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Journal Article

1000-Hour Durability Evaluation of a Prototype 2007 Diesel Engine with Aftertreatment Using B20 Biodiesel Fuel

2009-11-02
2009-01-2803
A prototype 2007 ISL Cummins diesel engine equipped with a diesel oxidation catalyst (DOC), diesel particle filter (DPF), variable geometry turbocharger (VGT), and cooled exhaust gas recirculation (EGR) was tested at Southwest Research Institute (SwRI) under a high-load accelerated durability cycle for 1000 hours with B20 soy-based biodiesel blends and ultra-low sulfur diesel (ULSD) fuel to determine the impact of B20 on engine durability, performance, emissions, and fuel consumption. At the completion of the 1000-hour test, a thorough engine teardown evaluation of the overhead, power transfer, cylinder, cooling, lube, air handling, gaskets, aftertreatment, and fuel system parts was performed. The engine operated successfully with no biodiesel-related failures. Results indicate that engine performance was essentially the same when tested at 125 and 1000 hours of accumulated durability operation.
Technical Paper

Alternative Fuel Vehicle Fleet Buyer's Guide

1999-05-03
1999-01-1510
Fleet managers need a tool to assist them in assessing their need to comply with EPAct and to provide them with the ability to obtain information that will allow them to make alternative fuel vehicle purchasing decisions. This paper will describe the Web-based tool that will inform a fleet manager, based on their geographic location, the type of fleet they own or operate, and the number and types of vehicles in their fleet, whether or not they need to meet the requirements of EPAct, and, if so, the percentage of new vehicle purchases needed to comply with the law. The tool provides detailed specifications on available OEM alternative fuel vehicles, including the purchase cost of the vehicles, fuel and fuel system characteristics, and incentives and rebates surrounding the purchase of each vehicle. The full set of federal, state, and local incentives is made available through the tool, as well as detailed access to refueling site and dealership locations.
Journal Article

Biodiesel Impact on Engine Lubricant Dilution During Active Regeneration of Aftertreatment Systems

2011-12-06
2011-01-2396
Experiments were conducted with ultra low sulfur diesel (ULSD) and 20% biodiesel blends (B20) to compare lube oil dilution levels and lubricant properties for systems using late in-cylinder fuel injection for aftertreatment regeneration. Lube oil dilution was measured by gas chromatography (GC) following ASTM method D3524 to measure diesel content, by Fourier transform infrared (FTIR) spectrometry following a modified ASTM method D7371 to measure biodiesel content, and by a newly developed back-flush GC method that simultaneously measures both diesel and biodiesel. Heavy-duty (HD) engine testing was conducted on a 2008 6.7L Cummins ISB equipped with a diesel oxidation catalyst (DOC) and diesel particle filter (DPF). Stage one of engine testing consisted of 10 consecutive repeats of a forced DPF regeneration event. This continuous operation with late in-cylinder fuel injection served as a method to accelerate lube-oil dilution.
Technical Paper

Cost Comparison of Wind Energy Delivered as Electricity or Hydrogen for Vehicles

2013-04-08
2013-01-1038
A simple cost analysis framework compares hydrogen and electricity as energy carriers delivering wind energy to light-duty vehicles (LDVs). We compare four wind energy pathways within a 2040-2050 timeframe and at large scale: a dedicated electricity transmission pathway and three distinct wind-hydrogen delivery pathways. Our results suggest that wind-hydrogen pathways will tend to be more costly than pure electricity transmission pathways on a per-mile driven cost basis ($/mile), but to a greater or lesser degree depending upon the pathway. The additional cost could be warranted to the degree that the hydrogen pathway adds value to consumers through full performance fuel cell electric vehicles (FCEV) compared to plug-in electric vehicles (PEVs), or through reduced variability in wind energy supply. If these benefits add value beyond the incremental costs suggested by our simple cost framework, some shift toward co-production or even dedicated hydrogen wind farms may be warranted.
Technical Paper

Development of a Compression Ignition Heavy Duty Pilot-Ignited Natural Gas Fuelled Engine for Low NOx Emissions

2004-10-25
2004-01-2954
A heavy-duty compression ignition engine using EGR and pilot-ignited directly injected natural gas fueling was calibrated for low NOx emissions. A Cummins ISX engine using cooled EGR was fitted with a Westport HPDI™ fuel system and an oxidation catalyst. The base engine hardware was modified to increase EGR rates (up to 40%). The engine, rated at 336 kW (450 hp) and 2236Nm (1650 ft-lbs), was calibrated and tested over steady state and transient test cycles. Steady state testing over the ESC 13-mode test cycle resulted in weighted composite NOx emissions of 0.36 g/bhp-hr and particulate matter emissions of 0.04 g/bhp-hr. Transient testing over the US EPA specified FTP cycle resulted in average NOx emissions of 0.6 g/bhp-hr and PM emissions of 0.03 g/bhp-hr.
Technical Paper

