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The authors used a mass spectrometer to determine an SOF reduction mechanism of a diesel oxidation catalyst. The results indicate that SOF reduction lies in the catalytic conversion of high molecular organic matter to low molecular organic matter. And unregulated emissions are also reduced through this conversion. It is also found that the SOF reduction performance is highly dependent up on the condition of the wash coat. There is some limitation to improving diesel oxidation catalyst performance because of the sulfur content found in diesel fuel. Finally, the authors have determined what we think are the specifications of the presently best catalytic converter.

A characteristic mechanism of in-cylinder combustion is “time-domain mixing” which mixes up unburned gas, products in the different stages of combustion process, and burned gas, by “eddy”, a flow component with its scales of several to 10 mm. It seems to play a role in completing the combustion. Now that direct injection is a central engine technology, a keyword to combustion control is “freedom of mixing”, that is, no restriction on mixture formation, realized by direct injection. Various kinds of combustion control technologies utilizing it, have been presented. After combustion control for a premixed leanburn gasoline engine, and a direct injection gasoline engine, was achieved by turbulence control, and mixing control, respectively, the next target of combustion control will be ignition control. It will be possible, by controlling some boundary condition on combustion and fuel chemistry. Time-domain mixing and freedom of mixing will support it.

A new prototype oxygen storage componented oxygen sensor has been developed which shows significant emission reductions of a 3-way catalyst system. This sensor is composed of ceria, as an oxygen storage component and supported pellets as a buffer layer surrounding the protective coating of the sensor element. This sensor offers a more rapid response than conventional ones under lean and rich fuel mixture excursions, which is caused by CO or O2 electrode poisoning.

A Finite Element Method (FEM) simulation was conducted to predict energy-absorbing characteristics in an impact of a head form against plastic plates. Static and dynamic material tests were conducted in order to determine material properties of the plastics. The properties were applied in an explicit FEM code. The FEM results were validated through the impact tests by the head form against the same plastic plates. It was proved that the FEM could simulate the test result well, when the precise material properties were introduced in the simulation. The method can be expected to be available to predict energy-absorbing characteristics during the impact by the head form against automobile plastic components such as shell portions of instrument panels.

The accuracy of real-time A/F measurement at engine test benches has been improved with a modified equation to calculate A/F from exhaust gas composition. In addition to CO, CO2, total hydrocarbon (THC) and O2, the proposed equation includes NO and NO2 concentration as variables. In an attempt to improve the accuracy of the assumed constants in the equation, experiments have been conducted using automotive exhaust H2O and H2 analyzers. The accuracy of the proposed equation was proven through experiments and it was also found useful for precise evaluation of three-way catalyst or oxygen sensor characteristics.

Catalytic performance can be improved by increasing geometric surface area (GSA) and reducing bulk density (BD), namely heat capacity, using high cell-density / thinwall advanced ceramic substrates. The advanced substrates, such as 3 mil/600 cpsi and 2 mil/900 cpsi have improved the catalytic performance over the conventional substrates, and are expected to help in complying with future emission regulations, as well as catalyst downsizing. This paper describes the effects of GSA and BD using Pd-based catalysts. The reduction of hydrocarbons emissions was demonstrated significantly at close-coupled location, and dual bed design was proven effective. The effectiveness at under-floor location was not as significant as the close-coupled location.

The electrically-heated catalyst ( EHC ) has been established as an effective technology for lower-emission regulations. High electrical power consumption was a major concern for the EHC system in the past. This issue was addressed through the development of the EHC design and the alternator-powered EHC system combined with a light-off ( L/O ) catalyst. The subsequent challenges have been to prove the EHC's reliability and durability. NGK has developed a durable, extruded EHC for very severe exhaust system installations. In addition, the EHC's electrical connector system is required to meet high performance and reliability objectives under extreme environmental conditions unique to this application. This report describes the design concept of NGK's EHC including our new electrical connector system and durability results. In summary, the NGK EHC design concept has been confirmed to have excellent durability performance.

Ceramic honeycomb wall flow diesel particulate filters (DPF) have been investigated for use in exhaust gas control of diesel vehicles. However, before they can be used, prevention of thermal shock failure during combustion regeneration is necessary. Studies were conducted on thermal shock failures on 9-inch diameter large volume DPF during regeneration by finite element analyses (FEA). These studies reveal that, within safe limits, maximum thermal stress is almost constant even at different gas flow rates and oxygen concentrations. Regeneration tests were also conducted on large volume DPF of several materials having different pore size distributions. FEA thermal stress was compared with mechanical strength of the material at safe levels.

The future emission limits for gasoline fuelled passenger cars require more and more efficient exhaust gas aftertreatment devices - the catalytic converter being one essential part of the complex system design. The present paper summarizes the results of several basic research programs putting major emphasis on the application of highly sophisticated three-way catalyst technologies being taylored for the utilization on ultra thin-wall ceramic substrates. In the first part of the investigation the following effects were examined in detail: Different washcoat loadings at constant PGM-loadings Different volumes of catalysts for constant amounts of PGM and washcoat Similar washcoat technologies at different ratios of WC-loading to precious metal concentration in the washcoat.

As emissions regulations are becoming more stringent, various efforts to improve emission performance have been carried out in different areas including the honeycomb structure of catalytic converters. This report describes the development of a simulation tool to predict emission performance and simulation results for different cell structures. The simulation model was developed based on global kinetic chemical reaction model [1]. Having tuned the reaction parameters through a light-off test and estimated oxygen storage capacity through an oxygen storage test, we ultimately tuned the model in a vehicle test (with Bags 1 and 2, FTP 75). As a result, the simulated cumulative tailpipe emissions are within ±25 percent of the test results. Parameter analyses indicate that the amount of emissions decreased as the density of cells increased and that the amount of emissions also decreased the thinner the wall thicknesses were.

