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High-efficiency, clean-combustion strategies for heavy-duty diesel engines are critical for meeting stringent emissions regulations and reducing the costs of aftertreatment systems that are currently required to meet these regulations. Results from previous constant-volume combustion-vessel experiments using a single jet of fuel under quiescent conditions have shown that mixing-controlled soot-free combustion (i.e., combustion where soot is not produced) is possible with #2 diesel fuel. These experiments employed small injector-orifice diameters (≺ 150 μm) and high fuel-injection pressures (≻ 200 MPa) at top-dead-center (TDC) temperatures and densities that could be achievable in modern heavy-duty diesel engines.

It is generally accepted that emissions of nitrogen oxides (NOx) increase as the volume fraction of bio diesel increases in blends with conventional diesel fuel. While many mechanisms based on bio diesel effects on in-cylinder processes have been proposed to explain this observation, a clear understanding of the relative importance of each has remained elusive. To gain further insight into the cause(s) of the bio diesel NOx increase, experiments were conducted in a single-cylinder version of a heavy-duty diesel engine with extensive optical access to the combustion chamber. The engine was operated using two bio diesel fuels and two hydrocarbon reference fuels, over a wide range of loads, and using undiluted air as well as air diluted with simulated exhaust gas recirculation.

Natural luminosity (NL) and chemiluminescence (CL) imaging diagnostics are employed to investigate fuel-property effects on mixing-controlled combustion, using select research fuels-a #2 ultra-low sulfur emissions-certification diesel fuel (CF) and four of the Fuels for Advanced Combustion Engines (FACE) diesel fuels (F1, F2, F6, and F8)-that varied in cetane number (CN), distillation characteristics, and aromatic content. The experiments were performed in a single-cylinder heavy-duty optical compression-ignition (CI) engine at two injection pressures, three dilution levels, and constant start-of-combustion timing. If the experimental results are analyzed only in the context of the FACE fuel design parameters, CN had the largest effect on emissions and efficiency.

Experiments conducted with a set of reference diesel fuels in an optically accessible, compression-ignition engine have revealed a strong correlation between hydrocarbon (HC) emissions and the flame lift-off length at the end of the premixed burn (EOPMB), with increasing HC emissions associated with longer lift-off lengths. The correlation is largely independent of fuel properties and charge-gas O2 mole fraction, but varies with fuel-injection pressure. A transient, one-dimensional jet model was used to investigate three separate mechanisms that could explain the observed impact of lift-off length on HC emissions. Each mechanism relies on the formation of mixtures that are too lean to support combustion, or “overlean.” First, overlean regions can be formed after the start of fuel injection but before the end of the premixed burn.

Computational fluid dynamic (CFD) simulations that include realistic combustion/emissions chemistry hold the promise of significantly shortening the development time for advanced high-efficiency, low-emission engines. However, significant challenges must be overcome to realize this potential. This paper discusses these challenges in the context of diesel combustion and outlines a technical program based on the use of surrogate fuels that sufficiently emulate the chemical complexity inherent in conventional diesel fuel.

Low-temperature combustion of diesel fuel was studied in a heavy-duty, single-cylinder, optical engine employing a 15-hole, dual-row, narrow-included-angle nozzle (10 holes × 70° and 5 holes × 35°) with 103-μm-diameter orifices. This nozzle configuration provided the spray targeting necessary to contain the direct-injected diesel fuel within the piston bowl for injection timings as early as 70° before top dead center. Spray-visualization movies, acquired using a high-speed camera, show that impingement of liquid fuel on the piston surface can result when the in-cylinder temperature and density at the time of injection are sufficiently low. Seven single- and two-parameter sweeps around a 4.82-bar gross indicated mean effective pressure load point were performed to map the sensitivity of the combustion and emissions to variations in injection timing, injection pressure, equivalence ratio, simulated exhaust-gas recirculation, intake temperature, intake boost pressure, and load.

The in-cylinder extent of liquid-phase fuel penetration (i.e., the liquid length) is an important parameter in combustion-chamber design because liquid lengths that are too long can lead to wall impingement and corresponding degradation of engine efficiency, emissions, and durability. Previous liquid-length measurements in constant-volume combustion chambers have shown that the liquid length is nominally independent of injection pressure, but these measurements have employed common-rail fuel systems where injection rate is approximately constant during the entire injection event, and they have been conducted under quasi-steady ambient thermodynamic conditions. The objective of the current work is to better understand the effects of injection-rate shape and injection pressure on the liquid length, including possible effects of unsteady ambient conditions in an engine.

