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Urea-selective catalytic reduction (SCR) catalysts are the leading aftertreatment technology for diesel engines, but there are major challenges associated with meeting future NOx emission standards, especially under transient drive cycle conditions that include large swings in exhaust temperatures. Here we present a simplified, transient, one-dimensional integral model of NOx reduction by NH₃ on a commercial small-pore Cu-zeolite urea-SCR catalyst for which detailed kinetic parameters have not been published. The model was developed and validated using data acquired from bench reactor experiments on a monolith core, following a transient SCR reactor protocol. The protocol incorporates NH₃ storage, NH₃ oxidation, NO oxidation and three global SCR reactions under isothermal conditions, at three space velocities and at three NH₃/NOx ratios.

In a conventional passenger vehicle, the AC system is the largest ancillary load. This paper proposes a novel control strategy to reduce the energy consumption of the air conditioning system of a conventional passenger car. The problem of reducing the parasitic load of the AC system is first approached as a multi-objective optimization problem. Starting from a validated control-oriented model of an automotive AC system, an optimization problem is formalized to achieve the best possible fuel economy over a regulatory driving cycle, while guaranteeing the passenger comfort in terms of cabin temperature and reduce the wear of the components. To complete the formulation of the problem, a set of constraints on the pressure in the heat exchanger are defined to guarantee the safe operation of the system. The Dynamic Programming (DP), a numerical optimization technique, is then used to obtain the optimal solution in form of a control sequence over a prescribed driving cycle.

An experimental study of the acoustic characteristics of automotive catalytic converters is presented. The investigation addresses the effects and relative importance of the elements comprising a production catalytic converter assembly including the housing, substrate, mat and seals. Attenuation characteristics are measured for one circular and one oval catalytic converter geometry, each having 400 cell per square inch substrates. For each geometry, experimental results are presented to address the effect of individual components in isolation, and in combination with other assembly components. Additional experiments investigate the significance of acoustic paths around the substrate and through the peripheral wall of the substrate. The experimental results are compared to address the significance of each component on the overall attenuation.

The effects of geometric parameters of open-cell aluminum foams on the performance of aluminum foam-phase change material (PCM) composites as heat sinks are investigated by experiments. Three types of open-cell aluminum 6061 foams with similar relative densities and different cell sizes are used. Paraffin is selected as the PCM due to its excellent thermal stability and ease of handling. The experimental results show that the performance of the heat sink is significantly affected by the surface area density of the aluminum foam. In general, as the surface area density of the foam increases, the performance of the heat sink is improved regardless of the current phase of the PCM.

In this paper, various micromechanics models based on actual microstructures of DP steels are examined in order to determine the reasonable range of martensite volume fraction where the methodology described in this study can be applied. For this purpose, various micromechanics-based finite element models are first created based on the actual microstructures of DP steels with different martensite volume fractions. These models are, then, used to investigate the influence of ductility of the constituent ferrite and martensite phases and also the influence of voids in the ferrite phase on the overall ductility of DP steels.

For multiphase advanced high strength steels (AHSS), the constituent phase properties play a crucial role in determining the overall mechanical behaviors. Therefore, it is important to accurately measure/estimate the constituent phase properties in the research of AHSS. In this study, a new nanoindentation-based inverse method that we developed was adopted in estimating the phase properties of a low alloy Quenching and Partitioning (Q&P) steel. A microstructure-based Finite Element (FE) model was also generated based on the Electron BackScatter Diffraction (EBSD) and Scanning Electron Microscopy (SEM) images of the Q&P steel. The phase properties estimated from nanoindentation were first compared with those estimated from in-situ High Energy X-Ray Diffraction (HEXRD) test and, then, employed in the generated FE model to examine whether they can be appropriately used as the input properties for the model.

Brønsted acidity of solution ion-exchanged and solid-state exchanged zeolites was compared for NaY, BaY, CaY, NaX, and CaX zeolites. These materials were chosen because they all exhibit catalytic activity in SCR of NOx in combination with a non-thermal plasma. Brønsted acidity was characterized qualitatively with retinol as an indicator dye. Our results show that the solid-state exchange using a chloride salt creates zeolites with lower acidity than zeolites obtained by conventional solution ion-exchange. NO2 adsorption was also found to create a significant quantity of acid sites at room temperature and a slight increase in acidity at 200°C. We speculate that the acid sites created by NO2 adsorption, because of their vicinity to metal cation sites in the zeolite, may lead to preferential reactions that lead to NOx reduction. BaY made by solution ion-exchange and BaY made by solid-state exchange using a chloride salt were tested for NOx reduction in a plasma-catalyst reactor system.

