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Two-line excitation LIF (Laser-Induced Fluorescence) technique for 2-dimensional temperature measurements in an engine cylinder before ignition is presented. From the fundamental examinations, the combination of toluene tracer with a pair of excitation lines of 248nm and 266nm has been selected because of the high LIF intensity ratio and closer excitation wavelengths. In-cylinder thermometry is conducted using a visualized single cylinder spark ignition engine both in PFI (port-fuel-injection) and DI (direct-injection) operation. The accuracy of this technique is determined through the homogeneous PFI experiment. Temperature and fuel distribution in unburned mixture are measured simultaneously in DI operation. It exists a strong correlation between equivalence ratio and temperature inside the mixture. Temperature in the fuel rich region is lower than in the fuel lean region.

Over the last few decades, in-cylinder visualization using optically accessible engines has been an important tool in the detailed analysis of the in-cylinder phenomena of internal combustion engines. However, most current optically accessible engines are recognized as being limited in terms of their speed and load, because of the fragility of certain components such as the elongated pistons and transparent windows. To overcome these speed and load limits, we developed a new generation of optically accessible engines which extends the operating range up to speeds of 6000 rpm for the SI engine version, and up to in-cylinder pressures of 20 MPa for the CI engine version. The main reason for the speed limitation is the vibration caused by the inertia force arising from the heavy elongated piston, which increases with the square of the engine speed.

Natural gas homogeneous charge compression ignition (HCCI) engines require high compression ratios and intake air heating because of the high auto-ignition temperature of natural gas. In the first study, the natural gas fueled HCCI combustion with internal exhaust gas recirculation (EGR) was achieved without an intake air heater. The effects of the combustion chamber configuration, turbocharging, and external EGR were investigated for expanding the operating range. As a result, it was cleared that the combination of internal / external EGR and turbocharging is effective for expanding the HCCI operational range toward high loads. Meanwhile, the HCCI combustion characteristics at high engine speeds were unstable because of an insufficient reaction time for auto-ignition. Although the engine operation with a richer air-fuel ratio was effective for improving the combustion stability, the combustion noise (CN) was at an unacceptable level.

The stoichiometric direct injection gasoline engines have higher torque performance than the port injection engines, as the volumetric efficiency can be increased due to the cooling effects of charging air by the fuel evaporation in the cylinder. They need only 3-way catalyst, leading to the cost down. However there exists the injection timing (region) that increased volumetric efficiency does not lead to higher torque. In order to investigate the phenomena, the in-cylinder mixture formation process has been analyzed by the LIF and the CFD techniques. As the results, it has been revealed that the phenomena are caused by the inhomogeneous mixture distribution before the ignition timing.

Methyl esters of saturated/unsaturated higher aliphatic acids (FAMEs) and a FAME of waste cooking oil (WCOME) were heated at 120°C in an air gas flow. The samples were analyzed before and after heating, using six different methods including electrospray ionization mass spectrometry. As a result, the samples after heating were found to contain low molecular weight aliphatic compounds and oligomers of the FAME. Based on the chemical structure of these oxidation products, reaction schemes were proposed for the deterioration of FAMEs. In addition, two unsaturated FAMEs containing 2,6-di-t-butyl-p-cresol (BHT) were similarly heated and analyzed to examine the effect of BHT on the oxidation of these FAME.

Fifty percent distillation temperature (T50) can be used as a warm-up driveability indicator for a hydrocarbon-type gasoline. MTBE-blended gasoline, however, provides poorer driveability than a hydrocarbon-type gasoline with the same T50. The purposes of this paper are to examine the reason for poor engine driveability caused by MTBE-blended gasolines, and to propose a new driveability indicator for gasolines including MTBE-blended gasolines. The static and dynamic evaporation characteristics of MTBE-blended gasolines such as the evaporation rate and the behavior of each component during evaporation were analyzed mainly by using Gas Chromatography/Mass Spectrometry. The results of the analysis show that the MTBE concentration in the vapor, evaporated at ambient temperature (e.g. 24°C), is higher than that in the original gasoline. Accordingly, the fuel vapor with enriched MTBE flows into the combustion chamber of an engine just after the throttle valve is opened.

