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Degreening is crucial in obtaining a stable catalyst prior to assessing its performance characteristics. This paper characterizes the light-off behavior and conversion efficiency of a Diesel Oxidation Catalyst (DOC) during the degreening process. A platinum DOC is degreened for 16 hours in the presence of actual diesel engine exhaust at 650°C and 10% water (H2O) concentration. The DOC's activity for carbon monoxide (CO) and for total hydrocarbons (THC) conversion is checked at 0, 1, 2, 3, 4, 6, 8, 10, 12, and 16 hours of degreening. Pre-and post-catalyst hydrocarbon species are analyzed via gas chromatography at 0, 4, 8, and 16 hours of degreening. It is found that both light-off temperature and species-resolved conversion efficiencies change rapidly during the first 8 hours of degreening and then stabilize to a large degree. T50, the temperature where the catalyst is 50% active towards a particular species, increases by 14°C for CO and by 11°C for THC through the degreening process.

Injecting liquid water into a fuel/air charge is a means to reduce NOx emissions. Such strategies are particularly important to hydrogen internal combustion engines, as engine performance (e.g., maximum load) can be limited by regulatory limits on NOx. Experiments were conducted in this study to quantify the effects of direct injection of water into the combustion chamber of a port-fueled, hydrogen IC engine. The effects of DI water injection on NOx emissions, load, and engine efficiency were determined for a broad range of water injection timing. The amount of water injected was varied, and the results were compared with baseline data where no water injection was used. Water injection was a very effective means to reduce NOx emissions. Direct injection of water into the cylinder reduced NOx emissions by 95% with an 8% fuel consumption penalty, and NOx emissions were reduced by 85% without any fuel consumption penalty.

Combined direct and port fuel injection (i.e., dual injection) in spark ignition engines is of increasing interest due to the advantages for fuel flexibility and the individual merits of each system for improving engine performance and reducing engine-out emissions. Greater understanding of the impact of dual injection will enable deriving the maximum benefit from the two injection systems. This study investigates the effects of dual injection on combustion, especially knock propensity and tolerance to exhaust gas recirculation (EGR) dilution at different levels of EGR. A baseline for comparison with dual injection results was made using direct injection fueling only. A splash blended E20 fuel was used for the direct injection only tests. For the dual injection tests, gasoline, representing 80% by volume of the total fuel, was injected using the direct injector, and ethanol, representing 20% by volume of the total fuel, was injected using the port fuel injector.

Numerous studies have demonstrated the benefits of ethanol in increasing the thermal efficiency of gasoline-fueled spark ignition engines via the higher enthalpy of vaporization and higher knock resistance of ethanol compared with gasoline. This study expands on previous work by considering a split fuel injection strategy with a boosted direct injection spark ignition engine fueled with E0 (100% by volume reference grade gasoline; with research octane number = 91 and motor octane number = 83), E100 (100% by volume anhydrous ethanol), and various splash-blends of the two fuels. Experiments were performed using a production 3-cylinder Ford Ecoboost engine where two cylinders were de-activated to create a single-cylinder engine with a displacement of 0.33 L. The engine was operated over a range of loads with boosted intake manifold absolute pressure (MAP) from 1 bar to 1.5 bar.

A method for detection of ethanol content in fuel for an engine equipped with direct injection (DI) is presented. The methodology is based on in-cylinder pressure measurements during the compression stroke and exploits the different charge cooling properties of ethanol and gasoline. The concept was validated using dynamometer data of a 2.0L DI turbocharged engine with variable valve timing (VVT). An algorithm was developed to process the experimental data and generate a residue from the complex cycle-to-cycle in-cylinder pressure evolution which captures the charge cooling effect. The experimental results show that there is a monotonic correlation between the residues and the fuel ethanol percentage in the majority of the cases. However, the correlation varies for different engine operating parameters; such as, speed, load, valve timing, fuel rail pressure, intake and exhaust temperature and pressure.

A single-cylinder Direct Injection Spark Ignition (DISI) engine with optical access was used to investigate the effects of ethanol/gasoline blends on in-cylinder formation of particulate matter (PM) and fuel spray characteristics. Indolene was used as a baseline fuel and two blends of 50% and 85% ethanol (by volume, balance indolene) were investigated. Time resolved thermal radiation (incandescence/natural luminosity) of soot particles and fuel spray characteristics were recorded using a high speed camera. The images were analyzed to quantify soot formation in units of relative image intensity as a function of important engine operating conditions, including ethanol concentration in the fuel, fuel injection timing (250, 300 and 320° bTDC), and coolant temperature (25°C and 90°C). Spatially-integrated incandescence was used as a metric to quantify the level of in-cylinder PM formed at the different operating conditions.

The U.S. EPA initiated the Common Sense Initiative (CSI) to develop “Cleaner, Cheaper, Smarter” environmental policy and management practices. This paper addresses the application of life cycle design and assessment tools to automotive instrument panels (IP) as part of the Automotive Manufacturing Sector CSI pilot project investigation. For this study, an “average IP” was modeled based on the instrument panels of three mid-sized U.S. car models: 1995 Chevrolet Lumina, 1996 Dodge Intrepid and 1996 Ford Taurus. This “average IP” consisted of seventeen different materials and weighed over 22 kg (49 lbs.). A life cycle inventory analysis was conducted to evaluate the environmental burdens associated with materials production, manufacturing, use, and retirement. A thorough evaluation of solid waste production and energy consumption was completed and partial inventories of air emission and water effluent releases were also conducted.

A detailed chemical kinetic mechanism, consisting of 22 species and 104 elementary reactions, has been used in conjunction with the multi-dimensional reactive flow code KIVA-3 to study autoignition of natural gas injected under compression ignition conditions. Calculations for three different blends of natural gas are performed on a three-dimensional computational grid by modeling both the injection and ignition processes. Ignition delay predictions at pressures and temperatures typical of top-dead-center conditions in compression ignition engines compare well with the measurements of Naber et al. [1] in a combustion bomb. Two different criteria, based on pressure rise and mass of fuel burned, are used to detect the onset of ignition. Parametric studies are conducted to show the effect of additives like ethane and hydrogen peroxide in increasing the fuel consumption rate.

Hydrogen fueled internal combustion engines have potential for high thermal efficiencies; however, high efficiency conditions can produce high nitrogen oxide emissions (NOx) that are challenging to treat using conventional 3-way catalysts. This work presents the results of an experimental study to reduce NOx emissions while retaining high thermal efficiencies in a single-cylinder research engine fueled with hydrogen. Specifically, the effects on engine performance of the injection of water into the intake air charge were explored. The hydrogen fuel was injected into the cylinder directly. Several parameters were varied during the study, including the amount of water injected into the intake charge, the amount of fuel injected, the phasing of the fuel injection, the number of fuel injection events, and the ignition timing. The results were compared with expectations for a conventionally operated hydrogen engine where load was controlled through changes in equivalence ratio.