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The effects of variable intake-valve-timing on the gas exchange process and performance of a 4-valve direct-injection HCCI engine were computationally investigated using a 1D gas dynamics engine cycle simulation code. A non-typical strategy to actuate the pair of intake valves was examined; whereby each valve was assumed to be actuated independently at different timing. Using such an intake valves strategy, the obtained results showed a considerable improvement of the engine parameters such as load and charging efficiency as compared with the typical identical intake valve pair timings case. Additional benefits of minimizing pumping losses and improving the fuel economy were demonstrated with the use of the non-simultaneous actuation of the intake valve pair having the opening timing of the early intake valve coupled with a symmetric degree of crank angle for the timing of exhaust valve closing.

In this work, the effects of ozone, hydrogen, carbon monoxide, and exhaust gas recirculation (EGR) addition to Haltermann gasoline combustion were investigated. For these additives, laminar and turbulent flame speeds were experimentally determined using spherically propagating premixed flames in a constant volume combustion vessel. Two initial mixture pressures of Po = 1 and 5 bar, two initial mixture temperatures of 358 and 373 K and a range of equivalence ratios (Ф) from 0.5 to 1 were investigated. The additives were added as single, binary and ternary mixtures to Haltermann gasoline over a wide range of concentrations. For the stoichiometric mixture, the addition of 10% H2, 5% CO and 1000 ppm O3 shows remarkable enhancement (80%) in SL0compared to neat Haltermann gasoline. In addition, for this same blend, increasing the mixture initial temperature and pressure results in a significant increase in SL0compared to the neat gasoline.

Pre-chamber combustion (PCC) engines allow extending the lean limit of operation compared to common SI engines, thus being a candidate concept for the future clean transportation targets. To understand the fundamental mechanisms of the main chamber charge ignition in PCC engines, the effects of the composition in the pre-chamber were investigated numerically. A well-stirred reactor combustion model coupled with a methane oxidation mechanism reduced from GRI 3.0 was used. An open-cycle simulation was run with initialization at exhaust valve opening (EVO). For posterior simulations, the initial flow field was attained by mapping the field variables obtained from the full cycle simulation. The entire simulation domain (pre-chamber and main chamber) global excess air ratio (λ) was set to 1.3.

The regulatory requirements to reduce both greenhouse gases and exhaust gas pollutants from heavy duty engines are driving new perspectives on the interaction between fuels and engines. Fuels that reliefs the burden on engine manufacturers to reach these goals are of particular interest. A low carbon fuel with a higher volatility and heating value than diesel is one such fuel that reduces engine-out emissions and carbon footprint from the entire hydrocarbon lifecycle (well-to-wheel) and improves fuel efficiency, which is a main enabler for gasoline compression ignition (GCI) technology. The present study investigated the potential of GCI technology by evaluating the performance of a low carbon high efficiency, high reactivity gasoline fuel in Doosan’s 6L medium duty diesel engine.

To elucidate the complex characteristics of pre-chamber combustion engines, the interaction of the hot gas jets initiated by an active narrow throated pre-chamber with lean premixed CH4/air in a heavy-duty engine was studied computationally. A twelve-hole KAUST proprietary pre-chamber geometry was investigated using CONVERGE software. The KAUST pre-chamber has an upper conical part with the spark plug, and fuel injector, followed by a straight narrow region called the throat and nozzles connecting the chambers. The simulations were run for an entire cycle, starting at the previous cycle's exhaust valve opening (EVO). The SAGE combustion model was used with the chemistry modeled using a reduced methane oxidation mechanism based on GRI Mech 3.0, which was validated against in-house OH chemiluminescence data from the optical engine experiments.

To provide insights into the fundamental characteristics of pre-chamber combustion engines, the ignition of lean premixed CH4/air due to hot gas jets initiated by a passive narrow throated pre-chamber in a heavy-duty engine was studied computationally. A twelve-hole pre-chamber geometry was investigated using CONVERGETM software. The numerical model was validated against the experimental results. To elucidate the main-chamber ignition mechanism, the spark plug location and spark timing were varied, resulting in different pressure gradient during turbulent jet formation. Different ignition mechanisms were observed for turbulent jet ignition of lean premixed CH4/air, based on the geometry effect. Ignition behavior was classified into the flame and jet ignition depending on the significant presence of hot active radicals. The jet ignition, mainly due to hot product gases was found to be advanced by the addition of a small concentration of radicals.

The autoignition resistance of a practical gasoline is best characterized by the Octane Index, OI, defined as RON-KS, where RON and MON are respectively, Research and Motor Octane Numbers, S is the sensitivity (RON-MON) and K is a constant depending on the pressure and temperature history of the fuel/air mixture in an engine. Experiments in knocking SI engines, HCCI engines and in premixed compression ignition (PCI) engines have shown that if two fuels of different composition have the same OI and experience the same pressure/temperature history, they will have the same autoignition phasing. A practical gasoline is a complex mixture of hydrocarbons and a simple surrogate is needed to describe its autoignition chemistry. A mixture of toluene and PRF (iso-octane + n-heptane), TPRF, can have the same RON and S as a target gasoline and so will have the same OI at any given K value and will be a very good surrogate for the gasoline.

