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A new 4.5 liter in-line 6 cylinder engine,1 FZ-FE has been developed for the Toyota Land Cruiser. To obtain high power, fuel efficient engine, we adopted the most advanced Toyota technologies, such as Toyota original 4 Valve DOHC system with scissors gear between camshafts, compact combustion chamber with smooth inlet and outlet system, KCS and so on. The engine produces 212 HP at 4600 rpm and 275 ft-lbs at 3200 rpm. Aluminum cylinder head,short skirt cylinder block stiffened with aluminum oil pan give the engine light weight and make it rigid enough to have low vibration and quietness. And we also designed every engine part appropriately so as to make the engine durable enough in severe operating condition of off-road vehicle.

A new proportional collection system for extremely low tailpipe emission measurement in transient conditions has been developed. The new system can continuously sample a minute flow of exhaust gas, at a rate that is proportional to the engine exhaust rate. A zero grade gas dilution technique is utilized to prevent the influence of pollutants in atmospheric air that are the same concentration level as those in the exhaust gas. The system has accuracy within ±5%. For the direct exhaust gas flow meter, a pitot tube type flow meter is utilized as it is simple, heat resistant, sufficiently accurate and has low flow-resistance characteristic. For the collection and dilution controllers, two mass flow controllers (MFC) were adopted. The MFCs' output can be adversely influenced by variation of the specific heat of the sample gas, resulting in flow reporting error.

A new 4.0 liter V8 engine, 1UZ-FE, has been developed for the luxury sedan, LEXUS LS400. The engine has 4 camshafts and 32 valves, and weighs only 195 kg (430 lbs) having many light alloy components and carefully designed configurations. The appropriate engine displacement and high technology adopted throughout from design to manufacturing process enable the LS400 to run powerfully with excellent fuel economy and a pleasant sounds. It develops 250HP at 5600 rpm and 260ft-lbs of torque at 4400 rpm, and its fuel economy figure, well exceeds the EPA's tax charge level of 22.5mpg. These figures have been achieved through the newest technologies applied to every part of the design, such as: Well studied intake and exhaust systems, centrally located spark plug in the TOYOTA original four-valve combustion chamber, which has a narrow valve including angle, and low friction components like aluminum alloy valve lifters and well balanced moving parts.

A new test machine has been developed which can evaluate vibration due to stick-slip using an actual full-scale clutch pack. Using this machine, a static breakaway friction coefficient measurement test method and a stick-slip test method have been established. Both methods have been shown to provide results which correlate with the results from both a full-scale assembly test and a vehicle shudder evaluation test. The evaluation of the frictional properties of commercial oils using these test methods showed that the static breakaway friction coefficient and the stick-slip properties have generally contradictory performance to each other for automatic transmission. The study of the frictional properties for typical additives and an analysis of the surface of the steel plates with ESCA (Electron Spectroscopy for Chemical Analysis) showed that the frictional properties are significantly affected by the additives adsorbed on the clutch plate sliding surface.

In the field of automobile disk wheels, demands for aluminum wheels have been increasing for the reason of ride comfort and better appearance. And over 90 percent of luxurious passenger cars are equipped with aluminum wheels. This trend is spurred also by the demand for higher fuel efficiency for the cause of environmental protection, which calls for weight reduction of automobiles. This paper reports our research on manufacturing light-weight, high-quality aluminum cast wheels; covering the entire process from basic design to casting, and placing emphasis on the following three points. 1) Determination of optimum wheel configuration through computer simulation 2) Selection of optimum material composition 3) Optimization of the thin plate casting conditions Combination of the above technologies developed for the purpose of weight reduction resulted in the weight reduction of approximately 20% over the conventional aluminum wheels.

Our two types of NOx storage-reduction (NSR) catalyst have been tested under various conditions of thermal endurance; the performance of these catalysts have been regressed to give the formulas that enable to estimate the performance after thermal endurance; and we have found the method to simplify (shorten the duration of) the thermal endurance tests and that the thermal deterioration of NSR catalysts is controlled by the worst condition of endurance (at least approximately). The regression formula for the amount of potassium that contributes to the catalyst performance (active K) after the endurance has also been obtained. These formulas predict that the amount of active K is the least for the worst condition of endurance and suggest a difference in deterioration mechanism that reflects the performance between low and high temperatures and the portion of worse deterioration (front or rear).

