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A prototype catalyst has been developed and integrated within the aftertreatment exhaust system to control the HC, CO, PM and NOx emissions from diesel exhaust gas. The catalyst activity in removing HC and nano-particles was examined with exhaust gas from a diesel engine operating on biodiesel - Rapeseed Methyl Ester (RME). The tests were carried out at steady-state conditions for short periods of time, thus catalyst tolerance to sulphur was not examined. The prototype catalyst reduced the amount of hydrocarbons (HC) and the total PM. The quantity of particulate with electrical mobility diameter in nucleation mode size < 10nm, was significantly reduced over the catalyst. Moreover, it was observed that the use of EGR (20% vol.) for the biodiesel fuelled engine significantly increases the particle concentration in the accumulation mode with simultaneous reduction in the particle concentration in the nuclei mode.

In this paper blends of diesel and gasoline (dieseline) fuelled Partially Premixed Compression Ignition (PPCI) combustion and the comparison to conventional diesel combustion is investigated. The tests are carried out using a light duty four cylinder Euro IV diesel engine. The engine condition is maintained at 1800 rpm, 52 Nm (equivalent IMEP around 4.3 bar). Different injection timings and different amounts of EGR are used to achieve the PPCI combustion. The results show that compared to the conventional diesel combustion, the smoke and NOx emissions can be reduced by more than 95% simultaneously with dieseline fuelled PPCI combustion. The particle number total concentration can be reduced by 90% as well as the mean diameter (from 54 nm for conventional diesel to 16 nm for G50 fuelled PPCI). The penalty is a slightly increased noise level and lower indicated efficiency, which is decreased from 40% to 38.5%.

Limits on the total future potential of biodiesel fuel due to the availability of raw materials mean that ambitious 20% fuel replacement targets will need to be met by the use of both first and next generation biodiesel fuels. The use of higher percentage biodiesel blends requires engine recalibration, as it affects engine performance, combustion patterns and emissions. Previous work has shown that the combustion of 50:50 blends of biodiesel fuels (first generation RME and next generation synthetic fuel) can give diesel fuel-like performance (i.e. in-cylinder pressure, fuel injection and heat release patterns). This means engine recalibration can be avoided, plus a reduction in all the regulated emissions. Using a 30% biodiesel blend (with different first and next generation proportions) mixed with Diesel may be a more realistic future fuel.

The paper presents analysis of performance and emission characteristics of a common rail diesel engine operating with RME, with and without EGR. In both cases, the RME fuel was pre-heated in a heat exchanger to control its temperature before being pumped to the common rail. The studied parameters include the in-cylinder pressure history, rate of heat release, mass fraction burned, and exhaust emissions. The results show that when the fuel temperature increases and the engine is operated without EGR, the brake specific fuel consumption (bsfc) decreases, engine efficiency increases and NOx emission slightly decreases. However, when EGR is used while fuel temperature is increased, the bsfc and engine efficiency is independent of fuel temperature while NOx slightly increases.

Natural gas has a high auto-ignition temperature, requiring high compression ratios and/or intake charge heating to achieve HCCI (homogeneous charge compression ignition) engine operation. Previous work by the authors has shown that hydrogen addition improves combustion stability in various difficult combustion conditions. It is shown here that hydrogen, together with residual gas trapping, helps also in lowering the intake temperature required for HCCI. It has been argued in literature that the addition of hydrogen advances the start of combustion in the cylinder. This would translate into the lowering of the minimum intake temperature required for auto-ignition to occur during the compression stroke. The experimental results of this work show that, with hydrogen replacing part of the fuel, a decrease in intake air temperature requirement is observed for a range of engine loads, with larger reductions in temperature noted at lower loads.

Biofuels development and specification are currently driven by the engine (mainly gasoline- and diesel-type) technology, existing fossil fuel specification and availability of feedstock. The ability to use biofuels with conventional fuels without jeopardising the standard fuel specifications is a very effective means for the implementation of these fuels. In this work the effect of dual fuelling with in-cylinder injected ULSD fuel or synthetic second generation biofuels (a Gas-To-Liquid GTL fuel as a surrogate of these biofuels as its composition, specifications and production process are very similar to second generation biofuels) and with inlet port injected bioethanol on the engine performance and emissions were investigated. The introduction of anhydrous bioethanol improved the NOx and smoke emissions, but increased total hydrocarbons and carbon monoxide.

