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Reduction of nitrogen oxides in Diesel exhaust gas is a challenging task. This paper reports results from an extensive study using Pt-based catalysts involving synthetic gas activity testing (SCAT), engine bench testing and tests on passenger cars. Preliminary SCAT work highlighted the importance of Pt-dispersion, and both SCAT and bench engine testing yielded comparable NOx conversions under steady state conditions at high HC:NOx ratios. On passenger cars in the European cycle without secondary fuel injection NOx conversion was lower than obtained in the steady state tests. Better conversion was obtained in the FTP cycle, where secondary injection was employed. Higher HC:NOx, ratios and more favourable temperature conditions which were present in the exhaust contributed to this higher conversion.

Enhancements in the thermal stability of three-way catalysts have been achieved by: 1) developing improved methods for the incorporation of ceria into catalyst formulations and 2) identifying a proprietary stabilizer which reduces the rate of ceria sintering at high temperature. Improvements in thermal stability are demonstrated by comparing the FTP and engine dynamometer performance of new formulations with a standard formulation after aging on several high temperature engine dynamometer cycles.

It has long been recognized that the key to achieving stringent emission standards such as ULEV is the control of cold-start hydrocarbons. This paper describes a new approach for achieving excellent cold-start hydrocarbon control. The most important component in the system is a catalyst that is highly active at ambient temperature for the exothermic CO oxidation reaction in an exhaust stream under net lean conditions. This catalyst has positive order kinetics with respect to CO for CO oxidation. Thus, as the concentration of CO in the exhaust is increased, the rate of this reaction is increased, resulting in a faster temperature rise over the catalyst.

A test programme has been conducted to study any potential long term effects of gasoline sulphur on catalyst performance, using a newly developed transient engine-bed ageing cycle. The ageing cycle, which was based on repeated European Extra Urban Drive Cycles, was chosen to ensure that the catalyst experienced a realistically wide range of temperatures and space velocities, together with transients, idle and periods of overrun. Two nominally identical platinum/rhodium catalysts (manufactured from the same batch) with matched lambda sensors, were aged for a period of 80,000 km each, one being aged using a gasoline containing 50 mg/kg (ppm wt) sulphur, the other being aged on the same fuel doped to 450 ppm wt S. The emissions performance of both catalysts was measured after 6,000, 40,000 and 80,000 km ageing, by fitting the catalysts to a test vehicle, and performing emissions tests over the European test cycle at both sulphur levels.

Studies using a bi-fuelled (autogas/gasoline) Renault Laguna vehicle meeting °the 1996 European exhaust emission legislation has demonstrated that over the European test cycle at 25°C the LPG operated vehicle provides substantial benefits of reduced emissions compared to unleaded reference gasoline. At lower test temperatures (i.e. 5°C) even larger reduction in emissions have been observed. Lower CO (up to 95% at -5°C and 65% at 25°C), HC (90% at -5°C and 40% at 25°C) emissions and lower ozone HC reactivity have been observed and could all offer significant environmental air-quality benefits for LPG. Various autogas mixtures have been tested including 70/30, 30/70 and 49/30/21 (% mass propane / butane / propene). Results show that NOx emissions for this vehicle appear dependent on autogas composition. The two gas mixtures containing only 30% butane gave about 50% more NOx at +25°C than the 70% butane autogas mixture.

This paper describes the use of advanced three-way catalysts to meet future European and California low emissions legislation. Firstly, it describes the performance of these catalysts tested using the European Stage II test cycle and contrasts their emissions performance over the proposed European Stage III test. The future legislation requires fast catalyst light-off for the low emissions standards to be achieved, therefore the performance of close-coupled catalysts was investigated. The close-coupled catalyst systems gave very low emissions. Space constraints often preclude the use of large volume close-coupled catalysts, and the combination of a small starter catalyst with an underfloor catalyst was tested. This gave performance levels better than the close-coupled configuration. The effect of reducing the underfloor catalyst volume is also described. The work was carried out on a 1.2 litre European Vehicle, the conclusions were verified on a 1.6 litre European vehicle.

Various types of after-treatment system for BS VI Stage 1 are being assessed for the Light Duty Diesel (LDD) segment. For BS VI Stage 2, Real Driving Emission (RDE) assessment will be newly introduced, which will require more robustness in emission control system capability. Although the detailed requirements for India BS VI stage 2 are still being discussed, a reasonable assumption is that similar systems to those being developed for Euro 6d, will work for India BS VI. This paper describes typical system designs for Euro 6d and also reveals newly developed SCRF® (Selective Catalytic Reduction Filter) based systems, which demonstrate excellent RDE emissions. In addition, newly developed Lean NOx Trap (NSC) coatings, which focus on low temperature NOx control used with SCRF® (NSC + SCRF®) also show excellent emission control capability as demonstrated in this case on the ARTEMIS Cycle. These systems have potential as promising LDD solutions for India BS VI stage 2.

