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Pursuing a sustainable energy scenario for transportation requires the blending of renewable oxygenated fuels such as alcohols into commercial hydrocarbon fuels. From a chemical kinetic perspective, this requires the accurate description of both hydrocarbon reference fuels (n-heptane, iso-octane, toluene, etc.) and oxygenated fuels chemistry. A recent systematic investigation of linear C2-C5 alcohols ignition in a rapid compression machine at p = 10-30 bar and T = 650- 900 K has extended the scarcity of fundamental data at such conditions, allowing for a revision of the low temperature chemistry for alcohol fuels in the POLIMI mechanism. Heavier alcohols such as n-butanol and n-pentanol present ignition characteristic of interest for application in HCCI engines, due to the presence of the hydroxyl moiety reducing their low temperature reactivity compared to the parent linear alkanes (i.e. higher octane number).

In this paper the low temperature reduction process of nitrates stored at high temperatures over model Pt-Ba/Al2O3 LNT catalysts using both H2 and C3H6 is analyzed. The results indicate that over the Pt-Ba/Al2O3 catalyst the reduction of stored NOx with both H2 and C3H6 occurs at temperature below those corresponding to their thermal stability. Accordingly, the reduction process occurs through a Pt-catalyzed surface reaction, which does not involve, as a preliminary step, the thermal decomposition of the adsorbed NOx species. The occurrence of such a pathway also requires the co-presence of the storage element and of the noble metal on the same support.

The accurate prediction of pollutant emissions generated by IC engines is a key aspect to guarantee the respect of the emission regulation legislation. This paper describes the approach followed by the authors to achieve a strict numerical coupling of two different 1D modeling tools in a co-simulation environment, aiming at a reliable calculation of engine-out and tailpipe emissions. The main idea is to allow an accurate 1D simulation of the unsteady flows and wave motion inside the intake and exhaust systems, without resorting to an over-simplified geometrical discretization, and to rely on advanced thermodynamic combustion models and kinetic sub-models for the calculation of cylinder-out emissions. A specific fluid dynamic approach is then used to track the chemical composition along the exhaust duct-system, in order to evaluate the conversion efficiency of after-treatment devices, such as TWC, GPF, DPF, DOC, SCR and so on.

Nowadays numerical simulations play a major role in the development of future sustainable powertrain thanks to their capability of investigating a wide spectrum of innovative technologies with times and costs significantly lower than a campaign of experimental tests. In such a framework, this paper aims to assess the predictive capabilities of an 1D-CFD engine model developed to support the design and the calibration of the innovative highly efficient spark ignition engine of the PHOENICE (PHev towards zerO EmissioNs & ultimate ICE efficiency) EU H2020 project. As a matter of fact, the availability of a reliable simulation platform is crucial to achieve the project target of 47% peak indicating efficiency, by synergistically exploiting the combination of innovative in-cylinder charge motion, Miller cycle with high compression ratio, lean mixture with cooled Exhaust Gas Recirculation (EGR) and electrified turbocharger.

The aim of this work is to propose modifications to the managing of the 1st generation Common Rail injectors in order to reduce actuation time towards multiple injection strategies. The current Common Rail injector driven by 1st ECU generation is capable of operating under stable conditions with a minimum dwell between two consecutive injections of 1.8 ms. This limits the possibility in using proper and efficient injection strategies for emission control purposes. A previous numerical study, performed by the electro-fluid-mechanical model built up by Matlab-Simulink environment, highlighted different area where injector may be improved with particular emphasis on electronic driving circuit and components design. Experiments carried out at injector Bosch test-bench showed that a proper control of the solenoid valve allowed reducing drastically the standard deviation during the pilot pulses.

Increasing demands on the capabilities of engine simulation and the ability to accurately predict both performance and acoustics has lead to the development of several numerical tools to help engine manufacturers during the prototyping stage. The aid of CFD tools (3D and 1D) can remarkably reduce the duration and the costs of this stage. The need of achieving good accuracy, along with acceptable computational runtime, has given the spur to the development of a geometry based quasi-3D approach. This is designed to model the acoustics and the fluid dynamics of both intake and exhaust system components used in internal combustion engines. Models of components are built using a network of quasi-3D cells based primarily on the geometry of the system. The solution procedure is based on an explicitly time marching staggered grid approach making use of a flux limiter to prevent numerical instabilities.

