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Technical Paper

A Correlation Between Tailpipe Hydrocarbon Emissions and Driveability

1996-10-01
962023
Simultaneous tests of emissions and driveability conducted at 4.4°C on a chassis dynamometer using 10 late model vehicles showed a strong correlation between degraded driveability and increased tailpipe hydrocarbon emissions. Other regulated emissions were uncorrelated to driveability, or were small in magnitude. The 24 test gasolines were systematically varied in front-end, mid-range, and tail-end volatility and so spanned much of the moderate and high DI (driveability index) fuel region. Splash blends of 10%.vol ethanol and 15%vol MTBE blended gasolines were tested in addition to hydrocarbon gasolines.
Technical Paper

A Diamond-Like Carbon Coating for Aluminum Alloy Piston/Bore Application

1996-02-01
960014
This paper examines the potential use of diamond-like carbon (DLC) on aluminum alloy pistons of internal combustion engines. Our approach is to apply a DLC coating on the piston running against an aluminum-390 bore thus eliminating the iron liners in a standard piston/bore system. Experimental data, using a pin-on-disk tribometer under unlubricated test conditions, indicate that the performance of the DLC coating against aluminum 390 exhibits superior friction resistance compared to aluminum-390 against cast iron; the latter material couple representing the materials currently being used in production for the piston/bore application. Moreover, by thermally cycling the DLC coatings we show that improved friction and wear properties can he maintained to temperatures as high as 400°C.
Technical Paper

A Micrographic Study of Deposit Formation Processes in a Combustion Chamber

1996-10-01
962008
Growing concern about the impact of combustion chamber deposits (CCD) on engine performance and exhaust emissions has renewed interest in understanding the deposit formation process in a combustion chamber. To provide a true picture of the deposit formation process, an extensive micrographic study of the deposits in a single cylinder engine has been conducted. Four retrievable deposit sampling probes were used. The sampling period for the deposits varied from 15 minutes to 20 hours to show how the deposits evolved with time. The coolant temperature was changed from 50°C to 95°C to observe the effect of surface temperature on deposit morphology. Impacts of deposit control additives on the deposit distribution and deposit morphology were also investigated. Deposits formed in different parts of the combustion chamber differed significantly in their morphology. The differences occur mainly because of variations in surface temperature.
Technical Paper

Bench Test for Scuff Evaluation of Surface Modified Piston and Bore Materials

1996-02-01
960013
This paper describes a bench method to evaluate the frictional behavior, under scuffing conditions, of some test coupons of standard materials currently used in making cylinder bores and pistons. The usefulness of this method is in evaluating new materials and coatings that may enable the elimination of iron liners from engine blocks. While investigating the potential application of Plasma Source Ion Implantation (PSII) on engine piston/bore materials, we have systematically studied the scuffing related friction behavior of aluminum 390 alloy and cast iron. A pin-on-disk tribometer is used under dry sliding conditions. Testing parameters for simulating cold scuff in bench tests have been specified. This proposed test method offers a screening tool desirable for the development of PSII technology and may also be useful for the design of other new surface modification techniques.
Technical Paper

Central Carolina Vehicle Particulate Emissions Study

2003-03-03
2003-01-0299
In-use, light-duty vehicles were recruited in Cary, North Carolina for emissions testing on a transportable dynamometer in 1999. Two hundred forty-eight vehicles were tested in as received condition using the IM240 driving cycle. The study was conducted in two phases, a summer and winter phase, with half of the vehicles recruited during each phase. Regulated emissions, PM10, carbonaceous PM, aldehydes and ketones were measured for every test. PM2.5, individual volatile hydrocarbons, polycyclic aromatic hydrocarbons, sterane and hopane emissions were measured from a subset of the vehicles. Average light-duty gasoline PM10 emission rates increased from 6.5 mg/mi for 1993-97 vehicles to 53.8 mg/mi for the pre-1985 vehicles. The recruited fleet average, hot-stabilized IM240 PM10 emission rate for gasoline vehicles was 19.0 mg/mi.
Technical Paper