A comparison of two different types of NOx reducing catalysts will be worked out. The potential of two De-NOx catalysts using engine out hydrocarbon emissions for NOx conversion will be shown by variation of different engine parameters. An analysis of the hydrocarbon species upstream and downstream catalyst will demonstrate, which components are responsible for the NOx reduction in the exhaust gas of a lean burn engine. By variation of different parameters during adsorbtion and regeneration phases of the adsorber catalyst the efficiency in NOx reduction will be optimized. An assessment of the suitability for lean burn engines will consider the emission reduction efficiency as well as the influence on engine fuel consumption.

0D-1D codes allow researchers to obtain a prediction of the behavior of internal combustion engines with little computational effort. One of the submodels of such codes is devoted to the centrifugal compressor. This model is often based on the compressor performance maps, therefore requiring the extrapolation of the maps so that all possible operating conditions are covered. Particularly, a suitable extrapolation of isentropic efficiency map is sought. This work first examines different available methods for compressor efficiency extrapolation into off-design conditions. No method is found to provide satisfactory results at all extrapolated regions: low and high compressor speeds and low compression ratio at measured speeds. Hence, a new method is proposed and its accuracy is assessed with the aid of compressor off-design measurements.

Reducing NOx tailpipe emissions is one of the major challenges when developing automotive Diesel engines which must simultaneously face stricter emission norms and reduce their fuel consumption/CO2 emission. In fact, the engine control system has to manage at the same time the multiple advanced combustion technologies such as high EGR rates, new injection strategies, complex after-treatment devices and sophisticated turbocharging systems implemented in recent diesel engines. In order to limit both the cost and duration of engine control system development, a virtual engine simulator has been developed in the last few years. The platform of this simulator is based on a 0D/1D approach, chosen for its low computational time. The existing simulation tools lead to satisfactory results concerning the combustion phase as well as the air supply system. In this context, the current paper describes the development of a new NOx emission model which is coupled with the combustion model.

The implementations of the Tier 2 and LEVII emission levels require fast catalyst light-off and fast closed loop control through high-speed engine management. The paper describes the development of innovative catalyst designs. During the development thermal and mechanical boundary conditions were collected and component tests conducted on test rigs to identify the emission and durability performance. The products were evaluated on a Super Imposed Test Setup (SIT) where thermal and mechanical loads are applied to the test piece simultanously and results are compared to accelerated vehicle power train endurance runs. The newly developed light-off catalyst with Perforated Foil Technology (PE) showed superior emission light-off characteristic and robustness.

This paper describes the development of new high performance three-way catalyst (TWC) formulations with improved activity and enhanced thermal stability. These new TWC formulations enable the converter to be fitted closer to the engine and allow this future legislation to be met with catalysts using PGM levels significantly lower than those currently being employed. The performance benefits of these advanced platinum- and palladium-based catalysts are demonstrated on a number of different vehicles after bench-engine ageing.

A test method, based on parallel sample testing with exhaust fuel injection and certain test procedures, has been developed for diesel lean-NOx catalyst evaluation purposes. The results of the verification tests show uniform distribution of both the exhaust gas and the injected fuel, and a high degree of fuel evaporation. Test procedures are discussed from several points of view. The test method offers a precise and efficient way of testing lean-NOx catalysts on heavy duty diesel engines.

The Particulate Measurement Programme (PMP) works on the identification of a method to replace or complete the existing particle mass (PM) measurement method. The French PMP subgroup, composed by IFP, PSA Peugeot-Citroën, Renault and UTAC, proposes an improved gravimetric method for the measurement of emitted particles, and conducted an inter-laboratory test to evaluate its performances. The technical programme is based on tests carried out on a Euro3 Diesel passenger car (PC), tested on the New European Driving Cycle (NEDC). To achieve low particulate matter (PM) emissions, the EGR is disconnected and a paraffinic fuel is used. The regulated pollutants are also measured. It is shown that the multiple filter weighing and a 0.1 μg balance instead of a 1 μg one are not necessary, as the first weighing and the 1 μg balance performances are satisfactory for type-approval purposes.