The tightening trend of regulations on the levels of admitted pollutant emissions has given a great spur to the research work in the field of combustion and after-treatment devices. Despite the improvements that can be applied to the development of the combustion process, pollutant emissions cannot be reduced to zero; for this reason, the aftertreatment system will become a key component in the path to achieving near-zero emission levels. This study focuses on the numerical analysis and optimization of different metallic substrates, specifically developed for three-way catalyst (TWC) and Diesel oxidation catalyst (DOC) applications, to improve their thermal efficiency by reducing radial thermal losses through the outer mantle. The optimization process relies on computational fluid dynamics (CFD) simulations supported by experimental measurements to validate the numerical models carried out under uncoated conditions, where chemical reactions do not occur.

Multiple injections and high EGR rates are now widely adopted for combustion and emissions control in passenger car diesel engines. In a wide range of operating conditions, fuel is provided through one to five separated injection events, and recirculated gas fractions between 0 to 30% are used. Within this context, fast and reliable multi-dimensional models are necessary to define suitable injection strategies for different operating points and reduce both the costs and time required for engine design and development. In this work, the authors have applied a modified version of the characteristic time-scale combustion model (CTC) to predict combustion and pollutant emissions in diesel engines using advanced injection strategies. The Shell auto-ignition model is used to predict auto-ignition, with a suitable set of coefficients that were tuned for diesel fuel.

Combustion phasing is crucial to achieve high performance and efficiency: for gasoline engines control variables such as Spark Advance (SA), Air-to-Fuel Ratio (AFR), Variable Valve Timing (VVT), Exhaust Gas Recirculation (EGR), Tumble Flaps (TF) can influence the way heat is released. The optimal control setting can be chosen taking into account performance indicators, such as Indicated Mean Effective Pressure (IMEP), Brake Specific Fuel Consumption (BSFC), pollutant emissions, or other indexes inherent to reliability issues, such as exhaust gas temperature, or knock intensity. Given the high number of actuations, the calibration of control parameters is becoming challenging.

The reduction of the catalyst light-off time at the engine cold start represents a key factor for the pollutant emissions control from vehicles tested on homologation cycles and real drive conditions. The adoption of heating strategies to increase the temperature of the catalytic substrate in the early phase of the engine start is regarded as a promising solution. The present study focuses on the application of electrical heated catalyst (EHC) in an after-treatment line for a spark-ignition gasoline engine. The analysis is carried out by means of an advanced CFD framework, which includes the modeling of catalytic reactions in the substrates and accounts for the thermal evolution of all the components included in the after-treatment system.

In the last years, as a response to the more and more restrictive emission legislation, new devices (SRC, DOC, NOx-trap, DPF) have been progressively introduced as standard components of modern after-treatment system for Diesel engines. In addition, the adoption of electrical heating is nowadays regarded with interest as an effective solution to promote the light-off of the catalyst at low temperature, especially at the start-up of the engine and during the low load operation of the engine typical of the urban drive. In this work, a state-of-the-art 48 V electrical heated catalyst is considered, in order to investigate its effect in increasing the abatement efficiency of a standard DOC. The electrical heating device considered is based on a metallic support, arranged in a spiral layout, and it is heated by the Joule effect due to the passage of the electrical current.

Predictive combustion models are useful tools towards the development of clean and efficient engines operating with alternative fuels. This work intends to validate two different combustion models on compression-ignition engines fueled with Dimethyl Ether. Both approaches give a detailed characterization of the combustion kinetics, but they substantially differ in how the interaction between fluid-dynamics and chemistry is treated. The first one is single-flamelet Representative Interactive Flamelet, which considers turbulence-kinetic interaction but cannot correctly describe the stabilization of the flame. The second, named Tabulated Well Mixed, correctly accounts for local flow and mixture conditions but does not consider interaction between turbulence and chemistry. An experimental campaign was carried out on a heavy-duty truck engine running on DME at a constant load considering trade-off of EGR and SOI.

NH₃/urea SCR is a very effective and widely used technology for the abatement of NOx from diesel exhaust. The SCR mechanism is well understood and the catalyst behavior can be predicted by mathematical models - as long as operation above the temperature limit for AdBlue® injection is considered. The behavior below this level is less understood. During the first seconds up to minutes after cold start, complete NOx abatement can be observed over an SCR catalyst in test bench experiments, together with a significant increase in temperature after the converter (ca. 100 K). In this work these effects have been investigated over a monolith Cu-zeolite SCR catalyst. Concentration step experiments varying NO, NO₂ and H₂O have been carried out in lab scale, starting from room temperature. Further, the interaction of C₃H₆ and CO with NOx over the SCR has been investigated.

This work focuses on the development and validation of a data-driven model capable of predicting the maximum in-cylinder pressure during the operation of an internal combustion engine, with the least possible computational effort. The model is based on two parameters, one that represents engine load and another one the combustion phase. Experimental data from four different gasoline engines, two turbocharged Gasoline Direct Injection Spark Ignition, a Naturally Aspirated SI and a Gasoline Compression Ignition engine, was used to calibrate and validate the model. Some of these engines were equipped with technologies such as Low-Pressure Exhaust Gas Recirculation and Water Injection or a compression ignition type of combustion in the case of the GCI engine. A vast amount of engine points were explored in order to cover as much as possible of the operating range when considering automotive applications and thus confirming the broad validity of the model.