Combustion behaviour and emissions characteristics of different blending ratios of diesel and gasoline fuels (Dieseline) were investigated in a light-duty 4-cylinder compression-ignition (CI) engine operating on partially premixed compression ignition (PPCI) mode. Experiments show that increasing volatility and reducing cetane number of fuels can help promote PPCI and consequently reduce particulate matter (PM) emissions while oxides of nitrogen (NOx) emissions reduction depends on the engine load. Three different blends, 0% (G0), 20% (G20) and 50% (G50) of gasoline mixed with diesel by volume, were studied and results were compared to the diesel-baseline with the same combustion phasing for all experiments. Engine speed was fixed at 1800rpm, while the engine load was varied from 1.38 to 7.85 bar BMEP with the exhaust gas recirculation (EGR) application.

Exhaust Gas Fuel Reforming has potential to be used for on-board generation of hydrogen rich gas, reformate, and to act as an energy recovery system allowing the capture of waste exhaust heat. High exhaust gas temperature drives endothermic reforming reactions that convert hydrocarbon fuel into gaseous fuel when combined with exhaust gas over a catalyst - the result is an increase in overall fuel energy that is proportional to waste energy capture. The paper demonstrates how the combustion of reformate in a direct injection gasoline (GDI) engine via Reformed Exhaust Gas Recirculation (REGR) can be beneficial to engine performance and emissions. Bottled reformate was inducted into a single cylinder GDI engine at a range of engine loads to compare REGR to conventional EGR. The reformate composition was selected to approximate reformate produced by exhaust gas fuel reforming at typical gasoline engine exhaust temperatures.

Due to the emission benefits of the oxygen in the fuel molecule, the interest for the use of ethanol as fuel blend components in compression ignition engines has been increased. However the use of fuel blends with high percentage of ethanol can lead to poor fuel blend quality (e.g. fuel miscibility, cetane number, viscosity and lubricity). An approach which can be used to improve these properties is the addition of biodiesel forming ternary blends (ethanol-biodiesel-diesel). The addition of castor oil-derived biodiesel (COME) containing a high proportion of methyl ricinoleate (C18:1 OH) is an attractive approach in order to i) reduce the use of first generation biodiesel derived from edible sources, ii) balance the reduction in viscosity and lubricity of ethanol-diesel blends due to the high viscosity and excellent lubricity of methyl ricinoleate.

Diesel engines are the versatile power source and is widely used in passenger car and commercial vehicle applications. Environmental temperature conditions, fuel quality, fuel injection strategies and lubricant have influence on cold start performance of the diesel engines. Strategies to overcome the cold start problem at very low ambient temperature include preheating of intake air, coolant, cylinder block. The present research work investigates the effect of coolant temperatures on passenger car diesel engine’s performance and exhaust emission characteristics during the cold start at cold ambient temperature conditions. The engine is soaked in the -7°C environment for 6 hours. The engine coolant is preheated to the desired coolant temperatures of 10 and 20°C by an external heater and the start ability tests were performed.

The lubricating properties of two sustainable alternative diesels blended with ultra low sulphur diesel (ULSD) were investigated. The candidate fuels were a biodiesel consisting of fatty acid methyl esters derived from rapeseed (RME) and gas-to-liquid (GTL). Lubricity tests were conducted on a high frequency reciprocating rig (HFRR). The mating specimen surfaces were analysed using optical microscopy and profilometery for wear scar diameters and profiles respectively. Microscopic surface topography and deposit composition was evaluated using a scanning electronic microscope (SEM) with an energy dispersive spectrometer (EDS). Like all modern zero sulphur diesel fuel (ZSD), GTL fuels need a lubricity agent to meet modern lubricity specifications. It has been proven that GTL responds well to typical lubricity additives in the marketplace.

Cold start is a critical operating condition for diesel engines because of the pollutant emissions produced by the unstable combustion and non-performance of after-treatment at lower temperatures. In this research investigation, a light-duty turbocharged diesel engine equipped with a common rail injection system was tested on a transient engine testing bed to study the starting process in terms of engine performance and emissions. The engine (including engine coolant, engine oil and fuel) was soaked in a cold cell at −7°C for at least 8 hours before starting the test. The engine operating parameters such as engine speed, air/fuel ratio, and EGR rate were recorded during the tests. Pollutant emissions (Hydrocarbon (HC), NOx, and particles both in mode of nucleation and accumulation) were measured before and after the Diesel Oxidation Catalyst (DOC). The results show that conversion efficiency of NOx was higher during acceleration period at −7°C start than the case of 20°C start.

