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In this paper a fast NOx model is presented which can be used for engine optimization, aftertreatment control or virtual mapping. A cylinder pressure trace is required as input data. High calculation speed is obtained by using table interpolation to calculate equilibrium temperatures and species concentrations. Test data from a single-cylinder engine and from a complete six-cylinder engine have been used for calibration and validation of the model. The model produces results of good agreement with emission measurements using approximately 50 combustion product zones and a calculation time of one second per engine cycle. Different compression ratios, EGR rates, injection timing, inlet pressures etc. were used in the validation tests.

In this paper, a theoretical study is presented where fuel rate shaping is analyzed in combination with EGR as a method for reducing NOx formation. The analytical tools used include an empirically based model to convert fuel rate to heat release rate, and a zero dimensional multizone combustion model to calculate combustion products, local flame temperatures and NOx emissions at a given heat release rate. The multizone model, which has been presented earlier, includes flame radiation and convective heat losses. Several geometrical shapes of the fuel rate are tested for different combustion timings and EGR rates. It is found that the fuel rate giving the lowest NOx formation varies with the injection timing. In order to lower the NOx emissions at normal and advanced injection timings, the fuel rate should have a rather long duration, and start at its maximum level followed by a slow decay.

A method for automatic reduction of detailed reaction mechanisms using simultaneous sensitivity, reaction flow and lifetime analysis has been developed and applied to a two-zone model of an SI engine fuelled with Primary Reference Fuel (PRF). Species which are less relevant for the occurrence of autoignition in the end gas are declared redundant. They are identified and eliminated for different pre-set minimum levels of reaction flow and sensitivity. The resulting skeletal mechanism is valid in the ranges of initial and boundary values for which the analyses have been performed. A measure of species lifetime is calculated from the chemical source terms, and the species with the lifetime shorter than and mass-fraction less than specified limits are selected for removal.

Homogeneous Charge Compression Ignition (HCCI) holds great promises for good fuel economy and low emissions of NOX and soot. The concept of HCCI is premixed combustion of a highly diluted mixture. The dilution limits the combustion temperature and thus prevents extensive NOX production. Load is controlled by altering the quality of the charge, rather than the quantity. No throttling together with a high compression ratio to facilitate auto ignition and lean mixtures results in good brake thermal efficiency. However, HCCI also presents challenges like how to control the combustion and how to achieve an acceptable load range. This work is focused on solutions to the latter problem. The high dilution required to avoid NOX production limits the mass of fuel relative to the mass of air or EGR. For a given size of the engine the only way to recover the loss of power due to dilution is to force more mass through the engine.

The objective of this paper is to investigate how the combustion chamber design will influence combustion parameters and emissions in a natural gas SI engine. Ten different geometries were tried on a converted Volvo TD102 engine. For the different combustion chambers emissions and the pressure in the cylinder have been measured. The pressure in the cylinder was then used in a one-zone heat-release model to get different combustion parameters. The engine was operated unthrottled at 1200 rpm with different values of air/fuel ratio and EGR. The air/fuel ratio was varied from stoichiometric to lean limit. EGR values from 0 to 30% at stoichiometric air/fuel ratio were used. The results show a remarkably large difference in the rate of combustion between the chambers. The cycle-to-cycle variations are fairly independent of combustion chamber design as long as there is some squish area and the air and the natural gas are well mixed.

A comparison of scanning mobility particle sizer (SMPS) and laser-induced incandescence (LII) measurements of diesel particulate matter (PM) was performed. The results reveal the significance of the aggregate nature of diesel PM on interpretation of size and volume fraction measurements obtained with an SMPS, and the accuracy of primary particle size measurements by LII. Volume fraction calculations based on the mobility diameter measured by the SMPS substantially over-predict the space-filling volume fraction of the PM. Correction algorithms for the SMPS measurements, to account for the fractal nature of the aggregate morphology, result in a substantial reduction in the reported volume. The behavior of the particulate volume fraction, mean and standard deviation of the mobility diameter, and primary particle size are studied as a function of the EGR for a range of steady-state engine speeds and loads for a turbocharged direct-injection diesel engine.

The cylinder to cylinder and cycle to cycle variations were measured in a production type Volvo natural gas engine. Cylinder pressure was measured in all six cylinders. Emission measurements were performed individually after all cylinders, and commonly after the turbocharger. Measurements (ECE R49 13-mode) were performed with different spark gap and two different locations for fuel injection, one before the throttle and one before the turbocharger. Heat-release and lambda calculations show substantial cylinder to cylinder variations, due to lambda variations between the cylinders. The slow burn combustion chamber, with low turbulence, results in high cycle to cycle variations (> 100% COV imep) for some of the load cases.

