Search Results

Asymmetric particulate filters (PF), where the inlet channel is wider than the outlet channel, are commonly used because of their greater capacity for ash. Somewhat surprisingly, very few models for asymmetric PFs have been published and none of these gives a correct/detailed description of the geometry. For example, octahedral channels may be treated as if they were square or the tapering walls between the inlet and outlet channels treated as if they were rectangular in cross section. Alternatively, the equations may be presented in generic form in terms of channel cross-sectional areas and perimeters, but without giving any indication of how to calculate these. This paper aims to address these deficiencies with a model that correctly describes the geometry of square and octo-square asymmetric PFs. Expressions for the solid fraction of the PF (which affects thermal mass) and channel cross section and perimeter (both when clean and soot/ash loaded) are presented.

Reduction of nitrogen oxides in Diesel exhaust gas is a challenging task. This paper reports results from an extensive study using Pt-based catalysts involving synthetic gas activity testing (SCAT), engine bench testing and tests on passenger cars. Preliminary SCAT work highlighted the importance of Pt-dispersion, and both SCAT and bench engine testing yielded comparable NOx conversions under steady state conditions at high HC:NOx ratios. On passenger cars in the European cycle without secondary fuel injection NOx conversion was lower than obtained in the steady state tests. Better conversion was obtained in the FTP cycle, where secondary injection was employed. Higher HC:NOx, ratios and more favourable temperature conditions which were present in the exhaust contributed to this higher conversion.

Biofuels are a renewable energy source. When used as extenders for transportation fuels, biofuels contribute to the global reduction of Green House Gas and CO2 emissions from the transport sector and to security and independence of energy supply. On a “Well to Wheel” basis they are much more CO2 efficient than conventional fossil fuels. All vehicles currently in circulation in Europe are capable of using 5 % biodiesel. The introduction of higher percentages biodiesel needs new specific standards and vehicle tests validation. The development of vehicles compatible with 30% biodiesel blends in diesel fuel includes the validation of each part of both engine and fuel vehicle systems to guarantee normal operation for the entire life of the vehicle.

Progress in Diesel spray modelling highly depends on a better knowledge of the instantaneous injection velocity and of the hydraulic section at the exit of each injection hole. Additionally a better identification of the mechanisms which cause fragmentation is needed. This necessitates to begin with a precise computation of the two-phase flow which arises due to the presence of cavitation within the injectors. For that aim, a VOF type interface tracking method has been developed and improved (Segment Lagrangian VOF method) which allows to describe numerically the onset and development of cavitation within Diesel injectors. Furthermore, experiments have been performed for validation purpose, on transparent one-hole injectors for high pressure injection conditions. Two different entrance geometries (straight and rounded) and various upstream and downstream pressure levels have been considered.

To reduce greenhouse gas emissions such as CO2, automakers are actively pursuing alternative propulsion systems. Improvements to current engine technology are being investigated along with new power plant technologies. Fuel Cell Vehicles offer an exciting option by producing electric power through a reaction that combines hydrogen and oxygen to make water. However, hydrogen storage onboard vehicles and construction of an expensive hydrogen distribution and fueling infrastructure remain as challenges today. In addition, greenhouse gas emissions from the production of hydrogen must be considered since most hydrogen is currently produced from non-renewable sources. While these issues are being worked on, Renault has chosen to pursue a fuel cell vehicle with a fuel processor that converts gasoline and other liquid fuels to hydrogen onboard the vehicle.

Enhancements in the thermal stability of three-way catalysts have been achieved by: 1) developing improved methods for the incorporation of ceria into catalyst formulations and 2) identifying a proprietary stabilizer which reduces the rate of ceria sintering at high temperature. Improvements in thermal stability are demonstrated by comparing the FTP and engine dynamometer performance of new formulations with a standard formulation after aging on several high temperature engine dynamometer cycles.

The paper presents the VALEO and RENAULT approach to study odor problems for passengers compartment. The first part describes the method chosen to form a panel, and the second part presents a vehicle application.

It has long been recognized that the key to achieving stringent emission standards such as ULEV is the control of cold-start hydrocarbons. This paper describes a new approach for achieving excellent cold-start hydrocarbon control. The most important component in the system is a catalyst that is highly active at ambient temperature for the exothermic CO oxidation reaction in an exhaust stream under net lean conditions. This catalyst has positive order kinetics with respect to CO for CO oxidation. Thus, as the concentration of CO in the exhaust is increased, the rate of this reaction is increased, resulting in a faster temperature rise over the catalyst.

