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Engine and vehicle tailpipe emissions can be measured in laboratories equipped with engine dynamometers and chassis dynamometers, respectively. In addition to laboratory testing, there is an increase in interest to measure on-road vehicle emissions using portable emissions measurement systems in order to determine real-driving emissions. Current methods to quantify engine, vehicle tailpipe, and real-driving emissions include the raw continuous, dilute continuous, and dilute bag measurement methods. Although the dilute bag measurement method is robust, recent improvements to the raw and dilute continuous measurement methods can account for the time delay between the probe tip and analyzer in addition to gas transport dynamics in order to reliably recover the tailpipe concentration signals. These improvements significantly increase the reliability of results using the raw and dilute continuous measurement methods, making them possible alternatives to the bag method.

The described investigation was carried out under the umbrella of IEA Advanced Motor Fuels Agreement. The purpose was to evaluate the emissions of carbon monoxide (CO), unburned hydrocarbons (HC), nitrogen oxides (NOx), particulate matter (PM) and polycyclic aromatic hydrocarbons (PAH) from vehicles fuelled by Fischer Tropsch (FT) based diesel and gasoline fuel, compared to the emissions from ordinary diesel and gasoline. The comparison for diesel fuels was based on a literature review, whereas the gasoline comparison had to be based on our own experiments, since almost no references were found in this field. In this context measurement according to the Federal Test Procedure (FTP) and the New European Driving Cycle (NEDC) were carried out on a chassis dynamometer with a directly injected gasoline vehicle. Experiments were carried out with a reference fuel, a fuel based 70% on FT and an alkylate fuel (Aspen), which was taken to be the ultimate formula of FT gasoline.

Studies were performed with three commonly used additive metals, cerium copper, and iron, with a conventional and a low sulfur fuel in order to investigate fuel additive effects on engine particulate emissions before a particulate filter. Measurements were made on a 4 cylinder direct injection diesel engine and included total particulate mass, soluble organic fraction for both fuels, and polynuclear aromatic hydrocarbon emissions for the low sulfur fuel. The cerium based additive reduced the emissions with both fuels, with the largest effect being on the non-SOF fraction. With the other additives and the high sulfur fuel, non-SOF emissions were increased, increasing total particulate emissions. Copper was found to reduce the polynuclear aromatic hydrocarbons, and cerium was found to have the least effect. The use of an SiC wall flow filter reduced particulate and polynuclear aromatic emissions by over 90%.

The impact of ignition quality and chemical properties on engine performance and emissions during low load partially premixed combustion (PPC) in a light-duty diesel engine were investigated. Four fuels in the gasoline boiling range, together with Swedish diesel (MK1), were operated at loads between 2 and 8 bar IMEPg at 1500 rpm, with 50% heat released located at 6 crank angle degrees (CAD) after top dead center (TDC). A single injection strategy was used, wherein the start of injection (SOI) and the injection duration were adjusted to achieve desired loads with maintained CA50, as the injection pressure was kept constant at 1000 bar. The objective of this work was to examine the low-load limit for PPC at approximately 50% EGR and λ=1.5, since these levels had been suggested as optimal in earlier studies. The low-load limits with stable combustion were between 5 and 7 bar gross IMEP for the gasoline fuels, higher limit for higher RON values.

The main purpose of this study was to investigate the influence of diesel engine conditions on the mutagenic activity of the exhaust. Special emphasis was put on investigation of the influence of nitrogen oxides content. Experiments with a diesel engine have been carried out in the laboratory and the emissions of carbon monoxide (CO), carbon dioxide (CO2), nitrogen oxides (NOx) and particulate matter (PM) have been measured at different engine conditions. The particulate matter was extracted in order to obtain the soluble organic fraction (SOF), and this fraction was analyzed for mutagenic activity in the Salmonella/microsome assay (AMES test). It was found that the mutagenic activity evidently depended on the PAH content (PAH = Polycyclic Aromatic Hydrocarbons) of the exhaust gas rather than the NOx content. However, the percentage of the direct mutagenic activity of the total mutagenic activity increased as the NOx content in the exhaust gas increased.

Engine experiments were carried out on a six cylinder DI-diesel engine using synthetic fuel and lubricant containing no PAH (Polycyclic Aromatic Hydrocarbons) [1]. By selectively doping the fuel and oil with pyrene, the effect of fuel and oil originating PAH on the exhaust emissions could be investigated. The experimental results are analyzed in a new way by suggesting a general transport model for PAH. By estimating as many transport quantities as possible it is attempted to gain knowledge about the most dominant mechanisms. The main finding is not surprisingly that for commercial fuels containing substantial concentrations of PAH, the by far major contributor to exhaust PAH is unburned fuel PAH. The concentration of PAH in the oil sump affects only weakly the PAH concentration in the exhaust for engines operating on commercial fuels. The PAH desorbing from the liner are getting burned efficiently, thereby being insignificant.