“Hot Bulb engines” was the popular name of the early direct injected 2-stroke oil engine, invented and patented by Carl W. Weiss 1897. This paper covers engines of this design, built under license in Sweden by various manufacturers. The continuous development is demonstrated through examples of different combustion chamber designs. The material is based on official engine performance evaluations on stationary engines and farm tractors from 1899 to 1995 made by the National Machinery Testing Institute in Sweden (SMP). Hot-bulb, diesel and spark ignited engines are compared regarding efficiency, brake mean effective pressure and specific power (power per displaced volume). The evaluated hot-bulb engines had a fairly good efficiency, well matching the contemporary diesel engines. At low mean effective pressures, the efficiency of the hot-bulb engines was even better than that of subsequent diesel engines.

This paper reports an one–dimensional modeling procedure of the hot spot autoignition with a detailed chemistry and multi–species transport in the end gas in an SI engine. The governing equations for continuity of mass, momentum, energy and species for an one–dimensional, unsteady, compressible, laminar, reacting flow and thermal fields are discretized and solved by a fully implicit method. A chemical kinetic mechanism is used for the primary reference fuels n–heptane and iso–octane. This mechanism contains 510 chemical reactions and 75 species. The change of the cylinder pressure is calculated from both flame propagation and piston movement. The turbulent velocity of the propagating flame is modeled by the Wiebe function. Adiabatic conditions, calculated by minimizing Gibb's free energy at each time step, are assumed behind the flame front in the burned gas.

An ionization sensor has been used to study the combustion process in a six-cylinder lean burn, truck-sized engine fueled with natural gas and optimized for low emissions of nitric oxides. The final goal of the investigations is to study the prospects of using the ionization sensor for finding the optimal operating position with respect to low NOx emission and stable engine operation. The results indicate that unstable combustion can be detected by analyzing the coefficient of variation (CoV) of the detector current amplitude. Close relationships between this measure and the CoV of the indicated mean effective pressure have been found during an air-fuel ratio scan with fixed ignition advance.

Two-dimensional cycle-resolved burnt gas temperatures were measured using two line atomic fluorescence (TLAF) in a single cylinder spark ignition car engine. Mapping of the in-cylinder flow was done under the same operating conditions using Particle Imaging Velocimetry (PIV). Experimental data for temperature and flow was compared to results from numerical simulations.

The present paper aims at discussing the flow/flame interaction in a lean burn spark ignition engine. The mean velocity and cycle resolved turbulence are measured with laser Doppler velocimetry. The cylinder pressure is recorded and a one-zone heat release calculation performed. The very early part of flame propagation is measured using two orthogonal Schlieren systems, each capturing one image of the progressing flame at a given time after spark onset. The two resulting 2D images are then, after preprocessing, used to reconstruct the three-dimensional flame. The volume of the true flame is estimated by simulating, using Markov Chain Monte Carlo techniques, a number of possible flames that are consistent with the projections on the images. The uncertainty of the estimated flame volume is given by the variation of the volume estimates. In the calculations, the volume of that part of the spark plug that is inside the flame is subtracted.

The fuel distribution in an air assist direct injection engine was measured with Planar Laser Induced Fluorescence, PLIF. The engine was fueled with isooctane and 3-pentanon was used as the fuel tracer. The optical engine was of the prolonged piston type, with a quartz ring in the upper part of the cylinder. Both the fuel injector and the spark plug were centrally located in the cylinder head. Two different pistons were examined: flat piston and bowl in piston. Results show that the differences in fuel stratification are very large for the flat piston compared to the piston with a bowl.

High-speed video imaging in a swirl-supported (Rs = 1.7), direct-injection heavy-duty diesel engine operated with moderate-to-high EGR rates reveals a distinct correlation between the spatial distribution of luminous soot and mean flow vorticity in the horizontal plane. The temporal behavior of the experimental images, as well as the results of multi-dimensional numerical simulations, show that this soot-vorticity correlation is caused by the presence of a greater amount of soot on the windward side of the jet. The simulations indicate that while flow swirl can influence pre-ignition mixing processes as well as post-combustion soot oxidation processes, interactions between the swirl and the heat release can also influence mixing processes. Without swirl, combustion-generated gas flows influence mixing on both sides of the jet equally. In the presence of swirl, the heat release occurs on the leeward side of the fuel sprays.

