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In internal combustion engines operating in Controlled Auto Ignition (CAI) mode, combustion phasing and heat-release rate is controlled by stratification of fuel, fresh air, and hot internally recirculated exhaust gases. Based on the Representative Interactive Flamelet (RIF) model, a two-dimensional flamelet approach is developed. As independent parameters, firstly the fuel mixture fraction and secondly the mixture fraction of internally recirculated exhaust gases are considered. The flamelet equations are derived from the transport equations for species mass fraction and total enthalpy, employing an asymptotic analysis. A subsequent coordinate transformation leads to the phase space formulation of the two-dimensional flamelet equations. By the use of detailed chemical reaction mechanisms, the effects of dilution, temperature, and chemical species composition due to the internally recirculated exhaust gases are represented.

A reduced kinetic reaction mechanism for the autoignition of dimethyl ether is presented in this paper. Dimethyl ether has proven to be one of the most attractive alternatives to traditional fossil fuels for compression ignition engines. It can either be produced from biomass or from fossil oil. For dimethyl ether, Fischer et al. (Int. J.Chem. Kinet. 32 ( 12 ) (2000) 713-740) proposed a detailed reaction mechanism consisting of 79 species and 351 elementary reactions. In the present work, this detailed mechanism is systematically reduced to 31 species and 49 reactions. The reduced mechanism is discussed in detail with special emphasis on the high temperature thermal decomposition of dimethyl ether and on the fuel specific depleting reactions, which produce the methoxymethyl radical. In addition, a reaction pathway analysis for low temperature combustion is applied, where hydroperoxy-methylformate is found to be the dominating parameter for the low temperature regime.

Gasoline Controlled Auto Ignition offers a high CO2 emission reduction potential, which is comparable to state-of-the-art, lean stratified operated gasoline engines. Contrary to the latter, GCAI low temperature combustion avoids NOX emissions, thereby trying to avoid extensive exhaust aftertreatment. The challenges remain in a restricted operation range due to combustion instabilities and a high sensitivity towards changing boundary conditions like ambient temperature, intake pressure or fuel properties. Once combustion shows instability, cyclic fluctuations are observed. These appear to have near-chaotic behavior but are characterized by a superposition of clearly deterministic and stochastic effects. Previous works show that the fluctuations can be predicted precisely when taking cycle-tocycle correlations into account. This work extends current approaches by focusing on additional dependencies within one single combustion cycle.

In this study the fuel influence of several bio-fuel candidates on homogeneous engine combustion systems with direct injection is investigated. The results reveal Ethanol and 2-Butanol as the two most knock-resistant fuels. Hence these two fuels enable the highest efficiency improvements versus RON95 fuel ranging from 3.6% - 12.7% for Ethanol as a result of a compression ratio increase of 5 units. Tetrahydro-2-methylfuran has a worse knock resistance and a decreased thermal efficiency due to the required reduction in compression ratio by 1.5 units. The enleanment capability is similar among all fuels thus they pose no improvements for homogeneous lean burn combustion systems despite a significant reduction in NOX emissions for the alcohol fuels as a consequence of lower combustion temperatures.

For gasoline engines controlled autoignition provides the vision of enabling the fuel consumption benefit of stratified lean combustion systems without the drawback of additional NOx aftertreatment. In this study the potential of certain biofuels on this combustion system was assessed by single-cylinder engine investigations using the exhaust strategy "combustion chamber recirculation" (CCR). For the engine testing sweeps in the internal EGR rate with different injection strategies as well as load sweeps were performed. Of particular interest was to reveal fuel differences in the achievable maximal load as well as in the NOx emission behavior. Additionally, experiments with a shock tube and a rapid compression machine were conducted in order to determine the ignition delay times of the tested biofuels concerning controlled autoignition-relevant conditions.

The influence of different fuels and injection pressures on the flame lift-off length (LOL), as well as the combustion structure under quiescent conditions in a heated high-pressure vessel were experimentally investigated using OH chemiluminescence measurements. This data was used to validate the newly developed G-equation coupled with MRIF (G-MRIF) model, which was designed to describe the lifted Diesel combustion process. The achieved results are very promising and could be used as a tool to apply this combustion mode into Diesel engines. Furthermore these measurements were used to validate the approach of a new combustion model, which was developed using former OH chemiluminescence measurements by the authors. Based on this approach the LOL is mainly determined by auto-ignition and therefore highly dependent on the cetane number. This model is presented in more detail within this work.

Due to their CO2 reduction potential and their high knock resistance gaseous fuels present a promising alternative for modern highly boosted spark ignition engines. Especially the direct injection of LPG reveals significant advantages. Previous studies have already shown the highest thermodynamic potential for the LPG direct injection concept and its advantages in comparison to external mixture formation systems. In the performed research study a comparison of different LPG fuels in direct injection mode shows that LPG fuels have better auto-ignition behavior than gasoline. A correlation between auto-ignition behavior and the calculated motor octane number could not be found. However, a significantly higher correlation of R2 = 0.88 - 0.99 for CR13 could be seen when using the methane number. One major challenge in order to implement the LPG direct injection concept is to ensure the liquid state of the fuel under all engine operating conditions.