The dissolution and exfoliation of chromium plating specific to Russia was studied. Investigation and analysis of organic compounds in Russian soil revealed contents of highly concentrated fulvic acid. Additionally, it was found that fulvic acid, together with CaCl2 (a deicing agent), causes chromium plating corrosion. The fulvic acid generates a compound that prevents reformation of a passivation film and deteriorates the sacrificial corrosion effectiveness of nickel.

By using analytical techniques (FT-IR, TG-MS, ICP) and DFT calculations, the potassium (K) used as a storage component in NOx Catalysts can be analyzed. The results from this study show that the, K exists as K2CO3, and that the amount, molecular structure, and thermal stability of K2CO3 are different, depending on the support material (ZrO2, Al2O3, or TiO2). If the amount of K that interacts with the support to form an inactive complex oxide is decreased, the amount of K2CO3 and NOx storage is increased. The amount of the inactive K varies with the basicity of the supports. K2CO3 that exists in unstable structures on the supports can be easy to react with NOx to form the nitrate. So, the higher the quantity of unstable K2CO3, the higher the NOx storage capacity. Based on these results, a development guideline was proposed to improve the NOx storage performance.

Sintered silicon nitride, particularly in structural ceramics, has superior properties such as low weight, heat resistance, wear resistance, etc. It is already being applied to automobile engine parts such as the swirl chamber and the turbine rotor. In recent years, the strength of silicon nitride has shown to be above 1000MPa. This has been achieved through advances in manufacturing technology such as materials powder, forming, sintering and so on. But the silicon nitride is easily damaged during grinding because it has less fracture toughness than metal. Consequently, the inherent strength of the material is not demonstrated in the actual products presently produced. It is assumed that the main cause of strength reduction is microcrack. In ordinary grinding methods, the length of microcrack has been estimated at approximately twenty micrometers by fracture mechanics analysis.

The anti-shudder effect of ATF additives and their mechanisms have been investigated. Anti-shudder durability was evaluated using an automatic transmission (AT) on an engine stand under continuously slip-controlled condition. The addition of over-based Ca-sulfonate and friction modifier (FM) remarkably improved the anti-shudder durability of ATF. The surface roughness of the contact area (contact area roughness) of the clutch plates was measured by an electron probe surface roughness analyzer. To evaluate the boundary frictional properties of the adsorbed film formed, the friction coefficient of the clutch plates in the absence of oil was examined after the anti-shudder durability test. It was found that shudder occurrence was strongly correlated with the contact area roughness and the boundary frictional property of the steel plate surface. Large contact area roughness and low boundary friction were preferred to prevent shudder.

Currently, to achieve the desired design in automotive paint, absorption pigments, such as organic pigments, are used in combination with brilliant pigments (ex. aluminum or mica etc.). However, many beautiful colors exist in the world, especially in the natural world. Until now, automotive paints have not been able to replicate those colors. In this project, by first analyzing the coloring principles of the natural world, we have focused on the development of a previously non-existent coloring technology (structural color). By combining this with nanostructure control technology, we have established a radically new coloring process enabling the design of hues, chromaticity and reflection intensity. This technology has tangible results, as new pigments are available for paint formulations.

A lean burn engine is effective in reducing fuel consumption. NOX storage-reduction catalysts (NSR catalyst) have been developed for these engines. In order to improve the performance of NSR catalysts, suppression of sulfur poisoning, which is one of the main causes of NSR catalyst deactivation, must be improved. In this paper, the sulfur desorption phenomenon has been analyzed from a novel point of view. Based on these results, an NSR catalyst with improved sulfur resistance has been developed by incorporation of highly dispersed titania, and use of a heat resistant zirconia with enhanced basicity.

