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Although metallic compounds are widely known to affect combustion in internal combustion engines, the potential of metallic additives in engine oils to initiate abnormal combustion has been unclear. In this study, we investigated the influence of combustion chamber deposits derived from engine oil additives on combustion in a spark-ignited engine. We used a single-cylinder four-stroke engine, and measured several combustion characteristics (e.g., cylinder pressure, in-cylinder ultraviolet absorbance in the end-gas region, and visualized flame propagation) to evaluate combustion anomalies. To clarify the effects of individual additive components, we formed combustion products of individual additives in a combustion chamber prior to measuring combustion characteristics. We tested three types of metallic additives: a calcium-based detergent, a zinc-based antiwear agent, and a molybdenum-based friction modifier.

Hydraulic fluid (HF) specifications for mobile construction equipment called JCMAS HK and HKB have been established by the Fuels and Lubricants Committee of Japan Construction Mechanization Association (JCMA). The specifications are designated by two viscosity categories of single grade and multigrade. Each category has ISO viscosity grade (VG) 32 and 46. The JCMAS HK oils are recommended for use in hydraulic systems designed at pressure up to 34.3MPa(5000psi) and to heat hydraulic fluid up to 100 °C. These oils also provide wear control, friction performance, oxidation and rust protection, seal swell control and filterability performance. Two piston pump test procedures were developed to evaluate lubricating performance of these oils under high pressure conditions. The JACMAS HKB oils are classified as environmentally friendly oils due to the additional requirement for biodegradability.

In the Japan Clean Air Program II (JCAP II) Diesel WG, effects of fuel properties on the performance of two types of diesel NOx emission aftertreatment devices, a Urea-SCR system and a NOx storage reduction (NSR) catalyst system, were examined. For a Urea-SCR system, the NOx emission reduction performance with and without an oxidation catalyst installed in front of the SCR catalyst at low exhaust gas temperature operation was compared. For an NSR catalyst system, the effect of fuel sulfur on both emissions and fuel economy during 50,000 km driving was examined. Furthermore, effects of other fuel properties such as distillation on exhaust emissions were investigated. The results show that sulfur is the influential factor for both devices. Namely, high NOx emission reduction performance of the Urea-SCR system with the oxidation catalyst at low exhaust gas temperature operation is influenced by sulfur.

Gasoline engine downsizing combined with a turbocharger is one of the more effective approaches to improve fuel efficiency without sacrificing power performance. The benefit comes from lower pumping loss, lower mechanical friction due to ‘downsizing’ of the engine displacement and ‘down-speeding’ of the engine by using higher transmission gear ratios which is allowed by the higher engine torque at lower engine speeds. However abnormal combustion referred to as Low-Speed Pre-ignition (LSPI) is known to be able to occur in low-speed and high-torque conditions. It is a potential restriction to maximize the engine performance and its benefit, therefore prevention of LSPI is strongly desired for long-term durability of engine performance. According to recent technical reports, auto-ignition of an engine oil droplet in a combustion chamber is believed to be one of major contributing factors of LSPI and its formulations have a significant effect on LSPI frequency.

In Biodiesel Fuel Research Working Group(WG) of Japan Auto-Oil Program(JATOP), some impacts of high biodiesel blends have been investigated from the viewpoints of fuel properties, stability, emissions, exhaust aftertreatment systems, cold driveability, mixing in engine oils, durability/reliability and so on. In the impact on exhaust emissions, the impact of high biodiesel blends into diesel fuel on diesel emissions was evaluated. The wide variety of biodiesel blendstock, which included not only some kinds of fatty acid methyl esters(FAME) but also hydrofined biodiesel(HBD) and Fischer-Tropsch diesel fuel(FTD), were selected to evaluate. The main blend level evaluated was 5, 10 and 20% and the higher blend level over 20% was also evaluated in some tests. The main advanced technologies for exhaust aftertreatment systems were diesel particulate filter(DPF), Urea selective catalytic reduction (Urea-SCR) and the combination of DPF and NOx storage reduction catalyst(NSR).

To explore the measures that can be used to improve the fuel economy of internal combustion engines, we investigated how friction at the piston ring-cylinder liner interface is influenced by the boundary lubrication performance of engine oils. We formulated several engine oils with varying boundary lubrication performance and tested them for ring-liner friction by using a floating liner friction tester. We used friction modifiers (FMs) to modify the boundary lubrication performance of engine oils. We found that ring-liner friction is well correlated with the friction coefficients in boundary lubrication regimes when measured by a laboratory friction tester. We also found that the impact of the boundary lubrication performance of engine oils was emphasized in low viscosity engine oils. It makes it possible for improved boundary lubrication performance to inhibit or overcome the viscosity reduction-induced increase of friction energy.