Recently, several studies conducted by automotive industry revealed the tremendous advantages of Advanced High Strength Steels (AHSS). TRansformation Induced Plasticity (TRIP) steel is one of the typical representative of AHSS. This kind of materials exhibits high strength as well as high formability. Analyzing the crack behaviour in TRIP steels is a challenging task due to the microstructure level inhomogeneities between the different phases (ferrite, bainite, austenite, martensite) that constitute these materials. This paper aims at investigating the fracture resistance of TRIP steels. For this purpose, a micromechanical finite element model is developed based on the actual microstructure of a TRIP 800 steel. Uniaxial tensile tests on TRIP 800 sheet notched specimens were also conducted and tensile properties and R-curves (Resistance curves) were determined.

The strain-induced diffusionless shear transformation of retained austenite to martensite during straining of transformation induced plasticity (TRIP) assisted steels increases strain hardening and delays necking and fracture leading to exceptional ductility and strength, which are attractive for automotive applications. A novel technique that provides the retained austenite volume fraction variation with strain with improved precision is presented. Digital images of the gauge section of tensile specimens were first recorded up to selected plastic strains with a stereo digital image correlation (DIC) system. The austenite volume fraction was measured by synchrotron X-ray diffraction from small squares cut from the gage section. Strain fields in the squares were then computed by localizing the strain measurement to the corresponding region of a given square during DIC post-processing of the images recorded during tensile testing.

Elastomeric joints are utilized in many automotive applications, and exhibit frequency and excitation amplitude dependent properties. Current methods commonly identify only the cross-point joint property using displacement excitation at stepped single frequencies. This process is often time consuming and is limited to measuring a single dynamic stiffness term of the joint stiffness matrix. This study focuses on developing tractable laboratory inverse experiments to identify frequency dependent stiffness matrices up to 1000 Hz. Direct measurements are performed on a commercial elastomer test system and an inverse experiment consisting of an elastic beam (with a square cross section) attached to a cylindrical elastomeric joint. Sources of error in the inverse methodology are thoroughly examined and explained through simulation which include ill-conditioning of matrices and the sensitivity to modeling error.

A comparison of welding techniques was performed to determine the most effective method for producing aluminum tailor-welded blanks for high volume automotive applications. Aluminum sheet was joined with an emphasis on post weld formability, surface quality and weld speed. Comparative results from several laser based welding techniques along with friction stir welding are presented. The results of this study demonstrate a quantitative comparison of weld methodologies in preparing tailor-welded aluminum stampings for high volume production in the automotive industry. Evaluation of nearly a dozen welding variations ultimately led to down selecting a single process based on post-weld quality and performance.

Due to the lack of biofidelity seen in GHBMC M50-O in rear-facing impact simulations involving interaction with the seat back in an OEM seat, it is important to explore how the boundary conditions might be affecting the biofidelity and potentially formulate methods to improve biofidelity of different occupant models in the future while also maintaining seat validity. This study investigated the influence of one such boundary condition, which is the seat back foam material properties, on the thorax and pelvis kinematics and injury outcomes of the GHBMC 50th M50-O model in a high-speed rear-facing frontal impact scenario, which involves severe occupant loading of the seat back. Two different seat back foam materials were used – a stiff foam with high densification and a soft foam with low densification. The peak magnitudes of the T-spine resultant accelerations of the GHBMC M50-O increased with the use of soft foam as compared to stiff foam.

This paper presents two methods of characterizing and describing the formability of tailor welded blanks (TWB). The first method involves using miniature tensile specimens, extracted from TWB weld material, to quantify mechanical properties and material imperfection within TWB welds. This technique combines statistical methods of describing material imperfection together with conventional M-K method modeling techniques to determine safe forming limit diagrams for weld material. The second method involves the use of an extended M-K method modeling technique, which places multiple material thickness and material imperfections inside one overall model of TWB performance. These methods of describing TWB formability and their application to specific aluminum TWB populations are described.

