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Hydrogen engines are currently considered as a viable solution to preserve the internal combustion engine as a power unit for vehicle propulsion. In particular, lean-burn gasoline Spark-Ignition (SI) engines have been a major subject of investigations due to the reduced emission levels and high thermodynamic efficiency. This strategy is suitable for the purpose of passenger car applications and cannot be tailored in the field of high performance engine, where the air mass delivered would require oversized turbocharging systems or more complex charging solutions. For this reason, the range of stoichiometric feeding condition is explored in the high performance engine, leading to the consequent issue of abatement of pollutant emissions. In this work a 1D model will be applied to the modeling of a V8 engine fueled with DI of hydrogen. The engine has been derived by a gasoline configuration and adapted to hydrogen in such a way to keep the same performance.

The continuous pursuit of higher combustion efficiencies, as well as the possible usage of synthetic fuels with different properties than fossil-ones, require reliable and low-cost numerical approaches to support and speed-up engines industrial design. In this context, SI engines operated with homogeneous ultra-lean mixtures both characterized by a classical ignition configuration or equipped with an active prechamber represent the most promising solutions. In this work, for the classical ignition arrangement, a 3DCFD strategy to model the impact of the ignition system type on the CCV is developed using the RANS approach for turbulence modelling. The spark-discharge is modelled through a set of Lagrangian particles, whose velocity is modified with a zero-divergence perturbation at each discharge event, then evolved according to the Simplified Langevin Model (SLM) to simulate stochastic interactions with the surrounding gas flow.

Active prechamber combustion systems for SI engines represent a feasible and effective solution in reducing fuel consumption and pollutant emissions for both marine and ground heavy-duty engines. However, reliable and low-cost numerical approaches need to be developed to support and speed-up their industrial design considering their geometry complexity and the involved multiple flow length scales. This work presents a CFD methodology based on the RANS approach for the simulation of active prechamber spark-ignition engines. To reduce the computational time, the gas exchange process is computed only in the prechamber region to correctly describe the flow and mixture distributions, while the whole cylinder geometry is considered only for the power-cycle (compression, combustion and expansion). Outside the prechamber the in-cylinder flow field at IVC is estimated from the measured swirl ratio.

A correct prediction of the initial stages of the combustion process in SI engines is of great importance to understand how local flow conditions, fuel properties, mixture stratification and ignition affect the in-cylinder pressure development and pollutant formation. However, flame kernel growth is governed by many interacting processes including energy transfer from the electrical circuit to the gas phase, interaction between the plasma channel and the flow field, transition between different combustion regimes and gas expansion at very high temperatures. In this work, the authors intend to present a comprehensive, multi-dimensional model that can be used to predict the initial combustion stages in SI engines. In particular, the spark channel is represented by a set of Lagrangian particles where each one of them acts as a single flame kernel.

SI engines fueled with hydrogen represent a promising powertrain solution to meet the ambitious target of carbon-free emissions at the tailpipe. Therefore, fast and reliable numerical tools can significantly support the automotive industry in the optimization of such technology. In this work, a 1D-3D methodology is presented to simulate in detail the combustion process with minimal computational effort. First, a 1D analysis of the complete engine cycle is carried out on the user-defined powertrain configuration. The purpose is to achieve reliable boundary conditions for the combustion chamber, based on realistic engine parameters. Then, a 3D simulation of the power-cycle is performed to mimic the combustion process. The flow velocity and turbulence distributions are initialized without the need of simulating the gas exchange process, according to a validated technique.

Pursuing a sustainable energy scenario for transportation requires the blending of renewable oxygenated fuels such as alcohols into commercial hydrocarbon fuels. From a chemical kinetic perspective, this requires the accurate description of both hydrocarbon reference fuels (n-heptane, iso-octane, toluene, etc.) and oxygenated fuels chemistry. A recent systematic investigation of linear C2-C5 alcohols ignition in a rapid compression machine at p = 10-30 bar and T = 650- 900 K has extended the scarcity of fundamental data at such conditions, allowing for a revision of the low temperature chemistry for alcohol fuels in the POLIMI mechanism. Heavier alcohols such as n-butanol and n-pentanol present ignition characteristic of interest for application in HCCI engines, due to the presence of the hydroxyl moiety reducing their low temperature reactivity compared to the parent linear alkanes (i.e. higher octane number).

In this paper the low temperature reduction process of nitrates stored at high temperatures over model Pt-Ba/Al2O3 LNT catalysts using both H2 and C3H6 is analyzed. The results indicate that over the Pt-Ba/Al2O3 catalyst the reduction of stored NOx with both H2 and C3H6 occurs at temperature below those corresponding to their thermal stability. Accordingly, the reduction process occurs through a Pt-catalyzed surface reaction, which does not involve, as a preliminary step, the thermal decomposition of the adsorbed NOx species. The occurrence of such a pathway also requires the co-presence of the storage element and of the noble metal on the same support.