Development of the HyStEP Device

2016-04-05
2016-01-1190
With the introduction of more fuel cell electric vehicles (FCEVs) on U.S. roadways, especially in California, the need for available hydrogen refueling stations is growing. While funding from the California Energy Commission is helping to solve this problem, solutions need to be developed and implemented to help reduce the time to commission a hydrogen station. The current practice of hydrogen station acceptance can take months because each vehicle manufacturer conducts their own testing and evaluation. This process is not practical or sufficient to support the timely development of a hydrogen fueling station network. To address this issue, as part of the Hydrogen Fueling Infrastructure Research and Station Technology (H2FIRST) Project Sandia National Laboratories and the National Renewable Energy Laboratory along with a team of stakeholders and contractor Powertech Labs has developed the Hydrogen Station Equipment Performance (HyStEP) Device.
Technical Paper

Effect of Biodiesel Blends on Urea Selective Catalytic Reduction Catalyst Performance with a Medium-Duty Engine

2008-10-06
2008-01-2484
Testing to investigate biodiesel's impact on the performance of a zeolite-based selective catalytic reduction (SCR) system was conducted. The tests employed a 2004 compliant Cummins ISB with common rail fuel injection, EGR, and variable geometry turbo. This 5.9L, 300HP engine was retrofitted with a Johnson-Matthey DPF + SCR (SCRT™) system. Testing was conducted over eight steady-state engine operating modes which provided a wide range of exhaust temperature and exhaust chemistry conditions. Fuels tested were a 2007 certification quality ultra-low sulfur diesel (ULSD), as well as a soy derived biodiesel in a B20 blend. B20 produced slightly lower catalyst temperatures and higher NO2:NOx ratios relative to ULSD, but no measureable difference in the overall NOx conversion over the SCR system. The dominant variable influencing SCR performance is the catalyst space velocity, which is unchanged with the use of B20.
Technical Paper

Effects of Heat of Vaporization and Octane Sensitivity on Knock-Limited Spark Ignition Engine Performance

2018-04-03
2018-01-0218
Knock-limited loads for a set of surrogate gasolines all having nominal 100 research octane number (RON), approximately 11 octane sensitivity (S), and a heat of vaporization (HOV) range of 390 to 595 kJ/kg at 25°C were investigated. A single-cylinder spark-ignition engine derived from a General Motors Ecotec direct injection (DI) engine was used to perform load sweeps at a fixed intake air temperature (IAT) of 50 °C, as well as knock-limited load measurements across a range of IATs up to 90 °C. Both DI and pre-vaporized fuel (supplied by a fuel injector mounted far upstream of the intake valves and heated intake runner walls) experiments were performed to separate the chemical and thermal effects of the fuels’ knock resistance. The DI load sweeps at 50°C intake air temperature showed no effect of HOV on the knock-limited performance. The data suggest that HOV acts as a thermal contributor to S under the conditions studied.
Journal Article

Expanding the Experimental Capabilities of the Ignition Quality Tester for Autoigniting Fuels

2010-04-12
2010-01-0741
This paper reports the development of new fuel ignition quality and combustion experiments performed using the Ignition Quality Tester (IQT). Prior SAE papers (961182, 971636, 1999-01-3591, and 2001-01-3527) documented the development of the IQT constant volume combustion chamber experimental apparatus to measure ignition qualities of diesel-type fuels. The ASTM International test method D6890 was developed around the IQT device to allow the rapid determination of derived cetane number (DCN). Interest in chemical kinetic models for the ignition of diesel and biodiesel model compounds is increasing to support the development of advanced engines and fuels. However, rigorous experimental validation of these kinetic models has been limited for a variety of reasons. Shock tubes and rapid compression machines are typically limited to premixed gas-phase studies, for example.
Journal Article

Field Evaluation of Biodiesel (B20) Use by Transit Buses

2009-10-06
2009-01-2899
The objective of this research project was to compare B20 (20% biodiesel fuel) and ultra-low-sulfur (ULSD) diesel-fueled buses in terms of fuel economy, vehicle maintenance, engine performance, component wear, and lube oil performance. We examined 15 model year (MY) 2002 Gillig 40-foot transit buses equipped with MY 2002 Cummins ISM engines. The engines met 2004 U.S. emission standards and employed exhaust gas recirculation (EGR). For 18 months, eight of these buses operated exclusively on B20 and seven operated exclusively on ULSD. The B20 and ULSD study groups operated from different depots of the St. Louis (Missouri) Metro, with bus routes matched for duty cycle parity. The B20- and ULSD-fueled buses exhibited comparable fuel economy, reliability (as measured by miles between road calls), and total maintenance costs. Engine and fuel system maintenance costs were also the same for the two groups after correcting for the higher average mileage of the B20 group.
Technical Paper

