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The RON(Research Octane Number) is the most important indicator of motor petrol, and the petrol refining process is one of the important links in petrol production. However, RON is often lost during petrol refining and RON Loss means the value of RON lost during petrol refining. The prediction of the RON loss of petrol during the refining process is helpful to the improvement of petrol refining process and the processing of petrol. The traditional RON prediction method relied on physical and chemical properties, and did not fully consider the high nonlinearity and strong coupling relationship of the petrol refining process. There is a lack of data-driven RON loss models. This paper studies the construction of the RON loss model in the petrol refining process.

The current extensive revisitation of the application of gasoline direct-injection to automotive, four-stroke, spark-ignition engines has been prompted by the availability of technological capabilities that did not exist in the late 1970s, and that can now be utilized in the engine development process. The availability of new engine hardware that permits an enhanced level of computer control and dynamic optimization has alleviated many of the system limitations that were encountered in the time period from 1976 to 1984, when the capabilities of direct-injection, stratified-charge, spark-ignition engines were thoroughly researched. This paper incorporates a critical review of the current worldwide research and development activities in the gasoline direct-injection field, and provides insight into new areas of technology that are being applied to the development of both production and prototype engines.

Several mechanisms are discussed to understand the formation of both regulated and unregulated emissions in a high speed, direct injection, single cylinder diesel engine using low sulphur diesel fuel. Experiments were conducted over a wide range of injection pressures, EGR rates, injection timings and swirl ratios. The regulated emissions were measured by the standard emission equipment. Unregulated emissions such as aldehydes and ketones were measured by high pressure liquid chromatography and hydrocarbon speciation by gas chromatography. Particulate mass was measured with a Tapered Element Oscillating Microbalance (TEOM). Analysis was made of the sources of different emission species and their relationship with the combustion process under the different operating conditions. Special attention is given to the low temperature combustion (LTC) regime which is known to reduce both NOx and soot. However the HC, CO and unregulated emissions increased at a higher rate.

Use of ethanol as gasoline replacement can contribute to the reduction of nitrogen oxide (NOx) and carbon oxide (CO) emissions. Depending on ethanol production, significant reduction of greenhouse-gas emissions is possible. Concentration of certain species, such as unburned ethanol and acetaldehyde in the engine-out emissions are known to rise when ratio of ethanol to gasoline increases in the fuel. This research explores on hydrous ethanol fueled port-fuel injection (PFI) spark ignition (SI) engine emissions that contribute to photochemical formation of ozone, or so-called ozone precursors and the precursor of peroxyacetyl nitrates (PANs). The results are compared to engine operation on gasoline. Concentration obtained by FTIR gas analyzer, and mass-specific emissions of formaldehyde (HCHO), acetaldehyde (MeCHO) and methane (CH4) under two engine speed, four load and two spark advance settings are analyzed and presented.

Polyoxymethylene dimethyl ethers (PODEn) have high cetane number, high oxygen content and high volatility, therefore can be added to gasoline to optimize the performance and soot emission of Gasoline Compression Ignition (GCI) combustion. High speed imaging was used to investigate the spray and combustion process of gasoline/PODEn blends (PODEn volume fraction 0%-30%) under various ambient conditions and injection strategies in a constant volume vessel. Results showed that with an increase of PODEn proportion from 10% to 30%, liquid-phase penetration of the spray increased slightly, ignition delay decreased from 3.8 ms to 2.0 ms and flame lift off length decreased 29.4%, causing a significant increase of the flame luminance. For blends with 20% PODEn, when ambient temperature decreased from 893 K to 823 K, the ignition delay increased 1.3 ms and the flame luminance got lower.

The direct injection gasoline spray-wall interaction was characterized inside a heated pressurized chamber using various visualization techniques, including high-speed laser-sheet macroscopic and microscopic movies up to 25,000 frames per second, shadowgraph, and doublespark particle image velocimetry. Two hollow cone high-pressure swirl injectors having different cone angles were used to inject gasoline onto a heated plate at two different impingement angles. Based on the visualization results, the overall transient spray impingement structure, fuel film formation, and preliminary droplet size and velocity were analyzed. The results show that upward spray vortex inside the spray is more obvious at elevated temperature condition, particularly for the wide-cone-angle injector, due to the vaporization of small droplets and decreased air density. Film build-up on the surface is clearly observed at both ambient and elevated temperature, especially for narrow cone spray.

In this research, propane flash boiling sprays discharged from a five-hole gasoline direct injector were studied in a constant volume vessel. The fuel temperature (Tfuel) ranged from 30 °C to 90 °C, and the ambient pressure (Pamb) varied from 0.05 bar to 11.0 bar. Different flash boiling spray behavior compared to that under sub-atmospheric conditions was found at high Pamb. Specifically, at the sub-atmospheric pressures, the individual flashing jets merged into one single jet due to the strong spray collapse. In contrast, at Pamb above 3.0 bar and Tfuel above 50 °C, the spray collapse was mitigated and the flashing jets were separated from each other. Further analyses revealed that the mitigation of spray collapse at high Pamb was ascribed to the suppression of jet expansion. In addition, it was found that the spray structure was much different at similar Rp, indicating that Rp lacked the generality in describing the structure of flash boiling sprays.