The accurate prediction of pollutant emissions generated by IC engines is a key aspect to guarantee the respect of the emission regulation legislation. This paper describes the approach followed by the authors to achieve a strict numerical coupling of two different 1D modeling tools in a co-simulation environment, aiming at a reliable calculation of engine-out and tailpipe emissions. The main idea is to allow an accurate 1D simulation of the unsteady flows and wave motion inside the intake and exhaust systems, without resorting to an over-simplified geometrical discretization, and to rely on advanced thermodynamic combustion models and kinetic sub-models for the calculation of cylinder-out emissions. A specific fluid dynamic approach is then used to track the chemical composition along the exhaust duct-system, in order to evaluate the conversion efficiency of after-treatment devices, such as TWC, GPF, DPF, DOC, SCR and so on.

Increasing demands on the capabilities of engine simulation and the ability to accurately predict both performance and acoustics has lead to the development of several numerical tools to help engine manufacturers during the prototyping stage. The aid of CFD tools (3D and 1D) can remarkably reduce the duration and the costs of this stage. The need of achieving good accuracy, along with acceptable computational runtime, has given the spur to the development of a geometry based quasi-3D approach. This is designed to model the acoustics and the fluid dynamics of both intake and exhaust system components used in internal combustion engines. Models of components are built using a network of quasi-3D cells based primarily on the geometry of the system. The solution procedure is based on an explicitly time marching staggered grid approach making use of a flux limiter to prevent numerical instabilities.

In the recent years, the interest in heavy-duty engines fueled with Compressed Natural Gas (CNG) is increasing due to the necessity to comply with the stringent CO2 limitation imposed by national and international regulations. Indeed, the reduced number of carbon atoms of the NG molecule allows to reduce the CO2 emissions compared to a conventional fuel. The possibility to produce synthetic methane from renewable energy sources, or bio-methane from agricultural biomass and/or animal waste, contributes to support the switch from conventional liquid fuels to CNG. To drive the engine development and reduce the time-to-market, the employment of numerical analysis is mandatory. This requires a continuous improvement of the simulation models toward real predictive analyses able to reduce the experimental R&D efforts. In this framework, 1D numerical codes are fundamental tools for system design, energy management optimization, and so on.

The tightening trend of regulations on the levels of admitted pollutant emissions has given a great spur to the research work in the field of combustion and after-treatment devices. Despite the improvements that can be applied to the development of the combustion process, pollutant emissions cannot be reduced to zero; for this reason, the aftertreatment system will become a key component in the path to achieving near-zero emission levels. This study focuses on the numerical analysis and optimization of different metallic substrates, specifically developed for three-way catalyst (TWC) and Diesel oxidation catalyst (DOC) applications, to improve their thermal efficiency by reducing radial thermal losses through the outer mantle. The optimization process relies on computational fluid dynamics (CFD) simulations supported by experimental measurements to validate the numerical models carried out under uncoated conditions, where chemical reactions do not occur.

This paper exploits the possibilities of achieving an efficient performance optimization methodology to be applied to different spark ignition engine configurations. The objective of the task described here is to determine the combination of parameters which provides the highest volumetric efficiency and effective torque. The definition of general strategy requires first the identification and grouping of the geometric and operating variables to be optimized (duct diameters and lengths, valve timing, spark advance, etc…). The high number of possibilities entails critical choices to reduce, from an engineering design point of view before than from a mathematical point of view, the required computational time. Once proper thermo-fluid dynamic decisions are taken, the most efficient optimization methodology is required. The application of Design of Experiments techniques allows to screen the design space and give a first estimation of the optimal point.

Multiple injections and high EGR rates are now widely adopted for combustion and emissions control in passenger car diesel engines. In a wide range of operating conditions, fuel is provided through one to five separated injection events, and recirculated gas fractions between 0 to 30% are used. Within this context, fast and reliable multi-dimensional models are necessary to define suitable injection strategies for different operating points and reduce both the costs and time required for engine design and development. In this work, the authors have applied a modified version of the characteristic time-scale combustion model (CTC) to predict combustion and pollutant emissions in diesel engines using advanced injection strategies. The Shell auto-ignition model is used to predict auto-ignition, with a suitable set of coefficients that were tuned for diesel fuel.