Countries and regions around the world are tightening emissions regulations in reaction to the increasing awareness of environmental conservation. At the same time, growing concerns about the depletion of raw materials as vehicle ownership continues to increase is prompting automakers to look for ways of decreasing the use of platinum-group metals (PGMs) in the exhaust systems. This research has developed a new catalyst with strong robustness against fluctuations in the exhaust gas and excellent nitrogen oxide (NOx) conversion performance. This catalyst incorporates rhodium (Rh) clusters with a particle size of several nanometers, and stabilized CeO2-ZrO2 solid-solution (CZ) with a pyrochlore crystal structure as a high-volume oxygen storage capacity (OSC) material with a slow O2 storage rate.

Recently, there has been a tendency of high power and high speed in automotive engines. In addition they have been also required high reliability. And engine bearings have been required to be advanced in wear resistance as well as seizure resistance. Therefore, copper-lead alloy bearings with overlay, which have better seizure resistance, have been widely used for high speed engines up to the present. But it becomes very important for them to advance the overlay wear resistance. In this paper, the composite overlay is mainly researched to improve wear resistance regarding kind of hard particles and their amounts in the overlay.

Technological development of materials derived from plants (e.g., polylactic acid (PLA), and the like) is required to break dependence on fossil fuels and reduce CO2. PLA has inferior hydrolysis resistance, impact resistance, and molding ability than polypropylene (PP), and in order to overcome these disadvantages, a novel PP/PLA alloy has been conceived where PLA is incorporated into a PP matrix. By optimizing compatibilizer and elastomer addition, PLA has been successfully dispersed into a PP matrix at a sub-micron order, and interior parts have been successfully developed that fulfill the performance, appearance, and mass-production capability requirements for practical application.

Diesel engines with relatively good fuel economy are known as an effective means of reducing CO₂ emissions. It is expected that diesel engines will continue to expand as efforts to slow global warming are intensified. Diesel particulate and NOx reduction system (DPNR), which was first developed in 2003 for introduction in the Japanese and European markets, shows high purification performance which can meet more stringent regulations in the future. However, it is poisoned by sulfur components in exhaust gas derived from fuel and lubricant. We then developed the sulfur trap DPNR with a sulfur trap catalyst that traps sulfur components in the exhaust gas. High purification performance could be achieved with a small amount of platinum group metal (PGM) due to prevention of sulfur poisoning and thermal deterioration.

In order to clarify the combustion behavior in the ultra high engine speed range, a new technique has been developed. This technique is composed of ionization current detection and flame observation, and is highly heat-resistant, vibration-resistant, and has a quick response. From analyzing the flame front propagation in the high-speed research engine, it was found that the flame propagated throughout the entire cylinder over almost the same crank angle period irrespective of engine speed introduction.

New ductile cast iron flywheel integrated with gear and its manufacturing process were developed to reduce the manufacturing steps and cost compared with conventional flywheel around which a steel ring gear is fit. In this process, the ring gear teeth around a cast iron flywheel are formed directly in net shape and free from any defect by the hot form-rolling method, followed by the thermomechanical treatment in a short time. The gear is superior to that made by the conventional hobbing and heat treatment in accuracy, strength and anti-wear property.

A new technologies for manufacturing of engine valve seats have been developed. This process, different from the conventional method that valve seats made of sintered alloy were press-fit into the cylinder head, is directly formed valve seats onto cylinder head by using the laser cladding technique. In order to develope the cylinder head with laser cladding valve seats, the laser cladding technology by which copper based alloy is deposited onto aluminum alloy with little dilution and stable bead has been established. And the unique cladding alloy, which is two phases in the liquid stage and in which iron or molybdenum rich hard particles are dispersed in the solid state, has been developed. Based on this technique, the practical process has been successfully completed.

Filiform corrosion phenomenon and its prevention method for 5000 series aluminum alloy sheet have been investigated. The painted aluminum alloy sheets were subject significantly to filiform corrosion caused by formation of a mottled and coarse zinc phosphate film during chemical conversion process. On the other hand, galvanized aluminum alloy sheet showed an uniform and fine phosphate film in a brief time and the filiform corrosion resistance was improved markedly. The test results of press-forming and corrosion for the prototype engine hoods made of this newly developed galvanized sheets have revealed a good formability and an excellent filiform corrosion resistance.