Gasoline engine powertrain development for 2025 and beyond is focusing on finding cost optimal solutions by balancing electrification and combustion engine efficiency measures. Besides Miller cycle application, cooled exhaust gas recirculation and variable compression ratio, the injection of water has recently gained increased attention as a promising technology for significant CO2 reduction. This paper gives deep insight into the fuel consumption reduction potential of direct water injection. Single cylinder investigations were performed in order to investigate the influence of water injection in the entire engine map. In addition, different engine configurations were tested to evaluate the influence of the altering compression ratios and Miller timings on the fuel consumption reduction potential with water injection.

In this article, the development challenges of a fuel cell system are explained using the example of the BREEZE! fuel cell range extender (FC-REX) applied in an FEV Liiona. The FEV Liiona is a battery electric vehicle based on a Fiat 500 developed by FEV. The BREEZE! system is the first applied 30 kW low temperature polymer electrolyte membrane (LT PEM) fuel cell system in the subcompact vehicle class. Due to the highly integrated system approach and dry cathode operation, a compact design of the range extender module with a system power density of 0.45 kW/l can be achieved so that the vehicle interior including trunk remains completely usable. System development for fuel cells significantly influences performance, efficiency, package, durability, and required maintenance effort of a fuel cell electric powertrain. In order to ensure safe and reliable operation, the fuel cell system has to be supplied with sufficient amounts of air, hydrogen, and coolant flows.

Hybrid and electric vehicles present a promising trade-off between the necessary reductions in emissions and fuel consumption, the improvement in driving pleasure and performance of today's and tomorrow's vehicles. These hybrid vehicles rely primarily on electronics for the control and the coordination of the different sub-systems or components. The number and complexity of the functions distributed over many control units is increasing in these vehicles. Functional safety, defined as absence of unacceptable risk due to the hazards caused by mal-function in the electric or electronic systems is becoming a key factor in the development of modern vehicles such as electric and hybrid vehicles. This important increase in functional safety-related issues has raised the need for the automotive industry to develop its own functional safety standard, ISO 26262.

Liquefied Petroleum Gas direct injection (LPG DI) is believed to be the key enabler for the adaption of modern downsized gasoline engines to the usage of LPG, since LPG DI avoids the significant low end torque drop, which goes along with the application of conventional LPG port fuel injection systems to downsized gasoline DI engines, and provides higher combustion efficiencies. However, especially the high vapor pressure of C3 hydrocarbons can result in hot fuel handling issues as evaporation or even in reaching the supercritical state of LPG upstream or inside the high pressure pump (HPP). This is particularly critical under hot soak conditions. As a result of a rapid fuel density drop close to the supercritical point, the HPP is not able to keep the rail pressure constant and the engine stalls.

So far, the effect of injection rate shaping on the diesel combustion in small-bore DI diesel engines has not been extensively investigated, especially at high part load conditions with high EGR rates. The benefit of injection rate shaping is already verified for heavy duty engines at high load conditions with and without EGR. For this investigation, single cylinder engine investigations were conducted at the VKA / RWTH Aachen University. In order to meet the future NOx legislation limits like US-Tier2Bin5 it is crucial to reduce NOx especially at the high load points of the certification cycles, as FTP75 or US06. For the single cylinder investigations two part load points were chosen, which have relevance for the mentioned certification cycles. The experimental work focuses on different rate shapes as rectangular (Common-Rail type), ramp and boot shape at high EGR rates.

The purpose of this study is to investigate the effect of spray-bowl interaction on combustion, and pollutants formation at one specific high-load point of a single-cylinder small-bore diesel engine through computational analysis. The simulations are performed using Representative Interactive Flamelet (RIF) model with detailed chemical kinetics. Detailed chemistry-based soot model is used for the prediction of soot emissions. The simulations are performed for five different injection timings. Model-predicted cylinder pressure and exhaust emissions are validated against the measured data for all the injection timings. A new method - Two-part analysis - is then applied to investigate the spray-bowl interaction. Two-part analysis splits the volume of the combustion chamber into two, namely the piston bowl and the squish volume. Through analysis, among others the histories of soot, carbon monoxide (CO) and nitric oxide (NO ) emissions inside both volumes are shown.

