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Ethanol fuel has received renewed attention in recent years because of its oxygenate content and its potential to reduce greenhouse gas emissions from spark ignition engines. The economic impact on farm industry has been one of the drivers for its use in engines in the U.S. Although ethanol, in various blends, has been used in automotive engines for almost a decade the fuel has seldom been utilized in off-highway engines where the fuel systems are not well controlled. This investigation was conducted to evaluate exhaust emissions and combustion characteristics of E85 fuel in an off-highway engine used in farm equipment. A single-cylinder, four-stroke, spark ignition engine equipped with a carburetor was used to investigate combustion and exhaust emissions produced by gasoline and blends of gasoline and ethanol fuels. The engine fuel system was modified to handle flow rates required by the engine. A variable size-metering orifice was used to control air-to-fuel ratios.

The Honda Particulate Matter Index (PMI) is a very helpful tool which provides an indication of a fuel’s sooting tendency. Currently, the index is being used by various laboratories and vehicle OEMs as a metric to understand a fuels impact on automotive engine sooting, in preparation for new global emissions regulations. The calculation of the index involves generating detailed hydrocarbon analysis (hydrocarbon molecular speciation) using gas chromatography laboratory equipment and the PMI calculation requires the exact list of compounds and correct naming conventions to work properly. The analytical methodology can be cumbersome, when the gas chromatography methodology has to be adjusted for new compounds that are not in the method, or if the compounds are not matching the list for quantification. Also, the method itself is relatively expensive, and not easily transferrable between labs.

This paper presents a comparison of aqueous corrosion rates in 5% NaCl solution for eight experimental creep-resistant magnesium alloys considered for automotive powertrain applications, as well as three reference alloys (pure magnesium, AM50B and AZ91D). The corrosion rates were measured using the techniques of titration, weight loss, hydrogen evolution, and DC polarization. The corrosion rates measured by these techniques are compared with each other as well as with those obtained with salt-spray testing using ASTM B117. The advantages and disadvantages of the various corrosion measurement techniques are discussed.

APPLICATION of nuclear energy for civilian automotive uses has possibilities, these authors say. Nuclear power for automotive applications, they feel, is technically feasible now where size and weight are not prime considerations; where size and weight are major parameters, discoveries of new materials for construction of nuclear-power reactors must be made. New materials are needed for reactor fuels, heat extractants, neutron reflectors, reactor construction materials, controls, and radiation shields which must have unique nuclear properties in addition to conventional engineering properties. This paper presents nuclear automotive propulsion devices in terms of technologies now available. The necessary radiation-shielding mass and weight requirements are presented for an ideal point-source nuclear-heat-power engine.

Gasoline-ethanol blends are being used or have been considered as a fuel for spark ignition engines. The motivation for using the blends varies in indifferent parts of the world and even in regions within a country. The increasing cost of gasoline, combined with regional tax incentives, is one of the reasons for increased interests in gasoline-ethanol blends in recent years in the U.S. Many vehicular engines are not designed to use a specific gasoline-ethanol blend. Rather, the engines have multi-blend capability, ranging from E0 to about E85. It is plausible that engine-out emissions will vary depending on the blend being used which may be further impacted by the level of EGR used with the blends. The present work was carried out to investigate engine out emissions when a vehicular spark-ignition engine was operated on E0 and E85 and different levels of EGR. A 4-cylinder, 2.5 liter, PFI engine was used in the experimental investigation.

Degreening is crucial in obtaining a stable catalyst prior to assessing its performance characteristics. This paper characterizes the light-off behavior and conversion efficiency of a Diesel Oxidation Catalyst (DOC) during the degreening process. A platinum DOC is degreened for 16 hours in the presence of actual diesel engine exhaust at 650°C and 10% water (H2O) concentration. The DOC's activity for carbon monoxide (CO) and for total hydrocarbons (THC) conversion is checked at 0, 1, 2, 3, 4, 6, 8, 10, 12, and 16 hours of degreening. Pre-and post-catalyst hydrocarbon species are analyzed via gas chromatography at 0, 4, 8, and 16 hours of degreening. It is found that both light-off temperature and species-resolved conversion efficiencies change rapidly during the first 8 hours of degreening and then stabilize to a large degree. T50, the temperature where the catalyst is 50% active towards a particular species, increases by 14°C for CO and by 11°C for THC through the degreening process.

A study was conducted to investigate combustion variability and exhaust emissions from high-speed, natural gas fueled engines. Two types of fuel systems were used in the investigation: a mixer and a port fuel injection. The overall engine performances were not much different at stoichiometric fuel-air ratio. But as the equivalence ratio was reduced the engine with the mixer produced higher levels of hydrocarbons and larger coefficient of variations in imep. The same engine exhibited longer flame development angle and rapid burn duration in comparison to the fuel injected engine. The differences in burn durations increased as the equivalence ratio decreased and the mixer system produced larger variations in their values at these operating points. The investigation showed the performance of the engine was better with natural gas injection system than with the mixer, particularly at lean equivalence ratios.

