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Dimethyl ether (DME) can be converted easily from methanol in a catalytic reactor, and it has very good compression ignition characteristics. This paper presents experimental results on a compression ignition methanol engine with DME as an ignition improver. The results show that engine operation is sufficiently smooth with high efficiency without spark or glow plugs. In the experiments, two methods for DME introduction were investigated: an aspiration and a torch ignition method. The aspiration method introduces DME into the intake manifold, and is structurally simple but suffers from poor emission characteristics at partial loads, and a large amount of DME is required for ignition. With the torch ignition method, DME is introduced into a torch ignition chamber during the intake stroke, and significant reductions in both the necessary DME quantity and emissions were obtained. Engine operation was also attempted with DME-dissolved methanol fuel without ignition aids.

This study makes use of the detailed mechanisms of n-heptane combustion, from gas reactions to soot particle formation and oxidation, and a two-stage model based on the CHEMKIN reactor network is developed and used to investigate the trade-off between soot and NOx emissions. The effects of the equivalence ratio, EGR, ambient pressure and temperature, and initial particle diameter are observed for various residence times. The results show that high rates of NOx formation are unavoidable under conditions where high reduction rates of soot particles are obtained. This suggests that suppression of the amount of soot during the formation stage is essential for simultaneous reductions in engine-out soot and NOx emissions.

Copper ion-exchanged ZSM-5 zeolite catalyst, which reduces nitrogen oxides (NOx) in the presence of oxygen and hydrocarbons, was applied to actual diesel engine exhaust. Copper ion-exchanged ZSM-5 zeolite effectively reduced NOx by 25% in normal engine operation, and by 80% when hydrocarbons in the exhaust were increased. Water in the exhaust gas decreased the NOx reduction efficiency, but oxygen and sulfur appeared to have only a small effect. Maximum NOx reduction was observed at 400°C irrespective of hydrocarbon species, and did not decrease with space velocity up to values of 20,000 1/h. THE PURPOSE of this paper is to evaluate the possibilities and problems in catalytic reduction of NOx in actual diesel engine exhaust. Here, a copper ion-exchanged ZSM-5 zeolite (Cu-Z) catalyst was applied to diesel engine exhaust to examine the dependency of the NOx reduction efficiency on temperature and space velocity. The effects of oxygen, water and hydrocarbons were also examined.

Silent, clean, and efficient combustion was realized with emulsified blends of aqueous ethanol and diesel fuel in a DI diesel with pilot injection and cooled EGR. The pilot injection sufficiently suppressed the rapid combustion to acceptable levels. The thermal efficiency with the emulsified fuel improved as the heat release with the pilot injection was retarded to near top dead center, due to poor ignitability and also due to a reduction in afterburning. With the emulsified fuel containing 40 vol% ethanol and 10 vol% water (E40W10), the smokeless operation range can be considerably extended even under low fuel injection pressure or low intake oxygen content conditions.

Water and diesel fuel emulsions containing 13% and 26% water by volume were investigated in a modern diesel engine with relatively early pilot injection, supercharging, and cooled EGR. The heat release from the pilot injection with water emulsions is retarded toward the top dead center due to the poor ignitability, which enables larger pilot and smaller main injection quantities. This characteristic results in improvements in the thermal efficiency due to the larger heat release near the top dead center and the smaller afterburning. With the 26% water emulsion, mild, smokeless, and very low NOx operation is possible at an optimum pilot injection quantity and 15% intake oxygen with EGR at or below 0.9 MPa IMEP, a condition where large smoke emissions are unavoidable with regular unblended diesel fuel. Heat transfer analysis with Woschni's equation did not show the decrease in cooling loss with the water emulsion fuels.

Combustion and exhaust gas emissions of alcohol and vegetable oil blends including a 20% ethanol + 40% 1-butanol + 40% vegetable oil blend and a 50% 1-butanol + 50% vegetable oil blend were examined in a single cylinder, four-stroke cycle, 0.83L direct injection diesel engine, with a supercharger and a common rail fuel injection system. A 50% diesel oil + 50% vegetable oil blend and regular unblended diesel fuel were used as reference fuels. The boost pressure was kept constant at 160 kPa (absolute pressure), and the cooled low pressure loop EGR was realized by mixing with a part of the exhaust gas. Pilot injection is effective to suppress rapid combustion due to the lower ignitability of the alcohol and vegetable oil blends. The effects of reductions in the intake oxygen concentration with cooled EGR and changes in the fuel injection pressure were investigated for the blended fuels.