Applying micro-alloyed steel as a cost-effective method of forging engine parts eliminates quench and temper processes and saves energy. We have expanded this application to timing gears and crankshafts by changing the connecting rod material to carbon steel and vanadium, applied at the outset. Then, micro-alloyed steel treated with a soft nitriding process was used. Our recent studies have been focused on materials which exhibit both higher tensile strength and better machinability. This paper describes the results of applying different types of micro-alloyed steel to those engine parts.

Several different steel sheets were tested for energy absorption, using hat square columns and dynamic crash testing. Results indicate that steel sheets containing large volume fraction of retained austenite have relatively high energy absorption. The relationship between retained austenite and energy absorption was analyzed. These special steel sheets have already been successfully used for production body parts, such a front-side-member, without difficulties arising in volume production.

The adoption of the diesel engine EGR systems, and increased uses of alcohol in spark ignited engines require wear resistant and low maintenance valve trains. Silicon nitride ceramic inserts were pressureless-sintered and successfully die-cast in rocker arms contacting the overhead cams in the valve trains. As fired, the insert sliding surface was fine and precise, eliminating any further processing. The comosite structure was machined with the sliding surface as a reference plane. Beside inherent high wear resistance, these lighter inserts reduced inertial forces of the trains and the torque required to drive the cams. The hard, brittle ceramics and a softer, more elastic aluminum alloy made the structure more durable and reliable. The process of development includes characterization, screening, manufacturing and quality control of the materials, and determination of wear resistance and reliability for this new structure.

The authors developed, for use in diesel engines, ceramic tappets cast in aluminum alloy that drastically improved wear resistance and valve train dynamics. The ceramic tappets consist of two parts: a ceramic head, which contacts the cam and push rod, and a tappet body made of aluminum alloy. Concerning the ceramic, silicon nitride was the best material of the three ceramics evaluated in the tests and the sliding surface, in contact with the cam and push rod, was left unground. As for the aluminum alloy, hyper-eutectic aluminum-silicon alloy with a controlled pro-eutectic silicon size was selected. A reliability analysis using the finite-element method (FEM) was also made on the structure of the ceramic tappet for enhanced durability and reliability. The combination of this tappet and a cam made of hardened ductile cast iron, hardened steel, or chilled cast iron, respectively exhibits excellent wear resistance.

This paper describes a calculating method to predict the quasi-static collapsing behaviors of spot-welded closed-hat section curved beams under axial compression. The overall deformat ions and the local buckling modes of beams were calculated using a geometrical model. Force-displacement relations were predicted by a elastic-plastic structural analysis method using the ‘plastic hinge’ concept. Collapsing tests were made on beams which are differenting section size, rotation angle, and metal sheet thickness. Comparisons between the calculated and experimental results of deformed shapes of beams, the local buckling modes and the force displacement relations are discussed.

This paper proposes a high temperature manifold converter with a thin wall ceramic substrate, such as; 4mil/400cpsi and 4mil/600cpsi. Double-wall cone insulation design was proposed for close-coupled converters to protect the conventional intumescent mat from high temperature. However, the double wall cone insulation is not applicable when the converter is directly mounted to the exhaust manifold without an inlet cone. The prototype manifold converter was tested under hot vibration test with a non-intumescent ceramic fiber mat and retainer rings as a supplemental support. The converter demonstrated durability for 10 hours under 80G acceleration and 100 hours under 60G acceleration with 1,050 °C catalyst bed temperature. The skin temperature of the heat shield was kept below 400 °C.

This paper describes the results of the study and research on ovate wire helical springs which have been jointly conducted by the members of the Japan Society for Spring Research consisting of the engineers from material suppliers, wire and spring producers and automotive manufacturers as well as researchers at Japanese universities. Attention is focused particularly on two types of wire cross sections, typical elliptical shape and Fuchs' egg-shape. Stresses on these two cross sections were analyzed by numerical calculations within the range of practical specification, and then the results have been compared with those of round wire spring. As a result, it has been found that the elliptical wire spring is superior to Fuchs- egg-shaped one for general application. Simple designing methods for the both types of wire helical springs have been developed based on the findings from the stress analysis.

An investigation of anti-corrosion steel sheets (non-galvanized) which contain copper for automobile body parts has been conducted. Copper additives accelerate the formation of amorphous substrates. These substrates decrease the rate of corrosion. In order to retain the steel's formability and weldability, the contents of the alloying elements have been optimized. As a result, this newly developed steel sheet can be used for many different applications such as door sashes and door panels of mass produced cars. This paper describes the key properties of the newly developed steel sheet and additionally the mechanism of corrosion prevention, weldability, formability, and so on.

Austempered ductile iron (ADI) is a material having excellent mechanical properties and damping capacity. However practical mass production of ADI gears has not been possible due to ADI's poor machinability and distortion during the austempering heat treatment. With a new process method of carrying out hobbing before austempering when the material is in its soft condition, then austempering it and lastly, conducting the shave finishing process, we have diminished the above defects and developed practical ADI gears. These new gears generate less noise than ordinary nitrocarburized steel gears and are superior in pitting resistance.

When replacing a metal engine part with plastic, it is necessary to regard vibration damping as one of the important factors in terms of noise reduction as well as strength and heat resistance as being characteristics of the material. Plastics are far better for vibration damping than steel or aluminum, but this property is reduced by the addition of glassfiber-reinforced or high heat-resisting resins. We have taken notice of SMC (Sheet Molding Compound) which has the excellent strength and heat resistance properties and studied it in order to increase its vibration damping property. Since organic polymers show the peak value for vibration damping performance in the vicinity of the glass transition temperature (Tg), we studied a method to shift the Tg near the operating temperature region in order to improve the vibration damping property.