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The purpose of present numerical study was to extend the operating range of alcohol (methanol and ethanol) fueled Homogeneous Charge Compression Ignition (HCCI) engine under low load conditions. Ignition of pure methanol and ethanol under HCCI mode of operation requires high intake temperatures and misfires at low loads are common in HCCI engines. Three methods have been adapted to optimize the use of methanol and ethanol for HCCI operation without increasing the intake temperature. First, blending methanol and ethanol with ignition improver, namely di-methyl ether (DME) and di-ethyl ether (DEE), was used to increase the cetane number and ignitability of premixed charge. Second, based on the blended fuels, the spark assistance was used to reduce required intake temperature for auto-ignition. Third, DME and DEE were directly injected to methanol and ethanol operated HCCI engine, in the form of Reactivity Controlled Compression Ignition (RCCI) combustion.

Ammonia has attracted the attention of a growing number of researchers in recent years. However, some properties of ammonia (e.g., low laminar burning velocity, high ignition energy, etc.) inhibit its direct application in engines. Several routes have been proposed to overcome these problems, such as oxygen enrichment, partial fuel cracking strategy and co-combustion with more reactive fuels. Improving the reactivity of ammonia from the oxidizer side is also practical. Ozone is a highly reactive oxidizer which can be easily and rapidly generated through electrical plasma and is an effective promoter applicable for a variety of fuels. The dissociation reaction of ozone increases the concentration of reactive radicals and promotes chain-propagating reactions. Thus, obtaining accurate rate constants of reactions related to ozone is necessary, especially at elevated to high pressure range which is closer to engine-relevant conditions.

To achieve higher efficiencies and lower emissions, dual-fuel strategies have arisen as advanced engine technologies. In order to fully utilize engine fuels, understanding the combustion chemistry is urgently required. However, due to computation limitations, detailed kinetic models cannot be used in numerical engine simulations. As an alternative, approaches for developing reduced reaction mechanisms have been proposed. Nevertheless, existing simplified methods neglecting the real engine combustion processes, which is the ultimate goal of reduced mechanism. In this study, we propose a novel simplified approach based on fuel reactivity. The high-reactivity fuel undergoes pyrolysis first, followed by the pyrolysis and oxidation of the low-reactivity fuel. Therefore, the simplified mechanism consists of highly lumped reactions of high-reactivity fuel, radical reactions of low-reactivity fuel and C0-C2 core mechanisms.

Increasingly strict emission regulations and unfavorable economic climate bring severe challenges to the energy conservation of marine low-speed engine. Besides traditional methods, the energy and exergy analysis could acknowledge the losses of fuel from a global perspective to further improve the engine efficiency. Therefore, the energy and exergy analysis is conducted for a marine low-speed engine based on the experimental data. Energy analysis shows the exhaust gas occupies the largest proportion of all fuel energy waste, and it rises with the increment of engine load. The heat transfer consumes the second largest proportion, while it is negatively correlated to engine load. The energy analysis indicates that the most effective way to improve the engine efficiency is to reduce the energy wasted by exhaust gas and heat transfer. However, the latter exergy analysis demonstrates that there are other effective approaches to improve the engine efficiency.

Computational fluid dynamics (CFD) modeling has many potentials for the design and calibration of modern and future engine concepts, including facilitating the exploration of operation conditions and casting light on the involved physical and chemical phenomena. As more attention is paid to the matching of different fuel types and combustion strategies, the use of detailed chemistry in characterizing auto-ignition, flame stabilization processes and the formation of pollutant emissions is becoming critical, yet computationally intensive. Therefore, there is much interest in using tabulated approaches to account for detailed chemistry with an affordable computational cost. In the present work, the tabulated flamelet progress variable approach (TFPV), based on flamelet assumptions, was investigated and validated by simulating constant-volume Diesel combustion with primary reference fuels - binary mixtures of n-heptane and iso-octane.

Combustion and emission characteristics of diesel and biodiesel blends (soybean methyl ester) were studied in a single-cylinder Direct Injection (DI) engine at different loads and a constant speed. The results show that NOx emission and fuel consumption are increased with increasing biodiesel percentage. Reduction of smoke opacity is significant at higher loads with a higher biodiesel ratio. Compared with the baseline diesel fuel, B20 (20% biodiesel) has a slight increase of NOx emission and similar fuel consumption. Smoke emission of B20 is close to that of diesel fuel. Results of combustion analysis indicate that start of combustion (SOC) for biodiesel blends is earlier than that for diesel. Higher biodiesel percentage results in earlier SOC. Earlier SOC for biodiesel blends is due to advanced injection timing from higher density and bulk modulus and lower ignition delay from higher cetane number.

It has been found that the spray impingement on piston for SIDI engines significantly influences engine emission and combustion efficiency. Fuel film sticking on the wall will dramatically cause deterioration of engine friction performance, incomplete combustion, and substantial cycle-to-cycle variations. When increasing the injection pressure, these effects are more pronounce. Besides, the ambient pressure also plays an important role on the spray structure and influences the footprint of impinging spray on the plate. However, the dynamic behavior of impinging spray and corresponding film was not investigated thoroughly in previous literature. In this study, simultaneous measurements of macroscopic structure (side view) and its corresponding footprint (bottom view) of impinging spray was conducted using a single-hole, prototype injector in a constant volume chamber.