Cycle-to-cycle changes in diesel exhaust gas emissions were investigated under two transient operation patterns: One, “an interval step decreasing and increasing load”, where the fuel amount is rapidly decreased from high to low loads, and after an interval, Δtint the fuel amount is abruptly returned to the initial level. The other is “a ramp increasing load”, where the fuel amount is increased gradually. Except just after the step increase in fuel amounts, the THC emissions were almost completely determined by the piston wall temperature and fuel amount. However, the THC concentrations immediately after the step increase in fuel amounts were much higher than the value of the corresponding steady state operation with the same piston wall temperature. This overshoot concentration, ΔTHC, was almost constant at different intervals, Δtint and it can be suppressed by ramp increased loading.

Changes in exhaust gas emissions during starting in a DI diesel engine were investigated. The THC after starting increased until around the 50th cycle when the fuel deposited on the combustion chamber showed the maximum, and THC then decreased to reach a steady value after about 1000 cycles when the piston wall temperature became constant. The NOx showed an initial higher peak just after starting, and increased to a steady value after about 1000 cycles. Exhaust odor had a strong correlation with THC, and at the early stage odor was stronger than would be expected from the THC concentration. The THC increased with increased fuel injection amounts, decreased cranking speeds, and fuels with higher viscosity, higher 90% distillation temperature, and lower ignitability.

To reduce NOx emissions from diesel engines, the urea-SCR (selective catalytic reduction) system has been introduced commercially. In urea-SCR, the freezing point of the urea aqueous solution, the deoxidizer, is −11°C, and the handling of the deoxidizer under cold weather conditions is a problem. Further, the ammonia escape from the catalyst and the generation of N2O emissions are also problems. To overcome these disadvantages of the urea-SCR system, the addition of a hydrocarbon deoxidizer has attracted attention. In this paper, a micro-reactor SCR system was developed and attached to the exhaust pipe of a single cylinder diesel engine. With the micro-reactor, the catalyst temperature, quantity of deoxidizer, and the space velocity can be controlled, and it is possible to use it with gas and liquid phase deoxidizers. The catalyst used in the tests reported here is Ag(1wt%)-γAl2O3.

Dual fuel combustion with premixed ethanol as the main fuel and direct injection of diesel fuel as an ignition source poses problems including large unburned emissions and excessively rapid combustion. In this report the influence of compression ratios, injection timings of diesel fuel, and intake oxygen concentrations was systematically investigated in a modern diesel engine. The combustion process was classified into three stages: the first rapid combustion of diesel fuel and the ethanol mixture entrained into the diesel fuel spray; the second mild combustion with flame propagation of the ethanol mixture; and the third rapid combustion with auto-ignition of the unburned ethanol mixture without knocking. The third stage combustion occurs occasionally at several operating conditions and has been termed as PREMIER (premixed mixture ignition in the end-gas region) combustion.

The HCCI engine offers the potential of low NOx emissions combined with diesel engine like high efficiency, however HCCI operation is restricted to low engine speeds and torques constrained by narrow noise (HCCI knocking) and misfiring limits. Gasoline like fuel vaporizes and mixes with air, but the mixture may auto-ignite at the same time, leading to heavy HCCI knocking. Retarding the CA50 (the crank angle of the 50% burn) is well known as a method to slow the maximum pressure rise rate and reduce HCCI knocking. The CA50 can be controlled by the fuel composition, for example, di-methyl ether (DME), which is easily synthesized from natural gas, has strong low temperature heat release (LTHR) characteristics and ethanol generates strong LTHR inhibitor effects. The utilization of DME-ethanol binary blended fuels has the potential to broaden the HCCI engine load-speed range.

Port injection of ethanol addition as an ignition inhibitor was implemented to control ignition timing and expand the operating range in DME fueled HCCI combustion. The ethanol reduced the rate of low-temperature oxidation and consequently delayed the onset of the high-temperature reaction with ultra-low NOx over a wide operating range. Along with the ethanol addition, changes in intake temperature, overall equivalence ratio, and engine speed are investigated and shown to be effective in HCCI combustion control and to enable an extension of operation range. A chemical reaction analysis was performed to elucidate details of the ignition inhibition on low-temperature oxidation of DME-HCCI combustion.

Dual fuel combustion with premixed natural gas as the main fuel and diesel fuel as the ignition source was investigated in a 0.83 L, single cylinder, DI diesel engine. At low loads, increasing the equivalence ratio of natural gas to around 0.5 with intake throttling makes it possible to reduce the THC and CO emissions as well as to improve the thermal efficiency. At high loads, increasing the boost pressure moderates the combustion, but increases the THC and CO emissions, resulting in deterioration of the thermal efficiency. The EGR is essential to suppress the rapid combustion. As misfiring occurs with a compression ratio of 14.5 and there is excessively rapid combustion with 18.5 compression ratio, 16.5 is a suitable compression ratio.