The effect of GTL diesel fuel on organic materials used in fuel delivery systems of vehicles was investigated. Specimens made from 16 kinds of organic materials were immersed in GTL diesel fuels synthesized at Refinery-A and Refinery-B (referred to as GTL-A and GTL-B, respectively) and then subjected to tensile testing. The tensile test results revealed that elongation of the nylon sample immersed in GTL-A was extremely small, about 4% of that of untreated nylon. In the light of this finding, the GTL diesel fuels and nylons before and after immersion test were analyzed in detail using about 20 analysis methods to determine the cause for poor elongation. The following points were found. (1) GTL-A consisted of low molecular-weight paraffins. (2) GTL-A had low molecular-weight i-paraffins. (3) The nylon immersed in GTL-A contained low molecular-weight paraffins. (4) The paraffins in the nylon immersed in GTL-A were richer in i-paraffins than the original GTL-A.

Toyota participated in Formula One1 (F1) Racing from 2002 to 2009. As a result of the downturn in the world economy, various engine developments within F1 were restricted in order to reduce the cost of competing in F1. The limit on the maximum number of engines allowed has decreased year by year. Toyota focused on the engine performance deterioration due to the combustion chamber deposits. In 2009, Toyota was successful in reducing around 40% of the deterioration by making combustion chamber cleaner in cooperation with ExxonMobil. This contributed to good result of 2009 F1 season for Toyota, including two second place finishes.

This report describes the implementation of the spark channel short circuit and blow-out submodels, which were described in the previous report, into a spark ignition model. The spark channel which is modeled by a particle series is elongated by moving individual spark particles along local gas flows. The equation of the spark channel resistance developed by Kim et al. is modified in order to describe the behavior of the current and the voltage in high flow velocity conditions and implemented into the electrical circuit model of the electrical inductive system of the spark plug. Input parameters of the circuit model are the following: initial discharge energy, inductance, internal resistance and capacitance of the spark plug, and the spark channel length obtained by the spark channel model. The instantaneous discharge current and the voltage are obtained as outputs of the circuit model.

The backward flow of the hot burned gas surrounding a diesel flame was found to be one of the factors dominating the set-off length (also called the lift-off length), that is, the distance from a nozzle exit into which a diffusion flame cannot intrude. In the combustion chamber of an actual diesel engine, the entrainment of the surrounding gas into a spray jet from a multi-hole nozzle is restricted by the walls and adjacent spray jets, which induces the backward flow of the surrounding gas. A new momentum theory to calculate the backward flow velocity was established by extending Wakuri's momentum theory. Shadowgraph imaging in an optical engine successfully visualized the backward flow of the hot burned gas.

The cause of the exhaust smoke and its reduction methods in a small DI Diesel engine with a small-orifice-diameter nozzle and common rail F.I.E. were investigated under high-speed and high-load condition, using both in-cylinder observations and Three-dimensional numerical analyses. The following points were clarified during this study. At these conditions, fuel sprays are easily pushed away by a strong swirl, and immediately flow out to the squish area by a strong reverse squish. Therefore, the air in the cavity is not effectively used. Suppressing the airflow in a piston cavity, using such ideas as enlarging the piston cavity diameter or reducing the port swirl ratio, decreases the excessive outflow of the fuel-air mixture into the squish area, and allows the full use of air in the whole cavity. Hence, exhaust smoke is reduced.

A study of diesel fuel as a lubricant for diesel engines was conducted with the aim of dramatically reducing engine friction and eliminating the need to change the lubricating oil. A prototype single-cylinder engine modified for diesel fuel lubrication was made, and it was confirmed that firing operation is possible. Piston friction during the firing operation was reduced by modifying the shape of the cylinder liner surface to improve the retention of the lubricating oil. The study produced valid findings concerning engine lubrication, not only with diesel fuel, but also with ultra-low viscosity oil.

In diesel engines with a straight intake port and a lipless cavity to restrict in-cylinder flow, an injector with numerous small-diameter orifices with a narrow angle can be used to create a highly homogeneous air-fuel mixture that, during PCCI combustion, dramatically reduces the NOX and soot without the addition of expensive new devices. To further improve this new combustion concept, this research focused on cooling losses, which are generally thought to account for 16 to 35% of the total energy of the fuel, and approaches to reducing fuel consumption were explored. First, to clarify the proportions of convective heat transfer and radiation in the cooling losses, a Rapid Compression Machine (RCM) was used to measure the local heat flux and radiation to the combustion chamber wall. The results showed that though larger amounts of injected fuel increased the proportion of heat losses from radiation, the primary factor in cooling losses is convective heat transfer.

Countries and regions around the world are tightening emissions regulations in reaction to the increasing awareness of environmental conservation. At the same time, growing concerns about the depletion of raw materials as vehicle ownership continues to increase is prompting automakers to look for ways of decreasing the use of platinum-group metals (PGMs) in the exhaust systems. This research has developed a new catalyst with strong robustness against fluctuations in the exhaust gas and excellent nitrogen oxide (NOx) conversion performance. This catalyst incorporates rhodium (Rh) clusters with a particle size of several nanometers, and stabilized CeO2-ZrO2 solid-solution (CZ) with a pyrochlore crystal structure as a high-volume oxygen storage capacity (OSC) material with a slow O2 storage rate.