Impact of Biodiesel Blends on Fuel System Component Durability

2006-10-16
2006-01-3279
An ultra-low sulfur diesel (ULSD) fuel was blended with three different biodiesel samples at 5 and 20 volume percent. The biodiesel fuels were derived from rapeseed and soybean oils, and in addition, a highly oxidized biodiesel was prepared from the soy biodiesel by oxidation under controlled conditions. A set of five elastomers commonly used in automotive fuel systems were examined before and after immersion in the six test blends and base fuel at 60°C for 1000 hours. The elastomers were evaluated for hardness, tensile strength, volume change and compression. Injector wear tests were also conducted on the base petrodiesel fuel and the biodiesel blends using a 500-hour test method developed for this study. Bosch VE (in-line) rotary pumps were evaluated for wear after testing for 500 hours on the base fuel, B5 and B20 test fuels. Additionally, a test procedure was developed to accelerate wear on common rail pumps over 500 hours.
Journal Article

Impact of a Diesel High Pressure Common Rail Fuel System and Onboard Vehicle Storage on B20 Biodiesel Blend Stability

2016-04-05
2016-01-0885
Adoption of high-pressure common-rail (HPCR) fuel systems, which subject diesel fuels to higher temperatures and pressures, has brought into question the veracity of ASTM International specifications for biodiesel and biodiesel blend oxidation stability, as well as the lack of any stability parameter for diesel fuel. A controlled experiment was developed to investigate the impact of a light-duty diesel HPCR fuel system on the stability of 20% biodiesel (B20) blends under conditions of intermittent use and long-term storage in a relatively hot and dry climate. B20 samples with Rancimat induction periods (IPs) near the current 6.0-hour minimum specification (6.5 hr) and roughly double the ASTM specification (13.5 hr) were prepared from a conventional diesel and a highly unsaturated biodiesel. Four 2011 model year Volkswagen Passats equipped with HPCR fuel injection systems were utilized: one on B0, two on B20-6.5 hr, and one on B20-13.5 hr.
Journal Article

Impacts of Biodiesel Fuel Blends Oil Dilution on Light-Duty Diesel Engine Operation

2009-06-15
2009-01-1790
Increasing interest in biofuels—specifically, biodiesel as a pathway to energy diversity and security—have necessitated the need for research on the performance and utilization of these fuels and fuel blends in current and future vehicle fleets. One critical research area is related to achieving a full understanding of the impact of biodiesel fuel blends on advanced emission control systems. In addition, the use of biodiesel fuel blends can degrade diesel engine oil performance and impact the oil drain interval requirements. There is limited information related to the impact of biodiesel fuel blends on oil dilution. This paper assesses the oil dilution impacts on an engine operating in conjunction with a diesel particle filter (DPF), oxides of nitrogen (NOx) storage, a selective catalytic reduction (SCR) emission control system, and a 20% biodiesel (soy-derived) fuel blend.
Technical Paper

Impacts of Biofuel Blending on MCCI Ignition Delay with Review of Methods for Defining Cycle-by-Cycle Ignition Points from Noisy Cylinder Pressure Data

2021-04-06
2021-01-0497
Conventional diesel combustion, also known as Mixing-Controlled Compression Ignition (MCCI), is expected to be the primary power source for medium- and heavy-duty vehicles for decades to come. Displacing petroleum-based ultra-low-sulfur diesel (ULSD) as much as possible with low-net-carbon biofuels will become necessary to help mitigate effects on climate change. Neat biofuels may have difficulty meeting current diesel fuel standards but blends of 30% biofuel in ULSD show potential as ‘drop-in’ fuels. These blends must not make significant changes to the combustion phasing of the MCCI process if they are to be used interchangeably with neat ULSD. An important aspect of MCCI phasing is the ignition delay (ID), i.e. the time between the start of fuel injection and the initial premixed autoignition that initiates the MCCI process.
Technical Paper

Methylal and Methylal-Diesel Blended Fuels for Use in Compression-Ignition Engines

1999-05-03
1999-01-1508
“Gas-to-liquids” catalytic conversion technologies show promise for liberating stranded natural gas reserves and for achieving energy diversity worldwide. Some gas-to-liquids products are used as transportation fuels and as blendstocks for upgrading crude-derived fuels. Methylal (CH3-O-CH2-O-CH3), also known as dimethoxymethane or DMM, is a gas-to-liquid chemical that has been evaluated for use as a diesel fuel component. Methylal contains 42% oxygen by weight and is soluble in diesel fuel. The physical and chemical properties of neat methylal and for blends of methylal in conventional diesel fuel are presented. Methylal was found to be more volatile than diesel fuel, and special precautions for distribution and fuel tank storage are discussed. Steady state engine tests were also performed using an unmodified Cummins B5.9 turbocharged diesel engine to examine the effect of methylal blend concentration on performance and emissions.
Journal Article