The Coal-To-Liquid (CTL) synthetic aviation fuel, Iso-Paraffinic Kerosene (IPK), was studied for ignition delay, combustion delay, pressure trace, pressure rise rate, apparent heat release rate in an experimental single cylinder indirect injection (IDI) compression ignition engine and a constant volume combustion chamber (CVCC). Autoignition characteristics for neat IPK, neat Ultra-Low Sulfur Diesel (ULSD), and a blend of 50%IPK and 50% ULSD were determined in the CVCC and the effects of the autoignition quality of each fuel were determined also in an IDI engine. ULSD was found to have a Derived Cetane Number (DCN) of 47 for the batch used in this experimentation. IPK was found to have a DCN of 25.9 indicating that is has a lower affinity for autoignition, and the blend fell between the two at 37.5. Additionally, it was found that the ignition delay for IPK in the CVCC was 5.3 ms and ULSD was 3.56 ms.

An experimental setup using rapid compression machine to provide excellent optical access to visualize simulated high-speed small-bore direct injection diesel engine combustion processes is described. Typical combustion visualization results of diesel spray combustion under different EGR, swirl, and injection pressure and nozzle conditions are presented. Different swirl intensities are achieved using an air nozzle with variable orientations and a check valve to connect the compression chamber and the combustion chamber. Different EGR ratios are achieved by pre-injection of diesel fuel prior to the main observation sequence. Clear visualization of the high-pressure fuel injection, ignition, combustion and spray/wall/swirl interactions is obtained. The injection system is a high-pressure common-rail system with either a VCO or a mini-sac nozzle. High-speed movies up to 35,000 frame-per-second are taken using a framing drum camera to record the combustion events.

Wide Distillation Fuel (WDF), with a distillation range from Initial Boiling Point of gasoline to Final Boiling Point of diesel, can be easily gained directly by blending diesel with gasoline. However, the reduced auto-ignitability of WDF could lead to higher HC emissions. Polyoxymethylene Dimethyl Ethers (PODE), with good volatility and oxygen content of up to 49%, have great potential to improve combustion and emission characteristics, especially for soot reduction. Experiments were carried out in a light-duty four-cylinder diesel engine fueled with neat diesel, gasoline/diesel blends (GD), GD/PODE blends (GDP) and the combustion and emission characteristics were carefully examined. Results showed that GDP had the lowest PM emission and diesel had the poorest one among the three fuels. Due to the addition of gasoline and the relatively poor ignitability, GD had lower combustion efficiency and higher Soluble Organic Fraction (SOF) emissions than diesel.

Wide Distillation Fuel (WDF) refers to the fuels with a distillation range from initial boiling point of gasoline to final boiling point of diesel. Recent experimental results have shown WDF by blending 50% gasoline and 50% diesel (G50) exhibits much lower soot emissions than diesel at medium load with similar thermal efficiency. However, the engine performances fueled by G50 at both low load end and high load end are still unknown. In this study, the combustion and emission characteristics of G50 and diesel are compared over a wide load range from 0.2 MPa IMEP to 1.4 MPa IMEP at a light-duty diesel engine. The results shown that at 0.2 MPa IMEP, G50 exhibits low combustion stability and thermal efficiency. With the increase of load, the poor combustion quality of G50 is improved. G50 can achieve soot-free combustion up to 1.0 MPa IMEP, while diesel cannot.

This paper presents an experimental study of the emission characteristics of a small Spark-Ignited, LPG engine. A single cylinder, four-stroke, water-cooled, 125cc SI engine for motorcycle is modified for using LPG fuel. The power output of LPG is above 95% power output of gasoline. The emission characteristics of LPG are compared with the gasoline. The test result shows that LPG for small SI engine will help to reduce the emission level of motorcycles. The HC and CO emission level can be reduced greatly, but NOx emissions are increased. The emission of motorcycle using LPG shows the potential to meet the more strict regulation.

An air-cooled, four-stroke, 125 cc electronic gasoline fuel injection SI engine for motorcycles is altered to burn ethanol fuel. The effects of nozzle orifice size, fuel injection duration, spark timing and the excess air/ fuel ratio on engine power output, fuel and energy consumptions and engine exhaust emission levels are studied on an engine test bed. The results show that the maximum engine power output is increased by 5.4% and the maximum torque output is increased by 1.9% with the ethanol fuel in comparison with the baseline. At full load and 7000 r/min, HC emission is decreased by 38% and CO emission is decreased 46% on average over the whole engine speed range. However, NOx levels are increased to meet the maximum power output. The experiments of the spark timing show that the levels of HC and NOx emission are decreased markedly by the delay of spark timing.