The role of numerical simulations in the development of innovative and sustainable powertrains is constantly growing thanks to their capabilities to significantly reduce the calibration efforts and to point out potential synergies among different technologies. In such a framework, this paper describes the development of a fully physical 1D-CFD engine model to support the calibration of the highly efficient spark ignition engine of the PHOENICE (PHev towards zerO EmissioNs & ultimate ICE efficiency) EU H2020 project. The availability of a reliable simulation platform is essential to effectively exploit the combination of the several features introduced to achieve the project target of 47% peak gross indicated efficiency, such as SwumbleTM in-cylinder charge motion, Miller cycle combined with high Compression Ratio (CR), lean mixture exploiting cooled low pressure Exhaust Gas Recirculation (EGR) and electrified turbocharging.

Especially in view of more and more stringent emission legislation in passenger cars it is required to reduce the amount of pollutants. In the case of Diesel engines mainly NOx and PM are emitted during engine operation. The main influence factors for these pollutants are the in-cylinder oxygen concentration and the injected fuel amount. Typically the engine control task can be divided into two separate main parts, the fuel and the air system. Commonly air system control, consisting of a turbocharger and exhaust gas recirculation control, is used to provide the required amount of oxygen and address the emission targets, whereas the fuel is used to provide the desired torque. Especially in transient maneuvers the different time scales of both systems can lead to emission peaks which are not desired. Against this background in this work instead of the common way to address the air system, the fuel system is considered to reduce emission peaks during transients.

The modern spark ignition engines, due to the introduced strategies for limiting the consumption without reducing the power, are sensitive to both the detonation and the increase of the inlet turbine temperature. In order to reduce the risk of detonation, the use of dilution with the products of combustion (EGR) is an established practice that has recently improved with the use of water vapor obtained via direct or indirect injection. The application and optimization of these strategies cannot ignore the knowledge of physical quantities characterizing the combustion such as the laminar flame speed and the ignition delay, both are intrinsic property of the fuel and are function of the mixture composition (mixture fraction and dilution) and of its thermodynamic conditions. The experimental measurements of the laminar flame speed and the ignition delay available in literature, rarely report the effects of dilution by EGR or water vapor.

This work focuses on the effects of cooled Low Pressure EGR and Water Injection observed by conducting experimental tests consisting mainly of Spark Advance sweeps at different cooled LP-EGR and WI rates. The implications on combustion and main engine performance indexes are then analysed and modelled with a control-oriented approach, showing that combustion duration and phase and exhaust gas temperature are the main affected parameters. Results show that cooled LP-EGR and WI have similar effects, being the associated combustion speed decrease the main cause of exhaust gas temperature reduction. Experimental data is used to identify control-oriented polynomial models able to capture the effects of LP-EGR and WI on both these aspects. The limitations of LP-EGR are also explored, identifying maximum compressor volumetric flow and combustion stability as the main ones.

In this paper an integrated experimental and numerical approach is applied to optimize a new 2.5l, four valve, turbocharged DI Diesel engine, developed by VM Motori. The study is focused on the EGR system. For this engine, the traditional dynamometer bench tests provided 3-D maps for brake specific fuel consumption and emissions as a function of engine speed and brake mean effective pressure. Particularly, a set of operating conditions has been considered which, according to the present European legislation, are fundamental for emissions. For these conditions, the influence of the amount of EGR has been experimentally evaluated. A computational model for the engine cycle simulation at full load has been built by using the WAVE code. The model has been set up against experiments, since an excellent agreement has been reached for all the relevant thermo-fluid-dynamic parameters. The simulation model has been used to gain a better insight on the EGR system operations.

Fuel lean combustion and exhaust gas dilution are known to increase the thermal efficiency and reduce NOx emissions. In this study, experiments are performed to understand the effect of equivalence ratio on flame kernel formation and flame propagation around the spark plug for different low turbulent velocities. A series of experiments are carried out for propane-air mixtures to simulate engine-like conditions. For these experiments, equivalence ratios of 0.7 and 0.9 are tested with 20 percent mass-based exhaust gas recirculation (EGR). Turbulence is generated by a shrouded fan design in the vicinity of J-spark plug. A closed loop feedback control system is used for the fan to generate a consistent flow field. The flow profile is characterized by using Particle Image Velocimetry (PIV) technique. High-speed Schlieren visualization is used for the spark formation and flame propagation.