Automotive engines especially turbocharged diesel engines produce higher level of emissions during transient operation than in steady state. In order to improve understanding of the engine transients and develop advanced technologies to reduce the transient emissions, the engine researchers require accurate data acquisition and appropriate post-processing techniques which are capable of dealing with noise and synchronization issues. Four alternative automated methods namely FFT (Fast Fourier Transform), low-pass, linear and zero-phase filters were implemented on in-cylinder pressure. The data of each individual cycle was compared and analyzed for the suitability of combustion diagnostic. FFT filtering was the best suited method since it eliminated most pressure fluctuation and provided smooth rate of heat release profiles for each cycle.

The purpose of this study is to improve the carbon monoxide (CO) and total hydrocarbons (THC) conversion efficiency of a diesel oxidation catalyst (DOC) by enhancing the monolith thermal behaviour through modification of the substrate cell density and wall thickness. The optimisation is based on catalyst properties (light off performance, conversion efficiency, pressure drop and mechanical durability). These properties were first estimated using theoretical equations derived from literature in order to select commercially available substrates for further modelling studies. The thermal behaviour and conversion efficiency of the selected catalysts under diesel exhaust gas conditions were numerically studied using data from an EU5 diesel engine operating a New European Driving Cycle (NEDC). This simulation was carried out on a commercial exhaust aftertreatment modelling program, AXISUITE. The predictions were compared to a reference coated 400/4 catalyst.

A prototype catalyst has been developed and integrated within the aftertreatment exhaust system to control the HC, CO, PM and NOx emissions from diesel exhaust gas. The catalyst activity in removing HC and nano-particles was examined with exhaust gas from a diesel engine operating on biodiesel - Rapeseed Methyl Ester (RME). The tests were carried out at steady-state conditions for short periods of time, thus catalyst tolerance to sulphur was not examined. The prototype catalyst reduced the amount of hydrocarbons (HC) and the total PM. The quantity of particulate with electrical mobility diameter in nucleation mode size < 10nm, was significantly reduced over the catalyst. Moreover, it was observed that the use of EGR (20% vol.) for the biodiesel fuelled engine significantly increases the particle concentration in the accumulation mode with simultaneous reduction in the particle concentration in the nuclei mode.

As SI engines strive for higher efficiency they are more likely to encounter knock and fuel anti-knock quality, which is currently measured by RON and MON, becomes more important. However, the RON and MON scales are based on primary reference fuels (PRF) - mixtures of iso-octane and n-heptane - whose autoignition chemistry is significantly different from that of practical fuels. Hence RON or MON alone can truly characterize a gasoline for its knock behavior only at their respective test conditions. The same gasoline will match different PRF fuels at different operating conditions. The true anti-knock quality of a fuel is given by the octane index, OI = RON −KS where S = RON − MON, is the sensitivity. K depends on the pressure and temperature evolution in the unburned gas during the engine cycle and hence is different at different operating conditions and is negative in modern engines.

There is an increasing recognition of injector deposit (ID) formation in fuel injection equipment as direct injection spark ignition (DISI) engine technologies advance to meet increasingly stringent emission legislation and fuel economy requirements. While it is known that the phenomena of ID in DISI engines can be influenced by changes in fuel composition, including increasing usage of aliphatic alcohols and additive chemistries to enhance fuel performance, there is however still a great deal of uncertainty regarding the physical and chemical structure of these deposits, and the mechanisms of deposit formation. In this study, a mechanical cracking sample preparation technique was developed to assess the deposits across DISI injectors fuelled with gasoline and blends of 85% ethanol (E85).

The effect of fuel equivalence ratio on the autoignition and combustion processes in a Homogeneous Charge Compression Ignition (HCCI) engine has been studied using a primary reference fuel (PRF60). Experiments have been performed on a single-cylinder engine operated in an alternate-fire mode. The operating conditions of the engine used in this work were an intake air pressure and temperature of 1.5 bar and 75°C respectively, an engine speed of 1200 rpm, compression ratio of 12:1, with varying fuel equivalence ratio (φ). A single zone CHEMKIN model using reduced chemical kinetic model of 560 species and 2818 reactions based on a 5 components gasoline surrogate from Reaction Design's Model Fuels Consortium was used to predict the HCCI engine combustion behavior for different fuel equivalence ratios.

While Homogeneous Charge Compression Ignition (HCCI) is a promising combustion mode with significant advantages in fuel economy improvement and emission reductions for vehicle engines, it is subject to a number of limitations, for example, hardware and control complexity, or NOx and NVH deterioration near its operating upper load boundary, diminishing its advantages. Conventional spark-ignition combustion mode is required for higher loads and speeds, thus the operating conditions near the HCCI boundaries and their corresponding alternatives in SI mode must be studied carefully in order to identify practical strategies to minimise the impact of the combustion mode transition on the performance of the engine. This paper presents the results of an investigation of the combustion mode transitions between SI and HCCI, using a combination of an engine cycle simulation code with a chemical kinetics based HCCI combustion code.