A concept of dual-fuel, Premixed Compression Ignition (PCI) combustion controlled by two fuels with different ignitability has been developed to achieve drastically low NOx and smoke emissions. In this system, isooctane, which was used to represent high-octane gasoline, was supplied from an intake port and diesel fuel was injected directly into an engine cylinder at early timing as ignition trigger. It was found that the ignition timing of this PCI combustion can be controlled by changing the ratio of amounts of injected two fuels and combustion proceeds very mildly by making spatial stratifications of ignitability in the cylinder even without EGR, as preventing the whole mixture from igniting simultaneously. The operable range of load, where NOx and smoke were less than 10ppm and 0.1 FSN, respectively, was extended up to 1.2MPa of IMEP using an intake air boosting system together with dual fueling.

The effect of the chemical reactivity of diesel fuel on PM formation was investigated using a flow reactor and a shock tube. Reaction products from the flow-reactor pyrolysis of the three diesel fuels used for the engine tests in Part 1(1) (“Base”, “Improved” and Swedish “Class-1”) were analyzed by gas chromatography. At 850C, Swedish “Class-1” fuel was found to produce the most PM precursors such as benzene and toluene among the three fuels, even though it contains very low amounts of aromatics. The chemical analyses described in Part 1 revealed that “Class-1” contains a large amount of branched and cyclic structures in the saturated hydrocarbon portion of the fuel. These results suggest that the presence of such branched and ring structures can increase exhaust PM emissions.

The EHD lubrication model of connecting rod big end bearings is compared with experiments using an automotive diesel engine. The axial load and the bending moment near the middle of rod length were derived from strain measurements and compared with the theoretical results based on engine dynamics. Although oscillation appeared on bending moment at 5000 rpm, the theoretical load almost agreed with the experiment. The EHD lubrication theory and the experiments were compared by the histories of clearances and the journal center orbits in the bearing. The theoretical results agreed well with the experimental one. The deformation of the bearing appeared both in the theory and in the experiment at 3000 rpm or above; these results confirm the necessity of the EHD lubrication theory.

The properties of diesel fuels were investigated in terms of particulate emissions to clarify the specification of such a diesel fuel for minimizing particulate emissions. Diesel fuels were analyzed using thin layer chromatography (TLC), and gas chromatography/mass spectrometry (GC/MS). These analysis revealed the entire composition of hydrocarbons in diesel fuels according to molecular formula. The entire composition of hydrocarbons in diesel fuels could be expressd on a three-dimensional graph: the X-axis as carbon number, the Y-axis as H/C ratio and the Z-axis as the amount of hydrocarbons of identical molecular formula. By using the graph, the properties reported so far were investigated. Also, simplified images of the fuel sprayed into a cylinder and its flame were derived from the observational results previously reported.

The compositions of hydrocarbons in diesel fuel, exhaust gas and particulates were analyzed and the relationships among them were determined. It was found that the compositions of the hydrocarbons in the exhaust gas were almost the same as that of the fuel, and that the hydrocarbons in the particulates corresponded to their heavy fractions. When the engine condition was fixed, both the soluble organic fraction (SOF) and insoluble fraction ( ISF) showed positive correlation coefficients versus HC×R310, where HC denotes the hydrocarbon emission and R310 denotes the backend fraction, as measured by the fraction of fuel boiling above 310°C. On the other hand, when the engine condition was varied, ISF had negative correlation coefficients versus HC×R310, while SOF showed positive correlation coefficients.

Precise analytical methods for characterizing diesel fuel yielding the lowest particulate emissions were developed. The methods consist of preparative-scale high pressure liquid chromatography (HPLC), field ionization mass spectrometry (FIMS), analytical-scale HPLC, and carbon-13 nuclear magnetic resonance spectrometry (13C-NMR). A diesel fuel was first separated into an aliphatic fraction and an aromatic fraction by semipreparative-scale HPLC. Then, the aliphatic fraction was analyzed by FIMS and the spectrum was compared with that of the whole fuel. The aromatic fraction was analyzed by analytical-scale HPLC to obtain the chromatogram of the aromatic hydrocarbons with a high S/N. In addition to these analyses, the fuel was analyzed by 13C-NMR to obtain the concentration of the carbon atoms of the straight chain, branched chain and aromatic-ring in hydrocarbons.