A test programme has been conducted to study any potential long term effects of gasoline sulphur on catalyst performance, using a newly developed transient engine-bed ageing cycle. The ageing cycle, which was based on repeated European Extra Urban Drive Cycles, was chosen to ensure that the catalyst experienced a realistically wide range of temperatures and space velocities, together with transients, idle and periods of overrun. Two nominally identical platinum/rhodium catalysts (manufactured from the same batch) with matched lambda sensors, were aged for a period of 80,000 km each, one being aged using a gasoline containing 50 mg/kg (ppm wt) sulphur, the other being aged on the same fuel doped to 450 ppm wt S. The emissions performance of both catalysts was measured after 6,000, 40,000 and 80,000 km ageing, by fitting the catalysts to a test vehicle, and performing emissions tests over the European test cycle at both sulphur levels.

Studies using a bi-fuelled (autogas/gasoline) Renault Laguna vehicle meeting °the 1996 European exhaust emission legislation has demonstrated that over the European test cycle at 25°C the LPG operated vehicle provides substantial benefits of reduced emissions compared to unleaded reference gasoline. At lower test temperatures (i.e. 5°C) even larger reduction in emissions have been observed. Lower CO (up to 95% at -5°C and 65% at 25°C), HC (90% at -5°C and 40% at 25°C) emissions and lower ozone HC reactivity have been observed and could all offer significant environmental air-quality benefits for LPG. Various autogas mixtures have been tested including 70/30, 30/70 and 49/30/21 (% mass propane / butane / propene). Results show that NOx emissions for this vehicle appear dependent on autogas composition. The two gas mixtures containing only 30% butane gave about 50% more NOx at +25°C than the 70% butane autogas mixture.

This paper describes the use of advanced three-way catalysts to meet future European and California low emissions legislation. Firstly, it describes the performance of these catalysts tested using the European Stage II test cycle and contrasts their emissions performance over the proposed European Stage III test. The future legislation requires fast catalyst light-off for the low emissions standards to be achieved, therefore the performance of close-coupled catalysts was investigated. The close-coupled catalyst systems gave very low emissions. Space constraints often preclude the use of large volume close-coupled catalysts, and the combination of a small starter catalyst with an underfloor catalyst was tested. This gave performance levels better than the close-coupled configuration. The effect of reducing the underfloor catalyst volume is also described. The work was carried out on a 1.2 litre European Vehicle, the conclusions were verified on a 1.6 litre European vehicle.

Various types of after-treatment system for BS VI Stage 1 are being assessed for the Light Duty Diesel (LDD) segment. For BS VI Stage 2, Real Driving Emission (RDE) assessment will be newly introduced, which will require more robustness in emission control system capability. Although the detailed requirements for India BS VI stage 2 are still being discussed, a reasonable assumption is that similar systems to those being developed for Euro 6d, will work for India BS VI. This paper describes typical system designs for Euro 6d and also reveals newly developed SCRF® (Selective Catalytic Reduction Filter) based systems, which demonstrate excellent RDE emissions. In addition, newly developed Lean NOx Trap (NSC) coatings, which focus on low temperature NOx control used with SCRF® (NSC + SCRF®) also show excellent emission control capability as demonstrated in this case on the ARTEMIS Cycle. These systems have potential as promising LDD solutions for India BS VI stage 2.

Electrical Low Pressure Impactor (ELPI) is often employed to measure the particle number and size distribution of internal combustion engines exhaust gas. If appropriate values of particle density are available, the particle mass can be estimated by this method. Exhaust particles of three Euro3 passenger cars (one gasoline operating under stoichiometric conditions, one Diesel and one Diesel equipped with Diesel Particulate Filter) are measured using the current European regulations (gravimetric method on the are New European Driving Cycle) and estimated by ELPI particle number and size distribution. Different values for particle density are used to estimate the particle mass using all ELPI stages or only some of them. The results show that the particle mass estimated by ELPI is well correlated with the mass determined by filters for PM emissions higher than 0.025 g/km. This correlation is not very good at lower emissions.

A comparison of two different types of NOx reducing catalysts will be worked out. The potential of two De-NOx catalysts using engine out hydrocarbon emissions for NOx conversion will be shown by variation of different engine parameters. An analysis of the hydrocarbon species upstream and downstream catalyst will demonstrate, which components are responsible for the NOx reduction in the exhaust gas of a lean burn engine. By variation of different parameters during adsorbtion and regeneration phases of the adsorber catalyst the efficiency in NOx reduction will be optimized. An assessment of the suitability for lean burn engines will consider the emission reduction efficiency as well as the influence on engine fuel consumption.