Diesel Engines: One Option to Power Future Personal Transportation Vehicles

1997-08-06
972683
In the twenty-first century, exhaust emission control will remain a major technical challenge especially as additional pressures for fuel and energy conservation mount. To address these needs, a wide variety of engine and powertrain options must be considered. For many reasons, the piston engine will remain the predominant engine choice in the twenty-first century, especially for conventional and/or parallel hybrid drive trains. Emissions constraints favor the conventional port fuel-injected gasoline engine with 3-way exhaust catalyst, while energy conservation favors direct-injection gasoline and diesel engines. As a result of recent technological progress from a competitive European market, diesels, and most recently, direct-injection (DI) diesels now offer driveability and performance characteristics competitive with those of gasoline engines. In addition, DI diesels offer the highest fuel efficiency.
Technical Paper

Effect of Fuel/Air Ratio Variations on Catalyst Performance and Hydrocarbon Emissions During Cold-Start and Warm-Up

1996-10-01
962075
Effects of fuel/air equivalence ratio variations (Φ = 1.0±0.02) on engine-out and catalyst-out hydrocarbon (HC) mass and speciated emissions were measured under simulated cold-start conditions in order to suggest ways to optimize the engine-controls-catalyst system for minimum HC mass emissions and specific reactivity. A single-cylinder engine (installed in a temperature-controlled room and using commercial-grade gasoline) is run under controlled steady-state conditions (at 24 °C or -7 °C) which simulate cold starting. Speciated and total hydrocarbon emissions are measured from engine-out exhaust samples and from samples taken after an oven-temperature-controlled catalyst (either a fresh platinum/rhodium production catalyst, a 50,000 mile vehicle-aged catalyst, or a ceramic brick with standard washcoat containing no noble metal). Changes in engine fuel/air equivalence ratio (Φ = 1.0±0.02) have a small effect on engine-out HC mass emissions (± 10 %) and specific reactivity (0 - 2%).
Technical Paper

Effects of Mixture Preparation on HC Emissions of a S.I. Engine Operating Under Steady-State Cold Conditions

1996-10-01
961958
The effects on engine-out HC emissions of a premixed propane system, and three PFI systems employing different types of injectors and using Phase II gasoline were investigated on a four-cylinder DOHC spark-ignition engine. Cold conditions resulted in significant increases in engine-out HC emissions. Phase II gasoline caused much higher emissions of HC than propane fuel. The difference in the HC emissions from the two fuels increased dramatically with lowering the coolant temperature of the engine. At cold conditions, liquid fuel entering the combustion chamber appears to be the primary source of engine out HC emissions. At the coldest temperature tested the estimated percent contribution of in-cylinder liquid fuel to the observed increase of HC emissions was as much as 96%.
Technical Paper

Effects of Piston Crevice Geometry on the Steady-State Engine-Out Hydrocarbons Emissions of a S.I. Engine

1995-10-01
952537
This study investigated the effects of piston Crevice geometry on the steady-state engine-out hydrocarbons (HC) from a Saturn DOHC four-cylinder production engine. A 50% reduction in top-land height produced about 20-25% reduction in HC emissions, at part loads. The effect of top-land radial clearance on HC emissions was found to depend on the value of top-land height, which suggests a complex relation between flame propagation in the piston crevice and crevice geometry. For idle, increasing top-land clearance resulted in an increase in HC emissions. This trend is opposite to the trend at part load. A simple model was developed which predicts surprisingly well the contribution of piston crevices to HC emissions. It was estimated that for the test engine, piston crevices contribute about 50% of the engine-out hydrocarbons. Finally exhaust gas recirculation appears to decrease the sensitivity of HC emissions to crevice dimensions.
Technical Paper

Multidimensional Port-and-in-Cylinder Flow Calculations and Flow Visualization Study in an Internal Combustion Engine with Different Intake Configurations