The reduction of the catalyst light-off time at the engine cold start represents a key factor for the pollutant emissions control from vehicles tested on homologation cycles and real drive conditions. The adoption of heating strategies to increase the temperature of the catalytic substrate in the early phase of the engine start is regarded as a promising solution. The present study focuses on the application of electrical heated catalyst (EHC) in an after-treatment line for a spark-ignition gasoline engine. The analysis is carried out by means of an advanced CFD framework, which includes the modeling of catalytic reactions in the substrates and accounts for the thermal evolution of all the components included in the after-treatment system.

In the last years, as a response to the more and more restrictive emission legislation, new devices (SRC, DOC, NOx-trap, DPF) have been progressively introduced as standard components of modern after-treatment system for Diesel engines. In addition, the adoption of electrical heating is nowadays regarded with interest as an effective solution to promote the light-off of the catalyst at low temperature, especially at the start-up of the engine and during the low load operation of the engine typical of the urban drive. In this work, a state-of-the-art 48 V electrical heated catalyst is considered, in order to investigate its effect in increasing the abatement efficiency of a standard DOC. The electrical heating device considered is based on a metallic support, arranged in a spiral layout, and it is heated by the Joule effect due to the passage of the electrical current.

The abatement of carbon dioxide and pollutant emissions on motorbike spark-ignition (SI) engines is a challenging task, considering the small size, the low cost and the high power-to-weight ratio required by the market for such powertrain. In this context, the passive pre-chamber (PPC) technology is an attractive solution. The combustion duration can be reduced by igniting the air-fuel mixture inside a small volume connected to the cylinder, unfolding the way to high engine efficiencies without penalization of the peak performance. Moreover, no injectors are needed inside the PPC, guaranteeing a cheap and fast retrofitting of the existing fleet. In this work, a 3D computational fluid dynamics (CFD) investigation is carried out over an experimental configuration of motorbike SI engine, operated at fixed operating conditions with both traditional and PPC configurations.

The thorough understanding of the effects due to the fuel direct injection process in modern gasoline direct injection engines has become a mandatory task to meet the most demanding regulations in terms of pollutant emissions. Within this context, computational fluid dynamics proves to be a powerful tool to investigate how the in-cylinder spray evolution influences the mixture distribution, the soot formation and the wall impingement. In this work, the authors proposed a comprehensive methodology to simulate the air-fuel mixture formation into a gasoline direct injection engine under multiple operating conditions. At first, a suitable set of spray sub-models, implemented into an open-source code, was tested on the Engine Combustion Network Spray G injector operating into a static vessel chamber. Such configuration was chosen as it represents a typical gasoline multi-hole injector, extensively used in modern gasoline direct injection engines.

Predictive combustion models are useful tools towards the development of clean and efficient engines operating with alternative fuels. This work intends to validate two different combustion models on compression-ignition engines fueled with Dimethyl Ether. Both approaches give a detailed characterization of the combustion kinetics, but they substantially differ in how the interaction between fluid-dynamics and chemistry is treated. The first one is single-flamelet Representative Interactive Flamelet, which considers turbulence-kinetic interaction but cannot correctly describe the stabilization of the flame. The second, named Tabulated Well Mixed, correctly accounts for local flow and mixture conditions but does not consider interaction between turbulence and chemistry. An experimental campaign was carried out on a heavy-duty truck engine running on DME at a constant load considering trade-off of EGR and SOI.

The employment of hydrogen as energy carrier for transportation sector represents a significant challenge for powertrains. Spark-ignition (SI) engines are feasible and low-cost devices to convert the hydrogen chemical energy into mechanical work. However, significant efforts are needed to successfully retrofit the available configurations. The computational fluid dynamics (CFD) modelling represents a useful tool to support experiments, clarifying the impact of the engine characteristics on both the mixture preparation and the combustion development. In this work, a CFD investigation is carried out on typical light-duty SI engine configurations, exploring the two main strategies of hydrogen addition: port fuel injection (PFI) and direct injection (DI). The purpose is to assess the behaviour of widely-used numerical models and methodologies when hydrogen is employed instead of traditional carbon-based fuels.

NH₃/urea SCR is a very effective and widely used technology for the abatement of NOx from diesel exhaust. The SCR mechanism is well understood and the catalyst behavior can be predicted by mathematical models - as long as operation above the temperature limit for AdBlue® injection is considered. The behavior below this level is less understood. During the first seconds up to minutes after cold start, complete NOx abatement can be observed over an SCR catalyst in test bench experiments, together with a significant increase in temperature after the converter (ca. 100 K). In this work these effects have been investigated over a monolith Cu-zeolite SCR catalyst. Concentration step experiments varying NO, NO₂ and H₂O have been carried out in lab scale, starting from room temperature. Further, the interaction of C₃H₆ and CO with NOx over the SCR has been investigated.