008-04-14
2008-01-1328
In order to meet future emissions legislation for Diesel engines and reduce their CO2 emissions it is necessary to improve diesel combustion by reducing the emissions it generates, while maintaining high efficiency and low fuel consumption. Advanced injection strategies offer possible ways to improve the trade-offs between NOx, PM and fuel consumption. In particular, use of high EGR levels (⥸ 40%) together with multiple injection strategies provides possibilities to reduce both engine-out NOx and soot emissions. Comparisons of optical engine measurements with CFD simulations enable detailed analysis of such combustion concepts. Thus, CFD simulations are important aids to understanding combustion phenomena, but the models used need to be able to model cases with advanced injection strategies.
Technical Paper

Application of Transient Temperature vs. Equivalence Ratio Emission Maps to Engine Simulations

2007-04-16
2007-01-1086
In order to acquire knowledge about temperature vs. equivalence ratio, T-ϕ, conditions in which emissions are formed and destroyed, T-ϕ parametric maps were constructed for: 1 Soot and soot precursors (C2H2) 2 Nitrogen oxides (NO and NO2) 3 Unburnt intermediates (CH2O, H2 and CO) 4 Important radicals (HO2 and OH) Each map was obtained by plotting data from a large number of simulations for various T-ϕ combinations in a zero-dimensional, 0D, closed Perfectly Stirred Reactor, PSR. Initially, the influences of elapsed reaction time, pressure and EGR level were examined, varying one parameter at a time. Then, since both the elapsed time and pressure change in an engine cycle, the maps were constructed according to engine pressure traces obtained from Computational Fluid Dynamics, CFD, simulations. Since the pressure is changing in elapsed time intervals the maps are called transient.
Technical Paper

Augmented Reality for Improved Dealership User Experience

2017-03-28
2017-01-0278
The potential for Augmented Reality (AR) spans many domains. Among other applications, AR can improve the discovery and learning experience for users inspecting a particular item. This paper discusses the use of AR in the automotive context; particularly, on improving the user experience in a dealership show room. Visual augmentation, through a tablet computer or glasses allows users to take part in a self-guided tour in learning about the various features, details, and options associated with a vehicle. The same approach can be applied to other learning scenarios, such as training and maintenance assistance. We evaluated a set of AR Glasses and a general purpose tablet. A table-top showroom was developed demonstrating what the actual user experience would be like for a self-guided dealership tour using natural markers and three-dimensional content spatially registered to physical objects in the user’s field of view.
Journal Article

Benefits of Pd Doped Zeolites for Cold Start HC/NOx Emission Reductions for Gasoline and E85 Fueled Vehicles

2018-04-03
2018-01-0948
In the development of HC traps (HCT) for reducing vehicle cold start hydrocarbon (HC)/nitrogen oxide (NOx) emissions, zeolite-based adsorbent materials were studied as key components for the capture and release of the main gasoline-type HC/NOx species in the vehicle exhaust gas. Typical zeolite materials capture and release certain HC and NOx species at low temperatures (<200°C), which is lower than the light-off temperature of a typical three-way catalyst (TWC) (≥250°C). Therefore, a zeolite alone is not effective in enhancing cold start HC/NOx emission control. We have found that a small amount of Pd (<0.5 wt%) dispersed in the zeolite (i.e., BEA) can significantly increase the conversion efficiency of certain HC/NOx species by increasing their release temperature. Pd was also found to modify the adsorption process from pure physisorption to chemisorption and may have played a role in the transformation of the adsorbed HCs to higher molecular weight species.
Technical Paper