To understand how laminar burning velocities of standard unleaded gasoline-air-mixtures change by varying the concentration of oxygen in the combustible mixture, experimentally and numerical investigations are conducted in this work. Experiments were performed using a heatable pressure vessel which enables optical access. A monochromatic high-speed Schlieren cinematography measurement system combined with a high-speed CCD camera were used to track the propagating spherical flame fronts in the vessel. Numerically, freely propagating one dimensional laminar steady flame calculations were conducted for Primary-Reference-Fuel Air Mixtures (PRF87 or RON87), corresponding for standard gasoline combustible mixtures. Two combustible mixtures were investigated: (1) with air as oxidizer; (2) oxidizer consisting of 15% O2 and 85% N2 by mole fractions. The initial temperature for all investigated mixtures was 373 K.

In this work very rich premixed laminar spherical flame kernels of hydrocarbon-air combustible mixtures were experimentally and numerically investigated under microgravity conditions. These microgravity combustion experiments were carried out in the Drop Tower of Bremen University. The Closed-Vessel-Bomb-Method (CVBM) was applied for all experimental investigations combined with a monochromatic Helium-Neon-Schlieren Measurement Technique. Images of the propagating spherical flames were tracked with a High-Speed-Camera. The pressure vessel enables optical access and contains a volume of approx. half a litre. Combustible Mixtures were investigated at initial pressures up to 30 bar and initial temperatures were 420 K for all experiments, whereas the equivalence ratio for investigated N-Pentane-Air-Mixtures was Φ=3.0, N-Hexane-Air-Mixtures was Φ=3.3, N-Heptane-Air-Mixtures was Φ=3.5 and the equivalence ratio for investigated Isooctane-Air-Mixtures was Φ=3.9 for all experiments.

The influence of two oxygenated tailor-made fuels on soot formation and oxidation in an optical single cylinder research diesel engine has been studied. For the investigation a planar laser-induced incandescence (PLII) measurement technique was applied to the engine in order to detect and evaluate the planar soot distribution for the two bio fuels within a laser light sheet. Furthermore the OH* chemiluminescence and broad band soot luminosity was visualized by high speed imaging to compare the ignition and combustion behavior of tested fuels: Two C8 oxygenates, di-n-butylether (DNBE) and 1-octanol. Both fuels have the same molecular formula but differ in their molecular structure. DNBE ignites fast and burns mostly diffusive while 1-octanol has a low cetane number and therefore it has a longer ignition delay but a more homogeneous mixture at time of ignition. The two bio fuels were finally compared to conventional diesel fuel.

An experimental and numerical investigation of commercial Gasoline (octane number = 90) with a reference fuel (PRF87) were accomplished. Laminar Flame Velocities and Markstein Numbers of these fuel air mixtures were investigated and compared with each other and with numerical results. PRF87 is presented as a reference fuel for Gasoline defined as 87 percent Iso-Octane and 13 percent N-Heptane by volume at ambient conditions. Spherical flames of Gasoline- and PRF87-Air-Mixtures at initial temperature of 373 K, initial pressure range from 10 bar to 25 bar and equivalence ratios from ϕ = 0.7 to ϕ = 1.2 were experimentally investigated using the Constant Volume Bomb Method.

With increasing interest in new biofuel candidates, 1-octanol and di-n-butylether (DNBE) were presented in recent studies. Although these molecular species are isomers, their properties are substantially different. In contrast to DNBE, 1-octanol is almost a gasoline-type fuel in terms of its auto-ignition quality. Thus, there are problems associated with engine start-up for neat 1-octanol. In order to find a suitable glow-plug position, mixture formation is studied in the cylinder under almost idle operating conditions in the present work. This is conducted by planar laser-induced fluorescence in a high-speed direct-injection optical diesel engine. The investigated C8-oxygenates are also significantly different in terms of their evaporation characteristics. Thus, in-cylinder mixture formation of these two species is compared in this work, allowing conclusions on combustion behavior and exhaust emissions.

In this paper an online method for automatically reducing complex chemical mechanisms for simulations of combustion phenomena has been developed. The method is based on the Quasi Steady State Assumption (QSSA). In contrast to previous reduction schemes where chemical species are selected only when they are in steady state throughout the whole process, the present method allows for species to be selected at each operating point separately generating an adaptive chemical kinetics. The method is used for calculations of a natural gas fueled engine operating under Homogenous Charge Compression Ignition (HCCI) conditions. We discuss criteria for selecting steady state species and the influence of these criteria on the results such as concentration profiles and temperature.

Heat transfer to the combustion chamber walls constitutes a significant portion of the overall energy losses over the working cycle of a direct injection (DI) diesel engine. In the last few decades, numerous research efforts have been devoted to investigating the prospects of boosting efficiency by insulating the combustion chamber. Relatively few studies have focused on the prospects of reducing emissions by applying combustion chamber insulation. A main purpose of this study is to assess the potential of reducing in-cylinder soot as well as boosting aftertreatment performance by means of partially insulating the combustion chamber. Based on the findings from a conceptual study, a Low Heat Rejection (LHR) design, featuring a Nimonic 80A insert into an Aluminum piston, was developed and tested experimentally at various loads in a single-cylinder Hatz-engine.