Combined direct and port fuel injection (i.e., dual injection) in spark ignition engines is of increasing interest due to the advantages for fuel flexibility and the individual merits of each system for improving engine performance and reducing engine-out emissions. Greater understanding of the impact of dual injection will enable deriving the maximum benefit from the two injection systems. This study investigates the effects of dual injection on combustion, especially knock propensity and tolerance to exhaust gas recirculation (EGR) dilution at different levels of EGR. A baseline for comparison with dual injection results was made using direct injection fueling only. A splash blended E20 fuel was used for the direct injection only tests. For the dual injection tests, gasoline, representing 80% by volume of the total fuel, was injected using the direct injector, and ethanol, representing 20% by volume of the total fuel, was injected using the port fuel injector.

With increasing use of biofuels in the automotive industry, it has become necessary to evaluate their effects on the properties of polymers used in the fuel delivery systems. In this study, we have considered the effect of biodiesel on the tensile properties of nylon-6, 30% E-glass fiber reinforced nylon-6 and impact-modified nylon-6. The tensile specimens were immersed in 100% biodiesel for up to 7 days before determining their tensile properties. Another set of specimens were immersed in 100% biodiesel under stressed condition and then their tensile properties were determined. The absorption of biodiesel and their effects on tensile modulus, tensile strength and failure strain are reported in this paper.

Numerous studies have demonstrated the benefits of ethanol in increasing the thermal efficiency of gasoline-fueled spark ignition engines via the higher enthalpy of vaporization and higher knock resistance of ethanol compared with gasoline. This study expands on previous work by considering a split fuel injection strategy with a boosted direct injection spark ignition engine fueled with E0 (100% by volume reference grade gasoline; with research octane number = 91 and motor octane number = 83), E100 (100% by volume anhydrous ethanol), and various splash-blends of the two fuels. Experiments were performed using a production 3-cylinder Ford Ecoboost engine where two cylinders were de-activated to create a single-cylinder engine with a displacement of 0.33 L. The engine was operated over a range of loads with boosted intake manifold absolute pressure (MAP) from 1 bar to 1.5 bar.

An experimental study was undertaken to investigate emissions of hydrocarbons, oxides of nitrogen, carbon monoxide, and methane hydrocarbons emitted by natural gas fueled engines and the extent of their conversion in catalysts. Two engines were used in the study: a four cylinder, 1.6 liter, spark ignition engine and a modified version of the same engine with only one of the cylinders operating at 0.4 liter capacity. Two-way and three-way catalysts were used to treat exhaust gases leaving the engine. Natural gas was supplied through gas carburetors operated at regulated pressures and supplying air-fuel ratios in the desired range. The results of the investigation showed that oxides of nitrogen could not be reduced in a three-way catalyst to the levels found in gasoline fueled engines when the operating air-fuel ratio was stoichiometric.

A method for detection of ethanol content in fuel for an engine equipped with direct injection (DI) is presented. The methodology is based on in-cylinder pressure measurements during the compression stroke and exploits the different charge cooling properties of ethanol and gasoline. The concept was validated using dynamometer data of a 2.0L DI turbocharged engine with variable valve timing (VVT). An algorithm was developed to process the experimental data and generate a residue from the complex cycle-to-cycle in-cylinder pressure evolution which captures the charge cooling effect. The experimental results show that there is a monotonic correlation between the residues and the fuel ethanol percentage in the majority of the cases. However, the correlation varies for different engine operating parameters; such as, speed, load, valve timing, fuel rail pressure, intake and exhaust temperature and pressure.

Natural gas quality, in terms of the volume fraction of higher hydrocarbons, strongly affects the auto-ignition characteristics of the air-fuel mixture, the engine performance and its controllability. The influence of natural gas composition on engine operation has been investigated both experimentally and through chemical kinetic based cycle simulation. A range of two component gas mixtures has been tested with methane as the base fuel. The equivalence ratio (0.3), the compression ratio (19.8), and the engine speed (1000 rpm) were held constant in order to isolate the impact of fuel autoignition chemistry. For each fuel mixture, the start of combustion was phased near top dead center (TDC) and then the inlet mixture temperature was reduced. These experimental results have been utilized as a source of data for the validation of a chemical kinetic based full-cycle simulation.

The diesel engine with direct injection of hydrogen gas has clear advantages over the hydrogen engine with forced ignition of a hydrogen-air mixture. Despite of this, the concept of hydrogen-diesel engine has not investigated until now. In the paper, a detailed study of the working process of hydrogen-diesel engine carried out for the first time. Based on the results of the experimental studies and mathematical modeling, it has established that the behavior of thermo-physical processes in the combustion chamber of hydrogen-diesel engine, in a number of cases, differs fundamentally from the processes that take place in the conventional diesel engines. There have been identified the reasons for their difference and determined the values of the operating cycle parameters of hydrogen diesel engine, which provide the optimal correlation between the indicator values and the environmental performance.