CI Methanol and Ethanol combustion using ignition improver

2019-12-19
2019-01-2232
To act on global warming, CO2 emissions must be reduced. This will require a reduction in the use of fossil fuels for transportation. Because of the large quantities of fossil fuels used in transportation, sources of renewable fuels other than biomass will have to be explored, such as electrofuels synthesized from CO2 using renewable electricity. Potential electrofuels include methanol and ethanol, which have shown promising results in SI engines. However, their low cetane numbers make these fuels unsuitable for CI engines because of their poor auto-ignition qualities. The main objective of this study was to evaluate the viability of using methanol and ethanol in CI engines at compression ratios of 16.7 and 20 with a pilot-main injection strategy in the PPC/CI regime. Single cylinder engine tests on a heavy duty engine were performed under medium load conditions (1262 rpm and 172 Nm).
Technical Paper

Co-fueling of Urea for Diesel Cars and Trucks

2002-03-04
2002-01-0290
Urea SCR is an established method to reduce NOx in dilute exhaust gas. The method is being used currently with stationary powerplants, and successful trials on motor vehicles have been conducted. The reason most often cited for rejecting urea SCR is lack of urea supply infrastructure, yet urea and other high nitrogen products are traded as commodities on the world market as a fertilizer grade, and an industrial grade is emerging. For a subset of commercial vehicles, urea can be provided by service personnel at designated terminals. But this approach does not support long distance carriers and personal use vehicles. The preferred delivery method is to add urea during vehicle refueling through a common fuel nozzle and fill pipe interface: urea / diesel co-fueling. Aqueous urea is well suited to delivery in this fashion.
Journal Article

Combined Fe-Cu SCR Systems with Optimized Ammonia to NOx Ratio for Diesel NOx Control

2008-04-14
2008-01-1185
Selective catalytic reduction (SCR) is a viable option for control of oxides of nitrogen (NOx) from diesel engines. Currently, copper zeolite (Cu-zeolite) SCR catalysts are favored for configurations where the exhaust gas temperature is below 450°C for the majority of operating conditions, while iron zeolite (Fe-zeolite) SCR catalysts are preferred where NOx conversion is needed at temperatures above 450°C. The selection of Cu-zeolite or Fe-zeolite SCR catalysts is based on the different performance characteristics of these two catalyst types. Cu-zeolite catalysts are generally known for having efficient NOx reduction at low temperatures with little or no NO2, and they tend to selectively oxidize ammonia (NH3) to N2 at temperatures above 400°C, leading to poor NOx conversion at elevated temperatures.
Technical Paper

Combustion Improvement of a Light Stratified-Charge Direct Injection Engine

2004-03-08
2004-01-0546
In the effort to improve combustion of a Light-load Stratified-Charge Direct-Injection (LSCDI) combustion system, CFD modeling, together with optical engine diagnostics and single cylinder engine testing, was applied to resolve some key technical issues. The issues associated with stratified-charge (SC) operation are combustion stability, smoke emission, and NOx emission. The challenges at homogeneous-charge operation include fuel-air mixing homogeneity at partial load operation, smoke emission and mixing homogeneity at low speed WOT, and engine knock tendency reduction at medium speed WOT operations. In SC operation, the fuel consumption is constrained with the acceptable smoke emission level and stability limit. With the optimization of piston design and injector specification, the smoke emission can be reduced. Concurrently, the combustion stability window and fuel consumption can be also significantly improved.
Technical Paper

Comparison of Analytically and Experimentally Obtained Residual Fractions and NOX Emissions in Spark-Ignited Engines

1998-10-19
982562
Using a fast-sampling valve, residual-fraction levels were determined in a 2.0L spark-ignited production engine, over varying engine operating conditions. Individual samples for each operating condition were analyzed by gas-chromatography which allowed for the determination of in-cylinder CO and CO2 levels. Through a comparison of in-cylinder measurement and exhaust data measurements, residual molar fraction (RMF) levels were determined and compared to analytical results. Analytical calculations were performed using the General Engine SIMulation (GESIM) which is a steady state quasi-dimensional engine combustion cycle simulation. Analytical RMF levels, for identical engine operating conditions, were compared to the experimental results as well as a sensitivity study on wave-dynamics and heat transfer on the analytically predicted RMF. Similarly, theoretical and experimental NOx emissions were compared and production sensitivity on RMF levels explored.
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