Experimental results are presented for a technique of converting Diesel fuel to a gas stream rich in carbon monoxide and hydrogen suitable for Lean NOx Trap (LNT) regeneration. The device is relatively simple and relies upon a premixed, rich flame to generate gas with 4.5% H2 and 10% CO. The device, referred to as a flame reformer, offers a number of advantages over other methods of reductant generation for bypass regeneration LNT systems. Specifically, the device offers rapid dynamic response, potential lower cost, with a similar level of performance to other proposed methods of reductant generation.

A double dielectric barrier discharge reactor driven by an alternating voltage is a relatively simple approach to promote oxidation of NO to NO2 for subsequent reduction in a catalyst bed. The chemical performance of such a non-thermal plasma reactor is determined by its current and electric field behavior in the gap, and by the fraction of the current carried by electrons, because the key reactants which initiate the NO oxidation and accompanying chemical changes are produced there, mostly by electron impact. We have tried to determine by models and experiments the bounds on performance of double dielectric barrier reactors and guidelines for optimization. Models reported here predict chemical results from time-resolved applied voltage and series sense capacitor data.

Recent work has shown that energy efficiencies as well as yields and selectivities of the NOx reduction reaction can be enhanced by combining a plasma discharge with select catalysts. While analysis of gas phase species with a chemiluminescent NOx meter and mass spectrometer show that significant removal of NOx is achieved, high background concentrations of nitrogen preclude the measurement of nitrogen produced from NOx reduction. Results presented in this paper show that N2 from NOx reduction can be measured if background N2 is replaced with helium. Nitrogen production results are presented for a catalyst system where the catalyst is in the plasma region and where the catalyst is downstream from the plasma. The amount of N2 produced is compared with the amount of NOx removed as measured by the chemiluminescent NOx meter. The measured nitrogen from NOx reduction accounts for at least 40% of the total NOx removed for both reactor configurations.

Diesel particulate samples were collected from a light duty engine operated at a single speed-load point with a range of biodiesel and conventional fuel blends. The oxidation reactivity of the samples was characterized in a laboratory reactor, and BET surface area measurements were made at several points during oxidation of the fixed carbon component of both types of particulate. The fixed carbon component of biodiesel particulate has a significantly higher surface area for the initial stages of oxidation, but the surface areas for the two particulates become similar as fixed carbon oxidation proceeds beyond 40%. When fixed carbon oxidation rates are normalized to total surface area, it is possible to describe the oxidation rates of the fixed carbon portion of both types of particulates with a single set of Arrhenius parameters. The measured surface area evolution during particle oxidation was found to be inconsistent with shrinking sphere oxidation.

Characterization of the plastic and ductile fracture behavior of a ferrous casting commonly used for the steering knuckle of an automotive suspension system is presented in this work. Ductile fracture testing for various coupon geometries was conducted to simulate a wide range of stress states. Failure data for the higher stress triaxiality were obtained from tension tests conducted on thin flat specimens, wide flat specimens and axisymmetric specimens with varying notch radii. The data for the lower triaxiality were generated from thin-walled tube specimens subjected to torsional loading and compression tests on cylindrical specimens. The failure envelopes for the material were developed utilizing the test data and finite element (FE) simulations of the corresponding test specimens. Experiments provided the load-displacement response and the location of fracture initiation.

Hydraulic bushings with amplitude sensitive and spectrally varying properties are commonly used in automotive suspension. However, scientific investigation of their dynamic properties has been mostly limited to linear system based theory, which cannot capture the significant amplitude dependence exhibited by the devices. This paper extends prior literature by introducing a nonlinear fluid compliance term for reduced-order bushing models. Quasi-linear models developed from step sine tests on an elastomeric test machine can predict amplitude dependence trends, but offer limited insight into the physics of the system. A bench experiment focusing on the compliance parameter isolated from other system properties yields additional understanding and a more precise characterization.

The application of hydraulic body mounts between a pickup truck frame and cab to reduce freeway hop and smooth road shake has been documented in literature and realized in production vehicles. Previous studies have demonstrated the potential benefits of these devices, often through iterative prototype evaluation. Component dynamic characterization has also shown that these devices exhibit significant dependence to preload and dynamic amplitude; however, analysis of these devices has not addressed these dependences. This paper aims to understand the amplitude and preload dependence on the spectrally-varying properties of a production hydraulic body mount. This double-pumping, three-spring mount construction has a shared compliant element between the two fluid-filled chambers.