This study compared the combustion and emission characteristics of Homogeneous Charge Compression Ignition (HCCI) and Direct Injection Compression Ignition (DICI) modes in a boosted and high compression ratio (17) engine fueled with gasoline and gasoline/diesel blend (80% gasoline by volume, denoted as G80). The injection strategy was adjusted to achieve the highest thermal efficiency at different intake pressures. The results showed that Low Temperature Heat Release (LTHR) was not observed in gasoline HCCI. However, 20% additional diesel could lower down the octane number and improve the autoignition reactivity of G80, which contributed to a weak LTHR, accounting for approximately 5% of total released heat. The combustion efficiency in gasoline DICI was higher than those in gasoline HCCI and G80 HCCI, while the exhaust loss and heat transfer loss in DICI mode were higher than those in HCCI mode.

Results of Computational Fluid Dynamic (CFD) analyses of different diesel fuel injector nozzle configurations using a commercial CFD code are presented here. The emphasis of this study is on comparing cavitation models available in the commercial code with respect to their mathematical approach. One of the models is a simple single-phase model based on the Barotropic equation of state, while the other model is a two-phase model based on the bubble dynamic considerations. Results are compared for various 3-D diesel injector nozzles using the two cavitation-modeling approaches. Simulation results are observed to substantiate some of the experimentally established facts like; nozzle efficiency improvements by using techniques like rounded orifice inlets and conical orifices. Also, simulation results agree well with the experimental results. Spray characteristics are predicted based on a primary breakup model.

Unburned hydrocarbon (UBHC) emissions from gasoline engines remain a primary engineering research and development concern due to stricter emission regulations. Gasoline engines produce more UBHC emissions during cold start and warm-up than during any other stage of operation, because of insufficient fuel-air mixing, particularly in view of the additional fuel enrichment used for early starting. Impingement of fuel droplets on the cylinder wall is a major source of UBHC and a concern for oil dilution. This paper describes an experimental study that was carried out to investigate the distribution and “footprint” of fuel droplets impinging on the cylinder wall during the intake stroke under engine starting conditions. Injectors having different targeting and atomization characteristics were used in a 4-Valve engine with optical access to the intake port and combustion chamber.

This paper studies the effect of nozzle geometry on the flow characteristics inside a diesel fuel injection nozzle and correlates to the subsequent atomization process under different operating conditions, using simple turbulent breakup model. Two kinds of nozzles, valve covered orifice (VCO) and mini-SAC nozzle, with various nozzle design parameters were studied. The internal flow inside the nozzle was simulated using 3-D computational fluid dynamics software with k-ε turbulence model. The flow field at the nozzle exit was characterized by two parameters: the fuel discharge coefficient Cd and the initial amplitude parameter amp0. The latter parameter represents the turbulence characteristics of the exit flow. The effects of nozzle geometry on the mean velocity and turbulent energy distribution of the exit flow were also studied. The characteristics of the exit flow were then incorporated into the spray model in KIVA-II to study the effect of nozzle design on diesel spray behavior.

Biodiesel has been widely accepted as an alternative for fossil-derived diesel fuel for use in compression ignition (CI) engines. Poor oxidative stability and cold flow properties restrict the use of biodiesel beyond current B20 blend levels (20% biodiesel in 80% ULSD) for vehicle applications. Maintaining the properties of B20 as specified by ASTM D7476-08 is important because, once out of spec, B20 may cause injector coke formation, fuel filter plugging, increased exhaust emissions, and overall loss of engine performance. While the properties of fresh B20 may be within the specifications, under engine operating and longer storage conditions B20 could deteriorate. In a diesel engine, the fuel that goes to the injector and does not enter the cylinder is recycled back to the fuel tank. The re-circulated fuel returns to the fuel tank at an elevate temperature, which can cause thermal oxidation.

The increase in regulatory demand to reduce CO2 emissions resulted in a focus on the development of novel combustion modes such as gasoline compression ignition (GCI). It has been shown by others that GCI can improve the overall engine efficiency while achieving soot and NOx emissions targets. In comparison with diesel fuel, gasoline has a higher volatility and has more resistance to autoignition, therefore, it has a longer ignition delay time which facilitates better mixing of the air-fuel charge before ignition. In this study, a GCI combustion system has been tested using a 2.2L compression ignition engine as part of a US Department of Energy funded project. For this purpose, a multiple injection strategy was developed to improve the pressure rise rates and soot emission levels for the same engine out NOx emissions.

Polyoxymethylene Dimethyl Ether (PODEn) is a promising green additive to diesel fuel, owing to the unique chemical structure (CH3O[CH2O]nCH3, n≥2) and high cetane number. Together with the general wide-distillation fuel (WDF), which has an attractive potential to reduce the cost of production of vehicle fuel, the oxygenated WDF with PODEn can help achieve a high efficiency and low emissions of soot, NOx, HC, and CO simultaneously. In this paper, the first detailed reaction mechanism (225 species, 1082 reactions) which can describe the ignition characteristics of PODE1 and PODE3 at low temperature was developed.