A study and analysis of the relation of biodiesel chemical structures to the resulting soot characteristics and soot oxidative reactivity is presented. Soot samples generated from combustion of various methyl esters, alkanes, biodiesel and diesel fuels in laminar co-flow diffusion flames are analyzed to evaluate the impact of fuel-bound oxygen in fatty acid esters on soot oxidation behavior. Thermogravimetric analysis (TGA) of soot samples collected from diffusion flames show that chemical variations in biodiesel ester compounds have an impact on soot oxidative reactivity and soot characteristics in contrast to findings reported previously in the literature. Soot derived from methyl esters with shorter alkyl chains, such as methyl butyrate and methyl hexanoate, exhibit higher reactivity than those with longer carbon chain lengths, such as methyl oleate, which are more representative of biodiesel fuels.

In this study, the performance and emissions of a 4 cylinder 2.5L light-duty diesel engine with methane fumigation in the intake air manifold is studied to simulate a dual fuel conversion kit. Because the engine control unit is optimized to work with only the diesel injection into the cylinder, the addition of methane to the intake disrupts this optimization. The energy from the diesel fuel is replaced with that from the methane by holding the engine load and speed constant as methane is added to the intake air. The pilot injection is fixed and the main injection is varied in increments over 12 crank angle degrees at these conditions to determine the timing that reduces each of the emissions while maintaining combustion performance as measured by the brake thermal efficiency. It is shown that with higher substitution the unburned hydrocarbon (UHC) emissions can increase by up to twenty times. The NOx emissions decrease for all engine conditions, up to 53%.

A single-cylinder Direct Injection Spark Ignition (DISI) engine with optical access was used to investigate the effects of ethanol/gasoline blends on in-cylinder formation of particulate matter (PM) and fuel spray characteristics. Indolene was used as a baseline fuel and two blends of 50% and 85% ethanol (by volume, balance indolene) were investigated. Time resolved thermal radiation (incandescence/natural luminosity) of soot particles and fuel spray characteristics were recorded using a high speed camera. The images were analyzed to quantify soot formation in units of relative image intensity as a function of important engine operating conditions, including ethanol concentration in the fuel, fuel injection timing (250, 300 and 320° bTDC), and coolant temperature (25°C and 90°C). Spatially-integrated incandescence was used as a metric to quantify the level of in-cylinder PM formed at the different operating conditions.

Natural gas (NG) is attractive for heavy-duty (HD) engines for reasons of cost stability, emissions, and fuel security. NG cannot be reliably compression-ignited, but conventional gasoline ignition systems are not optimized for NG and are challenged to ignite mixtures that are lean or diluted with exhaust-gas recirculation (EGR). NG ignition is particularly challenging in large-bore engines, where completing combustion in the available time is more difficult. Using two high-speed infrared (IR) cameras with borescopic access to one cylinder of an HD NG engine, the effect of ignition system on the early flame-kernel development and cycle-to-cycle variability (CCV) was investigated. Imaging in the IR yielded strong signals from water emission lines, which located the flame front and burned-gas regions and obviated image intensifiers. A 9.7-liter, six-cylinder engine was modified to enable exhaust-gas recirculation and to provide optical access.

An experimental study was undertaken to study exhaust emission from a lean-burn natural gas spark ignition engine. The possibility that such an engine may help to reduce exhaust emissions substantially by taking advantage of natural gas fuel properties, such as its antiknock properties and extended lean flammability limit compared to gasoline, was the main motivation behind the investigation. A four cylinder, automotive type spark ignition engine was used in the investigation. The engine was converted to operate on natural gas by replacing its fuel system with a gaseous carburetion system. A 3-way metal metrix catalytic converter was used in the engine exhaust system to reduce emission levels. The engine operated satisfactorily at an equivalence ratio as lean as 0.6, at all speeds and loads. As a result NOx emissions were significantly reduced. However, hydrocarbon emissions were high, particularly at very lean conditions and light loads.

The effect of natural gas composition on ignition delay has been investigated numerically by using detailed and reduced chemical kinetic mechanisms. Three different blends of natural gas have been analyzed at pressures and temperatures that are typical of top dead center conditions in compression ignition engines. The predicted ignition delay shows a decrease with temperature in an Arrhenius manner and has a first order dependence on pressure. Similar trends have been observed by Naber et al. [1] in their experimental study of natural gas autoignition in a bomb. It is shown that two kinetic mechanisms (GRI-Mech 1.2 and reduced set DRM22) are best capable of predicting the ignition delay of natural gas under compression ignition conditions. The DRM22 mechanism has been chosen for further studies as t involves lower computational costs compared to the full GRI-Mech 1.2 mechanism.