In this paper, the characteristics of performance and emissions of diesel and biodiesel blends are studied in a four-cylinder DI engine employing common rail injection system. The results show that engine output power is further reduced and brake specific fuel consumption (BSFC) increased with the increase of the blend concentration. B100 provides average reduction by 8.6% in power and increase by 11% in BSFC. With respect to the emissions, although NOx emissions were increased with increasing the blend concentration, the increase depends on the load. Filter smoke number is reduced with increasing the blend concentration. At the same time, NO, NO2 and other specific emissions are also investigated. In addition, difference of performance and emission between standard parameters of ECU and modified parameters of ECU is investigated for B10 and B20 based on same output power. The results show that NOx emission and FSN are still lower than baseline diesel.

In this paper, characteristics of gas emission and particle size distribution are investigated in a common rail diesel engine fueled with biodiesel blends. Gas emission and particle size distribution are measured by AVL FTIR - SESAM and SMPS respectively. The results show that although biodiesel blends would result in higher NOx emissions, characteristics of NOx emissions were also dependent on the engine load for waste cooking oil methyl ester. Higher blend concentration results in higher NO2 emission after two diesel oxidation catalyst s (DOC). A higher blend concentration leads to lower CO and SO2 emissions. No significant difference of Alkene emission is found among biodiesel blends. The particle size distributions of diesel exhaust aerosol consist of a nucleation mode (NM) with a peak below 50N• m and an accumulation mode with a peak above 50N • m. B100 will result in lower particulates with the absence of NM.

Increasingly stringent emission standards have promoted the interest in alternate fuel sources. Because of the comparable energy density to the existing fossil fuels and renewable production, alcohol fuels may be a suitable replacement, or an additive to the gasoline/diesel fuels to meet the future emission standards with minimal modification to current engine geometry. In this research, the combustion characteristics of neat n-butanol are analyzed under spark ignition operation using a single cylinder SI engine. The fuel is injected into the intake manifold using a port-fuel injector. Two modes of charge dilution were used in this investigation to test the limits of stable engine operation, namely lean burn using excess fresh air and exhaust gas recirculation (EGR). The in-cylinder pressure measurement and subsequently, heat release analysis are used to investigate the combustion characteristics of the fuel under low load SI engine operation.

To alleviate the shortage of petroleum resources and the air pollution caused by the burning of fossil fuels, the development of renewable fuels has attracted widespread attention. Among the various renewable fuels, ethanol can be produced from biomass and does not require much modification when applied to practical engines, so it has been widely used. However, ethanol fuel has a higher heat of vaporization than gasoline, it is difficult to evaporate and atomize under cold start conditions. Besides, the catalyst has not reached the conversion temperature at this time, resulting in lower conversion efficiency. These factors all lead to higher pollutant emission levels in ethanol-gasoline blends. To solve the above problems, this research used visualization techniques to compare the effects of flash boiling and high-energy ignition technologies on the in-cylinder combustion process and pollutant emission of ethanol-gasoline blends fuel.

An air-cooled, four-stroke, 125 cc electronic gasoline fuel injection SI engine for motorcycles is altered to burn ethanol fuel. The effects of nozzle orifice size, fuel injection duration, spark timing and the excess air/ fuel ratio on engine power output, fuel and energy consumptions and engine exhaust emission levels are studied on an engine test bed. The results show that the maximum engine power output is increased by 5.4% and the maximum torque output is increased by 1.9% with the ethanol fuel in comparison with the baseline. At full load and 7000 r/min, HC emission is decreased by 38% and CO emission is decreased 46% on average over the whole engine speed range. However, NOx levels are increased to meet the maximum power output. The experiments of the spark timing show that the levels of HC and NOx emission are decreased markedly by the delay of spark timing.

In the present study a novel surrogate model for biodiesel including methyl decanoate (MD) and methyl crotonate (MC) was proposed and validated. In the binary mixture of surrogate fuel, MD was chosen to represent saturated methyl esters, which exhibited great low-temperature reactivity with typical negative temperature-coefficient (NTC) behavior and MC represented unsaturated components in real biodiesel, which was mainly responsible for soot formation and evolution. The proportion of MD and MC was determined by matching the characteristics such as derived cetane number (DCN), molecular weight (MW), atom number, H/C ratio and unsaturated degree. All of the criterions were calculated by the least square principles and the calculated surrogate of biodiesel was comprised of 92% MD and 8% MC in mole fraction. Furthermore, detailed kinetic model of the surrogate fuel was constructed and developed with modifications, which was composed of 2918 species and 9164 reactions.