Automobile exhaust gas contains various harmful substances other than carbon dioxide, so exhaust gas post-processing devices have been developed to reduce their environmental load. Engine oil has contributed to the improvement of automobiles' environmental performance due to its excellent fuel-saving and long-drain properties. Recently, the lifetime of an exhaust gas post-processing device has been reported to decrease due to ash and phosphorus in engine oil. We have developed non-phosphorus and non-ash engine oil (NPNA), in which metal-based detergents and zinc dialkyldithiophosphate (ZnDTP) were not contained. We have performed a verification test for NPNA using an actual engine. In a performance test for a diesel particulate filter (DPF), the amount of soot and ash deposited onto a DPF was smaller when NPNA was used than when commercially available engine oil was used.

To evaluate the influence of FAME, which has poor oxidation stability, on engine oil performance, an engine test was conducted under large volumes of fuel dilution by post-injection. The test showed that detergent consumption and polymerization of FAME were accelerated in engine oil, causing a severe deterioration in piston cleanliness and sludge protection performance of engine oil.

Due to increasing demands for further CO2 reduction and tighter exhaust emissions regulations, automakers are increasingly downsizing turbo-charged diesel engines by raising specific power, or adopting low-pressure loop exhaust gas recirculation (LPL-EGR) systems to improve the EGR rate. However, adopting a higher boost pressure to increase the specific power, or introducing hot exhaust gas before the turbocharger compressor with the LPL-EGR system creates higher gas temperatures in the compressor, which results in soot-containing deposits derived from the engine oil in the compressor. This phenomenon causes significant deterioration of turbocharger efficiency. Therefore, countermeasures such as restricting boost pressure or limiting EGR usage in the operational map are necessary to prevent engine performance deterioration. Increasing the gas temperature in the compressor while preventing deposit formation should enable further improvements in fuel consumption and engine power.

The study of 10% ethanol blended gasoline (E10 gasoline) utilization has been conducted in the Japan Auto-Oil Program (JATOP). In order to clarify the impact of E10 gasoline on vehicle performances, exhaust emissions, evaporative emissions, driveability and material compatibility have been investigated by using domestic gasoline vehicles including mini motor vehicles which are particular to Japan. The test results reveal that E10 gasoline has no impact on exhaust emissions, engine startup time and acceleration period under the hot start condition, but a slight deterioration is observed in some test cases under the cold start condition using E10 gasolines with 50% distillation temperature (T50) level set to the upper limit of Japanese Industrial Standards (JIS) K 2202. Regarding evaporative emissions, the tested vehicles shows no remarkable increase in the hot soak loss (HSL), diurnal breathing loss (DBL) and running loss (RL) testing with E10 gasolines.

Crosscheck tests of fast electrical mobility spectrometers, Differential Mobility Spectroscopy (DMS) and Engine Exhaust Particle Sizer(EEPS), were conducted to evaluate the accuracy of fine particle measurement. Two kinds of particles were used as test particles for the crosscheck test of instruments: particles emitted from diesel vehicles and diluted in a full dilution tunnel, and particles generated by CAST. In the steady state tests, it was confirmed that the average concentration of each instrument was within the range of ±2σ from the average concentration of all the same type of instruments. In the transient tests, it is verified that the instruments have almost equal sensitivity. For application of the fast electrical mobility spectrometers to evaluation of particle number and size distributions, it is essential to develop a calibration method using reference particle counters and sizers (CPC, SMPS, etc.) and maintenance methods appropriate for each model.

Air Quality Modeling Working Group developed two models to evaluate effects of automobile emission reduction measures on air quality improvement: Urban Air Quality Simulation Model in which secondary aerosol formation processes have been incorporated, and Roadside Air Quality Simulation Model in which micro-scale traffic flow has been taken into consideration. Concretely, a model has been built up for estimating SPM concentration in ambient air in which high concentrated air pollutants have been contained during summer and winter. The model has been built up by using UAM (Urban Airshed Model) as base model, and the following modification has been made to the base model. First, ISSOROPIA (secondary inorganic aerosol equilibrium model) has been added to the base model, and a secondary organic aerosol formation/reaction model (SOA model) has been incorporated into the model.

Just as CO2 reduction is required of four wheeled vehicles for environmental protection, similar environmental concerns drive the development of motorcycle oil technology. Zinc dialkyldithiophosphate (Zn-DTP) type additives are widely used for engine oil formulations. However, phosphorus compounds are environmental load materials. The reduction of the quantity of phosphorus compounds in engine oils is required to reduce poisoning of three-way catalysts used to purify exhaust gases from internal combustion engines. Mr. Ito and his co-authors1) reported that they developed a sulfur-based additive as a substitute for Zn-DTP. Their non-phosphorus engine oil formulation for four-wheeled vehicles with a sulfur-based additive was examined to evaluate its anti-wear performance using the following test methods:JASO M328 for gasoline engines (KA24E) and JASO M354 for Diesel engine (4D34T4).