The emissions performance of catalytic converters under different conditions of flow distribution was investigated. Computational Fluid Dynamics methods were utilised to model the maldistribution effects of different inlet cones. The effects of maldistribution on ageing, light-off and conversion were investigated using steady state tests on an engine bench. Emission testing was also conducted on a vehicle throughout ECE and EUDC test cycles. Maldistribution was found to have a significant effect on the efficiency of the catalyst during the early stages of the ECE cycle for both fresh and aged catalysts. The effects were less significant over later stages of the ECE cycle and throughout the EUDC except NOx where maldistribution did have an effect on the conversion at higher flow rates during the later stages of the test.

Since its creation in 1996, Euroncap evaluated more than 80 cars, ranging from small and city cars, to larger vehicles such as executive cars and people carriers (MPVs). The testing protocol comprises 3 types of tests: a frontal offset test against a deformable barrier, a 90° lateral impact with a moving deformable barrier, and - since March 2000 - a pole side impact. In addition a set of subsystem tests with impactors on the bonnet and the front face of the car are conducted to assess the pedestrian protection. The aim of this paper is to review the testing and assessment protocols and to compare them with those used in other NCAP systems in the USA, Australia, Japan and Europe. In particular, important Euroncap issues such as the stiffness of heavier vehicles that could be increased in the future, and the nature and weight of the modifiers are discussed. Ways to improve the system are suggested in relation with real-world accident data.

One possibility to improve the fuel economy of SI-engines is to run the engine with a lean air-fuel-ratio (AFR). Hydrocarbon and carbon monoxide after-treatment has been proven under lean operation, but NOx-control remains a challenge to catalyst and car manufacturers. One strategy that is being considered is to run the engine lean with occasional operation at stoichiometry. This would be in conjunction with a three-way-catalyst (TWC) to achieve stoichiometric conversion of the three main pollutants in the normal way and a NOx trap. The NOx trap stores NOx under lean operation to be released and reduced under rich conditions. The trap also functions as a TWC and has good HC and CO conversion at both lean and stoichiometric AFR's. Under lean conditions NO is oxidised to NO2 on Pt which is then adsorbed on an oxide surface. Typical adsorbent materials include oxides of potassium, calcium, zirconium, strontium, lanthanum, cerium and barium.

This paper presents an investigation on the experimental determination of some characteristics of the flow issuing from a swirl injector dedicated to direct-injection spark-ignited engines. The reproducibility, from one injection to another, of the temporal evolution of the liquid flow characteristics during the opening of the injector was investigated. This was achieved by using a high-speed film camera set at 8,000 images/s. The resulting visualizations allowed us to measure the evolution of the penetration length and velocity as well as of the liquid cone angle. It was found that the spray produced is a low momentum spray whose penetration length and velocity are small. The good reproducibility of the temporal evolution of the liquid flow characteristics has been obtained, except for the liquid cone angle during the opening stage. A fast-shutter video camera was also used to make images of the early development of the issuing liquid flow.

The influence of catalyst volume, cell density and precious metal loading on the catalyst efficiency were investigated to design a low cost catalyst system. In a first experiment the specific loading was kept constant for a 500cpsi and a 900cpsi substrate. In a second experiment the palladium loading was reduced on the 900cpsi substrate and the same PM loading was applied to a 1200cpsi substrate with lower volume. Finally the loading was further reduced for the 1200cpsi substrate. The following parameters were studied after aging: Catalyst performance of standard cell density compared to high cell density technology Light-off performance and catalyst efficiency as a function of Palladium loading and substrate cell density Catalyst efficiency as a function of AFR biasing The performance of the aged catalysts was investigated in a lambda sweep test and in light-off tests at an engine bench.

Six 2001 International Class 6 trucks participated in a project to determine the impact of gas-to-liquid (GTL) fuel and catalyzed diesel particle filters (DPFs) on emissions and operations from December 2003 through August 2004. The vehicles operated in Southern California and were nominally identical. Three vehicles operated “as-is” on California Air Resources Board (CARB) specification diesel fuel and no emission control devices. Three vehicles were retrofit with Johnson Matthey CCRT® (Catalyzed Continuously Regenerating Technology) filters and fueled with Shell GTL Fuel. Two rounds of emissions tests were conducted on a chassis dynamometer over the City Suburban Heavy Vehicle Route (CSHVR) and the New York City Bus (NYCB) cycle. The CARB-fueled vehicles served as the baseline, while the GTL-fueled vehicles were tested with and without the CCRT filters. Results from the first round of testing have been reported previously (see 2004-01-2959).