Overcoming the Range Limitation of Medium-Duty Battery Electric Vehicles through the use of Hydrogen Fuel-Cells

2013-09-24
2013-01-2471
Battery electric vehicles possess great potential for decreasing lifecycle costs in medium-duty applications, a market segment currently dominated by internal combustion technology. Characterized by frequent repetition of similar routes and daily return to a central depot, medium-duty vocations are well positioned to leverage the low operating costs of battery electric vehicles. Unfortunately, the range limitation of commercially available battery electric vehicles acts as a barrier to widespread adoption. This paper describes the National Renewable Energy Laboratory's collaboration with the U.S. Department of Energy and industry partners to analyze the use of small hydrogen fuel-cell stacks to extend the range of battery electric vehicles as a means of improving utility, and presumably, increasing market adoption.
Technical Paper

Predicting the Fuel Economy Impact of “Cold-Start” for Reformed Gasoline Fuel Cell Vehicles

2003-06-23
2003-01-2253
Hydrogen fuel cell vehicles (FCVs) appear to be a promising solution for the future of clean and efficient personal transportation. Issues of how to generate the hydrogen and then store it on-board to provide satisfactory driving range must still be resolved before they can compete with conventional vehicles. Alternatively, FCVs could obtain hydrogen from on-board reforming of gasoline or other fuels such as methanol or ethanol. On-board reformers convert fuel into a hydrogen-rich fuel stream through catalytic reactions in several stages. The high temperatures associated with fuel processing present an engineering challenge to warm up the reformer quickly and efficiently in a vehicle environment. Without a special warmup phase or vehicle hybridization, the reformer and fuel cell system must provide all power to move the vehicle, including ¼ power in 30 s, and ½ power in 3 min to satisfy the Federal Test Procedure (FTP) cycle demands.
Technical Paper

Quantification of Biodiesel Content in Fuels and Lubricants by FTIR and NMR Spectroscopy

2006-10-16
2006-01-3301
The use of biodiesel requires the development of proper quantification procedures for biodiesel content in blends and in lubricants (fuel dilution in oil). Although the ester carbonyl stretch at 1746 wavenumbers (cm-1) is the most prominent band in the IR spectrum of biodiesel, it is difficult to use for quantification purposes due to a severe fluctuation of absorption strength from sample to sample, even at the same biodiesel content. We have demonstrated that the ester carbonyl fluctuation is not caused by variation in the ester alkyl chain length; but is most likely caused by the degree of hydrogen bonding of the ester functional group with water in the sample. Water molecules can form complexes with the ester compound affecting the strength of the ester carbonyl band. The impact of water on quantification of the biodiesel content of blends was significant, even for B100 samples that met the proposed ASTM D6751 water limit of 500 ppm by D6304 (Karl Fischer Methdod).
Technical Paper

Retail Infrastructure Costs Comparison for Hydrogen and Electricity for Light-Duty Vehicles

2014-04-01
2014-01-1969
Both hydrogen and plug-in electric vehicles offer significant social and environmental benefits to enhance energy security and reduce criteria and greenhouse gas emissions from the transportation sector. However, the rollout of electric vehicle supply equipment (EVSE) and hydrogen retail stations (HRS) requires substantial investments with high risks due to many uncertainties. We compare retail infrastructure costs on a common basis - cost per mile, assuming fueling service to 10% of all light-duty vehicles in a typical 1.5 million person city in 2025. Our analysis considers three HRS sizes, four distinct types of EVSE and two distinct EVSE scenarios. EVSE station costs, including equipment and installation, are assumed to be 15% less than today's costs. We find that levelized retail capital costs per mile are essentially indistinguishable given the uncertainty and variability around input assumptions.
Journal Article

Review: Fuel Volatility Standards and Spark-Ignition Vehicle Driveability

2016-03-14
2016-01-9072
Spark-ignition engine fuel standards have been put in place to ensure acceptable hot and cold weather driveability (HWD and CWD). Vehicle manufacturers and fuel suppliers have developed systems that meet our driveability requirements so effectively that drivers overwhelmingly find that their vehicles reliably start up and operate smoothly and consistently throughout the year. For HWD, fuels that are too volatile perform more poorly than those that are less volatile. Vapor lock is the apparent cause of poor HWD, but there is conflicting evidence in the literature as to where in the fuel system it occurs. Most studies have found a correlation between degraded driveability and higher dry vapor pressure equivalent or lower TV/L = 20, and less consistently with a minimum T50. For CWD, fuels with inadequate volatility can cause difficulty in starting and rough operation during engine warmup.
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