As well as a four-wheeled vehicle, in the field of motorcycle, development of the CO2 reduction technology and practical use are required for global environment. Zinc dialkyldithiophosphate (Zn-DTP) type additives are widely used for engine oil formulations. However, phosphorus compounds are environmental load materials. The reduction of the quantity of phosphorus compounds in engine oils is required to reduce poisoning of three-way catalysts used to purify exhaust gases from internal combustion engines. Ito1) reported that they developed a sulfur-based additive as a substitute for Zn-DTP. Their non-phosphorus engine oil formulation for four-wheeled vehicles with a sulfur-based additive was examined to evaluate its anti-wear performance using the following test methods: JASO M328 for gasoline engines (KA24E) and JASO M354 for Diesel engine (4D34T4).

The deposition of ash derived from engine oil on the surface of diesel particle filters (DPF) has recently been reported to degrade the performance of the DPF. It is generally known that phosphorus in engine oil is adsorbed on the surface of an automotive exhaust catalyst, reducing the performance of the catalyst. Thus, the amounts of ash and phosphorus in engine oil have been decreased. We have developed a non-phosphorus, non-ash engine oil (NPNA) that does not contain metal-based detergents or zinc dialkyldithiophosphate (ZnDTP). Various engine tests were performed, and we confirmed that under normal running conditions, the NPNA oil had a sufficiently high piston detergency and wear resistance-two important requirements for engine oil-to meet current American and Japanese standards. However, the piston detergency of NPNA required further improvement when engine running conditions were more severe.

A program with title of “Development of automobile and fuel technologies for air quality improvement (Japan Clean Air Program - abbreviated to JCAP) has been conducted as a five-year program. Under the program, an influence of fuel quality on automobile technology has been evaluated, and effect of air quality improvement due to implementation of automobile exhaust emission regulations has also been evaluated by using air quality models. Through the five years of JCAP activities from FY 1997 to FY 2001, following items have been evaluated: an influence of fuel properties and automobile exhaust emission reduction technologies, an evaluation of aftertreatment devices equipped on in-use vehicles, a detailed analysis of fuel properties and exhaust emissions, a prediction of air quality improvement effects due to the implementation of next stage stringent automobile exhaust emission regulations.

Modern formulation in a wide variety of lubricants including engine oils and transmission fluids is designed to control friction through film-forming tribochemical reactions induced by the functional additives mixtures. Although many cases on the synergistic or antagonistic effects of additives on friction have been reported, their mechanisms are poorly understood. This study focused on the influences of metallic detergents on tribochemical reactions. We examined the mechanical properties of detergent-containing lubricants confined at a single-asperity contact and their contributions to tribochemical phenomena. We found that detergents enlarged the confinement space required for generating repulsive force and shear resistance. This means that these detergents provide steric effects under nanoconfinement at interfacial contacts.

Engine oils normally contain calcium detergents and ZnDTPs to have detergency and antiwear performance. However, it has been recently understood that these additives could deteriorate filter performance in catalyst and DPF. In this background this paper explains the study and the development about new type of engine oil excluding metal detergents and phosphorus compounds. The developed engine oil shows good durability in several JASO engine tests and a fleet test by formulating newly developed additives as substitute for calcium detergents and ZnDTPs.

In order to achieve the highest power output and lowest fuel consumption for the rotary engine in endurance race such as Le Mans, two types of lubricating oils were developed by conducting a single - rotor engine test at the rotational speed of 7500 rpm under full load. One was the engine oil for the lubrication of the combustion chamber. The other was a so - called system oil for lubrication of the engine system outside the combustion chamber. The conclusions obtained from the development are as follows: 1) Engine oil for the combustion chamber The engine oil greatly influences spitback phenomenon1) which can cause rotary engine trouble in an endurance race. The spitback phenomenon is decreased by the decrease of carbonaceous deposit and ash in the apex seal grooves.

Recently, deposition of ash derived from engine oil on the surface of a diesel particle filter (DPF) has been reported to worsen the performance of the DPF. It is generally known that phosphorus in engine oil is adsorbed on the surface of an automotive exhaust catalyst and reduces the performance of the catalyst. Thus, the amounts of ash and phosphorus in engine oil have been decreased. We have developed a non-phosphorus and non-ash engine oil (NPNA) that does not contain metal-based detergents and zinc dialkyldithiophosphate (ZnDTP). We performed a performance test for NPNA using an actual engine and reported that the piston detergency and anti-wear performance of NPNA were sufficiently high. However, the piston detergency of NPNA required further improvement when engine running conditions were more severe.