SI Engine knock is caused by autoignition in the unburnt part of the mixture (end-gas) ahead of the propagating flame. Autoignition of the end-gas occurs when the temperature and pressure exceeds a critical limit when comparatively slow reactions-releasing moderate amounts of heat-transform into ignition and rapid heat release. In this paper the difference in the heat released in the end-gas-by low temperature chemistry-between lean, rich, stochiometric, and stoichiometric mixtures diluted with cooled EGR was examined by measuring the temperature in the end-gas with Dual Broadband Rotational CARS. The measured temperature history was compared with an isentropic temperature calculated from the cylinder pressure trace. The experimentally obtained values for knock onset were compared with results from a two-zone thermodynamic model including detailed chemistry modeling of the end-gas reactions.

The Homogeneous Charge Compression Ignition (HCCI) is the third alternative for combustion in the Internal Combustion (IC) engines. Here, a homogeneous charge is used as in a spark ignited engine but the charge is compressed to auto-ignition as in a diesel. The characteristics of HCCI were compared to SI using a 1.6 liter single cylinder engine with compression ratio 21:1 in HCCI mode and 12:1 in SI mode. Three different fuels were used; isooctane, ethanol and natural gas. Some remarkable results were noted in the experiments: The indicated efficiency of HCCI was much better than for SI operation. Very little NOx was generated with HCCI, eliminating the need for a LeanNOx catalyst. However, HCCI generated more HC and CO than SI operation. Stable and efficient operation with HCCI could be obtained with λ=3 to λ=9 using isooctane or ethanol. Natural gas, with a higher octane number, required a richer mixture to run in HCCI mode.

A FeCrAlloy mesh-type catalyst has been used to reduce hydrocarbons (HC) and carbon monoxide (CO) emissions from a 4-stroke HCCI engine. Significant for the HCCI engine is a high compression ratio and lean mixtures, which leads to a high efficiency, low combustion temperatures and thereby low NOx emissions, <5 pmm, but also low exhaust temperatures, around 300°C. It becomes critical to: 1. Ensure that the HCCI-combustion generates as low HC emissions as possible, this can be done by very precise control of engine inlet conditions and, if possible, compression ratio. 2. Ensure that the exhaust temperature is high enough, without loosing efficiency or producing NOx; in order to get an oxidizing catalyst to work. 3. Select proper catalyst material for the catalyst so that the exhaust temperature can be as low as possible.

One way to extend the lean burn limit of a natural gas engine is by addition of hydrogen to the primary fuel. This paper presents measurements made on a one cylinder 1.6 liter natural gas engine. Two combustion chambers, one slow and one fast burning, were tested with various amounts of hydrogen (0, 5, 10 and 15 %-vol) added to natural gas. Three operating points were investigated for each combustion chamber and each hydrogen content level; idle, part load (5 bar IMEP) and 13 bar IMEP (simulated turbocharging). Air/fuel ratio was varied between stoichiometric and the lean limit. For each operating point, a range of ignition timings were tested to find maximum brake torque (MBT) and/or knock. Heat-release rate calculations were made in order to assess the influence of hydrogen addition on burn rate. Addition of hydrogen showed an increase in burn rate for both combustion chambers, resulting in more stable combustion close to the lean limit.

Cycle-resolved end-gas temperatures were measured using dual-broadband rotational CARS in a single-cylinder spark-ignition engine. Simultaneous cylinder pressure measurements were used as an indicator for knock and as input data to numerical calculations. The chemical processes in the end-gas have been analysed with a detailed kinetic mechanism for mixtures of iso-octane and n-heptane at different Research Octane Numbers (RON'S). The end-gas is modelled as a homogeneous reactor that is compressed or expanded by the piston movement and the flame propagation in the cylinder. The calculated temperatures are in agreement with the temperatures evaluated from CARS measurements. It is found that calculations with different RON'S of the fuel lead to different levels of radical concentrations in the end-gas. The apperance of the first stage of the autoignition process is marginally influenced by the RON, while the ignition delay of the second stage is increased with increasing RON.

This paper presents results from a quantitative characterization of the NO distribution in a SI engine fueled with a stoichiometric iso-octane/air mixture. Different engine operating conditions were investigated and accurate results on NO concentrations were obtained from essentially the whole cylinder for crank angle ranges from ignition to the mid expansion stroke. The technique used to measure the two-dimensional NO concentration distributions was laser induced fluorescence utilizing a KrF excimer laser to excite the NO A-X (0,2) bandhead. Results were achieved with high temporal and spatial resolution. The accuracy of the measurements was estimated to be 30% for absolute concentration values and 20% for relative values. Images of NO distributions could also be used to evaluate the flame development. Both the mean and the variance of a combustion progress variable could be deduced.