Fuel consumption in internal combustion engines and their associated CO2 emissions have become one of the major issues facing car manufacturers everyday for various reasons: the Kyoto protocol, the upcoming European regulation concerning CO2 emissions requiring emissions of less than 130g CO2/km before 2012, and customer demand. One of the most efficient solutions to reduce fuel consumption is to downsize the engine and increase its specific power and torque by using turbochargers. The engine and the turbocharger have to be chosen carefully and be finely tuned. It is essential to understand and characterise the turbocharger's behaviour precisely and on its whole operating range, especially at low engine speeds. The characteristics at low speed are not provided by manufacturers of turbochargers because compressor maps cannot be achieve on usual test bench.

Lean NOx trap (LNT) and Selective Catalytic Reduction catalysts (SCR) are two leading candidates for diesel NOx after-treatment. Each technology exhibits good properties to reduce efficiently diesel NOx emissions in order to match the forthcoming EURO 6 standards. NOx reduction in LNT is made through a two-step process. In normal (lean) mode, diesel engine exhausts NOx is stored into the NOx trap; then when necessary the engine runs rich during limited time to treat the stored NOx. This operating mode has the benefit of using onboard fuel as NOx reducer. But NOx trap solution is restrained by limited active temperature windows. On the other hand, NH₃-SCR catalysts operate in a wider range of temperature and do not contain precious metals. However, NH₃-SCR systems traditionally use urea-water solution as reducing agent, requiring thus additional infrastructure to supply the vehicles with enough reducer. These pros and cons are quite restrictive in classical LNT or NH₃-SCR architecture.

This paper presents the Clean Air Project for Rio de Janeiro jointly managed by Renault and the City of Rio de Janeiro. This project is one of the results of a regional initiative of the World Bank which aimed to develop local public-private actions in order to improve air quality in major metropolitan regions of Latin America. In that case, the partnership will result in the installation of a model, adapted to the local needs and the use of this model to test scenarios, quantifying the impact in terms of emissions. This partnership represents a new kind of long-lasting relationship between the private sector, aware of its social responsibility and local authorities which tend to foster the development of technical capacity to strengthen their role and awareness in that field and open new possibilities for environment investments. This paper presents this case study from the management and technical standpoint underlining the principal benefits of such a partnership.

Flow-through diesel oxidation catalysts (DOC's) have been shown to be an effective means of reducing emissions from diesel engines. In this work, the further development of diesel oxidation catalysts for the control of emissions from heavy duty engines is illustrated. Laboratory reactor and engine dynamometer data obtained from engine-based accelerated poisoning and aging studies demonstrate that HC, CO and SO2 oxidation by DOC's can be modified by adjusting platinum and vanadium loadings in alumina-based Pt/V catalyst formulations. The performance and durability of this type of catalyst system are demonstrated with several aging cycles on heavy-duty engines. The fresh performance of two catalyst systems was determined on both US Heavy Duty Transient and ECE-R49 Test cycles with a 1991 calibration Perkins Phaser 6.0 L engine. Gas phase emissions were reduced by a similar amount for both catalysts over both cycles (HC: 60-70%, CO: 45-75%).

Reducing NOx tailpipe emissions is one of the major challenges when developing automotive Diesel engines which must simultaneously face stricter emission norms and reduce their fuel consumption/CO2 emission. In fact, the engine control system has to manage at the same time the multiple advanced combustion technologies such as high EGR rates, new injection strategies, complex after-treatment devices and sophisticated turbocharging systems implemented in recent diesel engines. In order to limit both the cost and duration of engine control system development, a virtual engine simulator has been developed in the last few years. The platform of this simulator is based on a 0D/1D approach, chosen for its low computational time. The existing simulation tools lead to satisfactory results concerning the combustion phase as well as the air supply system. In this context, the current paper describes the development of a new NOx emission model which is coupled with the combustion model.

The implementations of the Tier 2 and LEVII emission levels require fast catalyst light-off and fast closed loop control through high-speed engine management. The paper describes the development of innovative catalyst designs. During the development thermal and mechanical boundary conditions were collected and component tests conducted on test rigs to identify the emission and durability performance. The products were evaluated on a Super Imposed Test Setup (SIT) where thermal and mechanical loads are applied to the test piece simultanously and results are compared to accelerated vehicle power train endurance runs. The newly developed light-off catalyst with Perforated Foil Technology (PE) showed superior emission light-off characteristic and robustness.