Engine transient operation has attracted a lot of attention from researchers due to its high frequency of occurrence during daily vehicle operation. More emissions are expected compared to steady state operating conditions as a result of the turbo-lag problem. Ambient temperature has significant influences on engine transients especially at engine start. The effects of ambient temperature on engine-out emissions under the New European Driving Cycle (NEDC) are investigated in this study. The transient engine scenarios were carried out on a modern 3.0 L, V6 turbocharged common rail diesel engine fuelled with winter diesel in a cold cell within the different ambient temperature ranging between +20 °C and −7 °C. The engine with fuel, coolant, combustion air and lubricating oil were soaked and maintained at the desired test temperatures during the transient scenarios.

Two approaches were adopted to study soot oxidation by NO₂; firstly microreactor tests were performed on soot produced by a soot generator over a range of NO₂ concentrations and temperatures. This enabled measurement to be made under well-controlled conditions. Secondly, soot oxidation measurements were made on an engine bench to obtain data under more realistic, if less controlled, conditions. In the microreactor work NO₂ consumption by soot oxidation and the selectivity of the soot oxidation to CO and CO₂ were measured. The latter was found to vary only slightly with temperature and to be independent of NO₂ concentration. By modeling this data using a 1-dimensional model, rate equations for the soot-NO₂ reaction were determined. These were then tested against the engine data. The soot used in this study was characterized by thermogravimetric analysis, N₂ physisorption and transmission electron microscopy.

The fuel reforming technology has been extensively investigated as a way to produce hydrogen on-board a vehicle that can be utilized in internal combustion engines, fuel cells and aftertreatment technologies. Maximization of H2 production in the reforming process can be achieved when there is optimized water (steam) addition for the different reforming temperatures. A way to increase the already available water quantity on-board a vehicle (i.e. exhaust gas water content) is by using emulsified fuel (e.g. water-diesel blend). This study presents the effect of an emulsified diesel fuel (a blend of water and diesel fuel with an organic surfactant to make the mixture stable) on combustion in conjunction with exhaust gas assisted fuel reforming on a compression ignition engine. No engine modification was required to carry out these tests. The emulsified diesel fuel consisted of about 80% (mass basis) of conventional ultra low sulphur diesel (ULSD) fuel and fixed water content.

With the high auto ignition temperature of natural gas, various approaches such as high compression ratios and/or intake charge heating are required for auto ignition. Another approach utilizes the trapping of internal residual gas (as used before in gasoline controlled auto ignition engines), to lower the thermal requirements for the auto ignition process in natural gas. In the present work, the achievable engine load range is controlled by the degree of internal trapping of exhaust gas supplemented by intake charge heating. Special valve strategies were used to control the internal retention of exhaust gas. Significant differences in the degree of valve overlap were necessary when compared to gasoline operation at the same speeds and loads, resulting in lower amounts of residual gas observed. The dilution effect of residual gas trapping is hence reduced, resulting in higher NOx emissions for the stoichiometric air/fuel ratio operation as compared to gasoline.

Lithium-ion batteries (LiBs) have been widely used in electrified vehicles, and the battery thermal management (BTM) system is needed to maintain the temperature that is critical to battery performance, safety, and health. Conventionally, three-dimensional battery thermal models are developed at the early stage to guide the design of the BTM system, in which battery thermophysical parameters (radial thermal conductivity, axial thermal conductivity, and specific heat capacity) are required. However, in most literature, those parameters were estimated with greatly different values (up to one order of magnitude). In this paper, an investigation is carried out to evaluate the magnitude of the influence of those parameters on the battery simulation results. The study will determine if accurate measurements of battery thermophysical parameters are necessary.

In earlier work we have shown that engine operation with oxygenated fuels (e.g., biodiesel) reduces the particulate matter (PM) emissions and extends the engine tolerance to exhaust gas recirculation (EGR) before it reaches smoke limited conditions. The same result has also been reported when high cetane number fuels such as gas-to-liquid (GTL) are used. A likely mechanism for engine-out particulate growth is the reintroduction of particle nuclei into the cylinder through EGR. These recirculated PM particles serve as sites for further condensation and accumulation promoting larger and greater number of particles. In order to further our understanding of EGR influence on total PM production, a diesel particulate filter (DPF) was integrated into the EGR loop. A PM reduction of approximately 50% (soot) was achieved with diesel fuel through filtered EGR, whilst still maintaining a significant NOX reduction.