1994-10-01
941871
Multidimensional simulations of coupled intake port/valve and in-cylinder flow structures in a pancake-shape combustion chamber engine are reported. The engine calculations include moving piston, moving intake valve, and valve stem. Direct comparisons of three intake configurations for the same cylinder geometry are presented: (1) standard intake valve; (2) intake valve with high-swirl shroud orientation; and (3) intake valve with across-head shroud orientation. In order to verify the calculated results, qualitative flow visualization experiments were carried out for the same intake geometries during the induction process using a transient water analog. During the intake process the results of the multidimensional simulation agreed very well with the qualitative flow visualization experiments.
Technical Paper

Overview of Techniques for Measuring Friction Using Bench Tests and Fired Engines

2000-06-19
2000-01-1780
This paper presents an overview of techniques for measuring friction using bench tests and fired engines. The test methods discussed have been developed to provide efficient, yet realistic, assessments of new component designs, materials, and lubricants for in-cylinder and overall engine applications. A Cameron-Plint Friction and Wear Tester was modified to permit ring-in-piston-groove movement by the test specimen, and used to evaluate a number of cylinder bore coatings for friction and wear performance. In a second study, it was used to evaluate the energy conserving characteristics of several engine lubricant formulations. Results were consistent with engine and vehicle testing, and were correlated with measured fuel economy performance. The Instantaneous IMEP Method for measuring in-cylinder frictional forces was extended to higher engine speeds and to modern, low-friction engine designs.
Technical Paper

Piston Fuel Films as a Source of Smoke and Hydrocarbon Emissions from a Wall-Controlled Spark-Ignited Direct-Injection Engine

2003-03-03
2003-01-0547
Thin films of liquid fuel can form on the piston surface in spark-ignited direct-injection (SIDI) engines. These fuel films can result in pool fires that lead to deposit formation and increased hydrocarbon (HC) and smoke emissions. Previous investigations of the effects of piston fuel films on engine-out HC and smoke emissions have been hampered by their inability to measure the fuel-film mass in operating direct-injection engines. In this paper, a recently developed high-speed refractive-index-matching imaging technique is used for quantitative time- and space-resolved measurements of fuel-film mass on a quartz piston window of an optically-accessible direct-injection engine operating over a range of fully-warmed-up stratified-charge conditions with both a high-pressure hollow-cone swirl-type injector and with a high-pressure multihole injector.
Technical Paper

The Emissions Performance of Oxygenated Diesel Fuels in a Prototype DI Diesel Engine

2001-03-05
2001-01-0650
As part of a cooperative development program, six diesel fuels (a reference and five blends containing oxygenates) were evaluated under four steady-state conditions using a prototype 1.26-L 3-cylinder four-valve common-rail DI diesel engine. All of the fuels contained low sulfur (mostly < 5 ppm by mass), and they were chosen to determine the impacts of oxygenate volatility, concentration, and chemical type (paraffinic or aromatic) on exhaust emissions - with particular emphasis on particulate emissions. In addition to HC, CO, NOx and PM emissions measurements, emissions of the volatile portion of the PM and particle size were determined. Relative to the very low sulfur reference fuel, the oxygenated fuels reduced PM and NOx under some operating conditions, but produced little effect on either HC or CO emissions. Aliphatic oxygenates at 6 wt. percent oxygen in the reference fuel reduced simulated FTP PM emissions by 15 - 27 %.
Technical Paper

Understanding Fuel Effects on Hydrocarbon Permeation through Vehicle Fuel System Materials

2007-10-29
2007-01-4089
Hydrocarbon permeation is one of the remaining main sources of vehicle evaporative hydrocarbon emission. However, very little information exists on the role of fuel properties on permeation losses. Therefore, experimental and modeling studies were conducted to determine the relationships between hydrocarbon permeation through HDPE (high density polyethylene) and fuel properties. Half-gallon HDPE bottles without EVOH were used in this study, because they were easily available and because steady state permeation can be measured in a matter of few days instead of several months in the case of HDPE/EVOH bottles. A permeation equation was developed using both theory and experimental data, which shows that permeation increases exponentially with fuel aromatic content, increases linearly with fuel RVP, and increases exponentially with temperature. The equation is useful for predicting how fuel and ambient temperature affect hydrocarbon permeation through vehicle fuel system.
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