Dimethyl ether (DME) has very good compression ignition characteristics, and can be converted from methanol using a γ - alumina catalyst. A previous report investigated a compression ignition methanol engine with DME as an ignition improver. The results showed that the engine operation was sufficiently smooth without either spark or glow plugs. Two methods were studied, one was an aspiration method, and the other was a torch ignition chamber method (TIC method). The aspiration method allows a simple engine structure, but suffers from poor engine emissions and requires large amounts of DME. With the TIC method where the DME was introduced into a torch ignition chamber (TIC) during the intake stroke, the diffusion of the DME into the main combustion chamber was limited, and significant reductions in both the necessary quantity of DME and emissions were obtained [1][2].

The fuel spray distribution in a DI diesel engine with pilot injection was actively controlled by pilot and main fuel injections at different piston positions to prevent the main fuel injection from hitting the pilot flame. A CFD analysis demonstrated that the movement of the piston with a cavity divided by a central lip along the center of the sidewall effectively separates the cores of the pilot and main fuel sprays. Experiments showed that an ordinary cavity without the central lip emitted more smoke, while smokeless, low NOx operation was realized with a cavity divided by a central lip even at heavy loads where ordinary operation without pilot injection emits smoke.

Premixed diesel combustion modes including low temperature combustion and MK combustion are expected to realize smokeless and low NOx emissions. As ignition must be delayed until after the end of fuel injection to establish these combustion modes, methods for active ignition control are being actively pursued. It is reported that alcohols including methanol and ethanol strongly inhibit low temperature oxidation in HCCI combustion offering the possibility to control ignition with alcohol induction. In this research improvement of diesel combustion and emissions by ethanol intake port injection for the promotion of premixing of the in-cylinder injected diesel fuel, and by increased EGR for the reduction of combustion temperature.

The authors have previously reported significant reductions in particulate emissions by generating strong turbulence during the combustion process. Extending this, it was attempted to reduce NOx, particulate, and fuel consumption simultaneously by two-stage combustion: forming a fuel rich mixture at the initial combustion stage to prevent NOx formation, and inducing strong turbulence in the combustion chamber at the later stage of combustion to oxidize the particulate. The purpose of this study is to examine the effect of two-stage combustion in emission control. The paper gives an evaluation of the NO reaction-kinetics of the system and experimental results for a combustion chamber specially made for the two-stage combustion. With this combustion system, it was possible to reduce NOx levels to 1/3 of the base engine. Combination of EGR and the two-stage combustion was also examined.

The purpose of this investigation is to evaluate the feasibility of rapeseed oil and palm oil for diesel fuel substitution in a naturally aspirated D.I. diesel engine, and also to find means to reduce the carbon deposit buildup in vegetable oil combustion. In the experiments, the engine performance, exhaust gas emissions, and carbon deposits were measured for a number of fuels: rapeseed oil, palm oil, methylester of rapeseed oil, and these fuels blended with ethanol or diesel fuel with different fuel temperatures. It was found that both of the vegetable oil fuels generated an acceptable engine performance and exhaust gas emission levels for short term operation, but they caused carbon deposit buildups and sticking of piston rings after extended operation.

Smokeless and ultra low NOx combustion without knocking in a dual-fuel diesel engine with induced LPG as the main fuel was established with a uniquely developed piston cavity divided by a lip in the sidewall. A small quantity of diesel fuel was directly injected at early compression stroke into the lower part of the cavity as an ignition source for this confined area, and this suppressed explosively rapid combustion just after ignition and spark-knock like combustion at later stage. A combination of the divided cavity, EGR, and intake air throttling was effective to simultaneously eliminate knocking, and reduce THC and NOx significantly.

Premixed diesel combustion blending high volatility fuels into diesel fuel were investigated in a modern diesel engine. First, various fractions of normal heptane and diesel fuel were examined to determine the influence of the blending of a highly ignitable and volatile fuel into diesel fuel. The indicated thermal efficiency improves almost linearly with increasing normal heptane fraction, particularly at advanced injection timings when the fuel is not injected directly into the piston cavity. This improvement is mainly due to decreases in the other losses, ϕother which are calculated with the following equation based on the energy balance. ηu: The combustion efficiency calculated from the exhaust gas compositions ηi: The indicated thermal efficiency ϕex: The exhaust loss calculated from the enthalpy difference between intake and exhaust gas The decreases in the other losses with normal heptane blends are due to a reduction in the unburned fuel which does not reach the gas analyzer.