This paper examines the diesel-ethanol dual fuel combustion at medium engine loads on a single-cylinder research diesel engine with a compression ratio of 16.5:1. The effect of exhaust gas recirculation (EGR) and ethanol energy ratio was investigated for the dual fuel combustion to achieve simultaneously ultra-low NOx and soot emissions. A medium ethanol ratio of about 0.6 was found suitable to meet the requirements for mixing enhancement and ignition control, which resulted in the lowest NOx and soot emissions among the tested ethanol ratios. A double-pilot injection strategy was found competent to lower the pressure rise rate owing to the reduced fuel quantity in the close-to-TDC injection. The advancement of pilot injection timing tended to reduce the CO and THC emissions, which is deemed beneficial for high EGR operations. The reactivity mutual-modulation between the diesel pilot and the background ethanol mixture was identified.

Combustion instability often occurs inside the combustion chamber of aero engine. Fuel atomization and evaporation, one of the controlling processes of combustion rate, is an important mechanism of the combustion instability. To tackle combustion instability, it challenges a deep understanding of the underlying mechanism of fuel atomization and evaporation. In this paper, acoustic field was established to simulate the pressure oscillation. Transient spray images of ethanol and kerosene were recorded using high-speed camera. The obtained images were processed by MATLAB to extract and analyze the related data. Spatial fuel atomization characteristics was analytically examined by multi-threshold image method to analyze the effect of the high frequency acoustic field on the fuel break-up and disintegration. The results show that the half spray cone angle on the side with speaker is suppressed by the presence of the imposed acoustic field compared with the case without speaker.

Ignition quality tester (IQT) is a standard experimental device to determine ignition delay time of liquid fuels in a controlled environment in the absence of gas exchange. The process involves fuel injection, spray breakup, evaporation and mixing, which is followed by auto-ignition. In this study, three-dimensional computational fluid dynamics (CFD) is used for prediction of auto-ignition characteristics of diethyl ether (DEE) and ethanol. In particular, the sensitivity of the ignition behavior to different injection rate profiles is investigated. Fluctuant rate profile derived from needle lift data from experiments performs better than square rate profile in ignition delay predictions. DEE, when used with fluctuant injection rate profile resulted in faster ignition, while for ethanol the situation was reversed. The contrasting results are attributed to the difference in local mixing.

Increasing the injection pressure in DISI engine is an efficient way to obtain finer droplets but it will also potentially cause spray impingement on the cylinder wall and piston. Consequently, the fuel film sticking on the wall can dramatically increase the soot emission of the engine especially in a cold start condition. On the other hand, ethanol is widely used as an alternative fuel in DI engine due to its sustainable nature and high octane number. In this study, the fuel film characteristics of single-plume ethanol impinging spray was investigated. The experiments were performed under ultra-low fuel/plate temperature to simulate the cold start condition in cold areas. A low temperature thermostatic bath combined with specially designed heat exchangers were used to achieve ultra-low temperature for both the impinging plate and the fuel. Laser induced fluorescence (LIF) technique was employed to measure the thickness of fuel film deposited on the impinging plate.

Applications of methanol and biodiesel in internal combustion engines have raised widespread concerns, but there is still huge scope for improvement in efficiency and emissions. The brand-new combustion mode, named as Intelligent Charge Compression Ignition (ICCI) combustion, was proposed with methanol-biodiesel dual fuel direct injection. In this paper, effects of injection parameters such as two-stage split-injections, injection timings, injection pressure and intake pressure on engine combustion and emissions were investigated at IMEP = 8, 10, and 12 bar. Results show that the indicated thermal efficiency up to 53.5% and the NOx emissions approaching to EURO VI standard can be obtained in ICCI combustion mode.

As the vehicle emission regulations become stricter worldwide, one way to meet the emission requirements is to engage the use of alternative fuels in engine combustion. In this investigation, the early combustion processes of regular gasoline and alternative fuels, including ethanol and butanol, were studied by simultaneously recording both the in-cylinder pressure and the crank angle-resolved high-speed flame images in a single-cylinder spark-ignition direct-injection engine. The engine was equipped with a quartz insert in the piston which provided an optical access to its cylinder through the piston. The effects of engine coolant & oil temperatures and intake air swirl ratio on the early flame development were also studied. The heat release was derived from the in-cylinder pressure measurements and the corresponding flame area characteristics were extracted from the images.

A segment of steel tube with the inner diameter of 60 mm and length of 100 mm was fixed between the intake manifold and cylinder head in a direct injection natural aspirated diesel engine. The surface of the tube could be heated to be above 400 °C by the heater enwrapped outside within several minutes under the power less than 600 W. The tip of an injector traditionally used for in-cylinder diesel direct injection was extended to the axis of the tube. The diesel sprays could impinge onto the hot inner surface of the tube and atomize quickly if the temperature of the tube was high enough. Then the fuel-air mixture would be sucked into the cylinder, and HCCI combustion could be fulfilled. The vaporization ratio of the impinged diesel sprays was estimated by fuel consumption, intake air flux and excess air coefficient (λ) calculated from the volumetric concentration of O2, CO2 and CO emissions. The NOx emission was always very low.