The detailed mechanisms by which oxygenated diesel fuels reduce engine-out soot emissions are not well understood. The literature contains conflicting results as to whether a fuel's overall oxygen content is the only important parameter in determining its soot-reduction potential, or if oxygenate molecular structure or other variables also play significant roles. To begin to resolve this controversy, experiments were conducted at a 1200-rpm, moderate-load operating condition using a modern-technology, 4-stroke, heavy-duty DI diesel engine with optical access. Images of broadband natural luminosity (i.e., light emission without spectral filtering) from the combustion chamber, coupled with heat-release and efficiency analyses, are presented for three test-fuels. One test-fuel (denoted GE80) was oxygenated with tri-propylene glycol methyl ether; the second (denoted BM88) was oxygenated with di-butyl maleate. The overall oxygen contents of these two fuels were matched at 26% by weight.

An experimental study of the glow-plug-assisted ignition and combustion of pure methanol (M100) was conducted using a modern-technology, 4-stroke, heavy-duty DI diesel engine that has been modified to provide extensive optical access into the combustion chamber. For comparison purposes, results also are presented for a two-component paraffinic diesel reference fuel with a cetane number of 45 (CN45). A 1200-rpm, moderate-load operating condition was studied. Images of direct luminosity from the combustion chamber are used along with thermodynamic analyses of cylinder pressure data to identify differences between the ignition and combustion characteristics of the two fuels. The M100 data show significant departures from the traditional diesel combustion features exhibited by CN45. Whereas CN45 readily autoignites at the conditions studied, M100 does not. The glow-plug-assisted ignition of M100 was found to be strongly dependent on glow plug (GP) temperature and proximity to a fuel jet.

The relationship between combustion processes and engine-out soot was investigated in an optically accessible DI diesel engine using diethylene glycol diethyl ether (DGE) fuel, a viable diesel oxygenate. The high oxygen content of DGE enables operation without soot emissions at higher loads than with a hydrocarbon fuel. The high cetane number of DGE enables operation at charge-gas temperatures below those required for current diesel fuels, which may be advantageous for reducing NOx emissions. In-cylinder optical measurements of flame lift-off length and natural luminosity were obtained simultaneously with engine-out soot measurements while varying charge-gas density and temperature. The local mixture stoichiometry at the lift-off length was characterized by a parameter called the oxygen ratio that was estimated from the measured flame lift-off length using an entrainment correlation for non-reacting sprays.

The addition of oxygenates to diesel fuel can reduce particulate emissions, but the underlying chemical pathways for the reductions are not understood. While measurements of particulate matter (PM), unburned hydrocarbons (HC), and carbon monoxide (CO) are routine, determining the contribution of carbon atoms in the original fuel molecules to the formation of these undesired exhaust emissions has proven difficult. Using accelerator mass spectrometry (AMS) diagnostics, carbon atoms in a specific bond position in a specific fuel molecule can be labeled with carbon-14 (14C) and traced through the combustion event to determine whether they reside in PM, HC, CO, CO2, or other emission products. This knowledge of how specific molecular structures produce certain emissions can be used to refine chemical-kinetic combustion models and to optimize fuel composition to reduce undesired emissions.

The maximum extent of liquid-phase fuel penetration into in-cylinder gases is an important parameter in compression-ignition (CI) engine design. Penetration of the fuel is needed to promote fuel-air mixing, but over-penetration of the liquid phase and impingement on the bowl wall can lead to higher emissions. This maximum liquid-phase fuel penetration, or “liquid length,” is a function of fuel properties, in-cylinder conditions, and injection characteristics. The goal of this study was to measure and correlate the liquid lengths of fuels with wide physical property variations. The fuels were injected into a large range of in-cylinder temperature (700 to 1300 K) and density (3.6 to 59.0 kg/m3) conditions, at an injection pressure (140 MPa) that is characteristic of those provided by current high-pressure injection equipment.

This study summarizes the peer-reviewed literature regarding the use of raw pyrolysis liquids (PLs) created from woody biomass as fuels for compression-ignition (CI) engines. First, a brief overview is presented of fast pyrolysis and the potential advantages of PLs as fuels for CI engines. Second, a discussion of the general composition and properties of PLs relative to conventional, petroleum-derived diesel fuels is provided, with emphasis on the differences that are most likely to affect PL performance in CI-engine applications. Next, a synopsis is given of the peer-reviewed literature describing experimental studies of CI engines operated using neat PLs and PLs combined in various ways with other fuels. This literature conclusively indicates that raw PLs and PL blends cannot be used as “drop-in replacements” for diesel fuel in CI engines, which is reflected in part by none of the cited studies reporting successful operation on PL fuels for more than twelve consecutive hours.