The new fuel, 2, 5-dimenthylfuran, known as DMF, captured worldwide attention since the discovery of its new production method. As a potential bio-fuel, DMF is competitive to gasoline in many areas, such as energy density, combustion efficiency and emissions. However, little work has been performed on its unconventional combustion mode. In this work, high speed imaging and thermal investigation are carried out to study DMF and gasoline dual-injection on a single cylinder, direct injection spark ignition optical engine. This dual-injection strategy combines direct injection (DI) and port fuel injection (PFI) simultaneously which means two different fuels can blend in the cylinder with any ratio. It provides a flexible way to use bio-fuels with gasoline. DMF DI with gasoline PFI and ethanol DI with gasoline PFI are studied under different injection proportions (by volume) and IMEPs.

In this study, the authors investigated the effect of fuel properties on the combustion characteristics by employing methane, methanol, ethanol, and primary reference fuels (PRFs) as the main chamber fuel while using methane for the pre-chamber. Global excess air ratios (λ) from 1.6 to lean limit were tested, while 13% of total fuel energy supplied to the engine was delivered via the pre-chamber. The gaseous methane was injected into the pre-chamber at the gas exchange top-dead-center (TDC). Port fuel injection was tested with both open and closed inlet valves. The pre-chamber assembly was designed to fit into the diesel injector pocket of the base engine, which resulted in a narrow throat diameter of 3.3 mm. The combustion stability limit was set at 5% of the coefficient of variation of gross IMEP, and the knock intensity limit was set at 10 bar. GT-Power software was used to estimate the composition of pre-chamber species and was used in heat release analysis of the two chambers.

Gasoline-ethanol-methanol (GEM) blends, with constant stoichiometric air-to-fuel ratio (iso-stoichiometric blending rule) and equivalent to binary gasoline-ethanol blends (E2, E5, E10 and E15 in % vol.), were defined to investigate the effect of methanol and combined mixtures of ethanol and methanol when blended with three FACE (Fuels for Advanced Combustion Engines) Gasolines, I, J and A corresponding to RON 70.2, 73.8 and 83.9, respectively, and their corresponding Primary Reference Fuels (PRFs). A Cooperative Fuel Research (CFR) engine was used under Spark Ignition and Homogeneous Charge Compression Ignited modes. An ignition quality tester was utilized in the Compression Ignition mode. One of the promising properties of GEM blends, which are derived using the iso-stoichiometric blending rule, is that they maintain a constant octane number, which has led to the introduction of methanol as a drop-in fuel to supplement bio-derived ethanol.

The increasing demand for high-octane fuels is pushing the combustion research towards investigating new potential fuels and octane boosters. In addition to their high-octane, those additives should be environmentally friendly. In this study, the anti-knock properties of Dicyclopentadiene (DCPD) as an additive to primary reference fuels (PRF) and toluene primary reference fuels (TPRF) have been investigated. The Research octane number (RON) and Motor octane number (MON) were measured using Cooperative Fuels Research (CFR) engine for four different fuel blends; PRF 60 + 10% DCPD, PRF 60 + 20% DCPD, PRF 70 + 10% DCPD and TPRF 70 + 10% DCPD. In addition, homogenous charge compression ignition (HCCI) was also performed using the CFR engine to show the effect of DCPD on suppressing low temperature chemistry of reference fuels.

The effect of ethanol blended with three FACE (Fuels for Advanced Combustion Engines) gasolines, I, J and A corresponding to RON 70.3, 71.8 and 83.5, respectively, were compared to PRF70 and PRF84 with the same ethanol concentrations, these being 2%, 5%, 10%, 15% and 20% by volume. A Cooperative Fuel Research (CFR) engine was used to understand the blending effect of ethanol with FACE gasolines and PRFs in spark-ignited and homogeneous charge compression ignited mode. Blending octane numbers (BON) were obtained for both the modes. All the fuels were also tested in an ignition quality tester to obtain Blending Derived Cetane numbers (BDCN). It is shown that fuel composition and octane number are important characteristics of all the base fuels that have a significant impact on octane increase with ethanol. The dependency of octane number for the base fuel on the blending octane number depended on the combustion mode operated.

The blending behavior of ethanol in five different hydrocarbon base fuels with octane numbers of approximately 70 and 84 was examined under Spark-Ignited (SI) and Homogeneous Charge Compression Ignited (HCCI) operating conditions. The Blending octane number (BON) was used to characterize the blending behavior on both a volume and molar basis. Previous studies have shown that the blending behavior of ethanol generally follows several well-established rules. In particular, non-linear blending effects are generally observed on a volume basis (i.e. BON > RON or MON of pure ethanol; 108 and 89, respectively), while linear blending effects are generally observed on a molar basis (i.e. BON = RON or MON of pure ethanol). This work firstly demonstrates that the non-linear volumetric blending effects traditionally observed under SI operating conditions are also observed under HCCI operating conditions.